WO2007119762A1 - 水性塗料組成物 - Google Patents
水性塗料組成物 Download PDFInfo
- Publication number
- WO2007119762A1 WO2007119762A1 PCT/JP2007/058022 JP2007058022W WO2007119762A1 WO 2007119762 A1 WO2007119762 A1 WO 2007119762A1 JP 2007058022 W JP2007058022 W JP 2007058022W WO 2007119762 A1 WO2007119762 A1 WO 2007119762A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mass
- polymerizable unsaturated
- resin
- parts
- coating composition
- Prior art date
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 68
- 239000000178 monomer Substances 0.000 claims abstract description 123
- 229920005989 resin Polymers 0.000 claims abstract description 100
- 239000011347 resin Substances 0.000 claims abstract description 100
- 238000000576 coating method Methods 0.000 claims abstract description 95
- 239000011248 coating agent Substances 0.000 claims abstract description 84
- -1 vinyl aromatic compound Chemical class 0.000 claims abstract description 78
- 239000000839 emulsion Substances 0.000 claims abstract description 64
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 63
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 51
- 229920001577 copolymer Polymers 0.000 claims abstract description 37
- 239000004640 Melamine resin Substances 0.000 claims abstract description 35
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 27
- 239000002904 solvent Substances 0.000 claims abstract description 25
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 90
- 239000003973 paint Substances 0.000 claims description 62
- 239000000203 mixture Substances 0.000 claims description 45
- 239000007787 solid Substances 0.000 claims description 33
- 239000000049 pigment Substances 0.000 claims description 32
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 26
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 21
- 229920001225 polyester resin Polymers 0.000 claims description 19
- 239000004645 polyester resin Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 150000001491 aromatic compounds Chemical class 0.000 claims description 5
- 239000010419 fine particle Substances 0.000 claims description 5
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 241000239366 Euphausiacea Species 0.000 claims 1
- 241000543375 Sideroxylon Species 0.000 claims 1
- 229910052614 beryl Inorganic materials 0.000 claims 1
- 244000309464 bull Species 0.000 claims 1
- 238000004581 coalescence Methods 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 8
- 239000002932 luster Substances 0.000 abstract description 2
- 239000002562 thickening agent Substances 0.000 description 35
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 33
- 150000001875 compounds Chemical class 0.000 description 23
- 238000004519 manufacturing process Methods 0.000 description 21
- 238000010438 heat treatment Methods 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- 239000000047 product Substances 0.000 description 12
- 239000012736 aqueous medium Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 229920001228 polyisocyanate Polymers 0.000 description 10
- 239000005056 polyisocyanate Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000004925 Acrylic resin Substances 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 150000003863 ammonium salts Chemical class 0.000 description 8
- 125000003700 epoxy group Chemical group 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 8
- 239000003505 polymerization initiator Substances 0.000 description 8
- 229920000178 Acrylic resin Polymers 0.000 description 7
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- 229920001187 thermosetting polymer Polymers 0.000 description 6
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 5
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 5
- WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000012874 anionic emulsifier Substances 0.000 description 5
- 239000012141 concentrate Substances 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- 150000003460 sulfonic acids Chemical class 0.000 description 5
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- KBPLFHHGFOOTCA-UHFFFAOYSA-N caprylic alcohol Natural products CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 3
- 239000005456 alcohol based solvent Substances 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 3
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 3
- 229920003180 amino resin Polymers 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 3
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000010445 mica Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000004584 polyacrylic acid Substances 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- JLIDVCMBCGBIEY-UHFFFAOYSA-N 1-penten-3-one Chemical compound CCC(=O)C=C JLIDVCMBCGBIEY-UHFFFAOYSA-N 0.000 description 2
- STFXXRRQKFUYEU-UHFFFAOYSA-N 16-methylheptadecyl prop-2-enoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)C=C STFXXRRQKFUYEU-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 102000011632 Caseins Human genes 0.000 description 2
- 108010076119 Caseins Proteins 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 239000012965 benzophenone Substances 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000010960 cold rolled steel Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
- PSZLOSABHFZLDK-VOTSOKGWSA-N (e)-n-(2,2,6,6-tetramethylpiperidin-4-yl)but-2-enamide Chemical compound C\C=C\C(=O)NC1CC(C)(C)NC(C)(C)C1 PSZLOSABHFZLDK-VOTSOKGWSA-N 0.000 description 1
- YAXWOADCWUUUNX-UHFFFAOYSA-N 1,2,2,3-tetramethylpiperidine Chemical compound CC1CCCN(C)C1(C)C YAXWOADCWUUUNX-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- LHENQXAPVKABON-UHFFFAOYSA-N 1-methoxypropan-1-ol Chemical compound CCC(O)OC LHENQXAPVKABON-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- PAMIQIKDUOTOBW-UHFFFAOYSA-N 1-methylpiperidine Chemical compound CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- KCZIRQGMWBGPRP-UHFFFAOYSA-N 2-(2-hydroxyacetyl)oxyethyl 2-hydroxyacetate Chemical compound OCC(=O)OCCOC(=O)CO KCZIRQGMWBGPRP-UHFFFAOYSA-N 0.000 description 1
- PRAMZQXXPOLCIY-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethanesulfonic acid Chemical compound CC(=C)C(=O)OCCS(O)(=O)=O PRAMZQXXPOLCIY-UHFFFAOYSA-N 0.000 description 1
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical group CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical compound CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 description 1
- QGVQOXWNOSEKGM-UHFFFAOYSA-N 2-hydroxyacetic acid;prop-1-ene Chemical compound CC=C.OCC(O)=O QGVQOXWNOSEKGM-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- MDZCXYVALWXHCJ-UHFFFAOYSA-N 2-tert-butylperoxy-2-methylpropane octanoic acid Chemical compound C(CCCCCCC)(=O)O.C(C)(C)(C)OOC(C)(C)C MDZCXYVALWXHCJ-UHFFFAOYSA-N 0.000 description 1
- XYFRHHAYSXIKGH-UHFFFAOYSA-N 3-(5-methoxy-2-methoxycarbonyl-1h-indol-3-yl)prop-2-enoic acid Chemical compound C1=C(OC)C=C2C(C=CC(O)=O)=C(C(=O)OC)NC2=C1 XYFRHHAYSXIKGH-UHFFFAOYSA-N 0.000 description 1
- FERWBXLFSBWTDE-UHFFFAOYSA-N 3-aminobutan-2-ol Chemical compound CC(N)C(C)O FERWBXLFSBWTDE-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N 3-phenylprop-2-enal Chemical compound O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 1
- CYUZOYPRAQASLN-UHFFFAOYSA-N 3-prop-2-enoyloxypropanoic acid Chemical compound OC(=O)CCOC(=O)C=C CYUZOYPRAQASLN-UHFFFAOYSA-N 0.000 description 1
- CPIVYSAVIPTCCX-UHFFFAOYSA-N 4-methylpentan-2-yl acetate Chemical compound CC(C)CC(C)OC(C)=O CPIVYSAVIPTCCX-UHFFFAOYSA-N 0.000 description 1
- ZPQAKYPOZRXKFA-UHFFFAOYSA-N 6-Undecanone Chemical compound CCCCCC(=O)CCCCC ZPQAKYPOZRXKFA-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- RYUGEIJYQVXTQF-QXMHVHEDSA-N C(=O)(C(=C)C)C(C(=O)O)CCCCCC\C=C/CCCCCCCC Chemical compound C(=O)(C(=C)C)C(C(=O)O)CCCCCC\C=C/CCCCCCCC RYUGEIJYQVXTQF-QXMHVHEDSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- XEUCQOBUZPQUMQ-UHFFFAOYSA-N Glycolone Chemical compound COC1=C(CC=C(C)C)C(=O)NC2=C1C=CC=C2OC XEUCQOBUZPQUMQ-UHFFFAOYSA-N 0.000 description 1
- UWIULCYKVGIOPW-UHFFFAOYSA-N Glycolone Natural products CCOC1=C(CC=CC)C(=O)N(C)c2c(O)cccc12 UWIULCYKVGIOPW-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- PWATWSYOIIXYMA-UHFFFAOYSA-N Pentylbenzene Chemical compound CCCCCC1=CC=CC=C1 PWATWSYOIIXYMA-UHFFFAOYSA-N 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- CEWXPUQWLIIXHM-UHFFFAOYSA-N [3-(2-benzoylphenoxy)-2-hydroxypropyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(O)COC1=CC=CC=C1C(=O)C1=CC=CC=C1 CEWXPUQWLIIXHM-UHFFFAOYSA-N 0.000 description 1
- AUNAPVYQLLNFOI-UHFFFAOYSA-L [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O Chemical compound [Pb++].[Pb++].[Pb++].[O-]S([O-])(=O)=O.[O-][Cr]([O-])(=O)=O.[O-][Mo]([O-])(=O)=O AUNAPVYQLLNFOI-UHFFFAOYSA-L 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005370 alkoxysilyl group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000746 allylic group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- ZDNFTNPFYCKVTB-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,4-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C=C1 ZDNFTNPFYCKVTB-UHFFFAOYSA-N 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- SXPLZNMUBFBFIA-UHFFFAOYSA-N butyl(trimethoxy)silane Chemical compound CCCC[Si](OC)(OC)OC SXPLZNMUBFBFIA-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 229940071162 caseinate Drugs 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- SPTHWAJJMLCAQF-UHFFFAOYSA-M ctk4f8481 Chemical compound [O-]O.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-M 0.000 description 1
- 150000001913 cyanates Chemical class 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 1
- 229940043276 diisopropanolamine Drugs 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000004698 iron complex Chemical class 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 description 1
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 1
- GWVMLCQWXVFZCN-UHFFFAOYSA-N isoindoline Chemical compound C1=CC=C2CNCC2=C1 GWVMLCQWXVFZCN-UHFFFAOYSA-N 0.000 description 1
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 125000005439 maleimidyl group Chemical group C1(C=CC(N1*)=O)=O 0.000 description 1
- 229910052914 metal silicate Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- RXTNIJMLAQNTEG-UHFFFAOYSA-N methylamyl acetate Natural products CCCCC(C)OC(C)=O RXTNIJMLAQNTEG-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- WSGCRAOTEDLMFQ-UHFFFAOYSA-N nonan-5-one Chemical compound CCCCC(=O)CCCC WSGCRAOTEDLMFQ-UHFFFAOYSA-N 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229910017059 organic montmorillonite Inorganic materials 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000007717 redox polymerization reaction Methods 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229940080237 sodium caseinate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- JZFHXRUVMKEOFG-UHFFFAOYSA-N tert-butyl dodecaneperoxoate Chemical compound CCCCCCCCCCCC(=O)OOC(C)(C)C JZFHXRUVMKEOFG-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- SSBBXKVCFFZKCZ-UHFFFAOYSA-N tert-butylperoxy propyl carbonate Chemical compound CCCOC(=O)OOOC(C)(C)C SSBBXKVCFFZKCZ-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08L61/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
- C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/06—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/36—Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/22—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L27/24—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers modified by chemical after-treatment halogenated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31547—Of polyisocyanurate
Definitions
- the present invention relates to an aqueous coating composition and a method for forming a coating film using the aqueous coating composition.
