CN101835529B - 气体分离膜 - Google Patents

气体分离膜 Download PDF

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Publication number
CN101835529B
CN101835529B CN200880113192.XA CN200880113192A CN101835529B CN 101835529 B CN101835529 B CN 101835529B CN 200880113192 A CN200880113192 A CN 200880113192A CN 101835529 B CN101835529 B CN 101835529B
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porous support
gas separation
separation membrane
gas
film
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Chinese (zh)
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CN101835529A (zh
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清水敦
近藤真佐雄
山元淳一
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Asahi Kasei Corp
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Asahi Kasei Chemicals Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10Supported membranes; Membrane supports
    • B01D69/107Organic support material
    • B01D69/1071Woven, non-woven or net mesh
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/002Organic membrane manufacture from melts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0023Organic membrane manufacture by inducing porosity into non porous precursor membranes
    • B01D67/0025Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching
    • B01D67/0027Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching by stretching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0023Organic membrane manufacture by inducing porosity into non porous precursor membranes
    • B01D67/003Organic membrane manufacture by inducing porosity into non porous precursor membranes by selective elimination of components, e.g. by leaching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0083Thermal after-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081After-treatment of organic or inorganic membranes
    • B01D67/0095Drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10Supported membranes; Membrane supports
    • B01D69/107Organic support material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12Composite membranes; Ultra-thin membranes
    • B01D69/1213Laminated layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/26Polyalkenes
    • B01D71/261Polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/26Polyalkenes
    • B01D71/262Polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/30Polyalkenyl halides
    • B01D71/32Polyalkenyl halides containing fluorine atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/30Polyalkenyl halides
    • B01D71/32Polyalkenyl halides containing fluorine atoms
    • B01D71/36Polytetrafluoroethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2256/00Main component in the product gas stream after treatment
    • B01D2256/12Oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/102Nitrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/06Specific viscosities of materials involved
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/15Use of additives
    • B01D2323/20Plasticizers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/02Details relating to pores or porosity of the membranes
    • B01D2325/0281Fibril, or microfibril structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/02Details relating to pores or porosity of the membranes
    • B01D2325/0283Pore size
    • B01D2325/028321-10 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/02Details relating to pores or porosity of the membranes
    • B01D2325/0283Pore size
    • B01D2325/02833Pore size more than 10 and up to 100 nm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/02Details relating to pores or porosity of the membranes
    • B01D2325/0283Pore size
    • B01D2325/02834Pore size more than 0.1 and up to 1 µm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/04Characteristic thickness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/20Specific permeability or cut-off range
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/22Thermal or heat-resistance properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/24Mechanical properties, e.g. strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/34Molecular weight or degree of polymerisation

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
CN200880113192.XA 2007-10-26 2008-10-23 气体分离膜 Active CN101835529B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2007-279430 2007-10-26
JP2007279430 2007-10-26
PCT/JP2008/069246 WO2009054460A1 (ja) 2007-10-26 2008-10-23 気体分離膜

Publications (2)

Publication Number Publication Date
CN101835529A CN101835529A (zh) 2010-09-15
CN101835529B true CN101835529B (zh) 2013-11-06

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Country Status (6)

Country Link
US (1) US8206493B2 (enExample)
EP (1) EP2206546B1 (enExample)
JP (2) JPWO2009054460A1 (enExample)
KR (1) KR101151189B1 (enExample)
CN (1) CN101835529B (enExample)
WO (1) WO2009054460A1 (enExample)

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US20130228529A1 (en) * 2011-11-04 2013-09-05 Ppg Industries Ohio, Inc. Microporous material having filtration and adsorption properties and their use in fluid purification processes
US20130228519A1 (en) * 2011-11-04 2013-09-05 Ppg Industries Ohio, Inc. Microporous material having filtration and adsorption properties and their use in fluid purification processes
US20140069862A1 (en) * 2011-11-04 2014-03-13 Ppg Industries Ohio, Inc. Coated microporous materials having filtration and adsorption properties and their use in fluid purification processes
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CN103463995B (zh) * 2013-08-19 2015-09-09 武汉龙飞翔科技产品制造有限公司 用于口罩的五防和富氧功能的聚合物超薄膜复合膜及应用
CN103446680B (zh) * 2013-08-19 2016-08-31 武汉龙飞翔科技产品制造有限公司 带聚合物超薄膜复合膜的能防pm2.5的五防富氧口罩
CN106413859B (zh) 2013-11-01 2019-07-05 麻省理工学院 减轻膜中的渗漏
CN104055247B (zh) * 2014-07-07 2016-06-08 岳阳唯尔复合材料科技有限公司 高透气性防pm2.5、防雾霾、防病毒、防病菌的亚纳滤膜口罩
KR101537353B1 (ko) * 2015-01-27 2015-07-17 한국산업기술시험원 분리막 성능평가장치
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CN106621853B (zh) * 2016-12-20 2019-04-12 大连欧科膜技术工程有限公司 全氟聚合物复合膜及其制备方法和应用
JP6643223B2 (ja) * 2016-12-28 2020-02-12 日立造船株式会社 ガス分離膜の品質評価方法とその評価装置
KR101986119B1 (ko) * 2018-01-23 2019-09-03 연세대학교 산학협력단 자가-가교가 가능한 공중합체를 이용한 기체 분리막 및 그 제조방법
WO2020006484A1 (en) 2018-06-28 2020-01-02 Massachusetts Institute Of Technology Coatings to improve the selectivity of atomically thin membranes
EP3669973A1 (de) * 2018-12-20 2020-06-24 Evonik Operations GmbH Verbundkörper
US11471823B2 (en) 2019-02-12 2022-10-18 Haffmans B.V. System and method for separating a gas mixture
WO2020203901A1 (ja) * 2019-03-29 2020-10-08 東レ株式会社 ポリオレフィン微多孔膜、電池用セパレータ、二次電池及びポリオレフィン微多孔膜の製造方法
JP7349886B2 (ja) * 2019-10-31 2023-09-25 旭化成株式会社 ガス分離膜
JP7451142B2 (ja) * 2019-10-31 2024-03-18 旭化成株式会社 ガス分離膜
US20210308630A1 (en) * 2020-04-07 2021-10-07 Ralph Aaron Bauer Support for Nano-Thickness Membranes
CN113562708A (zh) * 2021-08-13 2021-10-29 云南安锋气体有限公司 一种低能耗制备氩、氮气体的制备方法

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Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0488018A2 (de) * 1990-11-28 1992-06-03 Akzo N.V. Kapillarmembran für die Gastrennung
US20020038602A1 (en) * 2000-06-13 2002-04-04 Praxair Technology, Inc. Method of preparing composite gas separation membranes from perfluoropolymers

Also Published As

Publication number Publication date
US20100212504A1 (en) 2010-08-26
WO2009054460A1 (ja) 2009-04-30
JP2015037791A (ja) 2015-02-26
EP2206546A4 (en) 2011-05-18
JPWO2009054460A1 (ja) 2011-03-10
EP2206546B1 (en) 2018-07-04
KR101151189B1 (ko) 2012-06-08
US8206493B2 (en) 2012-06-26
KR20100061743A (ko) 2010-06-08
CN101835529A (zh) 2010-09-15
EP2206546A1 (en) 2010-07-14

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