WO2006035868A1 - Perruque en polyester ignifuge - Google Patents

Perruque en polyester ignifuge Download PDF

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Publication number
WO2006035868A1
WO2006035868A1 PCT/JP2005/017941 JP2005017941W WO2006035868A1 WO 2006035868 A1 WO2006035868 A1 WO 2006035868A1 JP 2005017941 W JP2005017941 W JP 2005017941W WO 2006035868 A1 WO2006035868 A1 WO 2006035868A1
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Prior art keywords
flame retardant
polyester
flame
artificial hair
retardant
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PCT/JP2005/017941
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English (en)
Japanese (ja)
Inventor
Toshiyuki Masuda
Original Assignee
Kaneka Corporation
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Priority to JP2006537799A priority Critical patent/JPWO2006035868A1/ja
Publication of WO2006035868A1 publication Critical patent/WO2006035868A1/fr

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/252—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing bromine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

Definitions

  • the present invention relates to a flame retardant polyester obtained by exhausting a polyester filament formed from a composition containing a flame retardant assistant, organic fine particles and Z or inorganic fine particles in polyester. It relates to artificial hair. More specifically, it relates to artificial hair that maintains fiber properties such as flame retardancy, heat resistance, and high elongation, and is excellent in gloss, touch, comb, and setability.
  • Polyethylene terephthalate or a fiber made of polyester terephthalate mainly composed of polyethylene terephthalate has a high melting point, a high elastic modulus, and excellent heat resistance and chemical resistance. Therefore, curtains, rugs, clothing, Widely used in blankets, sheets, tablecloths, chair upholstery, wall coverings, human hair, automotive interior materials, outdoor reinforcements, safety nets, etc.
  • modacrylic fiber As an artificial hair material, modacrylic fiber has been frequently used due to its flame-retardant characteristics, but it is insufficient in terms of heat resistance.
  • the fiber having a polyester strength represented by polyethylene terephthalate is insufficient in flame resistance since it is a flammable material.
  • Patent Documents 2 and 3 As a method of copolymerizing a flame retardant monomer, a polyester fiber copolymerized with a phosphorus compound (Patent Documents 2 and 3) has been proposed, but sufficient flame retardancy is obtained. In order to achieve this, the amount of copolymerization must be increased, and as a result, the heat resistance of the polyester is greatly reduced, making melt spinning difficult. Melting'drips would cause problems.
  • Patent Document 5 a method of incorporating a flame retardant into a polyester fiber by post-processing (flame retardant exhaustion)
  • Patent Document 5 A method of containing a bromine atom-containing alkylcyclohexane (Patent Document 5) has been proposed.
  • Patent Document 5 A method of containing a bromine atom-containing alkylcyclohexane (Patent Document 5)
  • Patent Document 4 discloses a technique for finely dispersing a halogenated cycloalkane compound in order to improve the exhaust efficiency of a flame retardant, but it is more than that of a halogenated cycloalkane compound.
  • halogenated aromatic flame retardants having high hydrophobicity there was a problem that it was difficult to stabilize the finely dispersed state.
  • Patent Document 6 A method for improving dyeability and flame retardant exhaustion (Patent Document 6) has been proposed.
  • this method has the problem that the heat resistance becomes insufficient due to the lowering of the melting point of the polyester itself, so that troubles in fusion are likely to occur, and the color change is likely to occur due to the decrease in light resistance. It was left behind.
  • Patent Document 1 Japanese Patent Laid-Open No. 9-268423
  • Patent Document 2 Japanese Patent Laid-Open No. 3-27105
  • Patent Document 3 Japanese Patent Laid-Open No. 5-339805
  • Patent Literature 4 Japanese Patent Publication No. 3-57990
  • Patent Document 5 Japanese Patent Publication No. 1-24913
  • Patent Document 6 Japanese Patent Laid-Open No. 9-324315
  • the present invention solves the conventional problems as described above, maintains the fiber properties such as heat resistance and strength of ordinary polyester fiber, and has flame retardancy, gloss, touch, combing and setability.
  • Another object of the present invention is to provide a flame-retardant polyester artificial hair which is excellent and has a controlled fiber wrinkle.
  • a polyester filament formed of a composition containing a flame retardant aid, organic fine particles and Z or inorganic fine particles in polyester is used.
  • Flame retardant polyester-based artificial fabric that maintains the physical properties of ordinary polyester fibers such as heat resistance and tensile strength, and has excellent flame retardancy, gloss, touch, combing and setability.
  • the inventors have found that hair fibers can be obtained and have completed the present invention.
  • the present invention relates to a flame retardant aid (B) 0 with respect to 100 parts by weight of a polyester (A) having at least one kind of polyalkylene terephthalate or a copolymer polyester mainly composed of polyalkylene terephthalate.
  • Polyester filaments formed from a resin composition containing ⁇ 10 parts by weight and organic fine particles (C) and Z or inorganic fine particles (D) 0.1 to 5 parts by weight
  • a flame retardant polyester-based artificial hair fiber obtained by exhausting a flame retardant, wherein the flame retardant (E) has an exhaust amount of 2 to 20% by weight based on the polyester filament.
  • Sarakuko relates to a flame-retardant polyester artificial hair obtained by simultaneously dyeing the above-mentioned flame-retardant polyester artificial hair at the time of exhausting the flame retardant.
  • a preferable embodiment is the above-mentioned flame-retardant polyester artificial hair fiber, which is at least one polymer selected from the group consisting of polyethylene terephthalate, polypropylene terephthalate and polybutylene terephthalate.
  • the group power consisting of melamine cyanurate, antimony triacid, antimony triacid, antimony tetraacid, antimony pentaacid and sodium antimonate was also selected as the form of flame retardant aid (B). It is a flame-retardant polyester artificial hair fiber that is at least one type.
  • the organic fine particles (C) are at least one selected from the group consisting of polyarylate, polyamide, fluorine resin, silicone resin, crosslinked acryl resin and crosslinked polystyrene. It is a fiber for polyester-based artificial hair.
  • the inorganic fine particles (D) are at least one selected from the group force consisting of calcium carbonate, silicon oxide, titanium oxide, aluminum oxide, zinc oxide, talc, ferroline, montmorillonite, bentonite and my power. It is a fiber for flame retardant polyester-based artificial hair that is a seed.
