WO2007145095A1 - 布帛への樹脂加工に使用するドクターブレード及びそれを使用した樹脂加工法 - Google Patents
布帛への樹脂加工に使用するドクターブレード及びそれを使用した樹脂加工法 Download PDFInfo
- Publication number
- WO2007145095A1 WO2007145095A1 PCT/JP2007/061305 JP2007061305W WO2007145095A1 WO 2007145095 A1 WO2007145095 A1 WO 2007145095A1 JP 2007061305 W JP2007061305 W JP 2007061305W WO 2007145095 A1 WO2007145095 A1 WO 2007145095A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fabric
- water
- blade
- resin
- resin composition
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
- B05C11/02—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
- B05C11/04—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface with blades
- B05C11/045—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface with blades characterised by the blades themselves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
- B05C11/02—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
- B05C11/04—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface with blades
- B05C11/048—Scrapers, i.e. metering blades having their edge oriented in the upstream direction in order to provide a reverse angle of attack
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
- D06B1/04—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by pouring or allowing to flow on to the surface of the textile material
- D06B1/06—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by pouring or allowing to flow on to the surface of the textile material flowing along an inclined surface
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
- D06B1/10—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material
- D06B1/12—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material by rubbing contact, e.g. with brushes or pads
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
- D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/02—Moisture-responsive characteristics
- D10B2401/021—Moisture-responsive characteristics hydrophobic
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2164—Coating or impregnation specified as water repellent
Definitions
- the present invention relates to a doctor blade capable of efficiently performing resin processing only on the surface of a fabric, and a resin processing method using the doctor blade.
- Patent Document 1 discloses that only a surface layer on one side of a woven or knitted fabric is used.
- a water-repellent agent By applying a water-repellent agent, it is disclosed that an unevenly-absorbent woven or knitted fabric for innerwear having water repellency only on the front surface and water absorption on the back side is disclosed.
- a method of applying the water repellent by a spray method to the interlock knitted fabric of 100% 2 cotton a method of co one coating water repellent agent at a reverse roll coater basis weight 2 50GZm polyester textured yarn of 100% plain weave fabric of 2 Is disclosed.
- Patent Document 2 as a method for imparting water absorption only to one side of the fabric, a water absorbing agent is applied to an interlock knitted fabric having a polyester force of 200 gZm 2 per unit area in Example 1 and having a basis weight of 200 gZm 2 .
- method of printing a method of coating the water-absorbing agent 3% solution plain weave fabric having a basis weight of 240 g Zm 2 which also blended yarn strength of the polyester-cotton is disclosed in example 2.
- Patent Document 3 discloses that a water repellent agent is applied to one surface of a fabric by a roller printing method, and only a convex surface portion of one surface of the fabric is subjected to a water repellent treatment.
- the example is eye with 130gZm 2 of 100% cotton jersey knit fabric, jersey knit fabric having a basis weight of 1 40gZm 2 also made cotton Z polyester blended yarn force is being used.
- Patent Document 4 discloses a force that discloses applying a water repellent only to the surface of a fabric with a floating knife coater. As shown in the drawing, the doctor blade used therein is an ordinary flat plate. Yes, if we are going to apply grease to a thin fabric, it is difficult to apply resin to only one side of the resin.
- Patent Document 1 Japanese Patent Laid-Open No. 56-144272
- Patent Document 2 JP-A-58-220873
- Patent Document 3 Japanese Patent Publication No. 1-53394
- Patent Document 4 Japanese Patent Publication No. 2004-523673
- the present invention provides a novel doctor blade and a resin processing method capable of reliably processing a resin only on one side even for a thin fabric having a basis weight of 120 gZm 2 or less, particularly 60 gZm 2 or less.
- the task is to do.
- the present inventor has studied the shape of the doctor blade in various ways, and by making the doctor blade into a special shape, the floating knife coater reliably processes the resin even on the surface of a very thin fabric without passing through it. We found that it was possible to solve this problem.
- doctor blade of the present invention and the coating method using the doctor blade (grease calcining method) are as follows.
- the lower part of the blade is bent and inclined, the resin composition is supplied onto the inclined surface of the blade, the cloth is moved from the tip side of the blade to the blade body side, and the surface of the cloth is coated with the resin composition.
- a doctor blade for resin processing wherein the lower part of the blade has a width of 2 to 12 cm and is bent so as to be inclined at an angle of 110 to 160 degrees with respect to the upper blade body. Doctor blade.
- the above-mentioned fabric is a woven fabric, a knitted fabric or a non-woven fabric having poor water absorption, and has a viscosity of S3000 to 6000 cps (preferably ⁇ 3500 to 5000 cps). .