- melamine resin as a cross-linking agent is blended with base resin such as acrylic resin and polyester resin having a hydrophilic functional group such as hydroxyl group and carboxyl group as intermediate coating and top coating used for the coating of automotive outer panels.
- base resin such as acrylic resin
- polyester resin having a hydrophilic functional group such as hydroxyl group and carboxyl group
- hydrophilic functional group such as hydroxyl group and carboxyl group
- Many water-based paints are used.
- Japanese Patent Application Laid-Open No. 2000-093-93 discloses that specific talyl resin, hydrophobic melamine resin and polyester resin are heated under specific conditions. It is disclosed that the aqueous resin dispersion containing the reaction product obtained in this way is excellent in storage stability and can form a coating film excellent in finish, water resistance and the like. However, when the aqueous resin dispersion contains bright pigments such as aluminum flakes and mica and is used as an aqueous metallic base coat paint, metallic unevenness occurs in the resulting coating film, or flip-flops. There is a problem that the smoothness is poor.
- JP-A-63-1939668 discloses an aqueous coating composition containing a crosslinking agent in which a hydrophobic melamine resin is dispersed in water in the presence of a water-soluble resin, and has excellent storage stability. It is disclosed that an aqueous base coat coating composition having good coating workability without defects such as sagging and unevenness in a wide humidity range is provided. However, the coating film formed by the aqueous coating composition has a problem that the smoothness is inferior.
- JP-A-7-4 1 7 2 9 discloses that an aqueous resin dispersion obtained by dispersing a graft resin and a hydrophobic melamine tree jelly in an aqueous medium has storage stability, thermal stability, mechanical It is disclosed that it has excellent stability.
- the coating film formed from the aqueous coating composition containing the aqueous resin dispersion has metallic unevenness, and the flip-flop property is inferior in smoothness, and a sufficient coating appearance is obtained. There is no problem. Disclosure of the invention
- An object of the present invention is to provide an aqueous coating composition capable of forming a coating film having no metallic unevenness and excellent in flip-flop properties, smoothness and water resistance, and a coating film forming method using the aqueous coating composition. That is.
- the present inventors have determined that a specific corenosyl emulsion resin having a crosslinked core and a hydrophobic shell, a high molecular weight melamine resin, and a relatively large amount of a hydrophobic solvent. It has been found that a water-based coating composition containing a non-deteriorating appearance such as metallic unevenness forms a coating film excellent in flip-flop properties, smoothness and water resistance, and has completed the present invention.
- the present invention provides an aqueous coating composition containing an emulsion resin (A), a melamine resin (B) and a hydrophobic solvent (C),
- melamine resin ( B) has a weight average molecular weight in the range of 1,000 to 5,000; and
- the emulsion resin (A) is in the range of 10 to 80 parts by mass
- the melamine resin (B) is in the range of 5 to 50 parts by mass
- the hydrophobic solvent (C) is contained within the range of 10 to 100 parts by mass
- An aqueous paint composition is provided.
- the above-mentioned aqueous coating composition is applied onto an object to be coated, and after the clear coating is applied onto the uncured coating film to be obtained, the two coating films are simultaneously cured by heating.
- the present invention provides a method for forming a multilayer coating film characterized by this.
- a multilayer coating film having no metallic unevenness and excellent in flip-flop properties, smoothness and water resistance can be formed.
- Aqueous coating composition of the present invention can be used to form a coating film having no metallic unevenness and excellent flip-flop and smoothness
- An interaction between (B) and the hydrophobic solvent (C) causes the aqueous coating composition of the present invention. It is presumed that this is due to the development of an appropriate viscosity behavior that gives an excellent coating film appearance.
- Emulsion resin (A) A vinyl aromatic compound (c), a relatively high molecular weight melamine resin that maintains a stable shape in the paint by having a cross-linked core, and is present in the shell portion of the emulsion resin
- An interaction between (B) and the hydrophobic solvent (C) causes the aqueous coating composition of the present invention. It is presumed that this is due to the development of an appropriate viscosity behavior that gives an
- the emulsion resin is resin fine particles emulsified and dispersed in an aqueous medium.
- the emulsion resin (A) used in the present invention is a polymerizable unsaturated monomer having two or more polymerizable unsaturated groups in one molecule. (A) 0.
- Examples of the polymerizable unsaturated monomer (a) having 2 or more, preferably 2 or 3, more preferably 2 polymerizable unsaturated groups in one molecule include allyl (meth) acrylate and ethylene glycol.
- the polymerizable unsaturated monomer (a) preferably has an amide group in addition to the polymerizable unsaturated group.
- examples of such a polymerizable unsaturated monomer include methylene bis (meth) acrylic acid. Mide, ethylenebis (meth) acrylamide and the like.
- (meta) acrylate means either attalate or metaacrylate.
- the other polymerizable unsaturated monomer (b) is a monomer having a polymerizable unsaturated group copolymerizable with the polymerizable unsaturated monomer (a), and one polymerizable unsaturated group, for example, , A compound having a vinyl group, a (meth) acryloylole group or the like is included.
- polymerizable unsaturated monomers (b) include, for example, methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, i-propyl (meth) acrylate, n-butyl (meth) acrylate, i-butynole (meth) acrylate, tert-butyl (meth) acrylate, n-hexynole (meth) acrylate, n-octyl (meth) acrylate, 2-ethyl Hexyl (meth) acrylate, Noel (meth) acrylate, tridecyl (meth) acrylate, lauryl (meth) acrylate, stearyl (meth) acrylate, "Isostearyl acrylate" (manufactured by Osaka Organic Chemical Industry Co., Ltd.) , Product name), cyclohexyl (me
- the polymerizable unsaturated monomer (a) is based on the total mass of the polymerizable unsaturated monomer (a) and the other polymerizable unsaturated monomer (b). 0.1 to 30% by mass, preferably 0.5 to 10% by mass, more preferably 1 to 4% by mass, and other polymerizable unsaturated monomers
- (b) is 70-99.9 mass%, preferably 9 0-9 9.5 mass, based on the total mass of the polymerizable unsaturated monomer (a) and the other polymerizable unsaturated monomer (b). %, More preferably 96 to 99 mass. Can be used within the range of / 0 .
- the bur aromatic compound (c) include styrene, ⁇ -methyl styrene, 2-birutoluene, dibuenole benzene, bur naphthalene and the like. Among these, styrene is preferable. These can be used alone or in combination of two or more.
- the other polymerizable unsaturated monomer (d) is a monomer having a polymerizable unsaturated group copolymerizable with the vinyl aromatic compound (c), one polymerizable unsaturated group in one molecule,
- a monomer having a bur group, a (meth) attalyloyl group, and the like are included.
- polymerizable unsaturated monomers (d) include, for example, methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, i-propyl (meth) acrylate, n-butyl (meth) acrylate, i-butyl acrylate (meth) acrylate, tert-butyl (meth) acrylate, n-hexyl (meth) acrylate, octyl (meth) attaly Rate, 2-ethylhexyl (meth) acrylate, nonyl (meth) acrylate, tridecyl (meth) acrylate, laurinole (meth) acrylate, stearyl (meth) acrylate, isostearyl acrylate (Osaka Organic Chemical Industry) Product name), cyclohexyl (meth) acrylate, methyl cyclohexyl (
- the vinyl aromatic compound (c) is 5 to 5 based on the total mass of the vinyl aromatic compound (c) and the other polymerizable unsaturated monomer (d). 0% by mass, preferably 7 to 40% by mass, more preferably 9 to 30% by mass, and the other polymerizable unsaturated monomer (d) is a vinyl aromatic compound.
