WO2005106938A1 - Method for forming a gate electrode having a metal - Google Patents
Method for forming a gate electrode having a metal Download PDFInfo
- Publication number
- WO2005106938A1 WO2005106938A1 PCT/US2005/009620 US2005009620W WO2005106938A1 WO 2005106938 A1 WO2005106938 A1 WO 2005106938A1 US 2005009620 W US2005009620 W US 2005009620W WO 2005106938 A1 WO2005106938 A1 WO 2005106938A1
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- WIPO (PCT)
- Prior art keywords
- inhibitor
- metal layer
- region
- layer
- gate electrode
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Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/80—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs
- H10D84/82—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components
- H10D84/83—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers characterised by the integration of at least one component covered by groups H10D12/00 or H10D30/00, e.g. integration of IGFETs of only field-effect components of only insulated-gate FETs [IGFET]
- H10D84/85—Complementary IGFETs, e.g. CMOS
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/04—Coating on selected surface areas, e.g. using masks
- C23C16/042—Coating on selected surface areas, e.g. using masks using masks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28026—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
- H01L21/28079—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being a single metal, e.g. Ta, W, Mo, Al
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/665—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of elemental metal contacting the insulator, e.g. tungsten or molybdenum
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D64/00—Electrodes of devices having potential barriers
- H10D64/60—Electrodes characterised by their materials
- H10D64/66—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes
- H10D64/665—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of elemental metal contacting the insulator, e.g. tungsten or molybdenum
- H10D64/666—Electrodes having a conductor capacitively coupled to a semiconductor by an insulator, e.g. MIS electrodes the conductor comprising a layer of elemental metal contacting the insulator, e.g. tungsten or molybdenum the conductor further comprising additional layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/0123—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs
- H10D84/0126—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs
- H10D84/0165—Integrating together multiple components covered by H10D12/00 or H10D30/00, e.g. integrating multiple IGBTs the components including insulated gates, e.g. IGFETs the components including complementary IGFETs, e.g. CMOS devices
- H10D84/0172—Manufacturing their gate conductors
- H10D84/0177—Manufacturing their gate conductors the gate conductors having different materials or different implants
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D84/00—Integrated devices formed in or on semiconductor substrates that comprise only semiconducting layers, e.g. on Si wafers or on GaAs-on-Si wafers
- H10D84/01—Manufacture or treatment
- H10D84/02—Manufacture or treatment characterised by using material-based technologies
- H10D84/03—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology
- H10D84/038—Manufacture or treatment characterised by using material-based technologies using Group IV technology, e.g. silicon technology or silicon-carbide [SiC] technology using silicon technology, e.g. SiGe
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10D30/00—Field-effect transistors [FET]
- H10D30/60—Insulated-gate field-effect transistors [IGFET]
- H10D30/601—Insulated-gate field-effect transistors [IGFET] having lightly-doped drain or source extensions, e.g. LDD IGFETs or DDD IGFETs
Definitions
- the present invention relates generally to semiconductor processing, and more specifically, to forming gate electrodes having a metal which may be used, for example, in dual metal gate integration.
- both PMOS and NMOS devices which require gate electrodes having different work functions, may be formed using different metals in contact with the respective gate dielectrics.
- problems arise in achieving this dual metal gate integration For example, in one approach for achieving dual metal gate integration known today, a first metal layer is blanket deposited on the gate dielectric (where this first metal layer may be used to form a metal-containing gate electrode stack of a first type of device, such as, for example, a PMOS device). However, this first metal layer then needs to be removed from portions of the gate dielectric which will be used to form a second type of device, such as, for example, an NMOS device, which requires a different metal layer in contact with the gate dielectric within its metal-containing gate electrode stack.
- a second metal layer may be formed (where this second metal layer may be used to form a metal-containing gate electrode stack of the second type of device.)
- portions of the first metal layer are removed by either a dry or wet etch using traditional photolithographic techniques.
- this deposition and subsequent etching of the first metal layer from portions of the gate dielectric introduces many problems which result in poorer devices.
- the etching may underetch the first metal layer, thus leaving behind residual material from the first metal layer on the gate dielectric which will negatively affect the work function of the resulting device.
- the subsequent etching of the first metal layer may result in overetching into the underlying gate dielectric which undesirably reduces the thickness of the gate dielectric in the regions in which the second metal electrode is formed.
