WO2008133290A1 - 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体 - Google Patents

重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体 Download PDF

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WO2008133290A1
WO2008133290A1 PCT/JP2008/057896 JP2008057896W WO2008133290A1 WO 2008133290 A1 WO2008133290 A1 WO 2008133290A1 JP 2008057896 W JP2008057896 W JP 2008057896W WO 2008133290 A1 WO2008133290 A1 WO 2008133290A1
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Prior art keywords
liquid crystal
polymerizable liquid
independently represent
crystal compound
polymerizable
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PCT/JP2008/057896
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English (en)
French (fr)
Inventor
Kei Sakamoto
Naoto Kogoshi
Yoshihide Yachi
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Zeon Corporation
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Publication date
Priority claimed from JP2008092162A external-priority patent/JP5401823B2/ja
Priority claimed from JP2008092093A external-priority patent/JP5401822B2/ja
Application filed by Zeon Corporation filed Critical Zeon Corporation
Priority to CN2008800218540A priority Critical patent/CN101687778B/zh
Priority to EP08740823.3A priority patent/EP2143710B1/en
Priority to KR1020097022273A priority patent/KR101233950B1/ko
Priority to US12/597,122 priority patent/US8158021B2/en
Publication of WO2008133290A1 publication Critical patent/WO2008133290A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
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    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
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    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/24—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing nitrogen-to-nitrogen bonds
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    • C09K19/3833—Polymers with mesogenic groups in the side chain
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    • C09K19/00—Liquid crystal materials
    • C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
    • C09K19/58—Dopants or charge transfer agents
    • C09K19/586—Optically active dopants; chiral dopants
    • C09K19/588—Heterocyclic compounds
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3016—Polarising elements involving passive liquid crystal elements
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
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    • C09K2019/0407—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit the structure containing one or more specific, optionally substituted ring or ring systems containing a carbocyclic ring, e.g. dicyano-benzene, chlorofluoro-benzene or cyclohexanone
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    • C09K2019/0448—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
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    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
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    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
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    • G02F1/133711—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by organic films, e.g. polymeric films
    • G02F1/133726—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by organic films, e.g. polymeric films made of a mesogenic material
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    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
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    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
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  • Liquid Crystal Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Abstract

　本発明は、下記式（Ｉ）で示される重合性液晶化合物、該重合性液晶化合物及び重合可能なキラル化合物を含有する重合性液晶組成物、前記重合性液晶化合物又は重合性液晶組成物を重合して得られる液晶性高分子、該液晶性高分子を構成材料とする光学異方体である。 本発明によれば、より液晶相を示す温度範囲が広く、化学的に安定であり、安価に製造でき、しかも、選択反射波長帯域Δλが広い（Δｎが大きい）重合性液晶化合物等が提供される。 （式中、Ｙ１～Ｙ６は、－Ｏ－、－Ｏ－Ｃ（＝Ｏ）－、－Ｃ（＝Ｏ）－Ｏ－等を、Ｇ１及びＧ２は、炭素数１～２０の２価の脂肪族基等を、Ｚ１及びＺ２は炭素数２～１０のアルケニル基等を、Ａ１及びＡ２は炭素数１～３０の２価の有機基Ａを、Ｘ１～Ｘ８は水素原子等をそれぞれ表す。ａ、ｂは０又は１である。）
PCT/JP2008/057896 2007-04-24 2008-04-24 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体 WO2008133290A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2008800218540A CN101687778B (zh) 2007-04-24 2008-04-24 聚合性液晶化合物、聚合性液晶组合物、液晶高分子及光学各向异性体
EP08740823.3A EP2143710B1 (en) 2007-04-24 2008-04-24 Polymerizable liquid crystal compound, polymerizable liquid crystal composition, liquid crystalline polymer, and optically anisotropic material
KR1020097022273A KR101233950B1 (ko) 2007-04-24 2008-04-24 중합가능한 액정 화합물, 중합가능한 액정 조성물, 액정질 중합체, 및 광학 이방성 물질
US12/597,122 US8158021B2 (en) 2007-04-24 2008-04-24 Polymerizable liquid crystal compound, polymerizable liquid crystal composition, liquid crystalline polymer, and optical anisotropic article

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP2007114270 2007-04-24
JP2007-114270 2007-04-24
JP2007-327654 2007-12-19
JP2007327654 2007-12-19
JP2008-092162 2008-03-31
JP2008-092093 2008-03-31
JP2008092162A JP5401823B2 (ja) 2007-12-19 2008-03-31 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体
JP2008092093A JP5401822B2 (ja) 2007-04-24 2008-03-31 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体