  • the flame retardant (E) used for the flame retardant exhaust processing is a phosphorus flame retardant, a bromine-containing phosphorus flame retardant, a brominated aliphatic flame retardant, a brominated aromatic flame retardant.
  • a more preferred embodiment is a flame retardant polyester artificial hair in which the flame retardant (E) has a melting point of 160 ° C or higher.
  • a more preferred embodiment is a flame-retardant polyester artificial hair in which the flame retardant (E) has a molecular weight of 200 to 4000.
  • a more preferable embodiment is a flame retardant polyester artificial hair in which the exhaust amount of the flame retardant (E) is 3 to 20% by weight.
  • dyeing and flame retardant absorption for polyester filaments are preferred.
  • the present invention relates to a flame-retardant polyester artificial hair in which exhaustion is simultaneously performed at a temperature of 90 to 150 ° C., and the polyester artificial hair contains 0.1% by weight or more of a dye.
  • the flame-retardant polyester-based artificial hair fibers are preferably non-crimped raw silk and have a single fiber fineness of 10 to 1 OOdtex! / ⁇ .
  • a polyester-based filament formed from a composition containing a flame retardant aid and organic fine particles and Z or inorganic fine particles in polyester is subjected to a flame retardant exhausting process, thereby obtaining a normal polyester. It is possible to obtain polyester-based artificial hair that maintains the fiber properties such as heat resistance and tensile strength of the fiber, and is excellent in flame retardancy, gloss, touch, combing and setability.
  • the flame retardant polyester artificial hair of the present invention comprises a polyester (A), a flame retardant aid (B), and a polyester (A), a copolymer polyester mainly composed of polyalkylene terephthalate or polyalkylene terephthalate. Further, it is an artificial hair obtained by subjecting a polyester filament (fiber), which also has a compositional force containing organic fine particles (C) and Z or inorganic fine particles (D), to a flame retardant exhaustion process.
  • a polyester filament fiber
  • C organic fine particles
  • D inorganic fine particles
  • Sarakuko is the flame retardant polyester artificial hair of the present invention, which is an artificial hair obtained by dyeing the polyester filament simultaneously with the flame retardant exhausting process.
  • the polyalkylene terephthalate or the copolyester mainly composed of polyalkylene terephthalate contained in the polyester (A) used in the present invention includes, for example, polyalkylene terephthalate such as polyethylene terephthalate, polypropylene terephthalate and polybutylene terephthalate. And z or a copolymerized polyester mainly composed of these polyalkylene terephthalates and containing a small amount of a copolymer component.
  • polyethylene terephthalate, polypropylene terephthalate, and polybutylene terephthalate are particularly preferred from the standpoint of availability and cost. Yes.
  • the main component refers to containing 80 mol% or more.
  • Examples of the copolymer component include isophthalic acid, orthophthalic acid, naphthalenedicarboxylic acid, para-phenolic dicarboxylic acid, trimellitic acid, pyromellitic acid, succinic acid, glutaric acid, adipic acid, speric acid, and azelain.
  • Polycarboxylic acids such as acid, sebacic acid, dodecanedioic acid, rubonic acid, derivatives thereof, dicarboxylic acids including sulfonic acid salts such as 5-sodium sulfoisophthalic acid, dihydroxyethyl 5-sodium sulfoisophthalate, derivatives thereof, 1,2 propanediol, 1,3 propanediol, 1,4 butanediol, 1,6-hexanediol, neopentyl glycol, 1,4-cyclohexanedimethanol, diethylene glycolol, polyethylene glycol, trimethylolpropane , Pentaerythritol, 4-hydroxybenzoic acid Acid, epsilon prolatathon, etc.
  • sulfonic acid salts such as 5-sodium sulfoisophthalic acid, dihydroxyethyl 5-sodium sulfoisophthalate, derivatives thereof, 1,
  • the copolyester is usually made to react by containing a small amount of a copolymer component in a polymer of terephthalic acid, which is the main component, and a derivative thereof (for example, methyl terephthalate) and alkylene glycol.
  • a smaller amount of co-polymer is added to a mixture of the main terephthalic acid and cocoon or a derivative thereof (for example, methyl terephthalate) and alkylene glycol.
  • Manufacture by polymerizing a monomer or oligomer component that is a polymerization component.
  • the copolymer polyester is not particularly limited in the way of copolymerization and the like as long as the copolymer component is polycondensed to the main chain and side or side chain of the main polyalkylene terephthalate. .
  • copolymer polyester mainly composed of the polyalkylene terephthalate include, for example, a polyester mainly composed of polyethylene terephthalate and copolymerized with ethylene glycol ether of bisphenol, 1,4-cyclohexanedimethanol.
  • polyesters copolymerized and polyesters copolymerized with 5-hydroxysulfoisophthalate dihydroxyethyl include, for example, a polyester mainly composed of polyethylene terephthalate and copolymerized with ethylene glycol ether of bisphenol, 1,4-cyclohexanedimethanol. Examples include polyesters copolymerized and polyesters copolymerized with 5-hydroxysulfoisophthalate dihydroxyethyl.
  • the polyalkylene terephthalate or copolyester may be used singly or in combination of two or more.
  • polyethylene terephthalate Polypropylene terephthalate, polybutylene terephthalate, copolymerized polyester (polyester mainly composed of polyethylene terephthalate and copolymerized with ethylene glycol ether of bisphenol A, polyester copolymerized with 1,4-cyclohexanedimethanol, 5- Polyesters copolymerized with sodium sulfoisophthalate dihydroxyethyl) are preferred, and those in which two or more are mixed are also preferred.
  • the glass transition temperature of the polyester (A) used in the present invention is preferably 60 to 115 ° C, more preferably 65 to 105 ° C.
  • the glass transition temperature of the polyester (A) is lower than 60 ° C, the heat resistance tends to be inadequate and the ironing property tends to be reduced.
  • the glass transition temperature is higher than 115 ° C, the flame retardant There is a tendency for the dyeability to decrease.
