WO2008081855A1 - 水素透過膜、及びその製造方法 - Google Patents
水素透過膜、及びその製造方法 Download PDFInfo
- Publication number
- WO2008081855A1 WO2008081855A1 PCT/JP2007/075082 JP2007075082W WO2008081855A1 WO 2008081855 A1 WO2008081855 A1 WO 2008081855A1 JP 2007075082 W JP2007075082 W JP 2007075082W WO 2008081855 A1 WO2008081855 A1 WO 2008081855A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hydrogen permeable
- permeable film
- manufacturing
- same
- ceramic material
- Prior art date
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 6
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 6
- 239000001257 hydrogen Substances 0.000 title abstract 6
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 3
- 229910010293 ceramic material Inorganic materials 0.000 abstract 2
- 239000002923 metal particle Substances 0.000 abstract 2
- 239000010955 niobium Substances 0.000 abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract 1
- 150000004767 nitrides Chemical class 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0072—Inorganic membrane manufacture by deposition from the gaseous phase, e.g. sputtering, CVD, PVD
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/0215—Silicon carbide; Silicon nitride; Silicon oxycarbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0221—Group 4 or 5 metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
- B01D71/0223—Group 8, 9 or 10 metals
- B01D71/02231—Palladium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
- C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
- C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
- C01B3/505—Membranes containing palladium
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
- C30B25/06—Epitaxial-layer growth by reactive sputtering
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/16—Oxides
- C30B29/22—Complex oxides
- C30B29/30—Niobates; Vanadates; Tantalates
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/16—Oxides
- C30B29/22—Complex oxides
- C30B29/32—Titanates; Germanates; Molybdates; Tungstates
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/38—Nitrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/04—Characteristic thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/30—Chemical resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Physical Vapour Deposition (AREA)
Abstract
本発明により、IVa、Va、又はVIa族に属する金属元素の窒化物又は酸化物からなるセラミックス材料と、前記セラミックス材料中に分散させてなるパラジウム(Pd)、ニオブ(Nb)、バナジウム(V)、タンタル(Ta)及びこれらの合金から選ばれる少なくとも1種の水素透過性金属粒子とを有する水素透過膜であって、該水素透過膜中の水素透過性金属粒子の割合が20~70質量%であり、該水素透過膜の厚みが5~1000nmである水素透過膜が開示される。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07860304.0A EP2127733B1 (en) | 2006-12-28 | 2007-12-27 | Hydrogen permeable film and method for manufacturing the same |
JP2008552145A JP5363121B2 (ja) | 2006-12-28 | 2007-12-27 | 水素透過膜、及びその製造方法 |
US12/519,024 US8147596B2 (en) | 2006-12-28 | 2007-12-27 | Hydrogen permeable film and method for manufacturing the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006-356427 | 2006-12-28 | ||
JP2006356427 | 2006-12-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008081855A1 true WO2008081855A1 (ja) | 2008-07-10 |
Family
ID=39588537
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2007/075082 WO2008081855A1 (ja) | 2006-12-28 | 2007-12-27 | 水素透過膜、及びその製造方法 |
Country Status (4)
Country | Link |
---|---|
US (1) | US8147596B2 (ja) |
EP (1) | EP2127733B1 (ja) |
JP (1) | JP5363121B2 (ja) |
WO (1) | WO2008081855A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013066877A (ja) * | 2011-09-26 | 2013-04-18 | Toshiba Corp | 減酸素素子、減酸素装置及び冷蔵庫 |
WO2017018482A1 (ja) * | 2015-07-28 | 2017-02-02 | 北川工業株式会社 | 逆浸透膜の製造方法 |
JP2017064692A (ja) * | 2015-07-28 | 2017-04-06 | 北川工業株式会社 | 逆浸透膜の製造方法 |
WO2018212338A1 (ja) * | 2017-05-18 | 2018-11-22 | 公益財団法人地球環境産業技術研究機構 | 多孔質構造体 |
JP2021018164A (ja) * | 2019-07-22 | 2021-02-15 | 株式会社住化分析センター | ガス透過セル、ガス透過度測定方法、及びガス透過度測定装置 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2538577C2 (ru) * | 2013-01-22 | 2015-01-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Воронежский государственный университет" (ФГОУ ВПО "ВГУ") | Способ создания композиционной мембраны для очистки водорода |
KR102130069B1 (ko) * | 2013-09-06 | 2020-07-03 | 삼성전자주식회사 | 분리막, 이를 포함하는 수소 분리막, 및 상기 분리막의 제조 방법 |
CN109957772A (zh) * | 2017-12-26 | 2019-07-02 | 北京有色金属研究总院 | 一种钯/陶瓷复合薄膜 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07775A (ja) | 1993-06-15 | 1995-01-06 | Japan Pionics Co Ltd | 水素透過膜 |
