WO2006070543A1 - コーティング用組成物、ハードコートフィルムおよび光記録媒体 - Google Patents
コーティング用組成物、ハードコートフィルムおよび光記録媒体 Download PDFInfo
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- WO2006070543A1 WO2006070543A1 PCT/JP2005/021463 JP2005021463W WO2006070543A1 WO 2006070543 A1 WO2006070543 A1 WO 2006070543A1 JP 2005021463 W JP2005021463 W JP 2005021463W WO 2006070543 A1 WO2006070543 A1 WO 2006070543A1
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- WIPO (PCT)
- Prior art keywords
- hard coat
- organic compound
- coating composition
- compound
- oligomer
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/16—Chemical modification with polymerisable compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
- C09D171/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/044—Forming conductive coatings; Forming coatings having anti-static properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/056—Forming hydrophilic coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/10—Block or graft copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/254—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
- G11B7/2542—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers consisting essentially of organic resins
- G11B7/2545—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers consisting essentially of organic resins containing inorganic fillers, e.g. particles or fibres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/256—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers improving adhesion between layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/261—In terms of molecular thickness or light wave length
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Definitions
- the present invention provides an optical recording medium comprising the hard coat film (Inventions 5 and 6) (Invention 7).
- the reactive particles (A) can be produced by reacting the inorganic oxide particles with the organic compound (a).
- the surface of the inorganic oxide particles reacts with the organic compound (a). It is thought that there are components to be obtained, and the powdered inorganic oxide particles or the solvent-dispersed sol of inorganic oxide particles and the organic compound (a) are mixed in the presence or absence of moisture, and heated and stirred. By the treatment, the surface component of the inorganic oxide particles reacts with the organic compound (a) to obtain reactive particles (A).
- the content (in terms of solid content) of the first organic compound (B) in the coating composition is 20 to 80% by mass, preferably 30 to 70% by mass.
- the content of the first organic compound (B) is less than 20% by mass, the antistatic property of the coating layer obtained by curing the coating composition is insufficient, and the content of the first organic compound (B) is not sufficient.
- the amount exceeds 80% by mass the hardness of the resulting coating layer becomes insufficient.
- the hard coat layer has high hardness due to the action of the reactive particles (A) and the second organic compound (C), and exhibits excellent scratch resistance and scratch resistance. In addition, it exhibits excellent antistatic properties by the action of the first organic compound (B), and excellent fingerprint wiping properties by the action of the siloxane compound (D). Furthermore, even if the object to be coated is a plastic film, the warp of the plastic film is suppressed mainly by the effect of reducing the curing shrinkage of the reactive particles (A).
- Example 2 As the first organic compound (B), instead of EO-modified pentaerythritol tetraatalylate, trimethylolpropane tritalylate (manufactured by Shin-Nakamura KK, NK ester A-TMPT-6EO, solid content: 100 Mass%, Trifunctional, EO content: 47. 1%) A coating composition was prepared in the same manner as in Example 1 except that 60 parts by mass (D1 content (solid content conversion): 4. 0% by mass), and using the resulting coating composition, a hard coat film was produced in the same manner as in Example 1.
- Fingerprint mark wiping test Fingerprint marks were attached to the surface of the node coat film produced in the example or comparative example, and the fingerprint marks were wiped off by reciprocating five times with tissue paper. Thereafter, the surface condition of the hard coat film was visually evaluated according to the following criteria. The results are shown in Table 1.
