WO2008053897A1 - Conducteur à fils et son procédé de fabrication - Google Patents
Conducteur à fils et son procédé de fabrication Download PDFInfo
- Publication number
- WO2008053897A1 WO2008053897A1 PCT/JP2007/071142 JP2007071142W WO2008053897A1 WO 2008053897 A1 WO2008053897 A1 WO 2008053897A1 JP 2007071142 W JP2007071142 W JP 2007071142W WO 2008053897 A1 WO2008053897 A1 WO 2008053897A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- wire conductor
- wire
- heat treatment
- less
- electric wire
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/02—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
- H01B1/023—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/60—Continuous furnaces for strip or wire with induction heating
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/02—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working in inert or controlled atmosphere or vacuum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Definitions
- the present invention relates to an electric wire conductor and a method for manufacturing the electric wire conductor, and more particularly to an electric wire conductor suitably used for an automobile electric wire and a method for manufacturing the electric wire conductor.
- an aluminum electric wire having a conductor wire made of an aluminum-based material has been used because of its light weight and excellent electrical conductivity.
- copper wires with conductor wires made of copper-based materials with excellent electrical conductivity are used as signal wires and power wires!
- Japanese Patent Publication No. 2004-134212 discloses an electric wire for an automobile made of an Al—Mg—Si based aluminum alloy.
- Fe 0. 6 weight 0/0 less
- Si 0. 2 ⁇
- Mg 0. 2 ⁇
- the problem to be solved by the present invention is to provide a wire conductor excellent in tensile strength, elongation at break, impact resistance, conductivity, and fatigue resistance, and a method for producing the same.
- the aluminum alloy is further selected from Fe, Cu, Cr and Mn
- One or two or more kinds may be contained in a total amount of 0.5% by mass or less.
- the aluminum alloy may further contain one or more selected from Ti500ppm or less and B50ppm or less.
- the wire conductor can be suitably used for a cross-sectional area of 0.75 mm 2 or less.
- the solution treatment temperature of the stranded wire is preferably 500 to 580 ° C, and the aging heat treatment temperature is preferably 150 to 220 ° C.
- the heating during the solution treatment is preferably by high-frequency heating.
- the wire constituting the electric wire conductor is made of the above-mentioned specific range of A 1 Mg-Si based aluminum alloy, the electric wire conductor has a tensile strength of 240 MPa or more, and an elongation at break S10 %, Absorption shock energy is 8j / m or more, and conductivity is 40% IACS or more, so it has excellent tensile strength, elongation at break, impact resistance, conductivity, fatigue resistance, and can be applied to small-diameter wires. Become.
- the aluminum alloy force is further selected from Fe, Cu, Cr and Mn
- the strength of the wire conductor is further improved.
- the aluminum alloy strength further contains one or more selected from Ti500ppm or less and B50ppm or less, the strength and elongation of the wire conductor is further improved. This is presumably because the crystal structure is refined.
- the cross-sectional area of the wire conductor can be used for 0.75 mm 2 or less, the range of application of the aluminum wire is widened, and the ability to reduce the weight of the wire in the field of automobiles and the like. Touch with S.
- the wire conductor is subjected to a solution treatment after forming a stranded wire from the aluminum alloy wire, whereby the wire conductor absorbs impact energy due to recovery of elongation.
- the amount is improved.
- the strength can be improved by precipitation strengthening and the conductivity can be improved by decreasing the amount of solid solution elements. As a result, the tensile strength, elongation at break, impact resistance, conductivity, and fatigue resistance are excellent.
- the solution treatment is performed by high-frequency heating, local heating can be performed, so that the cooling area can be arranged immediately after the heating area.
- the heat capacity is small, such as an electric wire
- it can be rapidly cooled after the solution treatment.
- it since it becomes possible to continuously heat and cool, it is particularly suitable for long objects such as electric wires.
- the electric wire conductor according to the present invention is formed by twisting a plurality of aluminum alloy strands containing Si and Mg, the balance being substantially A1 and unavoidable impurities, and the tensile strength of the electric wire conductor is 240 MPa.
- the elongation at break is 10% or more
- the absorbed impact energy is 8j / m or more
- the conductivity is 40% IACS or more.
- Si is bonded to Mg, and Mg Si particles and the like are finely precipitated in the A1 matrix to form aluminum.
- the Si content should be 0.3 to 1.2%.
- the Si content is less than 0.3%, the tensile strength of the wire conductor, which has a small strength improvement effect, is difficult to exceed 240 MPa.
- the Si content exceeds 1.2%, the conductivity is difficult to reach 40% IACS or higher.
- Mg combines with Si to precipitate Mg Si particles, etc. finely in the A1 matrix
- Mg / Si 0.8 ⁇ ; More preferably, l. 0 ⁇ ; If Mg / Si is less than 0.8, the amount of Mg Si compound decreases, so the strength of the aluminum alloy wire
- the tensile strength of electric wire conductors with little improvement effect is difficult to exceed 240 MPa.