JP2000189771A (ja) * | 1998-12-25 | 2000-07-11 | Ngk Insulators Ltd | 水素分離体 |
JP2002071611A (ja) * | 2000-08-30 | 2002-03-12 | Fis Kk | 水素ガスセンサ |
JP2002336664A (ja) | 2001-05-14 | 2002-11-26 | Japan Steel Works Ltd:The | 水素透過膜ユニット及びその製造方法 |
JP2005058822A (ja) * | 2003-08-13 | 2005-03-10 | Ngk Insulators Ltd | 選択透過膜型反応器 |
JP2005270966A (ja) | 2004-02-27 | 2005-10-06 | Mikuni Corp | 水素透過膜及びその製造方法 |
JP2006204990A (ja) * | 2005-01-26 | 2006-08-10 | Nissan Motor Co Ltd | 水素分離膜及びその製造方法 |
JP2006314925A (ja) * | 2005-05-12 | 2006-11-24 | Toyota Motor Corp | 水素透過膜およびそれを備えた燃料電池 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2991609B2 (ja) * | 1993-10-18 | 1999-12-20 | 日本碍子株式会社 | ガス分離体と金属との接合体および水素ガス分離装置 |
JPWO2002064241A1 (ja) * | 2001-02-16 | 2004-06-10 | 住友電気工業株式会社 | 水素透過構造体およびその製造方法、修復方法 |
DE10122889C2 (de) * | 2001-05-11 | 2003-12-11 | Creavis Tech & Innovation Gmbh | Anorganische Kompositmembran zur Abtrennung von Wasserstoff aus Wasserstoff enthaltenden Gemischen |
US6569226B1 (en) * | 2001-09-28 | 2003-05-27 | The United States Of America As Represented By The United States Department Of Energy | Metal/ceramic composites with high hydrogen permeability |
US7001446B2 (en) * | 2002-03-05 | 2006-02-21 | Eltron Research, Inc. | Dense, layered membranes for hydrogen separation |
AU2003220048A1 (en) * | 2002-03-05 | 2003-09-22 | Eltron Research, Inc. | Hydrogen transport membranes |
JP3866208B2 (ja) * | 2002-03-25 | 2007-01-10 | 財団法人地球環境産業技術研究機構 | 限外濾過膜及び水素分離膜、その製造方法並びに水素の分離方法 |
US7393392B2 (en) * | 2004-02-27 | 2008-07-01 | Mikuni Corporation | Hydrogen-permeable membrane and process for production thereof |
US20070044662A1 (en) * | 2005-08-25 | 2007-03-01 | The University Of Chicago | Method for fabricating dense thin film cermet hydrogen separation membrane |
-
2007
- 2007-12-27 US US12/519,024 patent/US8147596B2/en not_active Expired - Fee Related
- 2007-12-27 WO PCT/JP2007/075082 patent/WO2008081855A1/ja active Application Filing
- 2007-12-27 EP EP07860304.0A patent/EP2127733B1/en not_active Not-in-force
- 2007-12-27 JP JP2008552145A patent/JP5363121B2/ja not_active Expired - Fee Related
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07775A (ja) | 1993-06-15 | 1995-01-06 | Japan Pionics Co Ltd | 水素透過膜 |
JP2000189771A (ja) * | 1998-12-25 | 2000-07-11 | Ngk Insulators Ltd | 水素分離体 |
JP2002071611A (ja) * | 2000-08-30 | 2002-03-12 | Fis Kk | 水素ガスセンサ |
JP2002336664A (ja) | 2001-05-14 | 2002-11-26 | Japan Steel Works Ltd:The | 水素透過膜ユニット及びその製造方法 |
JP2005058822A (ja) * | 2003-08-13 | 2005-03-10 | Ngk Insulators Ltd | 選択透過膜型反応器 |
JP2005270966A (ja) | 2004-02-27 | 2005-10-06 | Mikuni Corp | 水素透過膜及びその製造方法 |
JP2006204990A (ja) * | 2005-01-26 | 2006-08-10 | Nissan Motor Co Ltd | 水素分離膜及びその製造方法 |
JP2006314925A (ja) * | 2005-05-12 | 2006-11-24 | Toyota Motor Corp | 水素透過膜およびそれを備えた燃料電池 |
Non-Patent Citations (2)
Title |
---|
KITANO M. ET AL.: "Decomposition of water in the separate evolution of hydrogen and oxygen using visible light-responsive TiO2 thin film photocatalysis: Effect of the work function of the substrates on the yield of the reaction", APPLIED CATALYSIS, vol. 314, no. 2, 2006, pages 179 - 183, XP025142525 * |
See also references of EP2127733A4 |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013066877A (ja) * | 2011-09-26 | 2013-04-18 | Toshiba Corp | 減酸素素子、減酸素装置及び冷蔵庫 |
WO2017018482A1 (ja) * | 2015-07-28 | 2017-02-02 | 北川工業株式会社 | 逆浸透膜の製造方法 |
JP2017064692A (ja) * | 2015-07-28 | 2017-04-06 | 北川工業株式会社 | 逆浸透膜の製造方法 |
KR20180023964A (ko) * | 2015-07-28 | 2018-03-07 | 키타가와고우교가부시끼가이샤 | 역침투막의 제조 방법 |
CN107847877A (zh) * | 2015-07-28 | 2018-03-27 | 北川工业株式会社 | 反渗透膜的制造方法 |
KR101981644B1 (ko) | 2015-07-28 | 2019-05-23 | 키타가와고우교가부시끼가이샤 | 역침투막의 제조 방법 |
US10751668B2 (en) | 2015-07-28 | 2020-08-25 | Kitagawa Industries Co., Ltd. | Method of forming reverse osmosis membrane |
WO2018212338A1 (ja) * | 2017-05-18 | 2018-11-22 | 公益財団法人地球環境産業技術研究機構 | 多孔質構造体 |
JP2021018164A (ja) * | 2019-07-22 | 2021-02-15 | 株式会社住化分析センター | ガス透過セル、ガス透過度測定方法、及びガス透過度測定装置 |
JP7293022B2 (ja) | 2019-07-22 | 2023-06-19 | 株式会社住化分析センター | ガス透過セル、ガス透過度測定方法、及びガス透過度測定装置 |
Also Published As
Publication number | Publication date |
---|---|
US20100083836A1 (en) | 2010-04-08 |
JP5363121B2 (ja) | 2013-12-11 |
US8147596B2 (en) | 2012-04-03 |
JPWO2008081855A1 (ja) | 2010-04-30 |
EP2127733A1 (en) | 2009-12-02 |
EP2127733B1 (en) | 2013-07-03 |
EP2127733A4 (en) | 2012-12-05 |
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