- the total mass of (c) and other polymerizable unsaturated monomers (d) As a reference, 5 0-9 5 wt ° / o, preferably 6 0-9 3 mass 0/0, more preferably be used within a range of 7 0-9 1 mass%.
- the carboxyl group-containing polymerizable unsaturated monomer (e) is preferred.
- the carboxyl group-containing polymerizable unsaturated monomer (e) among those exemplified above, acrylic acid and methacrylic acid are particularly preferable.
- the amount of the carboxyl group-containing polymerizable unsaturated monomer (e) is selected from the viewpoints of stability of the emulsion resin in an aqueous medium and water resistance of the resulting coating film. Generally 1 to 40% by mass, preferably 6 to 25% by mass, and more preferably 7 to 19% by mass, based on the total mass of the unsaturated unsaturated monomer (d). Can be in the range of / 0 .
- the other polymerizable unsaturated monomer (d) may contain the hydroxyl group-containing polymerizable unsaturated monomer (as a component of at least a part of the component from the viewpoint of ensuring the stability of the obtained emulsion resin in an aqueous medium. It is preferable to contain f). Hydroxyl group-containing polymerizable unsaturated monomers (for example, among those exemplified above, 2-hydroxyhexyl (meth) acrylate, 2-hydroxypropynole (meth) acrylate, 3-hydroxypropylene Nore (meth) acrylate and 4-hydroxy butyl (meth) acrylate are suitable, and these can be used alone or in combination of two or more.
- Hydroxyl group-containing polymerizable unsaturated monomers for example, among those exemplified above, 2-hydroxyhexyl (meth) acrylate, 2-hydroxypropynole (meth) acrylate, 3-hydroxypropylene Nore (meth) acrylate and
- the amount of the hydroxyl group-containing polymerizable unsaturated monomer (f) used is determined from the viewpoint of the stability of the emulsion resin in the aqueous medium and the water resistance of the resulting coating film. based on the total weight of the unsaturated monomer (d), generally 1-4 0% by weight, preferably from 6 2 5 mass 0/0, more preferably 7 to 2 0 wt% Can be within range.
- the other polymerizable unsaturated monomer (d) preferably contains an alkyl (meth) acrylate (g) having an alkyl group having 2 to 4 carbon atoms as at least a part of its components.
- alkyl (meth) acrylate (g) include ethyl (meth) acrylate, n-propyl (meth) acrylate, i-propyl (meth) acrylate, n-butyl (meth) acrylate, i Examples thereof include butyl (meth) acrylate, tert-butyl (meth) acrylate and the like. Among them, n-butyl (meth) acrylate is preferable.
- the amount of alkyl (meth) acrylate (g) used is generally from 15 to 93% by weight, preferably based on the total weight of vinyl aromatic compound (c) and other polymerizable unsaturated monomers (d). Is 30-75 mass. / 0 , more preferably in the range of 40 to 60% by mass.
- the copolymer (II) is a vinyl aromatic compound (c) 9 based on the total mass of monomers used. ⁇ 25 mass%, carboxyl group-containing polymerizable unsaturated monomer (e) 6-25 mass. /. Hydroxyl group-containing polymerizable unsaturated monomer (f) 5 to 20% by mass and alkyl (meth) acrylate (g) 30 to 80% by mass. A copolymer obtained by copolymerizing / 0 is preferable.
- the emulsion resin (A) generally has an acid value in the range of 5-9 OmgKOH / g, especially 8-50 mgKOH / g, more particularly 10-35 mgKOHZg, from the viewpoint of storage stability and water resistance of the resulting coating film. It is suitable to have.
- the emulsion resin (A) is generally in the range of 1 to 70 mgKH / g, particularly 2 to 50 mgKOH / g, more particularly 5 to 30 mgKOH / g, from the viewpoint of water resistance of the resulting coating film. It preferably has a hydroxyl value. Furthermore, it has only one polymerizable unsaturated group per molecule as a vinyl aromatic compound (C) and other polymerizable unsaturated monomer (d) because it has an excellent appearance of the formed coating film. It is desirable to use a polymerizable unsaturated monomer and make the shell part of the emulsion resin (A) uncrosslinked.
- the emulsion resin (A) is obtained, for example, by emulsion polymerization of the monomer mixture (I) containing the polymerizable unsaturated monomer (a) and the other polymerizable unsaturated monomer (b) in the above-mentioned quantitative ratio.
- the monomer mixture (II) containing the aromatic vinyl compound (c) and other polymerizable unsaturated monomer (d) in the above-mentioned quantitative proportion is added, and further emulsion polymerization is performed. Can be obtained.
- the emulsion polymerization of the monomer mixture (I) can be performed by a method known per se, for example, using a polymerization initiator in the presence of an emulsifier.
- an anionic emulsifier or a nonionic emulsifier is preferable.
- the anionic emulsifier include sodium salts and ammonium salts of acids such as alkyl sulfonic acids, alkyl benzene sulfonic acids, and alkyl phosphoric acids, and examples of noion emulsifiers include polyoxyethylene sulfonates.
- Rail ether polyoxyethylene stearyl ethereol, polyoxyethylene laurinore ethereol, polyoxyethylene tridec ⁇ / ete_; le, polyoxyethylene phenole ethere, polyoxyethylene nourphenenoate ethere, polyoxyethylene Octino olefin ether, polyoxyethylene monolaurate, polyoxyethylene monostearate, polyoxyethylene monooleate, sorbitan monolaurate, sorbitan monostearate, sonolebitan mono Teareto, Sonorebitantori old, polyoxyethylene sorbitan monolaurate, and the like.
- a polyoxyalkylene group-containing anionic milk having an anionic group and a polyoxyalkylene group such as a polyoxyethylene group or a polyoxypropylene group in one molecule. It is also possible to use a reactive anionic emulsifier having an anionic group and a radically polymerizable unsaturated group in one molecule, and it is particularly preferable to use a reactive anionic emulsifier. It is.
- Examples of the reactive anionic emulsifier include sodium salts and ammonium salts of sulfonic acid compounds having radically polymerizable unsaturated groups such as (meth) aryl groups, (meth) acryloyl groups, propenyl groups, and butyr groups. Can be mentioned. From the standpoint of excellent water resistance of the resulting coating film, an ammonium salt of a sulfonic acid compound having a radically polymerizable unsaturated group is particularly preferable. Examples of commercially available ammonium salts of the sulfonic acid compound include Latemul S-1 18 O A (trade name, manufactured by Kao Corporation).
- ammonium salts of sulfonic acid compounds having a radical polymerizable unsaturated group are more preferable.
- examples of commercially available ammonium salts of sulfonic acid compounds having a radically polymerizable unsaturated group and a polyoxyalkylene group include, for example, Aqualon KH-1 0 (Daiichi Kogyo Seiyaku Co., Ltd., trade name), SR-1 0 2 5 A (trade name, manufactured by Asahi Denka Kogyo Co., Ltd.).
- the emulsifier is usually in the range of 0.1 to 15% by mass, preferably 0.5 to 10% by mass, more preferably 1 to 5% by mass, based on the total mass of all monomers used. Can be used.
- the polymerization initiator may be either oil-soluble or water-soluble, and examples of the oil-soluble polymerization initiator include benzoyl peroxide, octanoyl peroxide, lauroyl peroxide, stearoyl.
- Organic peroxides such as peroxides; azo compounds such as azobisisoptyronitrile and azobis (2,4-dimethylvaleronitol), and water-soluble initiators include, for example, , Cumenha Organic peroxides such as diperoxide, tert-butyl peroxide, tert-butyl peroxylaurate, tert-butyl peroxypropyl carbonate, tert-butyl peroxyacetate, diisopropylbenzene hydroperoxide; (2-methylpropiononitrile), azobis (2-methylptyronitrile), 4, 4'-azobis (4-cyanobtanic acid), dimethylazobis (2-methylpropionate), azobis [2-methyl-1-N- ( 2-Hydroxychetyl) Monopropionamide], Azobis ⁇ 2-Methyl-N— [2- (1-Hydroxybutyl)] Monopropionamide ⁇ and other azo compounds; persulfur
- the polymerization initiator may be combined with a reducing agent such as ⁇ , sodium formaldehyde sulfoxylate, or an iron complex to form a redox polymerization system.
- a reducing agent such as ⁇ , sodium formaldehyde sulfoxylate, or an iron complex to form a redox polymerization system.
- the polymerization initiator is preferably used in a range of from 0.0 to 5% by mass, particularly from 0.2 to 3% by mass, based on the total mass of all monomers used.
- the method for adding the polymerization initiator is not particularly limited, and can be appropriately selected according to the type and amount thereof.
- the polymerization initiator may be previously contained in the monomer mixture or the aqueous medium, or It may be added all at once during the polymerization, or it may be added dropwise.
