WO2009022544A1 - カルボン酸エステル製造用触媒、その製造方法、並びにカルボン酸エステルの製造方法 - Google Patents

カルボン酸エステル製造用触媒、その製造方法、並びにカルボン酸エステルの製造方法 Download PDF

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Publication number
WO2009022544A1
WO2009022544A1 PCT/JP2008/063767 JP2008063767W WO2009022544A1 WO 2009022544 A1 WO2009022544 A1 WO 2009022544A1 JP 2008063767 W JP2008063767 W JP 2008063767W WO 2009022544 A1 WO2009022544 A1 WO 2009022544A1
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Prior art keywords
carboxylic acid
acid ester
producing
catalyst
same
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PCT/JP2008/063767
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English (en)
French (fr)
Inventor
Ken Suzuki
Tatsuo Yamaguchi
Original Assignee
Asahi Kasei Chemicals Corporation
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Publication date
Application filed by Asahi Kasei Chemicals Corporation filed Critical Asahi Kasei Chemicals Corporation
Priority to CN200880102565A priority Critical patent/CN101815579A/zh
Priority to EP08791982.5A priority patent/EP2177267B1/en
Priority to KR1020107000552A priority patent/KR101169137B1/ko
Priority to ES08791982T priority patent/ES2431791T3/es
Priority to US12/673,159 priority patent/US8461373B2/en
Priority to BRPI0815166A priority patent/BRPI0815166A8/pt
Priority to JP2009528075A priority patent/JP4674921B2/ja
Publication of WO2009022544A1 publication Critical patent/WO2009022544A1/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/892—Nickel and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • B01J35/393—
    • B01J35/60—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/14—Silica and magnesia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B01J35/40—
    • B01J35/613—
    • B01J35/615—
    • B01J35/633—
    • B01J35/647—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying

Abstract

　酸素の存在下、（ａ）アルデヒドとアルコール、又は、（ｂ）１種もしくは２種以上のアルコール、を反応させてカルボン酸エステルを製造する際に用いられる触媒であって、 　酸化状態のニッケルと、Ｘ（Ｘはニッケル、パラジウム、白金、ルテニウム、金、銀及び銅からなる群から選択される少なくとも１種の元素を示す）と、が担体にＮｉ／（Ｎｉ＋Ｘ）原子比で０．２０～０．９９の範囲で担持されたカルボン酸エステル製造用触媒。
PCT/JP2008/063767 2007-08-13 2008-07-31 カルボン酸エステル製造用触媒、その製造方法、並びにカルボン酸エステルの製造方法 WO2009022544A1 (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CN200880102565A CN101815579A (zh) 2007-08-13 2008-07-31 羧酸酯制造用催化剂、其制造方法、以及羧酸酯的制造方法
EP08791982.5A EP2177267B1 (en) 2007-08-13 2008-07-31 Catalyst for carboxylic acid ester production, method for producing the same, and method for producing carboxylic acid ester
KR1020107000552A KR101169137B1 (ko) 2007-08-13 2008-07-31 카르복실산에스테르 제조용 촉매, 그 제조방법 및 카르복실산에스테르의 제조방법
ES08791982T ES2431791T3 (es) 2007-08-13 2008-07-31 Catalizador para la producción de éster del ácido carboxílico, procedimiento de producción del mismo y procedimiento para la producción de éster del ácido carboxílico
US12/673,159 US8461373B2 (en) 2007-08-13 2008-07-31 Catalyst for producing carboxylic acid esters, process for producing same and process for producing carboxylic acid esters
BRPI0815166A BRPI0815166A8 (pt) 2007-08-13 2008-07-31 Catalisador para uso na produção de éster de ácido carboxílico, processos para produzir o mesmo, e, para produzir éster de ácido carboxílico
JP2009528075A JP4674921B2 (ja) 2007-08-13 2008-07-31 カルボン酸エステル製造用触媒、その製造方法、並びにカルボン酸エステルの製造方法

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP2007210962 2007-08-13
JP2007-210962 2007-08-13
JP2007265375 2007-10-11
JP2007-265375 2007-10-11
JP2007-279411 2007-10-26
JP2007279411 2007-10-26
JP2008105103 2008-04-14
JP2008-105103 2008-04-14

Publications (1)

Publication Number Publication Date
WO2009022544A1 true WO2009022544A1 (ja) 2009-02-19

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PCT/JP2008/063767 WO2009022544A1 (ja) 2007-08-13 2008-07-31 カルボン酸エステル製造用触媒、その製造方法、並びにカルボン酸エステルの製造方法

Country Status (10)

Country Link
US (1) US8461373B2 (ja)
EP (1) EP2177267B1 (ja)
JP (1) JP4674921B2 (ja)
KR (1) KR101169137B1 (ja)
CN (3) CN101815579A (ja)
BR (1) BRPI0815166A8 (ja)
ES (1) ES2431791T3 (ja)
MY (1) MY152280A (ja)
TW (1) TWI396588B (ja)
WO (1) WO2009022544A1 (ja)

Cited By (20)

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JP2010221083A (ja) * 2009-03-19 2010-10-07 Asahi Kasei Chemicals Corp 貴金属担持物及びそれを触媒として用いるカルボン酸エステルの製造方法
JP2010221081A (ja) * 2009-03-19 2010-10-07 Asahi Kasei Chemicals Corp 複合粒子担持物及びその製造方法並びにカルボン酸エステルの製造方法
JP2010222151A (ja) * 2009-03-19 2010-10-07 Asahi Kasei Chemicals Corp シリカ系材料及びその製造方法並びに金属担持物
WO2011073120A1 (en) * 2009-12-17 2011-06-23 Basf Se Metal oxide support material containing nanoscaled iron-platinum group metal particles
WO2012035637A1 (ja) * 2010-09-16 2012-03-22 旭化成ケミカルズ株式会社 シリカ系材料及びその製造方法、並びに貴金属担持物及びそれを触媒として用いるカルボン酸類の製造方法
JP2013252519A (ja) * 2012-05-08 2013-12-19 Gunma Prefecture 水素含有ガスの製造用触媒および同触媒による水素含有ガスの製造方法。
JP2016000686A (ja) * 2015-06-29 2016-01-07 旭化成ケミカルズ株式会社 シリカ系材料及びその製造方法、並びに貴金属担持物及びそれを触媒として用いるカルボン酸類の製造方法
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KR20160102498A (ko) * 2013-12-20 2016-08-30 에보니크 룀 게엠베하 알데히드로부터의 직접 산화적 에스테르화에 의한 불포화 에스테르의 제조 방법
JP2017537781A (ja) * 2014-12-03 2017-12-21 中国石油化工股▲ふん▼有限公司 触媒およびその調製方法、ならびに当該触媒を利用することによるイソブチレンの調製方法
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EP2177267A1 (en) 2010-04-21
ES2431791T3 (es) 2013-11-28
KR101169137B1 (ko) 2012-07-30
US20110184206A1 (en) 2011-07-28
EP2177267A4 (en) 2011-12-07
CN105148921A (zh) 2015-12-16
CN105214683B (zh) 2018-02-09
TW200914130A (en) 2009-04-01
EP2177267B1 (en) 2013-07-31
BRPI0815166A8 (pt) 2016-12-20
US8461373B2 (en) 2013-06-11
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CN101815579A (zh) 2010-08-25
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