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US (1) US8158021B2 (ja)
EP (1) EP2143710B1 (ja)
KR (1) KR101233950B1 (ja)
CN (1) CN101687778B (ja)
TW (1) TWI465552B (ja)
WO (1) WO2008133290A1 (ja)

Cited By (11)

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WO2009078431A1 (ja) * 2007-12-19 2009-06-25 Zeon Corporation 重合性液晶化合物、重合性液晶組成物、液晶性高分子および光学異方体
WO2010001726A1 (ja) 2008-06-30 2010-01-07 日本ゼオン株式会社 非対称アジン化合物およびその製造方法
WO2010001725A1 (ja) * 2008-06-30 2010-01-07 日本ゼオン株式会社 重合性液晶化合物、重合性液晶組成物、液晶性高分子及び光学異方体
WO2010038591A1 (ja) * 2008-10-01 2010-04-08 日本ゼオン株式会社 重合性キラル化合物、重合性液晶組成物、液晶性高分子及び光学異方体
JP2010195691A (ja) * 2009-02-23 2010-09-09 Japan Finechem Co Inc 非対称アジン化合物の製造方法
JP2011068833A (ja) * 2009-09-28 2011-04-07 Nippon Zeon Co Ltd 液晶層形成用組成物、円偏光分離シート及びその製造方法、輝度向上フィルム並びに液晶表示装置
WO2012169424A1 (ja) * 2011-06-10 2012-12-13 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
US8883271B2 (en) 2010-03-31 2014-11-11 Zeon Corporation Polymerizable chiral compound, polymerizable liquid crystal compound, liquid crystal polymer and optically anisotropic body
CN105353572A (zh) * 2009-07-06 2016-02-24 株式会社日本显示器 液晶显示装置
WO2019176817A1 (ja) * 2018-03-16 2019-09-19 日本ゼオン株式会社 光学異方性層、光学異方性積層体、偏光板、並びに画像表示装置
US10633319B2 (en) 2016-03-01 2020-04-28 Zeon Corporation Method of producing solution composition containing monoetherified product, solution composition, and method of producing polymerizable compound

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WO2011111548A1 (ja) 2010-03-09 2011-09-15 日本ゼオン株式会社 断熱部材、断熱合わせガラス及び断熱合わせガラス物品
WO2012141245A1 (ja) 2011-04-15 2012-10-18 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
JP5979136B2 (ja) * 2011-04-27 2016-08-24 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
WO2012176679A1 (ja) * 2011-06-24 2012-12-27 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
KR20200024367A (ko) 2011-09-27 2020-03-06 제온 코포레이션 중합성 화합물의 제조 중간체 및 그 제조 방법
WO2013180217A1 (ja) 2012-05-30 2013-12-05 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
JP2014028916A (ja) * 2012-06-27 2014-02-13 Jnc Corp 重合性液晶組成物
CN107253935B (zh) 2012-07-09 2020-10-09 日本瑞翁株式会社 肼化合物、聚合性化合物的制备方法及将肼化合物作为聚合性化合物的制造原料使用的方法
KR102128555B1 (ko) 2012-10-19 2020-06-30 제온 코포레이션 중합성 화합물, 중합성 조성물, 고분자, 및 광학 이방체
WO2014065176A1 (ja) 2012-10-23 2014-05-01 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
WO2014069515A1 (ja) * 2012-10-30 2014-05-08 日本ゼオン株式会社 液晶組成物、位相差板、画像表示装置、および光学異方性層の波長分散制御方法
WO2014126113A1 (ja) * 2013-02-15 2014-08-21 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
KR20140136818A (ko) * 2013-05-21 2014-12-01 주식회사한빛엠디 수액치료 관리방법 및 수액치료 관리방법을 모바일 디바이스에서 실행할 수 있는 애플리케이션으로 기록한 기록매체
TWI634105B (zh) * 2013-05-29 2018-09-01 迪愛生股份有限公司 聚合性組成物溶液、及使用其之光學異向體
JP6425041B2 (ja) * 2013-07-10 2018-11-21 Jnc株式会社 重合性化合物、重合性組成物および液晶表示素子
CN103467255B (zh) * 2013-09-13 2015-07-01 陕西嘉禾植物化工有限责任公司 一种天然产物紫檀茋的合成方法
TW201601928A (zh) * 2014-03-31 2016-01-16 西克帕控股有限公司 包含對掌性液晶聚合物與發光物質的標記

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KR20100010924A (ko) 2010-02-02
EP2143710A4 (en) 2013-04-17
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