- the emulsion resin (A) is obtained by adding the monomer mixture (II) containing the vinyl aromatic compound (c) and the other polymerizable unsaturated monomer (d) to the emulsion (I) obtained as described above. Further, it can be obtained by emulsion polymerization.
- the monomer mixture (I I) may appropriately contain components such as a polymerization initiator, a chain transfer agent, a reducing agent, and an emulsifier as listed above, if necessary.
- the monomer mixture (II) can be added as it is, but in general, the monomer mixture (II) is dispersed in an aqueous medium to prepare a monomer emulsion. It is desirable to add a monomer emulsion. In this case, the particle size of the monomer emulsion is not particularly limited.
- the monomer mixture (II) which may be emulsified is added to the emulsion (I) all at once or dropwise and heated to an appropriate temperature while stirring. Is fisted.
- the emulsion resin (A) obtained as described above is a copolymer formed from a monomer mixture ( ⁇ ) containing a polymerizable unsaturated monomer (a) and another polymerizable unsaturated monomer (b) ( A core-shell type compound having I) as a core and a copolymer (II) formed from a monomer mixture (II) containing a vinyl aromatic compound (c) and other polymerizable unsaturated monomer (d) as a shell. It can have a layer structure.
- the ratio of copolymer (I) to copolymer (II) in emulsion resin (A) is determined from the viewpoint of flip-flop properties and metallic unevenness of the resulting coating film. It is preferable that the solid content mass ratio of the polymer (II) is generally in the range of 10Z90 to 90Z10, particularly 50 to 50 to 8571 5, and more particularly 65/35 to 80 to 20.
- the emulsion resin ( ⁇ ) obtained as described above has the form of fine particles dispersed in an aqueous medium, and generally has an average particle size in the range of 10 to: 1 000 nm, especially 20 to 500 nm. be able to.
- the average particle diameter of the emulsion resin (A) is a value measured by a Coulter counter method at a measurement temperature of 20 ° C. This measurement can be performed using, for example, “COULTER N4 type” (trade name, manufactured by Beckman Coulter Co.).
- the neutralizing agent is not particularly limited as long as it can neutralize acidic groups. Examples include sodium hydroxide, potassium hydroxide, trimethylamine, 2- (dimethylamino) ethanol, 2-amino-1-methyl-1-propanol, triethylamine, aqueous ammonia, etc., and neutralizers thereof. Is preferably used in such an amount that the pH of the neutralized emulsion resin is about 6.5 to 9.0.
- the melamine resin (B) used in the aqueous coating composition of the present invention is a resin obtained by the reaction of melamine and aldehyde, and includes both partially methylolated melamine resins and fully methylolated melamine resins. .
- the melamine resin (B) is generally 1, 0 0 to 5, 0 0, preferably 1, 2 0 0 to 4, 0 0 0, and more preferably 2, 0 0 0 to 3, 0
- a relatively high molecular weight having a weight average molecular weight in the range of 0 to 10 is suitable.
- aldehyde examples include formaldehyde, paraformaldehyde, acetoaldehyde, benzaldehyde, and the like. Formaldehyde is particularly preferable.
- methylolated melamine resins obtained by partially or completely etherifying methylol groups with a suitable alcohol can be used. Examples of alcohols that can be used for etherification include methyl alcohol.
- the melamine resin (B) includes, among others, a methyl etherified melamine resin in which the methylol group of a partially or fully methylolated melamine resin is partially or completely etherified with methyl alcohol; partially or completely methylolated melamine Butyl with partially or fully etherified methylol group of resin with butyl alcohol Etherified melamine resins; methyl-propyl mixed etherified melamine resins in which the methylol group of a partially or fully methylolated melamine resin is partially or fully etherified with both methyl alcohol and butyl alcohol can be suitably used. .
- the melamine resins (B) described above can be used alone or in combination of two or more.
- weight average molecular weight refers to the weight average molecular weight measured with a gel permeation chromatography (trade name “HLC81 20GPC” manufactured by Tosoh Corporation), based on the weight average molecular weight of polystyrene. This is the converted value.
- the hydrophobic solvent (C) used in the aqueous coating composition of the present invention has a mass that dissolves in 100 g of water at 20 ° C. of 10 g or less, preferably 5 g or less, and more preferably 1 g.
- Organic solvents such as the following: hydrocarbon solvents such as rubber volatile oil, mineral spirits, toluol, xylol, solvent naphtha; n-hexanol, n-octanol, 2-octanol, 2-ethylhexanol , N-decano monore, benzylenorenore, ethyleneglycone 2-ethenolehexenoreatenore, propylene glycol mononore nbutinoreatenore, dipropylene glycol mononore n-butinoleate, tripropylene glycol Nore n_Butyl etherenole, Propylene glycolate 2— Alcohol solvents such as
- hydrophobic solvent (C) from the viewpoint of flip-flop properties and metallic unevenness of the resulting coating film, alcohol solvents, especially alcohol solvents having 7 to 14 carbon atoms, especially 1-octanol, 2— Ottatanol, 2-ethylol-1, hexanol, ethylene glycolate 2-ethylenohexenoreethenole, propylene glycolone n-butyl ether, dipropylene dallicol n_butyl ether A solvent is preferred.
- the aqueous coating composition of the present invention can be prepared by uniformly mixing the emulsion resin (A), melamine resin (B) and hydrophobic solvent (C) described above.
- the contents of the emulsion resin (A), the melamine resin (B) and the hydrophobic solvent (C) in the aqueous coating composition are in the following range based on 10 parts by mass of the resin solid content of the aqueous coating composition. Can be in:
- Emulsion resin (A) 10 to 80 parts by mass, preferably 15 to 50 parts by mass, and more preferably 20 to 40 parts by mass.
- Melamine resin (B) 5-50 parts by mass, preferably 10-40 parts by mass, more preferably 20-30 parts by mass.
- Hydrophobic solvent (C) 10-100 parts by mass, preferably 20-80 parts by mass, further 2 Preferably 30-60 parts by weight.
- the aqueous coating composition of the present invention if the content of the emulsion resin (A) is out of the above range, the flip-flop property and smoothness of the formed coating film are lowered, and the content of the melamine resin (B) If the content is outside the above range, the water resistance of the resulting coating film will be reduced, and if the content of the hydrophobic solvent (C) is outside the above range, metallic unevenness may occur in the resulting coating film, The properties and gloss will be reduced.
- the solid content of the resin in the water-based coating composition is in addition to the resin solids such as the emulsion resin (A), the melamine resin (B), and the modifying resin, and these resins and crosslinked
- the total solid content including the solid content of the curing agent such as the polyisocyanate compound, the blocked polyisocyanate compound, the epoxy group-containing compound, the carboxyl group-containing compound, and the carbodiimide group-containing compound.
- the water-based paint composition of the present invention includes, as a resin component, a water-soluble or water-dispersible polyurethane resin, a polyester resin, an acrylic resin, an alkyd resin, a silicone resin, Modification resins such as fluororesins and epoxy resins can be included. Especially from the viewpoint of smoothness, gloss, water resistance, etc., water-soluble or water-dispersible polyester resins and water-soluble or water-dispersible acrylics. It is preferable to include at least one modifying resin selected from the group consisting of rosin.
- the water-soluble or water-dispersible polyester resin is, for example, an oil-free or oil-prepared oil prepared by esterification using a polyhydric alcohol and a polybasic acid, and if necessary, a monobasic acid, an oil component, etc. It can be obtained by neutralizing a modified carboxyl group-containing polyester resin.
- This polyester resin preferably has both a hydroxyl group and a carboxyl group, generally 10 to 30 Omg KOH / g, especially 50 to 250 mg KOHZg, more particularly 80 to: L hydroxyl value in the range of 80 mg KOH / g, And in general :!
- the polyester resin is generally in the range of 500 to 100,000, preferably 1,000 to 80,000, more preferably 1,500 to 30,000, particularly preferably 2,000 to 20,000. It can have a weight average molecular weight.
- the carboxyl group of the polyester resin can be neutralized using a basic substance.
- the basic substance is preferably water-soluble, specifically, for example, ammonia, methylamine, ethylamine, propylamine, butylamine, dimethylamine, trimethylamine, triethylamine, ethylenediamine, morpholine, 2- (methylamino)
- Examples include ethanol, 2- (dimethylamino) ethanol, diethanolamine, triethanolamine, diisopropanolamine, 2-amino-2-methylpropanol, and these are used alone or in combination of two or more. be able to.
- the amount of the water-soluble or water-dispersible polyester resin is usually 2 to 70 parts by weight, particularly 10 to 50 parts by weight, more particularly 15 to 15 parts by weight, based on 100 parts by weight of the resin solid content of the aqueous coating composition. It is preferable to be within the range of 40 parts by mass.
- water-soluble or water-dispersible acrylic resin examples include a hydrophilic group-containing polymerizable unsaturated monomer such as the carboxyl group-containing polymerizable unsaturated monomer (e), a hydroxyl group-containing polymerizable unsaturated monomer, and the like.
- a hydrophilic group-containing polymerizable unsaturated monomer such as the carboxyl group-containing polymerizable unsaturated monomer (e), a hydroxyl group-containing polymerizable unsaturated monomer, and the like.