  • the intrinsic viscosity of the polyester (A) used in the present invention is preferably 0.5 to 1.4, more preferably 0.6 to 1.2. If the intrinsic viscosity is less than 0.5, the mechanical strength of the resulting fiber tends to decrease, and if it exceeds 1.4, the melt viscosity increases with increasing molecular weight, making melt spinning difficult, There is a tendency for the fineness to become uneven.
  • the flame retardant aid (B) used in the present invention is difficult to interact with phosphorus-based flame retardants or bromine-containing flame retardants used in post-processing such as nitrogen-containing compounds or antimony compounds. As long as the effect of imparting flammability can be enhanced, it can be used without particular limitation.
  • Specific examples of the nitrogen-containing compound in the present invention include melamine cyanurate.
  • Specific examples of the antimony compound in the present invention include, for example, antimony trimonate, antimony tetroxide, antimony pentoxide, and sodium antimonate. These may be surface-treated with an epoxy compound, a silane compound, an isocyanate compound, a titanate compound, or the like, if necessary.
  • the flame retardant aid (B) used in the present invention can be used if it has an average particle size of 15 m or less.
  • the average particle size of the auxiliary agent (B) is preferably 0.2 m or less or 1.5 to 15 m, preferably 0.15 / zm or less or 1.7 to 12 111, more preferably 0 or less or 1.9.
  • ⁇ : LO / zm is more preferable.
  • the amount of the flame retardant aid (B) used in the present invention is 100 parts by weight of polyester. 0 to 10 parts by weight is preferred 0.5 to 10 parts by weight is more preferred 0.7 to 8 parts by weight is even more preferred. Flame retardancy is exhibited even when the amount of flame retardant aid (B) used is 0 parts by weight, but in order to obtain higher flame retardancy, it is preferable to use 0.5 parts by weight or more. When the amount of the flame retardant aid (B) used is more than 10 parts by weight, the processing stability, appearance and transparency tend to be impaired.
  • any organic resin component having a structure that is incompatible with or partially incompatible with the main component polyester (A) is used.
  • polyarylate, polyamide, fluorine resin, silicone resin, bridged acrylic resin, crosslinked polystyrene, etc. are preferably used. These may be used alone or in combination of two or more.
  • crosslinked polyester particles and crosslinked acrylic particles are preferred from the viewpoint of heat resistance and dispersibility.
  • the crosslinked polyester particles are obtained by water-dispersing the unsaturated polyester and the bull-type monomer, followed by crosslinking and curing.
  • the unsaturated polyester used here is not particularly limited, for example, ex, j8-unsaturated acid or a mixture of it and a saturated acid and a dihydric alcohol or a trihydric alcohol polymerized. Can do.
  • Examples of the unsaturated acid include fumaric acid, maleic acid, and itaconic acid.
  • Examples of the saturated acid include phthalic acid, terephthalic acid, succinic acid, dartaric acid, tetrahydrophthalic acid, adipic acid, and sebacic acid. can give.
  • dihydric alcohols and trihydric alcohols examples include ethylene glycol, diethylene glycol, propylene glycol, neopentyl glycol, 1,3-propanediol, 1,6-hexanediol, trimethylolpropane, and the like.
  • the vinyl monomer is not particularly limited, and examples thereof include styrene, chlorostyrene, butyltoluene, dibulene benzene, acrylic acid, methyl acrylate, acrylonitrile, ethyl acrylate and diallyl phthalate. It is done.
  • the crosslinked acrylic particles are obtained by water-dispersing an acrylic monomer and a crosslinking agent and crosslinking and curing.
  • acrylic monomers used herein include acrylic acid and acrylic acid derivatives such as methyl acrylate, butyl acrylate, hexyl acrylate, cyclohexyl acrylate, hydroxyethyl acrylate, and acrylonitrile.
  • methacrylic acid examples include N-but-2-pyrrolidone, metatali-tolyl, methacrylamide, N-methylolmethacrylamide, 2-methacrylic acid 2-hydroxyethyl having a single bull group in one molecule. . These can be used alone or in combination of two or more.
  • the crosslinking agent may be any monomer as long as it has two or more bur groups in one molecule, but one having two vinyl groups in one molecule is preferable.
  • the preferable monomer include dibutenebenzene, a reaction product of glycol and methacrylic acid or acrylic acid (for example, ethylene glycol dimetatalylate, neopentyldaricol dimetatalylate, etc.). However, it is not limited to these.
  • the addition amount of the crosslinking agent is preferably 0.02 to 5 parts by weight per 100 parts by weight of the monomer having one vinyl group.
  • peroxide radical polymerization initiators such as benzoyl peroxide, 2-ethylhexyl perbenzoate, di-tert-butyl peroxide, cumene hydroperoxide, methyl. Ethyl ketone peroxide and the like.
  • the radical polymerization initiator is preferably used in an amount of 0.05 to L0 parts by weight per 100 parts by weight of the monomer having one vinyl group.
  • the inorganic fine particles (D) used in the present invention preferably have a refractive index close to the refractive index of the polyester (A) because of the effect on the transparency and color developability of the fibers.
  • Specific examples of inorganic fine particles include, for example, calcium carbonate, silicon oxide, titanium oxide, acid aluminum aluminum, acid sodium hydroxide, kaolin, montmorillonite, bentonite, my strength, and melamine resin.
  • composite particles such as Z-silica composites, mainly composed of acid and oxide oxides. These may be used alone or in combination of two or more.
  • the inorganic fine particles (D) used in the present invention may be surface-treated with an epoxy compound, a silane compound, an isocyanate compound, a titanate compound, or the like, if necessary.
  • the average particle size of the organic fine particles (C) and Z or inorganic fine particles (D) is preferably 0.1 to 15 m force S, more preferably 0.2 to 10 m force, and more preferably 0.5 to 8 111. preferable.
  • the particle size is smaller than 0.1 ⁇ m, the gloss adjustment effect tends to be small, and when the particle size is larger than 15 m, the gloss adjustment effect tends to be small or thread breakage tends to occur. There is.
