WO2010035956A3 - 분리막 레저버를 이용하는 리튬 회수 장치, 이를 이용한 리튬 회수 방법, 및 이를 이용한 리튬 흡탈착 시스템 - Google Patents

분리막 레저버를 이용하는 리튬 회수 장치, 이를 이용한 리튬 회수 방법, 및 이를 이용한 리튬 흡탈착 시스템 Download PDF

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Publication number
WO2010035956A3
WO2010035956A3 PCT/KR2009/004541 KR2009004541W WO2010035956A3 WO 2010035956 A3 WO2010035956 A3 WO 2010035956A3 KR 2009004541 W KR2009004541 W KR 2009004541W WO 2010035956 A3 WO2010035956 A3 WO 2010035956A3
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WO
WIPO (PCT)
Prior art keywords
lithium
adsorption
seawater
separator reservoir
manganese oxide
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Application number
PCT/KR2009/004541
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English (en)
French (fr)
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WO2010035956A2 (ko
Inventor
정강섭
이재천
이환
Original Assignee
한국지질자원연구원
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Filing date
Publication date
Priority claimed from KR1020080095493A external-priority patent/KR101083256B1/ko
Application filed by 한국지질자원연구원 filed Critical 한국지질자원연구원
Priority to US13/121,558 priority Critical patent/US8741150B2/en
Priority to JP2011528917A priority patent/JP2012504190A/ja
Publication of WO2010035956A2 publication Critical patent/WO2010035956A2/ko
Publication of WO2010035956A3 publication Critical patent/WO2010035956A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C22B3/24—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00—Ion-exchange processes in general; Apparatus therefor
    • B01J47/10—Ion-exchange processes in general; Apparatus therefor with moving ion-exchange material; with ion-exchange material in suspension or in fluidised-bed form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J47/00—Ion-exchange processes in general; Apparatus therefor
    • B01J47/12—Ion-exchange processes in general; Apparatus therefor characterised by the use of ion-exchange material in the form of ribbons, filaments, fibres or sheets, e.g. membranes
    • B01J47/127—Ion-exchange processes in general; Apparatus therefor characterised by the use of ion-exchange material in the form of ribbons, filaments, fibres or sheets, e.g. membranes in the form of filaments or fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/53—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for cationic exchangers
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/02—Apparatus therefor
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Water Treatment By Sorption (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

본 발명은 고분자나 다른 유용한 재질의 막으로 이루어진 외벽 및 내부의 빈 공간을 포함하는 분리막 레저버와 상기 분리막 레저버 내부의 빈 공간에 포함된 리튬 흡착제인 망간 산화물을 포함하는 리튬 회수 장치, 이를 이용하여 리튬을 회수하는 방법, 및 리튬에 대하여 높은 선택성을 갖는 리튬 흡착제로서 이용될 수 있는 망간 산화물로 제조된 리튬 흡착제를 이용하여 해수 중에 용존된 리튬의 흡착 및 탈착에 의한 리튬 회수가 하나의 시스템 내에서 이루어질 수 있는 리튬 흡탈착 시스템에 관한 것이다. 본 발명은, 다공성 구조의 고분자나 다른 유용한 재질의 막으로 이루어진 외벽을 포함하는 분리막 레저버를 이용하므로 외부에서의 추가적인 압력이 없이도 용액, 특히 해수의 이동이 자유로워 해수에 직접 적용할 수 있으며, 내화학성 및 기계적 강도가 강한 고분자나 다른 유용한 재질의 재료를 이용하여 해수 및 산 수용액에서 우수한 안정성을 가져, 리튬의 회수를 필요로 하는 분야에 널리 이용될 수 있다.
PCT/KR2009/004541 2008-09-29 2009-08-13 분리막 레저버를 이용하는 리튬 회수 장치, 이를 이용한 리튬 회수 방법, 및 이를 이용한 리튬 흡탈착 시스템 WO2010035956A2 (ko)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US13/121,558 US8741150B2 (en) 2008-09-29 2009-08-13 Lithium recovery device using separator reservoir, lithium recovery method and lithium adsorption/desorption system using the same
JP2011528917A JP2012504190A (ja) 2008-09-29 2009-08-13 分離膜貯留層を用いるリチウム回収装置、これを用いるリチウム回収方法、及びこれを用いるリチウム吸脱着システム

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
KR10-2008-0095493 2008-09-29
KR1020080095493A KR101083256B1 (ko) 2008-09-29 2008-09-29 분리막 레저버를 이용하는 리튬 회수 장치
KR10-2008-0116204 2008-11-21
KR20080116204 2008-11-21
KR20080126534 2008-12-12
KR10-2008-0126534 2008-12-12

Publications (2)

Publication Number Publication Date
WO2010035956A2 WO2010035956A2 (ko) 2010-04-01
WO2010035956A3 true WO2010035956A3 (ko) 2010-05-20

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PCT/KR2009/004541 WO2010035956A2 (ko) 2008-09-29 2009-08-13 분리막 레저버를 이용하는 리튬 회수 장치, 이를 이용한 리튬 회수 방법, 및 이를 이용한 리튬 흡탈착 시스템

Country Status (3)

Country Link
US (1) US8741150B2 (ko)
JP (1) JP2012504190A (ko)
WO (1) WO2010035956A2 (ko)

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WO2010035956A2 (ko) 2010-04-01
US8741150B2 (en) 2014-06-03
US20110174739A1 (en) 2011-07-21
JP2012504190A (ja) 2012-02-16

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