- a weight average molecular weight 1,000 to 200,000, preferably 2,000 to 100,000, which is obtained by copolymerizing a mixture containing other polymerizable unsaturated monomers by a solution polymerization method or the like.
- More preferred is a carboxyl group acryl copolymer in the range of 3,000 to 80,000, particularly preferably 5,000 to 70,000.
- the carboxy group of the acryl copolymer can be neutralized using a basic substance as described above
- the acrylic resin is generally 1-20 OmgKOHZg, especially 2-100 mg K0HZ g, Especially hydroxyl values in the range of 3-60 mg KH / g, and in general :! It is preferred to have an acid value in the range of ⁇ 20 O mg KOH / g, in particular 2 to 150 mg KOH / g, more particularly 5 ⁇ : L 0 0 mg K0HZ g.
- the modifying resins can be used alone or in combination of two or more.
- the modifying resin is generally 5 to 70 parts by weight, preferably 10 to 60 parts by weight, more preferably, based on 100 parts by weight of the resin solid content in the aqueous coating composition of the present invention. It can be blended in the range of 20 to 50 parts by mass.
- the aqueous coating composition of the present invention can contain the melamine resin (B).
- a curing agent having a crosslinkable functional group capable of reacting with the functional group can be contained.
- the curing agent include an amino resin, a polyisocyanate compound, a blocked polyisocyanate compound, an epoxy group-containing compound, a carboxyl group-containing compound, a carboxyl group-containing compound, and the like. Cyanate compounds and carbodiimide group-containing compounds are preferred.
- the isocyanate group of the polyisocyanate compound having at least two isocyanate groups in one molecule is blocked with a blocking agent such as oxime, phenol, alcohol, lactam, or mercaptan. Can be used.
- a blocking agent such as oxime, phenol, alcohol, lactam, or mercaptan.
- the curing agent is generally used in a range of 1 to 40 parts by weight, particularly 5 to 20 parts by weight, based on 100 parts by weight of the resin solid content in the aqueous coating composition of the present invention. Is preferred.
- the aqueous coating composition of the present invention can contain a glitter pigment (D).
- the glitter pigment (D) is a pigment that imparts a brilliant pearly light interference pattern to the coating film.
- a non-leafing type or leafy pigment is used. Ning type aluminum (including vapor-deposited aluminum), cocoon, zinc, brass, nickel, aluminum oxide, mica, aluminum oxide coated with titanium oxide or iron oxide, mica coated with titanium oxide or iron oxide, etc. Can be used.
- These glitter pigments are preferably in the form of flakes.
- the bright pigment (D) has a longitudinal dimension of 1 to 100 ⁇ m, particularly 5 to 40 ⁇ , and a thickness of 0.0001 to 5 mm, particularly 0.001 to 2 ⁇ m.
- the ones in are suitable.
- the glitter pigment (D) is generally 1 to 50 parts by weight, preferably 5 to 35 parts by weight, more preferably 8 based on 100 parts by weight of the resin solid content in the aqueous coating composition of the present invention. It can mix
- the aqueous coating composition of the present invention preferably further contains a thickener.
- the thickener include inorganic thickeners such as silicates, metal silicates, montmorillonite, organic montmorillonite, colloidal alumina; polyacrylic acid and (meth) acrylic ester copolymers
- Polyacrylic acid thickeners such as sodium polyacrylate (commercially available products such as “Primal AS E-60”, “Primal TT— 6 1 5”, “Primal RM— 5 ”;“ SN Sitner 6 1 3 ”,“ SN Thickener 6 1 8 ”,“ SN Thickener 6 30 ”,“ SN Thickener 634 ”,“ 31 ⁇ Thickener 636 ”(all are trade names) And having a hydrophilic part and a hydrophobic part in one molecule.
- the hydrophobic part is adsorbed on the surface of the pigment or emulsion particles in the paint, or the hydrophobic part is the same.
- Associative thickeners that effectively increase the viscosity when they are associated (commercially available products such as “UH-420”, “UH-450”, “UH—462” manufactured by ADEKA) , “UH-472", “UH-540”, “UH-752”, “UH-75 6VF", “UH-814N”;”PrimalRM-8” manufactured by Rohm and Haas “W”, “Primal RM—825”, “Primal RM—2020NPR”, “Primal RM—12W”, “Primal S CT—275”; “SN thickener 612”, “SN thickener 621 N” manufactured by San Nopco, "SN thickener 625 N”, “SN thickener 627 N”, “SN thickener 660 Tj (all of which are trade names), etc.); Fiber derivative thickeners such as carboxymethyl
- Polyvinyl thickener Pluronic polyether, polyether dialkyl ester, polyether Polyether thickeners such as rudialkyl ethers and polyether epoxy modifiers; Maleic anhydride copolymer thickeners such as partial esters of butyl methyl ether monomaleic anhydride copolymers; Polyamides such as polyamide amine salts These thickeners can be used alone or in combination of two or more.
- the thickener examples include the polyacrylic acid-based thickener and / or the associative thickener, particularly the associative thickener, and more particularly a hydrophobic group at the terminal, and urethane in the molecular chain.
- a uretan-associative thickener containing a bond is preferred.
- the uretan associative thickener examples include “UH-420”, “UH-462”, “UH_472”, “UH-540”, “UH-756 VF”, “UH-814N” manufactured by ADEKA. ; "SN thickener 612", “SN thickener 621 N", “S” made by San Nopco
- the blending amount of the thickener is usually 0.01 to 1 based on 100 parts by mass of the resin solid content in the aqueous coating composition of the present invention. It is preferably within the range of 0 to 5 parts by mass, particularly 0.05 to 3 parts by mass, and more particularly 0.1 to 2 parts by mass.
- the compounding amount of the sticking agent is 0.11 to 10 parts by weight, particularly 0.05 to 2 parts by weight, based on 100 parts by weight of the resin solid content in the water-based paint yarn and the composition of the present invention. Further, it is particularly preferably within the range of 0.1 to 1 part by mass.
- the water-based coating composition of the present invention may further comprise a color pigment, an extender pigment, a curing catalyst, an ultraviolet absorber, a light stabilizer, an antifoaming agent, a plasticizer, an organic solvent, a surface conditioner, and an anti-settling agent as necessary.
- the usual paint additives such as can be contained alone or in combination of two or more.
- coloring pigment examples include titanium oxide, zinc white, carbon black, molybdenum red, Prussian blue, cobalt blue, azo pigment, phthalocyanine pigment, quinatalidone pigment, isoindoline pigment, selenium pigment, and perylene pigment.
- extender pigment examples include talc, clay, kaolin, Norita, barium sulfate, barium carbonate, calcium carbonate, silica, and alumina white.
- curing catalyst examples include sulfonic acids such as p-toluenesulfonic acid, dodecylbenzene sulfonic acid, and dinoninolenaphthalene sulfonic acid, and salts of these acids and amines.
- sulfonic acids such as p-toluenesulfonic acid, dodecylbenzene sulfonic acid, and dinoninolenaphthalene sulfonic acid, and salts of these acids and amines.
- the water-based coating composition of the present invention can be applied to various objects to be coated.
- the article to which the water-based coating composition of the present invention can be applied is not particularly limited, but for example, the body of various vehicles such as automobiles, motorcycles and containers is preferable.
- the water-based coating composition of the present invention also includes a cold-rolled steel sheet, a zinc-plated steel sheet, a zinc alloy-plated steel sheet, It can also be applied to steel plates such as stainless steel plates and tin-plated steel plates; metal substrates such as aluminum plates and aluminum alloy plates; and various plastic materials.
- These coatings can be subjected in advance to surface treatments such as phosphate treatment, chromate treatment, composite oxide treatment, or various undercoating and / or intermediate coatings such as various electrodeposition coatings. It may be formed.
- the coating method of the water-based paint composition of the present invention is not particularly limited, and examples thereof include air spray coating, airless spray coating, rotary atomization coating, curtain coat coating, and the like. And rotary atomization coating is preferred. These coating methods may be electrostatically applied as necessary. A wet coating film can be formed by these coating methods.
- the coating amount of the water-based coating composition can be changed depending on the use of the article to be coated, but the cured film thickness is usually preferably about 5 to 70 ⁇ .
- the wet coating film can be cured by applying the aqueous coating composition of the present invention to an object to be coated and then heating it.
- Heating can be performed by a known heating means, for example, using a drying furnace such as a hot air furnace, an electric furnace, or an infrared induction heating furnace.
- the heating temperature is usually in the range of 80 to 180 ° (preferably in the range of 100 to 160 ° C.
- the heating time is not particularly limited, but usually 20 to It can be as long as 40 minutes.
- the water-based paint composition of the present invention can be suitably used as a paint for automobiles.
- a water-based base coat paint containing a glittering pigment and a pigment or a colored pigment is applied on an object to be coated, and then a tarier paint. It can be suitably used as a water-based base coat paint in a painting method for painting.
- the water-based paint composition of the present invention is used as a water-based base coat paint
- the water-based paint composition of the present invention is applied on an object to be electrodeposited and coated with no or intermediate coating.
- 2 coat 1 beta system after coating the product, coating the uncoated film on the uncured film without curing the formed film, and then simultaneously curing the uncured film and the clear film
- a multi-layer coating film can be formed.