  • the amount of organic fine particles (C) and Z or inorganic fine particles (D) used in the present invention is not particularly limited, but is preferably 0.1 to 5 parts by weight per 100 parts by weight of polyester. 2 to 3 parts by weight is more preferred 0.3 to 2 parts by weight is even more preferred. If the amount of organic fine particles (C) and Z or inorganic fine particles (D) used exceeds 5 parts by weight, appearance, hue and color development tend to be impaired. Since there are fewer fine protrusions formed on the surface, there is a tendency that gloss adjustment on the fiber surface is insufficient.
  • the polyester-based composition used in the present invention includes, for example, polyester (A), flame retardant aid (B), and organic fine particles (C) and Z or orientation fine particles (D) after dry blending. It can manufacture by melt-kneading using the general kneading machine.
  • Examples of the kneader include, for example, a single screw extruder, a twin screw extruder, a roll, a Banbury mixer, and a kneader. Of these, the twin screw extruder is also preferable because of adjustment of the kneading degree and ease of operation.
  • the barrel temperature is 260-300 ° C
  • the discharge rate is 50-150 kgZhr
  • the screw rotation speed is 150-200 rpm
  • the strand is taken out from the die.
  • the composition of the present invention can be obtained by pelletizing with a strand cutter.
  • the flame-retardant polyester artificial hair of the present invention can be produced by melt spinning the flame-retardant polyester composition by a normal melt spinning method.
  • the temperature of the extruder, gear pump, die, etc. is set to 270 to 310 ° C, melt-spun, and the spun yarn is passed through a heating tube, and then cooled to the glass transition point or lower.
  • ⁇ 500 A spun yarn is obtained by taking it up at a speed of OmZ. It is also possible to control the fineness by cooling the spun yarn in a water tank containing cooling water. The temperature and length of the heating cylinder, the temperature and amount of cooling air, the temperature of the cooling water tank, the cooling time, and the take-up speed can be adjusted as appropriate according to the discharge amount and the number of holes in the base.
  • the obtained unstretched yarn is heat-stretched, and stretching can be performed by either a two-step method in which the unstretched yarn is first wound and then stretched, or a direct spin-stretching method in which stretching is continuously performed without winding. It is also possible to use this method.
  • the hot stretching is performed by a single-stage stretching method or a multi-stage stretching method having two or more stages.
  • a heating means in the heat stretching a heating roller, a heat plate, a steam jet device, a hot water tank, or the like can be used, and these can be used in combination as appropriate.
  • the flame retardant polyester-based artificial hair of the present invention includes various kinds of heat-resistant agents, light stabilizers, fluorescent agents, antioxidants, antistatic agents, pigments, plasticizers, lubricants, and the like as necessary. Additives can be included. By incorporating a pigment, a primary fiber can be obtained.
  • the flame-retardant polyester artificial hair of the present invention can use a silicone fiber treatment agent, a non-silicone fiber treatment agent, and the like in order to improve the feel and combing.
  • silicone fiber treating agent examples include dimethylpolysiloxane, methylhydrogen polysiloxane, hydroxylated dimethylpolysiloxane at both terminals, vinyl group-containing organopolysiloxane, epoxy group-containing organopolysiloxane, and amino group-containing organopolysiloxane. Sun, ester group-containing organopolysiloxane, and polyoxyalkylene-containing organopolysiloxane.
  • non-silicone fiber treating agent examples include polyether compounds, fatty acid ester compounds, organic amine compounds, and organic amides. Examples thereof include organic compounds, organic fatty acid esters, organic ammonium salts, organic fatty acid salts, organic sulfonic acid salts, organic sulfuric acid ester salts, and organic phosphoric acid ester salts.
  • a necessary amount of the fiber treatment agent may be attached at the time of spinning, or may be attached at the time of exhausting the flame retardant, or may be attached after the exhausting of the flame retardant.
  • the flame retardant (E) used in the present invention includes a phosphorus flame retardant, a bromine-containing phosphorus flame retardant, a brominated cycloalkane flame retardant, a brominated aromatic flame retardant, a brominated polystyrene flame retardant, Brominated benzaryl acrylate flame retardant, brominated epoxy flame retardant, brominated polycarbonate flame retardant, tetrabromobisphenol A derivative, bromine-containing triazine At least one selected from a compound and a bromine-containing isocyanuric acid compound
  • flame retardant (E) examples include, for example, 1,4-phenolenebis (dixylyl phosphate), biphenyl-rubis (dixylenyl phosphate), and the following formulas (1) to (4): );
  • Phosphorus flame retardants such as a compound represented by the formula: Brominated aliphatic compounds such as dibromoneopentyldaricol, tribromoneopentyldaricol, hexasuboxycyclohexadecane, pentabromotoluene, hexabromobenzene, Decabromodiphenyl, Decabromodiphenyl ether, Bis (tribromophenoxy) ethane, Tetrabromophthalic anhydride, Ethylene bis (tetrabromophthalimide), Ethylene bis (pentabromophenyl), Otatab Mouth trimethylphenylindane Brominated aromatic flame retardants such as bromine-containing phosphorus flame retardants such as tris (tribromoneopentyl) phosphate, the following formula (5);
  • Brominated polycarbonate oligomers represented by: Tetrabromobisphenol A, Tetrabromobisphenol A-bis (2,3-dibromopropinole ether), Tetrabromobisphenol A-bis (aryl ether) , Bromine-containing triazine compounds such as tetrabromobisphenol A-bis (hydroxychetyl ether), tetrabromobisphenol A derivatives, tris (tribromophenoxy) triazine, tris (2,3-dibromopropyl) iso cyanurate Bromine-containing isocyanuric acid compounds such as
  • the flame retardant has a melting point of 160 ° C or higher, or the flame retardant has a molecular weight of 200 to 4000.
  • the particle size of the flame retardant (E) used has an important effect on the flame retardant performance imparted to the fiber product. The smaller the is, the higher flame retardancy can be imparted to the textile.
  • the flame retardant is sufficiently diffused into the polyester fiber by post-processing, and the flame retardant performance of the flame retardant in the polyester fiber is durable. Therefore, the flame retardant (E)
  • the average particle diameter is preferably from 0.1 to 15 111, more preferably from 0.2 to LO / zm.
  • the amount of the flame retardant to be contained is adjusted by exhausting the flame retardant to the polyester-based artificial hair, compared with the flame retardant kneading method or the copolymerization method.