- (10) It consists of a water-absorbing fabric having a basis weight of less than 130 gZm 2 and is obtained by applying a water repellent only to one side of the fabric by the resin processing method of (3) above, only on one side Resin-treated cloth with water repellency and water absorption on the other side.
- a water-absorbent fabric cover having a basis weight of 100 to 450 gZm 2 is also obtained, which is obtained by applying a water repellent to both the front and back sides of the fabric by the resin processing method of (3) above.
- the front and back surfaces have water repellency.
- the inner layer is a resin-treated cloth with water absorption.
- the doctor blade of the present invention may have any width and length similar to those used in a normal coating method, but the lower side of the doctor blade, that is, the side in contact with the workpiece fabric.
- the resin rotates in a columnar shape on the fabric to be processed at the tip of the inclined surface.
- the fabric to be processed is an ultra-thin fabric with a basis weight of less than 30 g / m 2 and 60 gZm 2 or less, uniform resin processing is applied only to the surface that does not pass through. It makes it possible.
- the lower width inclined by the blade may be about 2 to 12 cm, but is usually preferably about 3.5 to 9 cm.
- the bending angle below the blade body with respect to the blade body may be 110 to 160 degrees (preferably about 120 to 150 degrees).
- the cloth is subjected to resin processing (coating) by moving the force at the blade tip side toward the blade body while the tip of the blade to be applied is applied to the fabric.
- the lower tip of the blade may be further deformed depending on the type of fabric to be processed and the viscosity of the resin composition used.
- the lower tip of the blade is 3 to: LOmm wide, and the blade When the blade is placed at a position where the blade body is perpendicular to the fabric to be processed, the blade tip is 90 to 20 with respect to the fabric to be processed. You may make it contact
- the tip of the blade can be inclined and the resin composition for resin processing can be supplied from above, the resin composition (at the time of resin processing (coating)) (The refining liquid or paste) rotates in a columnar shape at the point of contact with the fabric at the tip of the inclined blade, uniformly and efficiently contacts the entire width of the fabric, and enables coating of a thin film without unevenness.
- a woven fabric, a knitted fabric or a non-woven fabric having water absorption is used as a fabric that is preferably processed with a floating knife coater using a water-based emulsion composition comprising a water-based emulsion, the resin composition
- the viscosity of is preferably 15000 cps or more.
- the woven fabric, knitted fabric or non-woven fabric having water absorbability may be a fiber having inherently water absorbency, such as cellulosic fibers, but the water absorbency is poor. It may be treated and given water absorption.
- any resin composition may be used, but those composed of a water-repellent agent such as silicone or fluorine can be applied very efficiently.
- the viscosity of the resin composition is preferably 3000 to 5000 cps.
- a water-absorbent fabric that has been subjected to a water-repellent treatment in advance. In this case, it can be effectively applied to the application of a water-repellent resin composition on one side.
- both sides are coated with a water repellent, and both sides have water repellency, but the inner layer has water absorption. It is also possible to finish such a product.
- a relatively thick fabric such as a basis weight of lOOgZm 2 or more, for example, 200 gZm 2 or 400 gZm 2
- both sides are coated with a water repellent, and both sides have water repellency, but the inner layer has water absorption. It is also possible to finish such a product.
- Such a surface water-repellent processed fabric is a layer having a water-absorbing property immediately under the water-repellent surface due to a capillary phenomenon that prevents water droplets from spreading on the surface having water-repellent properties. Absorbed into 'diffused. Therefore, when clothing is manufactured using this surface-layer water-repellent fabric, the sweat is transferred to another layer as soon as it remains on the skin surface by making the water-repellent surface inside and touching the skin. Therefore, it is possible to always keep the surface that touches the skin refreshing.
- the surface layer water-repellent fabric used in clothing is provided with a water-repellent agent only on one side of the fabric, it gives water repellency to both sides of the fabric and the inner layer has water-absorbing properties. It may be what you did.
- a water-absorbing fabric having a basis weight of about 80 to 300 gZm 2 is used, and the water repellent agent may be applied as long as one side has water repellency and the other side has water absorption.
- a water-absorbing fabric having a basis weight of about 100 to 450 gZm 2 and preferably about 130 to 400 g Zm 2 is used, and both surfaces of the fabric have water repellency.
- the intermediate layer may have water absorbency. .
- this processed fabric sweat is quickly absorbed by the water-absorbing intermediate layer from the inner water-repellent surface that touches the skin and diffused there, but the surface layer also has water-repellent properties, so that the surface absorbs water.
- the perspired sweat does not ooze out. Therefore, the garment manufactured with this processed fabric not only keeps the surface that touches the skin always fresh, but also keeps the surface refreshing to prevent the appearance of sweat on the surface.