- the uncured coating includes a touch-dried coating and a semi-cured coating.
- the aqueous coating composition of the present invention When the aqueous coating composition of the present invention is applied by a 2-coat 1-bake method, the aqueous coating composition usually has a dry film thickness of 5 to 40 111, preferably 10 to 30 111, and more preferably 10 to 2. It is preferable to paint so that it is within the range of O zm, and the above clear coating has a dry film thickness of usually 10-80 ⁇ 1! 1, preferably 15-60 ⁇ m. It is preferable to paint.
- the coating film is preferably preheated (preheated) at room temperature to 100 ° C, preferably 40 to 90 ° C for 1 to 15 minutes.
- the clear paint it can be preheated at room temperature for about 1 to 60 minutes or at about 40 to 80 ° C for 1 to 60 minutes as necessary.
- the aqueous coating composition of the present invention and the coating film of the talya paint can be cured using the heating means known per se, specifically, for example, 80 to 180 ° C., preferably It is preferable to cure both coatings simultaneously by heating at a temperature of 100 to 160 ° C for about 10 to 40 minutes.
- an intermediate coating is applied on the object to be coated, and the aqueous coating composition of the present invention is applied as an aqueous base coating on the uncured intermediate coating without curing the formed coating.
- Heat-cured 3-coat 1-beta system can be used to form a multilayer coating.
- the aqueous coating composition of the present invention is applied by the above 3-coat 1-beta method
- the coating material is preferably applied so that the dry film thickness is in the range of 10 to 60 ⁇ , preferably 20 to 40 ⁇ m
- the aqueous coating composition of the present invention comprises a dry film. It is preferable to apply the coating so that the thickness is in the range of 5 to 40 m, preferably 10 to 30 ⁇ ⁇ , and more preferably 10 to 2 ⁇ . Is preferably 10 to 80 m, preferably 15 to 60 ⁇ .
- preheat preheat
- preheating is preferably performed at room temperature to 100 ° C., preferably 40 to 90 ° C. for 1 to 15 minutes.
- an interval of 1 to 60 minutes at room temperature or a preheating at about 40 to 80 ° C for 1 to 60 minutes can be applied as necessary. it can.
- Curing of the coating film can be performed by the above-mentioned heating means known per se, specifically, for example, 80 to 180 ° C., preferably 100 to 160. It is preferable that the three layers of the coating film are simultaneously cured by heating at a temperature of (:) for about 10 to 40 minutes.
- thermosetting intermediate coating a known thermosetting intermediate coating can be used.
- a base resin such as an alkyd resin, a polyester resin, an acrylic resin, or a urethane resin is used.
- a paint comprising a suitable combination of a curing agent having a reactive functional group and a reactive group contained in the base resin, such as an amino resin, a polyisocyanate compound, and a block polyisocyanate compound. be able to.
- high solid type paints, 7-type paints, powder paints, etc. that use a small amount of organic solvent can be suitably used.
- talya paint for example, those known per se that are usually used in the coating of automobile bodies can be used. Specifically, for example, a hydroxyl group, a carboxyl group, an epoxy group, a silanol group, etc.
- Acrylic with crosslinkable functional groups Resin, polyester resin, alkyd resin, urethane resin, epoxy resin, fluororesin and other base resin, melamine resin, urea resin, optionally blocked polyisocyanate compound, carboxyl group-containing compound or resin, epoxy group-containing compound Organic solvent-based thermosetting paints, water-based thermosetting paints, thermosetting powder paints, etc. containing a crosslinking agent such as a product or resin as a resin component.
- thermosetting paint containing a hydroxyl group-containing acrylate resin and a melamine resin a thermosetting paint containing a carboxyl group-containing resin and an epoxy group-containing resin, and a heat containing a polyisocyanate compound that may be blocked with a hydroxyl group-containing resin.
- a curable paint is preferred.
- the tally paint may be a one-component paint or a two-component paint such as a two-component urethane resin coating.
- the above-mentioned talya paint can contain coloring pigments, bright pigments, dyes, etc. to such an extent that transparency is not hindered. Further, extender pigments, ultraviolet absorbers, antifoaming agents, Thickeners, antifungal agents, surface conditioners, etc. can be included as appropriate.
- the following monomer emulsion (2) was added dropwise over 1 hour, aged for 1 hour, and then cooled to 30 ° C while gradually adding 40 parts of 5.0% dimethylethanolamine aqueous solution to the reaction vessel.
- the sample is discharged while being filtered, and the average particle size is 10011 m (submicron particle size distribution analyzer ⁇ COULTER N4 type) (trade name, manufactured by Beckman Coulter, Inc.).
- an emulsion resin (A1) having an acid value of 33 mg KOH / g, a hydroxyl value of 25 mg KO HZ g, and a solid content concentration of 30% was obtained.
- Aqualon KH-10 Polyoxyethylene alkyl ether sulfate ester sterammonium salt: Daiichi Kogyo Seiyaku Co., Ltd., trade name, active ingredient 97%.
- Monomer emulsion (1) 42 parts of deionized water, Aqualon KH—10 0.72 parts, 2.1 parts of aryl methacrylate, 2.8 parts of styrene, 16 parts of methyl methacrylate, 28 parts of ethyl acrylate And 21 parts of n_butyl acrylate were mixed and stirred to obtain a monomer emulsion (1).
- Monomer emulsion (2) Deionized water 18 parts, Aqualon KH—10 0.31 parts, Ammonium persulfate 0.03 parts, Methacrylic acid 5.1 parts, 2-Hydroxyl acetylate 5.1 parts, Styrene 3 Part, 6 parts of methyl methacrylate, 1.8 parts of ethyl acrylate and 9 parts of n-butyl acrylate were mixed and stirred to obtain a monomer emulsion (2).
- Production Examples 2-14 Deionized water 18 parts, Aqualon KH—10 0.31 parts, Ammonium persulfate 0.03 parts, Methacrylic acid 5.1 parts, 2-Hydroxyl acetylate 5.1 parts, Styrene 3 Part, 6 parts of methyl methacrylate, 1.8 parts of ethyl acrylate and 9 parts of n-butyl acrylate were mixed and stirred to obtain a monomer emulsion (2).
- polyester resin solution having an acid value of 46 mg KOH / g, a hydroxyl value of 150 mg KOH / g, a solid content concentration of 70% and a weight average molecular weight of 6,400.
- Polyester resin in the same manner as in Production Example 15 except that 2-ethyl-1-hexanol as a diluent solvent is replaced with dipropylene glycol n-propyl ether (mass dissolved in 100 g of water at 20 ° C: 19 g). A solution (PE 2) was obtained.
- Production Example 17
- a polyester resin solution (PE) was prepared in the same manner as in Production Example 15 except that the diluting solvent 2-ethyl-1-hexanol was replaced with ethylene glycol / lemonobutyl ether (mass dissolved in 100 g of water at 20 ° C: infinite). 3) Production example of acrylic resin solution
- Production Example 18 85 Charge 35 parts of propylene dallicol monopropyl ether into a reaction vessel equipped with a thermometer, thermostat, stirrer, reflux condenser and dripping device. After raising the temperature to C, 30 parts of methyl methacrylate, 20 parts of 2-ethylhexyl acrylate, 29 parts of 11-methyl acrylate, 15 parts of hydroxyethyl acrylate, 6 parts of attalic acid, propylene glycol monopropyl 15 parts of ether and 2,2'-azobis (2,4-dimethylpallet-tolyl) 2. 3 parts of the mixture was added dropwise to the flask over 4 hours, and aged for 1 hour after completion of the addition.
- Phosphoric acid group-containing resin solution Into a reaction vessel equipped with a stirrer, temperature controller and refrigerator, put 27.5 parts of methoxypropanol and 27.5 parts of iseptanol in a mixed solvent. 1 Heated to 10 ° C, 25 parts of styrene, 27.5 parts of n-butyl methacrylate, “Isostearyl Atylate” (trade name, manufactured by Osaka Organic Chemical Industry Co., Ltd., trade name, branched higher alkyl acrylate) 20 Parts, 4-hydroxypropyl acrylate 7.5 parts, phosphate group-containing polymerizable monomer (Note 3) 15 1 part, 2-methacryloyloxychetyl acid phosphate 12.5 parts, isobutanol 10 parts and t-butyl peroxide octanoate 4 parts 121.
- a mixture consisting of 0.5 part of t-butyl peroxyiotanoate and 20 parts of isopropanol was added dropwise over 1 hour. Thereafter, the mixture was aged and stirred for 1 hour to obtain a phosphate group-containing resin solution having a solid content concentration of 50%.
- This resin had an acid value of 83 mg KOH / g, a hydroxyl value of 29 mg KOH / 7 g, and a weight average molecular weight of 10,000.
- Phosphoric acid group-containing polymerizable monomer Into a reaction vessel equipped with a stirrer, temperature controller, and refrigerator, put 57.5 parts of monoptyl phosphoric acid and 41 parts of isobutanol and raise the temperature to 90 ° C. Thereafter, 42.5 parts of glycidyl methacrylate was added dropwise over 2 hours, followed by stirring and aging for another hour. Thereafter, 59 parts of isopropanol was added to obtain a phosphate group-containing polymerizable monomer solution having a solid concentration of 50%. The acid value due to phosphate groups was 285 mg KOH7.