  • the flame retardant content can be changed according to the required flame retardant level.
  • the exhaust amount of the flame retardant (E) in the present invention is preferably 2 to 20% by weight, more preferably 4 to 15% by weight, based on the polyester-based artificial hair. If the exhaust amount of the flame retardant (E) is less than 2% by weight, there is a tendency that sufficient flame retardancy cannot be imparted to the polyester-based artificial hair. May cause problems such as worsening.
  • the flame retardant (E) used in the flame retardant exhaust processing in the present invention is used as a dispersion liquid dispersed in water in the presence of a surfactant or a solution dissolved in an organic solvent.
  • the flame retardant (E) When the flame retardant (E) is dispersed in water, the flame retardant (E) can be made fine particles by pulverization in a dry or wet manner.
  • the surfactant to be used as a dispersion a non-ionic surfactant or a char-on surfactant is used, and a non-ionic surfactant and a char-on surfactant are used in combination. May be.
  • nonionic activator examples include higher alcohol alkylene oxide adducts, alkylphenol alkylene oxide adducts, fatty acid alkylene oxide adducts, polyhydric alcohol aliphatic ester alkylene oxide adducts, and higher alkyls.
  • examples include polyoxyalkylene type nonionic surfactants such as minalkylene oxide adducts and fatty acid amide alkylene oxide adducts, and polyhydric alcohol type nonionic surfactants such as alkylglycoxides and sucrose fatty acid esters. .
  • Examples of the above-mentioned surfactants include sulfates such as higher alcohol sulfates, higher alkyl ether sulfates, sulfated fatty acid ester salts, alkylbenzene sulfonates, alkyl naphthalene sulfones. Examples thereof include sulfonates such as acids, higher alcohol phosphate esters, and higher alcohol alkylene oxide adduct phosphate salts.
  • examples of the organic solvent include alcohols such as methanol, ethanol and isopronool, aromatic hydrocarbons such as benzene, toluene and xylene, ethers such as dioxane and ethylene glycol, acetone, Examples thereof include ketones such as methyl ethyl ketone, amides such as dimethylformamide, sulfoxides such as dimethyl sulfoxide, and halogenated hydrocarbons such as methylene chloride and chloroform.
  • alcohols such as methanol, ethanol and isopronool
  • aromatic hydrocarbons such as benzene, toluene and xylene
  • ethers such as dioxane and ethylene glycol
  • acetone examples thereof include ketones such as methyl ethyl ketone, amides such as dimethylformamide, sulfoxides such as dimethyl sulfoxide, and halogenated hydrocarbons such as methylene chloride and
  • the surfactant and the organic solvent may be used singly or in combination of two or more as required.
  • the dispersion used in the present invention can be obtained using an emulsifier or a disperser such as a homogenizer, a colloid mill, a ball mill, or a sand grinder.
  • a disperser such as a homogenizer, a colloid mill, a ball mill, or a sand grinder.
  • the solid content concentration of the aqueous dispersion of the flame retardant (E) or the organic solvent solution depends on the dispersion stability and the efficiency of exhaust processing. In this respect, 1 to 50% by weight is preferable, and 5 to 40% by weight is more preferable.
  • the exhaust amount of the flame retardant (E) in the present invention can be adjusted by adjusting the concentration of the flame retardant dispersion, the exhaust processing temperature, or the time.
  • the method for exhausting the flame retardant of the present invention is not particularly limited.
  • the flame retardant dispersion or solution is attached to the polyester artificial hair by spraying and dried. Then, there is a method in which heat treatment is performed at a temperature of 100 to 220 ° C, more preferably 140 to 190 ° C for 30 seconds to 10 minutes. If the heat treatment temperature is less than 100 ° C, the amorphous regions in the polyester fiber molecules cannot relax or expand to a level that can accept the flame retardant molecules or particles, and tend to be sufficiently exhausted. If the heat treatment temperature is higher, the flame retardant can be more firmly fixed. If the heat treatment temperature exceeds 220 ° C, the fiber strength of the artificial hair may be lowered, or there may be a problem in the separation of the fibers. .
  • a polyester artificial hair is immersed in a fuel dispersion or solution, and heat treatment is performed at a temperature of 90 to 150 ° C, more preferably 110 to 140 ° C for 3 to 60 minutes. . If the immersion heat treatment temperature is less than 90 ° C, the non-crystalline region force flame retardant molecules or particles in the polyester fiber molecules cannot relax or expand to an acceptable level and tend to be sufficiently exhausted. If the immersion heat treatment temperature exceeds 150 ° C, the fiber strength of the artificial hair may be lowered, or a fiber separation failure may occur.
  • the thus obtained flame retardant polyester-based artificial hair fiber of the present invention is a non-crimped raw fiber-like fiber, and its fineness is usually 10 to: LOOdtex, further 20 to 90 dtex. Some are suitable for artificial hair.
  • the artificial hair fiber has heat resistance that can be used for beauty heat appliances (hair irons) at 160-200 ° C, and has self-extinguishing properties that are difficult to ignite.
  • the flame-retardant polyester fiber of the present invention When the flame-retardant polyester fiber of the present invention is attached, it can be used as it is, but when it is not attached, it is dyed under the same conditions as ordinary flame-retardant polyester fiber. can do.
  • Pigments, dyes, auxiliaries and the like used for dyeing have good weather resistance and flame retardancy Is preferred.
  • the fiber for flame retardant polyester-based artificial hair of the present invention is characterized in that, when performing exhaustion processing of a flame retardant for imparting flame retardancy, dyeing is performed simultaneously and the fiber can be colored.
  • the cost can be reduced by omitting the process, and the physical properties by heating and the like can be reduced compared to the case where exhaust processing and dyeing are performed separately. It is possible to obtain a flame-retardant polyester artificial hair that does not cause deterioration in quality.
  • the dye used in the present invention is not particularly limited as long as it is generally used, and can be arbitrarily used, such as black, yellow, red, brown, etc. It may be used.
  • Specific dyes include, for example, benzeneazo (monoazo, disazo, etc.), heterocyclic azo (thiazonolezo, benzothiazonolezo, quinolineazo, pyridine azo, imidazolazo, thiophenazo, etc.), anthraquinone, Condensed dyes (quinophthalene, styryl, coumarin, etc.) disperse dyes.
