WO2009054460A1 - 気体分離膜 - Google Patents

気体分離膜 Download PDF

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Publication number
WO2009054460A1
WO2009054460A1 PCT/JP2008/069246 JP2008069246W WO2009054460A1 WO 2009054460 A1 WO2009054460 A1 WO 2009054460A1 JP 2008069246 W JP2008069246 W JP 2008069246W WO 2009054460 A1 WO2009054460 A1 WO 2009054460A1
Authority
WO
WIPO (PCT)
Prior art keywords
gas separation
separation membrane
supporting body
gas
porous supporting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/069246
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
Atsushi Shimizu
Masao Kondo
Junichi Yamamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Chemicals Corp
Original Assignee
Asahi Kasei Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Kasei Chemicals Corp filed Critical Asahi Kasei Chemicals Corp
Priority to CN200880113192.XA priority Critical patent/CN101835529B/zh
Priority to US12/739,292 priority patent/US8206493B2/en
Priority to EP08842793.5A priority patent/EP2206546B1/en
Priority to JP2009538255A priority patent/JPWO2009054460A1/ja
Publication of WO2009054460A1 publication Critical patent/WO2009054460A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/107—Organic support material
    • B01D69/1071—Woven, non-woven or net mesh
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/002—Organic membrane manufacture from melts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
    • B01D67/0025—Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching
    • B01D67/0027—Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching by stretching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
    • B01D67/003—Organic membrane manufacture by inducing porosity into non porous precursor membranes by selective elimination of components, e.g. by leaching
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0083—Thermal after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0095—Drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/107—Organic support material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B01D69/1213—Laminated layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/26—Polyalkenes
    • B01D71/261—Polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/26—Polyalkenes
    • B01D71/262—Polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/30—Polyalkenyl halides
    • B01D71/32—Polyalkenyl halides containing fluorine atoms
    • B01D71/36—Polytetrafluoroethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/12—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/06—Specific viscosities of materials involved
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/15—Use of additives
    • B01D2323/20—Plasticizers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/0281—Fibril, or microfibril structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/0283—Pore size
    • B01D2325/02832—1-10 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/0283—Pore size
    • B01D2325/02833—Pore size more than 10 and up to 100 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/02—Details relating to pores or porosity of the membranes
    • B01D2325/0283—Pore size
    • B01D2325/02834—Pore size more than 0.1 and up to 1 µm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/04—Characteristic thickness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/20—Specific permeability or cut-off range
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/22—Thermal or heat-resistance properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/24—Mechanical properties, e.g. strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/34—Molecular weight or degree of polymerisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
PCT/JP2008/069246 2007-10-26 2008-10-23 気体分離膜 Ceased WO2009054460A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN200880113192.XA CN101835529B (zh) 2007-10-26 2008-10-23 气体分离膜
US12/739,292 US8206493B2 (en) 2007-10-26 2008-10-23 Gas separation membrane
EP08842793.5A EP2206546B1 (en) 2007-10-26 2008-10-23 Gas separation membrane
JP2009538255A JPWO2009054460A1 (ja) 2007-10-26 2008-10-23 気体分離膜

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-279430 2007-10-26
JP2007279430 2007-10-26

Publications (1)

Publication Number Publication Date
WO2009054460A1 true WO2009054460A1 (ja) 2009-04-30

Family

ID=40579562

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/069246 Ceased WO2009054460A1 (ja) 2007-10-26 2008-10-23 気体分離膜

Country Status (6)

Country Link
US (1) US8206493B2 (enExample)
EP (1) EP2206546B1 (enExample)
JP (2) JPWO2009054460A1 (enExample)
KR (1) KR101151189B1 (enExample)
CN (1) CN101835529B (enExample)
WO (1) WO2009054460A1 (enExample)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011083729A (ja) * 2009-10-16 2011-04-28 Ngk Insulators Ltd 複合分離膜及びその製造方法
JP2011083728A (ja) * 2009-10-16 2011-04-28 Ngk Insulators Ltd 複合分離膜及びその製造方法
JP2018103150A (ja) * 2016-12-28 2018-07-05 日立造船株式会社 ガス分離膜の品質評価方法とその評価装置
JP2021069985A (ja) * 2019-10-31 2021-05-06 旭化成株式会社 ガス分離膜
JP2021069990A (ja) * 2019-10-31 2021-05-06 旭化成株式会社 ガス分離膜