- FIG. 1 illustrates a cross-sectional view of a substrate having a gate dielectric layer overlying the substrate, in accordance with one embodiment of the present invention
- FIG. 2 illustrates a cross-sectional view of the substrate of FIG. 1 and a stamp mask aligned over the substrate, in accordance with one embodiment of the present invention
- FIG. 3 illustrates a cross-sectional view of the substrate of FIG. 2 after application of the stamp mask and a resulting inhibitor layer formed over a region of the substrate, in accordance with one embodiment of the present invention
- FIG. 4 illustrates a cross-sectional view of the substrate of FIG.
- FIG. 5 illustrates a cross-sectional view of the substrate of FIG. 4 after removal of the inhibitor layer, in accordance with one embodiment of the present invention
- FIG. 6 illustrates a cross-sectional view of the substrate of FIG. 5 after formation of a second metal-containing gate layer, a polysilicon gate layer, an antireflective coating (ARC) layer, and a patterned masking layer in accordance with one embodiment of the present invention
- FIG. 7 illustrates a cross-sectional view of the substrate of FIG. 6 after formation of gate electrode stacks using the patterned masking layer and after removal of the patterned masking layer, in accordance with one embodiment of the present invention
- FIG. 7 illustrates a cross-sectional view of the substrate of FIG. 6 after formation of gate electrode stacks using the patterned masking layer and after removal of the patterned masking layer, in accordance with one embodiment of the present invention
- FIG. 8 illustrates a cross-sectional view of the substrate of FIG. 7 after formation of two substantially completed devices within different regions of the substrate, in accordance with one embodiment of the present invention.
- Skilled artisans appreciate that elements in the figures are illustrated for simplicity and clarity and have not necessarily been drawn to scale. For example, the dimensions of some of the elements in the figures may be exaggerated relative to other elements to help improve the understanding of the embodiments of the present invention. Detailed Description of the Drawings
- transistors having a metal- containing gate electrode where a metal layer of the metal-containing gate electrode is in direct contact with an underlying gate dielectric.
- This may allow, for example, for improved scalability and improved work function characteristics.
- different types of devices such as, for example, PMOS and NMOS devices
- PMOS and NMOS devices typically require different metal layers to be in contact with the underlying gate dielectric within their respective gate electrode stacks in order to provide the desired work functions. Therefore, one embodiment of the present invention forms a gate dielectric layer and then selectively deposits a first metal layer over portions of the gate dielectric layer in which devices will be formed using the first metal layer.
- FIG. 1 illustrates a semiconductor structure 11 in accordance with one embodiment of the present invention. Note that, in one embodiment, semiconductor 11 may be a portion of a semiconductor wafer. Semiconductor structure 11 of FIG.
- FIG. 1 includes a substrate 10 having an isolation region 16 and a gate dielectric layer 18 overlying substrate 10 and isolation region 16. Note that in an alternate embodiment, gate dielectric layer 18 may not overlie isolation region 16.
- Semiconductor structure 11 of FIG. 1 is divided into two regions: a first device region 12 and a second device region 14.
- Device regions 12 and 14 define regions of substrate 10 in which different types of devices will be formed. For example, in one embodiment, device region 12 corresponds to an NMOS device region in which NMOS devices will be formed, and device region 14 corresponds to a PMOS device region in which PMOS devices will be formed. However, note that in alternate embodiments, device region 12 may correspond to a PMOS device region and device region 14 may correspond to an NMOS device region.
- device regions 12 and 14 may be any type of regions in which different devices will be formed.
- semiconductor structure 11 may include any number of device regions, as needed, in which different types of devices will be formed.
- substrate 10 is a semiconductor substrate, such as, for example, a silicon substrate, gallium arsenide substrate, silicon germanium substrate, germanium substrate, etc.
- substrate 10 includes a bulk substrate, but in alternate embodiments, substrate 10 may include a silicon-on-insulator (SOI) substrate having any type of semiconductor material (such as, for example, silicon, gallium arsenide, silicon germanium, germanium, etc.) overlying an insulator, such as, for example, a buried oxide.
- SOI silicon-on-insulator
- Gate dielectric layer 18 may include any type of gate dielectric material, such as, for example, hafnium oxide, hafnium silicate, zirconium silicate, zirconium oxide, tantalum oxide, titanium oxide, nitrided silicon dioxide, etc. Gate dielectric layer 18 may be formed using conventional techniques. In the illustrated embodiment, note that gate dielectric layer 18 is formed over both regions 12 and 14; however, in alternate embodiments, each of regions 12 and 14 may include a different type of gate dielectric material such that a first gate dielectric layer overlies substrate 10 in region 12 and a second gate dielectric layer, different from the first gate dielectric layer, overlies substrate 10 in region 14. Also note that substrate 10 may also include well implants (not shown) as needed for the formation of devices.