  • dyeing is preferably performed in an alkaline dyeing bath having a pH of 8.0 to LO: 0, preferably pH 8.5 to 9.0.
  • a pH of 8.0 to LO preferably pH 8.5 to 9.0.
  • the pH of the dye bath exceeds 10.0, the tendency to cause hydrolysis of the dye becomes strong, and it becomes necessary to select a dye that has a high possibility of hue change.
  • the pH in the alkaline range where most dyes can be used without problems is most preferably in the range of pH 8.5 to 9.0.
  • the pH 8.0-: LO. 0 dyeing bath is the pH in a dyeing bath containing dyes, dyeing assistants, pH adjusting agents, and the like.
  • a disperse dye is mainly used, and as a dyeing assistant, a dispersant, a leveling agent, an oligomer remover, and the like are used, but the dye is not particularly limited thereto.
  • the pigment, dye, auxiliary agent, and the like used for dyeing those having good weather resistance and flame retardancy are preferable.
  • dyeing assistant a dispersant, a leveling agent, and a leveling agent, which are agents that promote dispersibility and leveling properties, can be blended.
  • dyeing assistants include naphthalenesulfonic acid formaldehyde condensate, polyoxyalkylene alkyl aryl ether, Oxyalkylene alkyl ester, polyoxyalkylene alkyl aryl ether sulfate, polyoxyalkylene alkyl ether sulfate, and the like can be used.
  • Strong dyeing assistants are preferably used in the range of 0.5 to 2 gZL.
  • the pH adjuster has a function of controlling and maintaining the pH of the dyeing bath in the range of 8.0 to: LO. 0, preferably 8.5 to 9.0.
  • LO. preferably 8.5 to 9.0.
  • a combination of sodium acetate Z pyrophosphate, sodium dihydrogen phosphate, or an organic phosphorus compound and polycarboxylic acid can be used.
  • Powerful pH adjuster preferably 0.5-2g
  • the dye is exhausted by 0.1% by weight or more with respect to the polyester-based filament.
  • a dark color such as black hair, brown or red hair is used.
  • neutral colors such as, and light colors such as blonde hair and gray hair! Therefore, it is necessary to adjust appropriately for each color.
  • the dye exhaust amount in the present invention can be adjusted by the concentration of the dyeing bath, the dyeing temperature, and the time.
  • the flame retardant polyester artificial hair fiber of the present invention is excellent in curl setting using a beauty heat instrument (hair iron) and also excellent in curl retention.
  • the flame retardant polyester-based artificial hair fibers are moderately erased by the irregularities on the fiber surface, and can be used as artificial hair.
  • the flame-retardant polyester artificial hair fiber of the present invention comprises a modacrylic fiber, a polyvinyl chloride,
  • -It may be used in combination with other artificial hair materials such as fiber or nylon fiber, or in combination with human hair.
  • Human hair used in hair products such as wigs, hair wigs, and false hairs is generally treated, decolorized and dyed with a cuticle.
  • the fiber surface treatment agent and softener used in the present invention are flammable unlike untreated human hair, but the fiber for flame-retardant polyester artificial hair of the present invention and human hair are mixed with human hair. When mixed at a rate of 60% or less, good flame retardancy is exhibited.
  • the method for measuring the characteristic value is as follows.
  • the amount of flame retardant exhausted is converted to a flame-retardant processed filament, and the resulting powder lOOmg is compression-molded, and then fluorescent using an X-ray fluorescence analyzer (manufactured by Shimadzu Corporation, EDX-700HS). X-ray analysis was performed to determine and calculate the phosphorus atom content or bromine atom content.
  • the dye concentration was determined by dissolving the obtained dyed drawn yarn in orthochlorophenol and measuring the absorbance at a wavelength of 720 nm using a colorimeter (manufactured by Tokyo Koden Co., Ltd., ANA-18A +). The exhausted dye concentration was determined.
  • a tensile and compression tester (INTESCO Model 201, manufactured by Intescone Earth), measure the tensile strength and elongation of the filament. Take a 40 mm long filament, sandwich 10 mm of both ends of the filament with a backing sheet (thin paper) to which a double-sided adhesive tape has been applied, and let it air dry overnight to produce a 20 mm long sample. Place the sample on the tester, perform the test at a temperature of 24 ° C, humidity of 80% or less, load lZ30gF X fineness (denier), tensile speed 20mmZ, and measure the tensile strength and elongation at break. Repeat the test 10 times under the same conditions, and use the average value as the filament elongation.
  • INTESCO Model 201 manufactured by Intescone Earth
  • An evaluation was made by injecting a 20 mm flame into a fixed filament with an effective length of 120 mm for 3 seconds and burning it.
  • X l l or more.
  • a tow filament with a length of 30 cm and a total fineness of 100,000 dtex is visually evaluated under sunlight.
  • a tow filament with a length of 30 cm and a total fineness of 100,000 dtex is visually evaluated under sunlight.
  • POZEO random copolymer manufactured by Maruhishi Oil Chemical Co., Ltd., KWC-Q
  • cationic antistatic agent Maruhishi
  • a comb made by Delrin Sabah
  • the raw materials used in the examples and comparative examples are as follows.
  • polyester pellets for use PESM6100 B LACK manufactured by Dainichi Seika Kogyo Co., Ltd., carbon black content 30%, polyester content is included in the polyester (A) component
  • 2 parts are added and dry blended (Japan) It was supplied to Steelworks Co., Ltd. (TEX44), melt-kneaded at a barrel set temperature of 280 ° C, pelletized, and dried to a water content of lOOppm or less.
  • melt spinning machine (SV30, manufactured by Shinko Machinery Co., Ltd.), from a spinneret (set temperature 280 ° C) having a round cross-section nozzle hole with a nozzle diameter of 0.5 mm at a barrel set temperature of 280 ° C.
  • the molten polymer was discharged, cooled in a water bath at a water temperature of 50 ° C set at a position 30 mm below the base, and wound at a speed of lOOmZ to obtain an undrawn yarn.