- the air permeability is not lowered by the water-repellent processing, so that the drying is also good.
- the water-absorbent fabric may be a natural fiber as long as it has a fiber strength that causes wettability with water, or may be made of a chemical fiber. (Cotton, hemp, rayon, etc.) or cellulose fiber-based blends, woven or knitted fabrics that are preferred to use cellulose fiber
- FIG. 1 is an explanatory view showing an example of a resin processing method of the present invention.
- FIG. 2 is a side view illustrating a doctor blade of the present invention.
- FIG. 3 is an explanatory view illustrating the resin processing method of the present invention.
- FIG. 4 is an enlarged cross-sectional view showing an example of a processed fabric obtained by the present invention.
- the resin processing is preferably performed with a floating knife coater that floats the fabric 2 in the air at a position where the doctor blade 1 contacts as shown in FIG.
- doctor blade 1 for example, as illustrated in FIG. 2, a downward force of a flat doctor blade that is inclined forward at an angle of 110 to 160 degrees with respect to the blade body should be used.
- the tip of this blade is folded at an angle of 50 to 150 degrees backward with respect to the lower part of the blade depending on the purpose of the resin processing. It may be bent.
- the blade 1 in FIG. 2 (a) is made of a flat steel plate having a width of 95 mm, a length of 2000 mm, and a thickness of 2 mm.
- the lower portion 3 having a width of 75 mm is compared with the upper portion 4 having a width of 20 mm. Is bent forward at an angle of 135 degrees,
- Blade 1 in Fig. 2 (b) is made of flat steel with a width of 85 mm, a length of 2000 mm, and a thickness of 2 mm.
- the lower part 3 is at the front at an angle of 135 degrees with respect to the upper part 4 with a width of 30 mm.
- the tip portion 5 of the lower portion 3 is 5 mm wide and is bent backward so as to form an angle of 135 degrees with respect to the lower portion body (this tip portion). 5 is parallel to the upper part 4),
- the blade 1 in FIG. 2 (c) is made of a flat steel plate having a width of 85 mm, a length of 2000 mm, and a thickness of 2 mm.
- the lower portion 3 is at an angle of 135 degrees with respect to the upper portion 4 having a width of 30 mm. Bent forward, the tip 5 of the lower part 3 is 5 mm wide and bent backwards at an angle of 85 degrees with respect to the lower part body,
- the blade 1 in FIG. 2 (d) is made of a flat steel plate having a width of 85 mm, a length of 2000 mm, and a thickness of 2 mm.
- the lower portion 3 is at an angle of 135 degrees with respect to the upper portion 4 having a width of 30 mm.
- the front end 5 of the lower portion 3 is bent 5 mm wide and is bent rearward so as to form an angle of 68 degrees with respect to the lower portion main body.
- these blades 1 are such that the tip 2 of the blade 1 is in contact with the fabric 2 that is fed in the direction of the arrow as shown in FIG. Is thinly coated on fabric 2.
- the resin composition 6 rotates clockwise over the entire tip 5 of the blade 1 as shown in FIG. Evenly, it touches the fabric 2 and enables a thin and high-quality coating.
- the coating force is usually used when the fabric 2 is transported in the horizontal state as shown in Fig. 3A while the fabric 2 is coated with ultra thin fabric. 2 to 3: about LO degree It may be coated while being transferred while being inclined upward. In the latter case, as shown in FIG. 2 (a), it is preferable to use the one whose front end portion is bent backward (only the lower portion 3 is bent forward).
- the powerful coating method of the present invention as shown in FIG. 4, even if the fabric 2 is water-absorbing, even the very thin fabric 2 gives water repellency only to the surface, and the water-absorbing portion 7 And a processed fabric excellent in functionality in which the water repellent portion 8 coexists.
- a water repellent resin composition using fluorine-based resin (Teflon 'registered trademark) was prepared, and the following method was carried out.
- a cloth cotton pant fabric ⁇ 200 8 ⁇ 2
- a 6000-6500 cps viscosity resin composition by the method of A of Fig. 3 using the blade of Fig. 2 (b), Dried and heat treated.
- a water-absorbing product that is inherent to cotton on the back surface (see A in Fig. 4).
- a cloth cotton shirt fabric with a basis weight of 120gZm 2
- a rosin composition having a viscosity of 15000cps by the method of A in Fig. 3 using the blade in Fig. 2 (b), and then dried and heat-treated. did.
- Resin processing was performed on a water-repellently processed fabric using an acrylic resin composition for waterproofing that is usually used for an umbrella.
