WO2009060903A1 - ポリオール組成物、発泡用組成物およびポリウレタンフォーム - Google Patents

ポリオール組成物、発泡用組成物およびポリウレタンフォーム Download PDF

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WO2009060903A1
WO2009060903A1 PCT/JP2008/070220 JP2008070220W WO2009060903A1 WO 2009060903 A1 WO2009060903 A1 WO 2009060903A1 JP 2008070220 W JP2008070220 W JP 2008070220W WO 2009060903 A1 WO2009060903 A1 WO 2009060903A1
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WIPO (PCT)
Prior art keywords
composition
polyol
polyurethane foam
mgkoh
functional groups
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PCT/JP2008/070220
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English (en)
French (fr)
Inventor
Kenji Yamanaka
Masayoshi Idomoto
Kouji Fukui
Masashi Obata
Katsumi Inaoka
Masaaki Shibata
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Mitsui Chemicals Polyurethanes, Inc.
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Publication date
Application filed by Mitsui Chemicals Polyurethanes, Inc. filed Critical Mitsui Chemicals Polyurethanes, Inc.
Priority to CN2008801147171A priority Critical patent/CN101848955B/zh
Priority to KR1020107010016A priority patent/KR101529352B1/ko
Priority to JP2009540082A priority patent/JP5546864B2/ja
Priority to US12/734,552 priority patent/US8188156B2/en
Priority to EP08847096.8A priority patent/EP2208744B1/en
Publication of WO2009060903A1 publication Critical patent/WO2009060903A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4244—Polycondensates having carboxylic or carbonic ester groups in the main chain containing oxygen in the form of ether groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C08G18/4816—Two or more polyethers of different physical or chemical nature mixtures of two or more polyetherpolyols having at least three hydroxy groups
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4829—Polyethers containing at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4858—Polyethers containing oxyalkylene groups having more than four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

　ポリオール組成物は、水酸基価３００～５００ｍｇＫＯＨ／ｇ、平均官能基数２．０～２．５の芳香族系ポリエステルポリオールと、水酸基価１００～２５０ｍｇＫＯＨ／ｇ、平均官能基数２．０～４．０のポリオキシプロピレンユニットからなる中鎖ポリエーテルポリオールと、水酸基価１５～４０ｍｇＫＯＨ／ｇ、平均官能基数２．０～４．０であり、オキシエチレン含量１４重量％以下の、主としてポリオキシプロピレンユニットからなる長鎖ポリエーテルポリオールとを含有する。
PCT/JP2008/070220 2007-11-09 2008-11-06 ポリオール組成物、発泡用組成物およびポリウレタンフォーム WO2009060903A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN2008801147171A CN101848955B (zh) 2007-11-09 2008-11-06 多元醇组合物、发泡用组合物和聚氨酯泡沫
KR1020107010016A KR101529352B1 (ko) 2007-11-09 2008-11-06 폴리올 조성물, 발포용 조성물 및 폴리우레탄 폼
JP2009540082A JP5546864B2 (ja) 2007-11-09 2008-11-06 ポリオール組成物、発泡用組成物およびポリウレタンフォーム
US12/734,552 US8188156B2 (en) 2007-11-09 2008-11-06 Polyol composition, foaming composition and polyurethane foam
EP08847096.8A EP2208744B1 (en) 2007-11-09 2008-11-06 Polyol composition, foaming composition and polyurethane foam

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-292131 2007-11-09
JP2007292131 2007-11-09

Publications (1)

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WO2009060903A1 true WO2009060903A1 (ja) 2009-05-14

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PCT/JP2008/070220 WO2009060903A1 (ja) 2007-11-09 2008-11-06 ポリオール組成物、発泡用組成物およびポリウレタンフォーム

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US (1) US8188156B2 (ja)
EP (1) EP2208744B1 (ja)
JP (1) JP5546864B2 (ja)
KR (1) KR101529352B1 (ja)
CN (1) CN101848955B (ja)
MY (1) MY150037A (ja)
TW (1) TWI434874B (ja)
WO (1) WO2009060903A1 (ja)