  • the obtained undrawn yarn is drawn in a hot water bath at 80 ° C to make a 4-fold drawn yarn, wound using a heat roll heated to 200 ° C at a speed of lOOmZ, heat treated, and A polyester fiber (multifilament) with a fiber fineness of around 50 dtex was obtained.
  • a tow filament having a length of 30 cm and a total fineness of 100,000 dtex was produced.
  • a treatment liquid was prepared by diluting the flame retardant caloric agent obtained in Production Examples 7 to 10 to 10% omf.
  • the amount of KRE-05, KRE-08 and KRE-101 as fiber treatment agents was 0.15% omf, 0.05% omf and 0.1% omf, respectively.
  • Table 5 shows the results of evaluating the strength, flame retardancy, gloss, feel, combing and ironing properties of the obtained flame-retardant polyester artificial hair.
  • Table 5 shows the results of evaluation of iron setability using the obtained flame-retardant polyester-based artificial hair, with high elongation, flame retardancy, gloss, touch, and comb.
  • a wrinkle having a diameter of about 40 cm was prepared using 120 g of polyester fiber for artificial hair obtained in Production Examples 5-8.
  • a treatment liquid was prepared by mixing the flame retardant processing agent obtained in Production Examples 7 to 10 with the dyeing liquid prepared by dye receiving as shown in Table 6 so that the flame retardant was 10% owf.
  • the amount of KRE-05, KRE-08, and KRE-101 as the fiber treatment agents becomes 0.15% omf, 0.05% omf, and 0.1% omf, respectively.
  • the flame-retardant polyester type artificial hair was obtained.
  • Table 8 shows the results of evaluating the strength, flame retardancy, gloss, hue, touch, combing, and iron set properties of the obtained flame-retardant polyester artificial hair.
  • Example 18 the examples were the same except that the amount of flame retardant exhausted was adjusted to 3% by weight (Example 18) and 18% by weight (Example 19) by adjusting the immersion time. the same as In this way, a flame-retardant polyester artificial hair was obtained.
  • Table 8 shows the results of evaluating the strength, flame retardancy, gloss, hue, touch, combing, and iron setting properties of the obtained flame-retardant polyester artificial hair.
  • Table 8 shows the results of evaluating the strength, flame retardancy, gloss, hue, touch, combing, and iron setting properties of the obtained flame-retardant polyester artificial hair.
  • the molten polymer is discharged from a spinneret having a round cross-section nozzle hole with a cylinder diameter of 280 ° C and a nozzle diameter of 0.5 mm. It was cooled in a 50 ° C water bath installed at a position of 30 mm, and wound at a speed of lOOmZ to obtain an undrawn yarn.
  • the undrawn yarn obtained was drawn in a hot water bath at 80 ° C to make a 4-fold drawn yarn, wound using a heat roll heated to 200 ° C at a speed of lOOmZ, and heat-treated.
  • a polyester fiber (multifilament) having a single fiber fineness of about 50 dtex was obtained.
  • the flame retardant exhausting process and the flame retardant exhausting process and dyeing are performed at the same time, resulting in excellent elongation, flame retardancy, gloss, touch, combing, and setability. It was confirmed that it was possible to obtain a flame-retardant artificial hair fiber.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

La présente invention a pour objet une fibre polyester pour perruque qui conserve les propriétés physiques (telles que la résistance à la chaleur, la solidité à la rupture, et l’extensibilité) inhérente aux fibres polyester actuelles, et dont les propriétés ignifugeantes, de brillance, de texture au toucher, de facilité de coiffage et de conservation de forme sont excellentes. La présente invention a également pour objet une perruque fabriquée en utilisant ladite fibre. Une fibre telle que celle décrite par l’invention peut être fabriquée en soumettant des filaments de polyester à une finition par épuisement en les combinant avec un agent ignifuge (E), ce qui permet d'incorporer entre 2 et 20 % en masse d'agent ignifuge (E) dans les filaments. Lesdits filaments de polyesters sont obtenus par filage à l'état fondu d'une préparation élaborée en malaxant ensemble, à l'état fondu : 100 parts en masse d'un polyester (A) constitué d'un ou plusieurs composants sélectionnés parmi les polyalkylène téréphtalates et les copolyesters contenant des polyalkylène téréphtalates au titre de composants principaux ; entre 0 et 10 parts en masse d’un agent ignifuge auxiliaire (B) ; et entre 0,1 et 5 parts en masse de fines particules organiques (C) et/ou inorganiques (D).