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JP5507079B2 (ja) * 2006-04-28 2014-05-28 旭化成ケミカルズ株式会社 気体分離膜
JP5619755B2 (ja) * 2009-09-28 2014-11-05 旭化成ケミカルズ株式会社 膜エレメント、気体分離装置及び内燃機関
KR101063697B1 (ko) * 2011-05-25 2011-09-07 한국가스공사연구개발원 Ｄｍｅ 제조 공정에 적용되는 이산화탄소/수소 분리막
US20130228529A1 (en) * 2011-11-04 2013-09-05 Ppg Industries Ohio, Inc. Microporous material having filtration and adsorption properties and their use in fluid purification processes
US20130228519A1 (en) * 2011-11-04 2013-09-05 Ppg Industries Ohio, Inc. Microporous material having filtration and adsorption properties and their use in fluid purification processes
US20140069862A1 (en) * 2011-11-04 2014-03-13 Ppg Industries Ohio, Inc. Coated microporous materials having filtration and adsorption properties and their use in fluid purification processes
EP2825508A4 (en) * 2012-03-15 2015-10-21 Massachusetts Inst Technology FILTER BASED ON GRAPHENE
CN103463995B (zh) * 2013-08-19 2015-09-09 武汉龙飞翔科技产品制造有限公司 用于口罩的五防和富氧功能的聚合物超薄膜复合膜及应用
CN103446680B (zh) * 2013-08-19 2016-08-31 武汉龙飞翔科技产品制造有限公司 带聚合物超薄膜复合膜的能防pm2.5的五防富氧口罩
CN106413859B (zh) 2013-11-01 2019-07-05 麻省理工学院 减轻膜中的渗漏
CN104055247B (zh) * 2014-07-07 2016-06-08 岳阳唯尔复合材料科技有限公司 高透气性防pm2.5、防雾霾、防病毒、防病菌的亚纳滤膜口罩
KR101537353B1 (ko) * 2015-01-27 2015-07-17 한국산업기술시험원 분리막 성능평가장치
US9903323B2 (en) 2015-03-10 2018-02-27 Denso International America, Inc. Emissions reduction system for an internal combustion engine
US9745927B2 (en) 2015-03-10 2017-08-29 Denso International America, Inc. Emissions reduction system for an internal combustion engine
MX2019004895A (es) * 2016-11-08 2019-06-20 Ngk Insulators Ltd Metodo para secar membrana de separacion y metodo para producir estructura de membrana de separacion.
CN106621853B (zh) * 2016-12-20 2019-04-12 大连欧科膜技术工程有限公司 全氟聚合物复合膜及其制备方法和应用
KR101986119B1 (ko) * 2018-01-23 2019-09-03 연세대학교 산학협력단 자가-가교가 가능한 공중합체를 이용한 기체 분리막 및 그 제조방법
WO2020006484A1 (en) 2018-06-28 2020-01-02 Massachusetts Institute Of Technology Coatings to improve the selectivity of atomically thin membranes
EP3669973A1 (de) * 2018-12-20 2020-06-24 Evonik Operations GmbH Verbundkörper
US11471823B2 (en) 2019-02-12 2022-10-18 Haffmans B.V. System and method for separating a gas mixture
WO2020203901A1 (ja) * 2019-03-29 2020-10-08 東レ株式会社 ポリオレフィン微多孔膜、電池用セパレータ、二次電池及びポリオレフィン微多孔膜の製造方法
US20210308630A1 (en) * 2020-04-07 2021-10-07 Ralph Aaron Bauer Support for Nano-Thickness Membranes
CN113562708A (zh) * 2021-08-13 2021-10-29 云南安锋气体有限公司 一种低能耗制备氩、氮气体的制备方法

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WO1990015662A1 (en) 1989-06-15 1990-12-27 Du Pont Canada Inc. Perfluorodioxole membranes
JPH04267934A (ja) * 1990-11-28 1992-09-24 Akzo Nv 中空毛管膜の製造方法、ガス分離膜用支持膜及び非対称性完全ガス分離膜
JPH0696107B2 (ja) 1989-08-25 1994-11-30 松下電器産業株式会社 選択性気体透過膜
JPH1099665A (ja) 1996-09-27 1998-04-21 Japan Gore Tex Inc 気体分離膜および気体分離法
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JP5507079B2 (ja) * 2006-04-28 2014-05-28 旭化成ケミカルズ株式会社 気体分離膜
JP5063604B2 (ja) * 2007-03-30 2012-10-31 イビデン株式会社 ハニカムフィルタ

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990015662A1 (en) 1989-06-15 1990-12-27 Du Pont Canada Inc. Perfluorodioxole membranes
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JP2011083729A (ja) * 2009-10-16 2011-04-28 Ngk Insulators Ltd 複合分離膜及びその製造方法
JP2011083728A (ja) * 2009-10-16 2011-04-28 Ngk Insulators Ltd 複合分離膜及びその製造方法
JP2018103150A (ja) * 2016-12-28 2018-07-05 日立造船株式会社 ガス分離膜の品質評価方法とその評価装置
WO2018123515A1 (ja) * 2016-12-28 2018-07-05 日立造船株式会社 ガス分離膜の品質評価方法とその評価装置
JP2021069985A (ja) * 2019-10-31 2021-05-06 旭化成株式会社 ガス分離膜
JP2021069990A (ja) * 2019-10-31 2021-05-06 旭化成株式会社 ガス分離膜
JP7349886B2 (ja) 2019-10-31 2023-09-25 旭化成株式会社 ガス分離膜
JP7451142B2 (ja) 2019-10-31 2024-03-18 旭化成株式会社 ガス分離膜

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CN101835529B (zh) 2013-11-06
US8206493B2 (en) 2012-06-26
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CN101835529A (zh) 2010-09-15
EP2206546A1 (en) 2010-07-14

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