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WO2013080787A1 (ja) * 2011-11-30 2013-06-06 三洋化成工業株式会社 切削加工用硬質ポリウレタン樹脂
JP2016514739A (ja) * 2013-03-25 2016-05-23 コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ 音響吸収性が高い硬質ポリウレタンフォーム
CN116253851A (zh) * 2022-10-31 2023-06-13 江苏省医疗器械检验所(江苏省食品药品监督管理局医药包装材料容器产品质量监督检验站) 骨科测试用聚氨酯材料及其制备方法和应用

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DE102010002880A1 (de) * 2010-03-15 2011-09-15 Wacker Chemie Ag Siliconhaltiger Polyurethanschaum
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DE102011079336A1 (de) * 2011-07-18 2013-01-24 Bayer Materialscience Aktiengesellschaft Versprühbarer, wassergetriebener PUR-/PIR-Hartschaumstoff
CN103012711A (zh) * 2011-09-21 2013-04-03 绍兴市恒丰聚氨酯实业有限公司 硬质聚氨酯模塑泡沫负压发泡原料配方及其生产方法
ITMI20131603A1 (it) * 2013-09-30 2015-03-30 Dow Global Technologies Llc Miscele di polioli e polioli poliesteri e preparazione di espansi poliuretanici rigidi
CA3005676A1 (en) * 2015-11-26 2017-06-01 Covestro Deutschland Ag Pur/pir rigid foams made of polyaddition oligoesters
CN105968269B (zh) * 2016-07-12 2019-03-12 佳化化学科技发展（上海）有限公司 一种可代替苯乙烯-丙烯腈共聚的pop使用的组合物
US11091652B2 (en) 2017-01-25 2021-08-17 Basf Se Cold flexible polyurethane formulation
CN110467709B (zh) * 2019-09-10 2021-03-02 南通四方节能科技有限公司 一种组合聚醚、应用其制备的pir夹芯板及制备方法
CN111253548B (zh) * 2020-01-22 2023-03-24 黎明化工研究设计院有限责任公司 一种车用吸音聚氨酯硬泡组合料

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JP2006348156A (ja) * 2005-06-15 2006-12-28 Inoac Corp 硬質ポリウレタン発泡体の製造方法

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013080787A1 (ja) * 2011-11-30 2013-06-06 三洋化成工業株式会社 切削加工用硬質ポリウレタン樹脂
JPWO2013080787A1 (ja) * 2011-11-30 2015-04-27 三洋化成工業株式会社 切削加工用硬質ポリウレタン樹脂
US9580570B2 (en) 2011-11-30 2017-02-28 Sanyo Chemical Industries, Ltd. Rigid polyurethane resin for cutting work
JP2016514739A (ja) * 2013-03-25 2016-05-23 コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ 音響吸収性が高い硬質ポリウレタンフォーム
CN116253851A (zh) * 2022-10-31 2023-06-13 江苏省医疗器械检验所(江苏省食品药品监督管理局医药包装材料容器产品质量监督检验站) 骨科测试用聚氨酯材料及其制备方法和应用
CN116253851B (zh) * 2022-10-31 2024-04-09 江苏省医疗器械检验所(江苏省食品药品监督管理局医药包装材料容器产品质量监督检验站) 骨科测试用聚氨酯材料及其制备方法和应用

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KR101529352B1 (ko) 2015-06-16
JPWO2009060903A1 (ja) 2011-03-24
EP2208744A1 (en) 2010-07-21
TWI434874B (zh) 2014-04-21
CN101848955B (zh) 2012-09-19
TW200932780A (en) 2009-08-01
MY150037A (en) 2013-11-29
US20100261804A1 (en) 2010-10-14
EP2208744A4 (en) 2011-12-28
US8188156B2 (en) 2012-05-29

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