- a bright pigment concentrate (P 3) was obtained in the same manner as in Production Example 19, except that 35 parts of 2-ethyl-1-hexanol was replaced with 35 parts of ethylene dallicol monobutyl ether.
- Emulsion resin obtained in Production Example 1 100 parts, Melamine resin (B 1) (Methyloopyl mixed etherified melamine resin, solid content 60%, weight average molecular weight 2,00 00) 50 parts, Production Example 15 57 parts of the obtained polyester resin (PE 1) and the bright pigment concentrate (P 1) obtained in Production Example 19 were uniformly mixed, and deionized water and 2- (dimethylamino) ethanol were added. As a result, a water-based paint composition (XI) having a pH of 8.0 and a solid content concentration of 23% was obtained. Examples 2 to: 14, Comparative Examples 1 to 6
- a water-based paint composition having a pH of 8.0 and a solid content concentration of 23% was obtained in the same manner as in Example 1 except that the components and amounts shown in Table 2 below were used instead of the components and amounts described in Example 1. The thing (X2)-(X20) was obtained.
- Melamine resin (B2) Methyl-butyl mixed etherified melamine resin, solid content 80%, weight average molecular weight 1,200.
- test plates were prepared and evaluated as follows. (Preparation of test article)
- Example 15 45 cm x 30 cm x 0.8 mm thick zinc phosphate-treated cold-rolled steel sheet, “ELECRON GT-10” (Kansai Paint Co., Ltd. ) was electrodeposited to a dry film thickness of 20 ⁇ m, cured by heating at 170 ° C for 30 minutes, and then the intermediate coating “Amirac TP-65-2” (Kansai Paint Co., Ltd.) Product name, polyester resin / amino resin, organic solvent-type intermediate coating) to a dry film thickness of 40 ⁇ , and cured by heating at 140 ° C for 30 minutes to cure. It was a thing.
- Example 15 Example 15
- Example 1 In a coating environment at a temperature of 23 ° C and a humidity of 75%, the water-based paint composition (XI) obtained in Example 1 above was applied to the test object to be coated with the rotary atomizing bell-type coating machine “ABB”. Using a “metallic bell coating machine” (trade name, manufactured by ABB Co., Ltd.), the coating was applied to a dry film thickness of 15 ⁇ , allowed to stand for 2 minutes, and then preheated at 80 ° C. for 3 minutes. Next, Magiclon KI NO-1210 (trade name, acrylic resin-based solvent-based clear paint) manufactured by Kansai Paint Co., Ltd. was applied on the uncured coating surface to a dry film thickness of 40 ⁇ and left for 7 minutes. Then, a test plate was prepared by heating at 140 ° C. for 30 minutes to cure both coating films simultaneously. Examples 16 to 28, Comparative Examples 7 to 12
- Example 16 to 28 and Comparative Examples 7 to 12 were prepared in the same manner as in Example 15 except that the aqueous coating composition (XI) in Example 15 was replaced with the aqueous coating composition shown in Table 3. Produced. Evaluation test
- test plates obtained in Examples 15 to 28 and Comparative Examples 7 to 12 were evaluated by the following test methods. Table 3 shows the evaluation results.
- A The change in color tone according to the viewing angle is extremely large, and it has extremely excellent flip-flop properties.
- ⁇ The color tone changes greatly depending on the viewing angle, and has excellent flip-flop properties.
- ⁇ The change in color tone according to the viewing angle is slightly small, and flip-flop 1 to raw are slightly inferior.
- ⁇ The smoothness is slightly inferior.
- Water resistance Immerse the test plate in warm water at 40 ° C for 24 hours and lift it up. After drying for 12 hours in C, cut the multilayer coating on the test plate into a grid with a force cutter so that it reaches the substrate, and make 100 squares of size 2 mm X 2 mm. Subsequently, an adhesive cellophane tape was applied to the surface, and the remaining state of the goby eye coating after the tape was rapidly peeled off at 20 ° C. was examined.
- the remaining number of Gobang eyes coating is 89 or less.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0820044A GB2453266B (en) | 2006-04-13 | 2007-04-05 | Water-based paint compositions |
US12/226,268 US7842751B2 (en) | 2006-04-13 | 2007-04-05 | Water-based paint compositions |
CN2007800132564A CN101421367B (zh) | 2006-04-13 | 2007-04-05 | 水性涂料组合物 |
JP2008510973A JP5225073B2 (ja) | 2006-04-13 | 2007-04-05 | 水性塗料組成物 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006-111412 | 2006-04-13 | ||
JP2006111412 | 2006-04-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007119762A1 true WO2007119762A1 (ja) | 2007-10-25 |
Family
ID=38609522
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2007/058022 WO2007119762A1 (ja) | 2006-04-13 | 2007-04-05 | 水性塗料組成物 |
Country Status (5)
Country | Link |
---|---|
US (1) | US7842751B2 (ja) |
JP (1) | JP5225073B2 (ja) |
CN (1) | CN101421367B (ja) |
GB (1) | GB2453266B (ja) |
WO (1) | WO2007119762A1 (ja) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009075389A1 (en) * | 2007-12-12 | 2009-06-18 | Kansai Paint Co., Ltd. | Water-based paint compositions |
KR20100111727A (ko) * | 2008-02-15 | 2010-10-15 | 바스프 코팅스 게엠베하 | 수성 코팅 조성물, 이의 제조 방법 및 이의 용도 |
CN101942254A (zh) * | 2010-09-29 | 2011-01-12 | 山东大学 | 一种含有纳米核壳结构聚吡咯的水性导电防腐涂料 |
JP2011515502A (ja) * | 2008-03-18 | 2011-05-19 | 関西ペイント株式会社 | 水性塗料組成物及び複層塗膜形成方法 |
JP2011131135A (ja) * | 2009-12-22 | 2011-07-07 | Nippon Paint Co Ltd | 複層塗膜形成方法 |
JP2011525415A (ja) * | 2008-06-24 | 2011-09-22 | 関西ペイント株式会社 | 複層塗膜形成方法 |
JP2011195838A (ja) * | 2010-03-23 | 2011-10-06 | Evonik Goldschmidt Gmbh | 製紙および紙加工用カーテン安定剤 |
US8128744B2 (en) * | 2008-02-15 | 2012-03-06 | BASF Coating GmbH | Aqueous coating composition, method for production of the same, and use thereof |
CN113355002A (zh) * | 2020-03-04 | 2021-09-07 | 关西涂料株式会社 | 涂料组合物和多层涂膜形成方法 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102086339B (zh) * | 2009-12-07 | 2013-05-15 | 立邦涂料(中国)有限公司 | 一种水性涂料组合物及其汽车中间涂层 |
CN102051098B (zh) * | 2010-11-26 | 2012-07-04 | 山东大学 | 一种环保型光催化水性涂料及其制备方法 |
SG11201402471SA (en) * | 2011-11-25 | 2014-08-28 | Nippon Soda Co | Photocatalyst-supporting structure |
WO2013118575A1 (ja) * | 2012-02-10 | 2013-08-15 | 関西ペイント株式会社 | 塗料組成物 |
CN103694844A (zh) * | 2013-12-07 | 2014-04-02 | 铜陵新九鼎铜文化产业有限公司 | 一种铜雕塑用耐热老化氨基树脂油漆 |
CN103740245A (zh) * | 2013-12-25 | 2014-04-23 | 苏州市邦成电子科技有限公司 | 一种金属保护用透明涂料及其制备方法 |
CN103773215A (zh) * | 2014-01-25 | 2014-05-07 | 苗光兴 | 一种pu树脂防水涂料及其制作工艺 |
EP3543265A4 (en) * | 2016-11-17 | 2020-04-15 | Mitsubishi Chemical Corporation | (METH) ACRYLCOPOLYMER, COATING MATERIAL COMPOSITION, COATED OBJECT, AND METHOD FOR PRODUCING A MULTILAYERED COATING FILM |