- the elongation at break is less than 10% and the absorbed impact energy is less than 8j / m due to the influence of excess Si crystallization.
- Mg / Si exceeds 1.8, the solid Mg content increases, so it is difficult to achieve a conductivity of 0% IACS or more.
- the aluminum alloy constituting the wire conductor according to the present invention may further contain one or more selected from Fe, Cu, Cr and Mn in addition to the above-described constituent elements. These additive elements contribute to increasing the strength of the aluminum alloy strand. In order to obtain the effect, the total content is preferably 0.5% or less. Further, it is preferable to use two or less additive elements. If the amount of these additive elements is large, the elongation at break and the impact energy are reduced. This is because there is a decrease in the amount of absorption and an increase in the conductor resistance! /, Easy! /.
- the wire conductor according to the present invention may further include one or more selected from Ti and B forces in addition to the above-described constituent elements.
- These additive elements have the effect of refining the crystal structure and contribute to increasing the strength and elongation of the aluminum alloy wire.
- Ti is preferably 500 ppm or less and B is 50 ppm or less. This is because if the amount of these additive elements is large, it is easy to increase the conductor resistance.
- the electric wire conductor according to the present invention is excellent in tensile strength, elongation at break, impact resistance, electrical conductivity, and fatigue resistance, and therefore can be suitably used for small-diameter electric wires.
- the conductor preferably has a cross-sectional area of 0.75 mm 2 or less, more preferably 0.22 to 0.75 mm 2 . As a result, the range of application of the anoremi wire is expanded, and the weight of the wire can be reduced in the field of automobiles and the like.
- the electric wire conductor may be a compressed conductor.
- the method for producing an electric wire conductor according to an embodiment includes the above-described alloy composition, a stranded wire process in which a plurality of aluminum alloy strands are twisted together to form a stranded wire, and a solution treatment of the stranded wire, followed by rapid cooling. And an aging heat treatment step.
- the molten alloy is forged with a continuous forging machine to produce a cast bar.
- a wire rod is produced with a hot rolling mill connected to the tandem with a boil.
- the wire rod may be manufactured by the continuous forging and rolling method described above, or by the billet forging-extrusion method. In the case of billet forging-extrusion, it is desirable to perform homogenization after billet forging. It is effective to add Ti and B as finening agents immediately before forging.
- the wire is drawn until a desired strand diameter is obtained by wire drawing.
- a softening treatment may be appropriately performed.
- the electric wire thus produced is twisted into a desired number in a twisting step to form a twisted wire. After forming a stranded wire, it undergoes a heat treatment step.
- the heating temperature during the solution treatment is preferably 500 to 580 ° C. Melting The Mg Si compound in the aluminum alloy is formed into a solution by the solution treatment. Below 500 ° C
- Quenching may be performed with cooling water or the like!
- the alloy is in a state of solid solution without precipitating the Mg Si compound that has been dissolved in the alloy by solution treatment by rapid cooling.
- the solution treatment and rapid cooling may be performed by a method in which a continuous softening machine provided with a cooling water tank is heated to a predetermined temperature in a heating unit and passed through a continuous cooling water tank.
- the continuous softening machine may be any of an energizing continuous softening machine, a pipe continuous softening machine, and a high-frequency continuous softening machine. Particularly preferred is a high-frequency continuous softening machine.
- a high-frequency continuous softening machine is used, since the solution treatment is performed by high-frequency heating, local heating is possible. Thereby, the cooling area can be arranged immediately after the heating area.
- a structural member with a large heat capacity can be maintained at a high temperature even after heating is stopped.
- a small heat capacity such as an electric wire
- when heating is stopped cooling begins immediately.
- the cooling area can be arranged immediately after the heating area, even if it has a small heat capacity and is likely to start slow cooling when the heating is stopped, it is possible to quickly cool it in the high temperature state. it can.
- the cooling area can be arranged immediately after the heating area, it becomes possible to continuously heat and quench, so that it is particularly suitable for a long object such as an electric wire. And by continuously heating and cooling, the productivity of the wire conductor is improved.
- the Mg Si compound dissolved in the alloy can be precipitated by solution treatment and rapid cooling. This gives strength and conductivity
- the aging heat treatment temperature is preferably 150 ° C to 220 ° C. Also when The effective heat treatment time is preferably 4 to 20 hours.
- the Mg Si compound is likely to grow into coarse grains after precipitation, so that it is difficult to obtain the strength improvement effect.
- the resistance of the conductor which is difficult to obtain the effect of improving the strength, tends to increase.
- the precipitated Mg Si compound tends to grow into coarse grains, which improves strength.
- the aging heat treatment is preferably performed in a state where the wire conductor is wound around a reel. Possible force even in air In order to avoid surface oxidation, it is preferable to carry out in a reducing gas atmosphere or an inert gas atmosphere.