- the total light transmittance and haze value of the node coat film produced in the examples or comparative examples were measured according to JIS K7105 using a haze meter (Nippon Denshoku Industries Co., Ltd., NDH2000). The results are shown in Table 1.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
- Paints Or Removers (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2005800475048A CN101111580B (zh) | 2004-12-28 | 2005-11-22 | 涂层用组合物、硬涂膜及光记录介质 |
| US11/794,358 US20070298248A1 (en) | 2004-12-28 | 2005-11-22 | Coating Composition, Hard Coat Film, and Optical Recording Medium |
| EP05809498A EP1835001A4 (en) | 2004-12-28 | 2005-11-22 | COATING COMPOSITION, HARD COIL FILM AND OPTICAL RECORDING MEDIUM |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004-382026 | 2004-12-28 | ||
| JP2004382026A JP4703180B2 (ja) | 2004-12-28 | 2004-12-28 | コーティング用組成物、ハードコートフィルムおよび光記録媒体 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2006070543A1 true WO2006070543A1 (ja) | 2006-07-06 |
Family
ID=36614669
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2005/021463 WO2006070543A1 (ja) | 2004-12-28 | 2005-11-22 | コーティング用組成物、ハードコートフィルムおよび光記録媒体 |
Country Status (7)
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8303704B2 (en) | 2006-11-15 | 2012-11-06 | Lg Chem, Ltd. | Siloxane based coating composition having excellent dyeabililty abrasion resistance, glossiness and transparency, and a preparation method thereof, and an optical lens coated by said coating composition |
| WO2019013082A1 (ja) * | 2017-07-13 | 2019-01-17 | リンテック株式会社 | ハードコート剤及び積層フィルム |
| CN116323188A (zh) * | 2020-09-29 | 2023-06-23 | 中国涂料株式会社 | 防污涂料组合物 |
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| US20100040871A1 (en) * | 2007-03-08 | 2010-02-18 | Kimoto Co., Ltd. | Hard coat film and layered material |
| TWI607231B (zh) * | 2007-07-04 | 2017-12-01 | 琳得科股份有限公司 | 硬被覆膜 |
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| EP2455938A4 (en) * | 2009-07-17 | 2014-06-25 | Sharp Kk | RECORDING MEDIUM FOR OPTICAL INFORMATION |
| CN102190915B (zh) * | 2010-01-25 | 2014-06-25 | 株式会社普利司通 | 光聚合性组合物及使用其的功能性面板 |
| CN102762371A (zh) * | 2010-02-26 | 2012-10-31 | 帝人杜邦薄膜日本有限公司 | 硬涂层膜及其制造方法 |
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- 2005-11-22 KR KR1020077016882A patent/KR101098222B1/ko active Active
- 2005-11-22 CN CN2005800475048A patent/CN101111580B/zh active Active
- 2005-11-22 US US11/794,358 patent/US20070298248A1/en not_active Abandoned
- 2005-11-22 EP EP05809498A patent/EP1835001A4/en not_active Withdrawn
- 2005-11-25 TW TW094141442A patent/TW200630448A/zh unknown
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8303704B2 (en) | 2006-11-15 | 2012-11-06 | Lg Chem, Ltd. | Siloxane based coating composition having excellent dyeabililty abrasion resistance, glossiness and transparency, and a preparation method thereof, and an optical lens coated by said coating composition |
| CN101617009B (zh) * | 2006-11-15 | 2013-12-04 | Lg化学株式会社 | 具有优异的染色性、耐磨性、光泽度和透明度的基于硅氧烷的涂料组合物，其制备方法及由该涂料组合物涂覆的光学透镜 |
| WO2019013082A1 (ja) * | 2017-07-13 | 2019-01-17 | リンテック株式会社 | ハードコート剤及び積層フィルム |
| JPWO2019013082A1 (ja) * | 2017-07-13 | 2020-05-07 | リンテック株式会社 | ハードコート剤及び積層フィルム |
| JP7111709B2 (ja) | 2017-07-13 | 2022-08-02 | リンテック株式会社 | ハードコート剤及び積層フィルム |
| CN116323188A (zh) * | 2020-09-29 | 2023-06-23 | 中国涂料株式会社 | 防污涂料组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006188557A (ja) | 2006-07-20 |
| EP1835001A4 (en) | 2010-01-06 |
| TWI367237B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2012-07-01 |
| CN101111580A (zh) | 2008-01-23 |
| TW200630448A (en) | 2006-09-01 |
| US20070298248A1 (en) | 2007-12-27 |
| KR101098222B1 (ko) | 2011-12-27 |
| CN101111580B (zh) | 2012-04-25 |
| KR20070091033A (ko) | 2007-09-06 |
| JP4703180B2 (ja) | 2011-06-15 |
| EP1835001A1 (en) | 2007-09-19 |
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