JP7090399B2 (ja) | 2017-02-21 | 2022-06-24 | 日本ペイント・オートモーティブコーティングス株式会社 | 水性塗料組成物および複層塗膜 |
JP7227220B2 (ja) * | 2017-08-15 | 2023-02-21 | ディディピー スペシャルティ エレクトロニック マテリアルズ ユーエス,エルエルシー | 二成分型室温硬化性強化エポキシ接着剤 |
JP6700340B2 (ja) * | 2018-06-27 | 2020-05-27 | 日本ペイント・オートモーティブコーティングス株式会社 | 水性塗料組成物および水性塗料組成物の製造方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07207220A (ja) * | 1994-01-25 | 1995-08-08 | Kansai Paint Co Ltd | 水性塗料組成物及びそれを用いた塗装法 |
JP2000154204A (ja) * | 1998-09-17 | 2000-06-06 | Kansai Paint Co Ltd | ゲル化重合体微粒子の製造方法 |
JP2005343966A (ja) * | 2004-06-01 | 2005-12-15 | Kansai Paint Co Ltd | 水性樹脂分散体の製造方法 |
WO2006009219A1 (ja) * | 2004-07-22 | 2006-01-26 | Kansai Paint Co., Ltd. | 熱硬化性水性塗料組成物及び塗膜形成方法 |
JP2006176618A (ja) * | 2004-12-22 | 2006-07-06 | Kansai Paint Co Ltd | 熱硬化性水性塗料及び塗膜形成方法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0759681B2 (ja) | 1987-02-06 | 1995-06-28 | 関西ペイント株式会社 | 水性被覆組成物 |
JPH05161869A (ja) * | 1991-12-12 | 1993-06-29 | Kansai Paint Co Ltd | 塗膜形成法 |
JP3385391B2 (ja) | 1993-05-24 | 2003-03-10 | 関西ペイント株式会社 | 水性樹脂分散体 |
EP0626417B1 (en) | 1993-05-24 | 1999-01-13 | Kansai Paint Co., Ltd. | Aqueous resin dispersion |
US5596047A (en) * | 1994-11-16 | 1997-01-21 | Cytec Technology Corp. | Water-dispersible and curable waterborne compositions containing 1,3,5-triazine carbamates |
JP4105360B2 (ja) * | 2000-03-15 | 2008-06-25 | 関西ペイント株式会社 | 水性2液型下塗塗料組成物 |
JP2002030253A (ja) * | 2000-07-14 | 2002-01-31 | Dainippon Toryo Co Ltd | 水性塗料 |
KR20030040467A (ko) * | 2000-09-21 | 2003-05-22 | 롬 앤드 하스 캄파니 | 극성 단량체 및 다가 양이온을 포함하는 조성물 및 그제조방법 |
US6673451B2 (en) * | 2000-10-12 | 2004-01-06 | Rohn And Haas Company | Process for forming an aqueous polymeric dispersion |
JP2002308993A (ja) | 2001-04-09 | 2002-10-23 | Kansai Paint Co Ltd | 水性樹脂分散液、及びこれを含む水性塗料組成物 |
JP2003286324A (ja) * | 2002-01-25 | 2003-10-10 | Daicel Chem Ind Ltd | 水性樹脂分散液及びその製造方法 |
KR20040075701A (ko) * | 2002-01-25 | 2004-08-30 | 다이셀 케미칼 인더스트리즈 리미티드 | 수성 수지 분산액 및 그 제조방법 |
JP4106248B2 (ja) * | 2002-07-19 | 2008-06-25 | 日本ペイント株式会社 | 複層塗膜形成方法 |
-
2007
- 2007-04-05 WO PCT/JP2007/058022 patent/WO2007119762A1/ja active Application Filing
- 2007-04-05 JP JP2008510973A patent/JP5225073B2/ja active Active
- 2007-04-05 CN CN2007800132564A patent/CN101421367B/zh active Active
- 2007-04-05 GB GB0820044A patent/GB2453266B/en active Active
- 2007-04-05 US US12/226,268 patent/US7842751B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07207220A (ja) * | 1994-01-25 | 1995-08-08 | Kansai Paint Co Ltd | 水性塗料組成物及びそれを用いた塗装法 |
JP2000154204A (ja) * | 1998-09-17 | 2000-06-06 | Kansai Paint Co Ltd | ゲル化重合体微粒子の製造方法 |
JP2005343966A (ja) * | 2004-06-01 | 2005-12-15 | Kansai Paint Co Ltd | 水性樹脂分散体の製造方法 |
WO2006009219A1 (ja) * | 2004-07-22 | 2006-01-26 | Kansai Paint Co., Ltd. | 熱硬化性水性塗料組成物及び塗膜形成方法 |
JP2006176618A (ja) * | 2004-12-22 | 2006-07-06 | Kansai Paint Co Ltd | 熱硬化性水性塗料及び塗膜形成方法 |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8575259B2 (en) | 2007-12-12 | 2013-11-05 | Kansai Paint Co., Ltd. | Water-based paint compositions |
GB2467701B (en) * | 2007-12-12 | 2013-03-13 | Kansai Paint Co Ltd | Water-based paint compositions |
GB2467701A (en) * | 2007-12-12 | 2010-08-11 | Kansai Paint Co Ltd | Water based paint compositions |
JP2011506620A (ja) * | 2007-12-12 | 2011-03-03 | 関西ペイント株式会社 | 水性塗料組成物 |
WO2009075389A1 (en) * | 2007-12-12 | 2009-06-18 | Kansai Paint Co., Ltd. | Water-based paint compositions |
KR20100111727A (ko) * | 2008-02-15 | 2010-10-15 | 바스프 코팅스 게엠베하 | 수성 코팅 조성물, 이의 제조 방법 및 이의 용도 |
KR101694415B1 (ko) | 2008-02-15 | 2017-01-09 | 바스프 코팅스 게엠베하 | 수성 코팅 조성물, 이의 제조 방법 및 이의 용도 |
US8128744B2 (en) * | 2008-02-15 | 2012-03-06 | BASF Coating GmbH | Aqueous coating composition, method for production of the same, and use thereof |
JP2011515502A (ja) * | 2008-03-18 | 2011-05-19 | 関西ペイント株式会社 | 水性塗料組成物及び複層塗膜形成方法 |
JP2011525415A (ja) * | 2008-06-24 | 2011-09-22 | 関西ペイント株式会社 | 複層塗膜形成方法 |
JP2011131135A (ja) * | 2009-12-22 | 2011-07-07 | Nippon Paint Co Ltd | 複層塗膜形成方法 |
JP2011195838A (ja) * | 2010-03-23 | 2011-10-06 | Evonik Goldschmidt Gmbh | 製紙および紙加工用カーテン安定剤 |
CN101942254B (zh) * | 2010-09-29 | 2012-05-30 | 山东大学 | 一种含有纳米核壳结构聚吡咯的水性导电防腐涂料 |
CN101942254A (zh) * | 2010-09-29 | 2011-01-12 | 山东大学 | 一种含有纳米核壳结构聚吡咯的水性导电防腐涂料 |
CN113355002A (zh) * | 2020-03-04 | 2021-09-07 | 关西涂料株式会社 | 涂料组合物和多层涂膜形成方法 |
CN113355002B (zh) * | 2020-03-04 | 2024-01-30 | 关西涂料株式会社 | 涂料组合物和多层涂膜形成方法 |
Also Published As
Publication number | Publication date |
---|---|
US7842751B2 (en) | 2010-11-30 |
CN101421367B (zh) | 2012-07-11 |
JPWO2007119762A1 (ja) | 2009-08-27 |
US20090305050A1 (en) | 2009-12-10 |
GB0820044D0 (en) | 2008-12-10 |
CN101421367A (zh) | 2009-04-29 |
GB2453266B (en) | 2011-11-02 |
GB2453266A (en) | 2009-04-01 |
JP5225073B2 (ja) | 2013-07-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2007119762A1 (ja) | 水性塗料組成物 | |
JP6180497B2 (ja) | 共重合体、該共重合体を含有する水性塗料組成物及び複層塗膜形成方法 | |
JP5148480B2 (ja) | 光輝性複層塗膜の形成方法 | |
JP5049963B2 (ja) | 光輝性顔料含有水性ベースコート塗料 | |
JP5116486B2 (ja) | 光輝性複層塗膜の形成方法 | |
JP5464575B2 (ja) | 積層塗膜形成方法および塗装物 | |
JP6851329B2 (ja) | 光輝性顔料含有水性ベースコート塗料、及びこれを用いた複層塗膜形成方法 | |
WO2009075389A1 (en) | Water-based paint compositions | |
WO2009157588A1 (en) | Method for forming multilayer coating film | |
WO2006028262A1 (ja) | 熱硬化性水性塗料組成物 | |
JP2008138179A (ja) | 水性ベース塗料組成物 | |
WO2008013290A1 (fr) | Composition aqueuse de revêtement | |
JPWO2007126134A1 (ja) | 水性塗料組成物 | |
JP6833016B2 (ja) | 複層塗膜形成方法 | |
JP2015187246A (ja) | 水性着色ベース塗料組成物及びそれを用いた補修塗装方法 | |
JP2017159217A (ja) | 複層塗膜形成方法 | |
JP2009114392A (ja) | 水性中塗り塗料 | |
JP4106248B2 (ja) | 複層塗膜形成方法 | |
JP4829416B2 (ja) | 水性着色ベース熱硬化型塗料とそれを使用した塗膜形成方法 | |
JP2009275170A (ja) | ビニル系重合体の製造方法、該ビニル系重合体を含有する塗料及び該塗料を用いた塗膜の形成方法。 | |
JP4280137B2 (ja) | 補修塗装工法 | |
JPWO2018079315A1 (ja) | Abaトリブロックポリマー、粘性調整剤及び水性塗料組成物 | |
JPWO2009081943A1 (ja) | 複層塗膜形成方法 | |
JP4673956B2 (ja) | 硬化性樹脂組成物及び上塗り塗膜形成方法 | |
WO2020203397A1 (ja) | 水性塗料組成物及び複層塗膜形成方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 07741458 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008510973 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 200780013256.4 Country of ref document: CN |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12226268 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 0820044 Country of ref document: GB Kind code of ref document: A Free format text: PCT FILING DATE = 20070405 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 0820044.6 Country of ref document: GB |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 07741458 Country of ref document: EP Kind code of ref document: A1 |