- the performance of the electric wire conductor according to the present invention can be obtained by the manufacturing method described above. And if the electric wire conductor obtained in this way is coat
- a cast bar was produced by forging the molten alloy melt with a continuous forging machine so that the alloy composition shown in Table 1 was obtained.
- a ⁇ 9.5 mm wire rod was produced by a hot rolling mill, and the obtained wire rod was cold-drawn to produce a 0.26 mm wire.
- seven wire strands were twisted to form a stranded wire. Thereafter, solution treatment, cooling, and aging heat treatment were performed under the conditions shown in Table 1 to obtain electric wire conductors.
- Wire conductors were obtained in the same manner as in the Examples with the alloy compositions and conditions shown in Table 1.
- wire conductors were obtained in the same manner as in the Examples, except that solution treatment, cooling, and aging heat treatment were not performed.
- a weight was attached to the tip of the wire conductor with a distance of lm between the grades, lifted upwards by lm, dropped free, and W (j / m) when the maximum weight weight at which the wire did not break was W (N).
- An impact energy absorption of 8 j / m or more before fracture was considered acceptable.
- the aluminum alloy constituting the wire conductor is SiO.
- the tensile strength is less than 240 MPa
- the aging heat treatment temperature exceeds 220 ° C
- the heat treatment time is 20 hours.
- the tensile strength was less than 240 MPa.
- a force that is indicated by a wire conductor formed by twisting seven wire strands! / is not particularly limited to this.
- the electric wire conductor according to the present invention is suitably used for, for example, an automobile electric wire.
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE112007002585.9T DE112007002585B4 (de) | 2006-10-30 | 2007-10-30 | Verfahren zur Herstellung eines Leiters und Leiter |
US12/312,033 US8278555B2 (en) | 2006-10-30 | 2007-10-30 | Electric wire conductor and a method of producing the same |
CN2007800407637A CN101536112B (zh) | 2006-10-30 | 2007-10-30 | 电线导体及其制造方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006294130A JP5128109B2 (ja) | 2006-10-30 | 2006-10-30 | 電線導体およびその製造方法 |
JP2006-294130 | 2006-10-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008053897A1 true WO2008053897A1 (fr) | 2008-05-08 |
Family
ID=39344238
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2007/071142 WO2008053897A1 (fr) | 2006-10-30 | 2007-10-30 | Conducteur à fils et son procédé de fabrication |
Country Status (5)
Country | Link |
---|---|
US (1) | US8278555B2 (ja) |
JP (1) | JP5128109B2 (ja) |
CN (2) | CN101536112B (ja) |
DE (1) | DE112007002585B4 (ja) |
WO (1) | WO2008053897A1 (ja) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011052644A1 (ja) * | 2009-10-30 | 2011-05-05 | 住友電気工業株式会社 | アルミニウム合金線 |
JP2011219838A (ja) * | 2010-04-13 | 2011-11-04 | Motoki Saito | アルミニウム合金製品の製造方法 |
CN102456442A (zh) * | 2010-10-26 | 2012-05-16 | 上海中天铝线有限公司 | 导电率为57%的中强度铝合金线的制造方法 |
WO2012141041A1 (ja) * | 2011-04-11 | 2012-10-18 | 住友電気工業株式会社 | アルミニウム合金線およびそれを用いたアルミニウム合金撚り線、被覆電線、ワイヤーハーネス |
JP2013076168A (ja) * | 2011-04-11 | 2013-04-25 | Sumitomo Electric Ind Ltd | アルミニウム合金線、アルミニウム合金撚り線、被覆電線、及びワイヤーハーネス |
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NO346538B1 (no) * | 2008-07-25 | 2022-09-26 | Technip France Sa | Umbilical |
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JP2020186450A (ja) * | 2019-05-16 | 2020-11-19 | 株式会社フジクラ | アルミニウム合金撚線の製造方法、これを用いた電線の製造方法及びワイヤハーネスの製造方法 |
JP2020186449A (ja) * | 2019-05-16 | 2020-11-19 | 株式会社フジクラ | アルミニウム合金導電線の製造方法、これを用いた電線の製造方法及びワイヤハーネスの製造方法 |
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JP2016108603A (ja) * | 2014-12-05 | 2016-06-20 | 矢崎総業株式会社 | アルミニウム合金電線及びそれを用いたワイヤーハーネス |
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CN115948684A (zh) * | 2022-12-21 | 2023-04-11 | 广东领胜新材料科技有限公司 | 一种高强度高导电率铝合金导线及其制造方法 |
Also Published As
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JP2008112620A (ja) | 2008-05-15 |
CN102360589A (zh) | 2012-02-22 |
JP5128109B2 (ja) | 2013-01-23 |
DE112007002585T5 (de) | 2009-10-15 |
DE112007002585B4 (de) | 2018-05-09 |
CN101536112A (zh) | 2009-09-16 |
US20100071933A1 (en) | 2010-03-25 |
CN101536112B (zh) | 2011-10-19 |
US8278555B2 (en) | 2012-10-02 |
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