- Polyester organdy (weighing: 40gZm 2 ) is treated with water repellent, and then a resin composition with a viscosity of 3500-4000cps is applied by the method shown in Fig. 3A using the blade shown in Fig. 2 (b). Fat processed.
- the resin composition does not come out to the surface, and one side that has the original texture of the fabric has a water repellent and excellent waterproof property. I was able to.
- a resin composition with a viscosity of 4000-5000cps is applied to the resin by the method of Fig. 3A using the blade of Fig. 2 (c). processed.
- the resin composition forms a resin layer with a thickness of about 2Z3 of the fabric, and one side can obtain an excellent waterproof fabric with a water repellent state that has the original texture of the fabric. did it
- the viscosity shown in the present application is a value measured with a Piscotester VT-04F manufactured by RION at room temperature (about 25 ° C).
- the product of 1) was sewn into sports shorts with the surface having water repellency located on the side touching the skin. Wearing this shorts and jogging, even if you sweat, sweat is absorbed and diffused to the surface side with water absorption immediately without wetting the shorts inside, so the inside of the shorts will always be in a dry state, Kept very comfortable.
- the surface layer water-repellent fabric thus obtained has water repellency on the outside, but the surface is located. I finished it in a long-sleeved shirt.
- the surface moisture repellent fabric according to the present invention was compared with the shirt B, which was sewn with a product that had been subjected to water repellent finish on the same fabric in a general manner when the shirt A was worn.
- the Shirt A which is powerful, keeps comfortable between the clothes and the skin when resting and exercising, and the humidity (absolute humidity) in the clothes is practical even after exercise.
- the temperature dropped to a comfortable humidity of 25 mmHg or less in a few minutes without exceeding 30 mmHg.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Treatment Of Fiber Materials (AREA)
- Coating Apparatus (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/304,574 US20090170390A1 (en) | 2006-06-16 | 2007-06-04 | Doctor Blade Used For Resin Finishing On A Cloth And Method For Resin Finishing With Use Of It |
CN2007800299149A CN101501264B (zh) | 2006-06-16 | 2007-06-04 | 布的树脂加工中使用的刮刀以及使用该刮刀的树脂加工方法 |
EP20070744664 EP2042637B1 (en) | 2006-06-16 | 2007-06-04 | Knife coater comprising a doctor blade for use in resin finishing on cloth and method of resin finishing |
HK10101119A HK1134119A1 (en) | 2006-06-16 | 2010-02-02 | Doctor blade for use in resin finishing on cloth and method of resin finishing therewith |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006166793 | 2006-06-16 | ||
JP2006-166793 | 2006-06-16 | ||
JP2006-272382 | 2006-10-04 | ||
JP2006272382A JP3965416B1 (ja) | 2006-06-16 | 2006-10-04 | 布帛への樹脂加工に使用するドクターブレード及びそれを使用した樹脂加工法 |
Publications (1)
Publication Number | Publication Date |
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WO2007145095A1 true WO2007145095A1 (ja) | 2007-12-21 |
Family
ID=38498656
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2007/061305 WO2007145095A1 (ja) | 2006-06-16 | 2007-06-04 | 布帛への樹脂加工に使用するドクターブレード及びそれを使用した樹脂加工法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20090170390A1 (ja) |
EP (1) | EP2042637B1 (ja) |
JP (1) | JP3965416B1 (ja) |
KR (1) | KR20090025334A (ja) |
CN (1) | CN101501264B (ja) |
HK (1) | HK1134119A1 (ja) |
WO (1) | WO2007145095A1 (ja) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101317751B1 (ko) * | 2011-11-16 | 2013-10-11 | 박명수 | 신축성이 뛰어난 편물용 코팅 장치 |
KR101296225B1 (ko) * | 2011-11-21 | 2013-08-13 | 김창운 | 섬유원단의 양면에 보호피막을 형성하는 방법과 이에 의해 제조된 섬유원단 및 이를 위한 시스템 |
FI126700B (fi) * | 2014-11-18 | 2017-04-13 | Valmet Technologies Inc | Patoterä |
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Also Published As
Publication number | Publication date |
---|---|
EP2042637A1 (en) | 2009-04-01 |
CN101501264B (zh) | 2012-05-23 |
EP2042637A4 (en) | 2010-10-13 |
JP3965416B1 (ja) | 2007-08-29 |
CN101501264A (zh) | 2009-08-05 |
US20090170390A1 (en) | 2009-07-02 |
HK1134119A1 (en) | 2010-04-16 |
JP2009079305A (ja) | 2009-04-16 |
KR20090025334A (ko) | 2009-03-10 |
EP2042637B1 (en) | 2012-08-15 |
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