PCT/JP2005/017941 2004-09-29 2005-09-29 Perruque en polyester ignifuge WO2006035868A1 (fr)

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Cited By (16)

* Cited by examiner, † Cited by third party
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JP2008127699A (ja) * 2006-11-17 2008-06-05 Kaneka Corp ポリエステル系人工毛髪用繊維の製造方法
WO2008071062A1 (fr) 2006-12-12 2008-06-19 Hiking Group Co., Ltd Fibre de polyacrylonitrile modifiée, son procédé de préparation et son utilisation
WO2008071063A1 (fr) 2006-12-12 2008-06-19 Hiking Group Co., Ltd Fibre de polyacrylonitrile modifiée, son procédé de préparation et son utilisation
JP2008163118A (ja) * 2006-12-27 2008-07-17 Sekisui Plastics Co Ltd 難燃性発泡性ポリスチレン系樹脂粒子の製造方法
WO2008119693A1 (fr) * 2007-04-03 2008-10-09 Basf Se Compositions retardatrices de flamme contenant des dérivés de dihydro-oxa-phospho-phénanthrène
JP2009174109A (ja) * 2007-12-27 2009-08-06 Marubishi Oil Chem Co Ltd ポリエステル繊維用難燃加工剤及び難燃性ポリエステル繊維の製造方法
JP2009203595A (ja) * 2007-09-26 2009-09-10 Dai Ichi Kogyo Seiyaku Co Ltd ポリエステル繊維の難燃加工剤とその加工方法
JP2011012352A (ja) * 2009-06-30 2011-01-20 Nicca Chemical Co Ltd ポリエステル繊維用難燃加工剤、それを用いた難燃性ポリエステル繊維製品の製造方法、およびそれにより得られた難燃性ポリエステル繊維製品
WO2011052864A1 (fr) * 2009-10-28 2011-05-05 코오롱글로텍주식회사 Composition ignifuge pour étoffes à fibres synthétiques et procédé de traitement d'ignifugation post-traitement faisant intervenir cette composition
CN102199804A (zh) * 2011-04-02 2011-09-28 上海瑞贝卡纤维材料科技有限公司 一种复合氮磷阻燃剂的假发用聚丙烯纤维及其生产方法
CN103266468A (zh) * 2013-05-30 2013-08-28 东华大学 一种膨胀阻燃体系对纯棉织物的阻燃整理方法
WO2015036998A1 (fr) * 2013-09-12 2015-03-19 Bromine Compounds Ltd. Polymères époxydes bromés utilisés comme formulations ignifuges de finition pour textiles
CN105133324A (zh) * 2015-09-07 2015-12-09 上海斯瑞科技有限公司 一种超高分子量聚乙烯阻燃编织带及其制备方法
CN107286603A (zh) * 2017-07-31 2017-10-24 郑宝胜 一种仿真发丝专用的无卤阻燃聚酯母粒及其制备方法
CN110331466A (zh) * 2019-07-30 2019-10-15 晋江市亿泰隆化纤制造有限公司 阻燃涤纶短纤填充物及其制作方法
US10626289B2 (en) 2013-09-12 2020-04-21 Bromine Compounds Ltd. Brominated epoxy polymers as wood coating flame retardant formulations

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JPH05140807A (ja) * 1991-11-18 1993-06-08 Toray Ind Inc 人工毛髪
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JPH10292049A (ja) * 1997-04-17 1998-11-04 Nanyo Bussan Kk かつら用ポリエステルモノフィラメントの難燃化に適した難燃剤エマルジョン
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Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008127699A (ja) * 2006-11-17 2008-06-05 Kaneka Corp ポリエステル系人工毛髪用繊維の製造方法
WO2008071062A1 (fr) 2006-12-12 2008-06-19 Hiking Group Co., Ltd Fibre de polyacrylonitrile modifiée, son procédé de préparation et son utilisation
WO2008071063A1 (fr) 2006-12-12 2008-06-19 Hiking Group Co., Ltd Fibre de polyacrylonitrile modifiée, son procédé de préparation et son utilisation
JP2008163118A (ja) * 2006-12-27 2008-07-17 Sekisui Plastics Co Ltd 難燃性発泡性ポリスチレン系樹脂粒子の製造方法
US8236881B2 (en) 2007-04-03 2012-08-07 Basf Se DOPO flame retardant compositions
WO2008119693A1 (fr) * 2007-04-03 2008-10-09 Basf Se Compositions retardatrices de flamme contenant des dérivés de dihydro-oxa-phospho-phénanthrène
US8101678B2 (en) 2007-04-03 2012-01-24 Basf Se DOPO flame retardant compositions
JP2009203595A (ja) * 2007-09-26 2009-09-10 Dai Ichi Kogyo Seiyaku Co Ltd ポリエステル繊維の難燃加工剤とその加工方法
JP2009174109A (ja) * 2007-12-27 2009-08-06 Marubishi Oil Chem Co Ltd ポリエステル繊維用難燃加工剤及び難燃性ポリエステル繊維の製造方法
JP2011012352A (ja) * 2009-06-30 2011-01-20 Nicca Chemical Co Ltd ポリエステル繊維用難燃加工剤、それを用いた難燃性ポリエステル繊維製品の製造方法、およびそれにより得られた難燃性ポリエステル繊維製品
WO2011052864A1 (fr) * 2009-10-28 2011-05-05 코오롱글로텍주식회사 Composition ignifuge pour étoffes à fibres synthétiques et procédé de traitement d'ignifugation post-traitement faisant intervenir cette composition
CN102199804B (zh) * 2011-04-02 2013-01-02 河南瑞贝卡发制品股份有限公司 一种复合氮磷阻燃剂的假发用聚丙烯纤维及其生产方法
CN102199804A (zh) * 2011-04-02 2011-09-28 上海瑞贝卡纤维材料科技有限公司 一种复合氮磷阻燃剂的假发用聚丙烯纤维及其生产方法
CN103266468A (zh) * 2013-05-30 2013-08-28 东华大学 一种膨胀阻燃体系对纯棉织物的阻燃整理方法
US10533278B2 (en) 2013-09-12 2020-01-14 Bromine Compounds Ltd. Brominated epoxy polymers as textile-finishing flame retardant formulations
WO2015036998A1 (fr) * 2013-09-12 2015-03-19 Bromine Compounds Ltd. Polymères époxydes bromés utilisés comme formulations ignifuges de finition pour textiles
CN105556028A (zh) * 2013-09-12 2016-05-04 溴化合物有限公司 作为纺织品整理阻燃剂制剂的溴化环氧聚合物
JP2016534250A (ja) * 2013-09-12 2016-11-04 ブローミン コンパウンズ リミテッド 織物仕上げ加工用難燃剤組成物としての臭素化エポキシポリマー
US11118084B2 (en) 2013-09-12 2021-09-14 Bromine Compounds Ltd. Brominated epoxy polymers as wood coating flame retardant formulations
CN105556028B (zh) * 2013-09-12 2021-06-18 溴化合物有限公司 作为纺织品整理阻燃剂制剂的溴化环氧聚合物
US10626289B2 (en) 2013-09-12 2020-04-21 Bromine Compounds Ltd. Brominated epoxy polymers as wood coating flame retardant formulations
CN105133324A (zh) * 2015-09-07 2015-12-09 上海斯瑞科技有限公司 一种超高分子量聚乙烯阻燃编织带及其制备方法
CN105133324B (zh) * 2015-09-07 2017-03-22 上海斯瑞科技有限公司 一种超高分子量聚乙烯阻燃编织带及其制备方法
CN107286603A (zh) * 2017-07-31 2017-10-24 郑宝胜 一种仿真发丝专用的无卤阻燃聚酯母粒及其制备方法
CN110331466A (zh) * 2019-07-30 2019-10-15 晋江市亿泰隆化纤制造有限公司 阻燃涤纶短纤填充物及其制作方法

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