- FIG. 2 illustrates semiconductor structure 11 with a stamp mask 20 aligned over substrate 10.
- Stamp mask 20 includes an inhibitor material 22 overlying a proud portion 23 of stamp mask 20 which extends beyond a surface 21 of stamp mask 20.
- the proud portion or portions of stamp mask 20 correspond to those portions which, when stamped onto a surface of a substrate, contact the substrate while the remaining portions of stamp mask 20 (those which are not proud) do not contact the surface of the substrate. Therefore, the material on the proud portions will be stamped or printed onto the surface of the substrate upon contact.
- stamp mask 20 is formed of an elastomeric material. Therefore, referring to FIG.
- stamp mask 20 includes proud portion 23 which, when appropriately aligned with substrate 10, corresponds to device region 12 of semiconductor structure 11 such that, when applied, inhibitor material 22 will be applied to region 12 but not region 14.
- inhibitor material 22 may be placed in a variety ways onto proud portion 23 of stamp mask 20.
- stamp mask 20 may be dipped into a dish of inhibitor material, such that only the proud portions of stamp mask 20 contact the inhibitor material (in this manner, the remaining surface, such as surface 21, does not receive any inhibitor material).
- the inhibitor material may be applied to stamp mask 20 using, for example, a roller that transfers the inhibitor material to the proud portions of stamp mask 20 without transferring the inhibitor material to the remaining surface of stamp mask 20, such as surface 21.
- stamp mask 20 is applied to semiconductor structure 11 such that proud portion 23 (but not surface 21) contacts gate dielectric layer 18.
- stamp mask 20 After lifting of stamp mask 20, note that all or a portion of inhibitor material 22 remains over gate dielectric layer 18 in region 12, thus forming inhibitor layer 24 over gate dielectric layer 18 within region 12 but not within region 14 of semiconductor structure 11. That is, the use of stamp mask 20 allows for inhibitor layer 24 to be selectively formed over portions of gate dielectric layer 18 (where, for example, these portions correspond to region 12 of FIG. 3).
- inhibitor layer 24 includes a methyl group, such as, for example, organosilanes and self assembled monolayers (SAMs).
- inhibitor layer 24 may include any number and type of materials so long as it includes a surface portion or layer which includes a methyl group. In one embodiment, sufficient inhibitor material 22 is used to ensure that inhibitor layer 24 formed over gate dielectric 18 is sufficiently thick to cover all nucleation sites of region 12 with at least a monolayer of inhibitor material. In an alternate embodiment, inhibitor layer 24 may be selectively formed over portions of gate dielectric layer 18 through traditional photolithographic techniques. In another alternate embodiment, inhibitor layer 24 is a photo definable polymer. In this embodiment, the photo definable polymer may be a methacrylate based polymer.
- FIG.4 illustrates semiconductor structure 11 after formation of a first metal layer 26 overlying gate dielectric layer 18 in region 14. As illustrated in FIG.
- first metal layer 26 is selectively deposited onto gate dielectric layer 18 using, for example, atomic layer deposition (ALD).
- Inhibitor layer 24 prevents the formation of first metal layer 26 on gate dielectric layer 18 within region 12. Therefore, note that first metal layer 26 is in direct contact with gate dielectric layer 18 within region 14 but is not formed in those places where inhibitor layer 24 is formed. This is because inhibitor layer 24 covers (and blocks) the nucleation sites of gate dielectric layer 18 within region 12, thus inhibiting the formation (e.g. deposition) of a metal layer within region 12 during the ALD formation of first metal layer 26.
- CVD selective chemical vapor deposition
- inhibitor layer 24 also prevents the formation of first metal layer 26 within region 12 since inhibitor layer 24 blocks nucleation sites.
- FIG. 5 illustrates semiconductor structure 11 after removal or neutralization of inhibitor layer 24.
- inhibitor layer 24 is removed using an anneal process. For example, an anneal at a temperature of at least 100 degrees Celsius, or, alternatively, in a range of about 100 to 900 degrees Celsius, may be used. This anneal causes inhibitor layer 24 to desorb or sublimate. Alternatively, other methods may be used to remove inhibitor layer 24, such as, for example, plasma treating, plasma etching, or ultra violet (UN) irradiation.
- FIG. 6 illustrates semiconductor structure 11 after formation of a second metal layer 28 over exposed portions of gate dielectric 18 and first metal layer 26.
- second metal layer 28 is formed by a blanket deposition.
- second metal layer 28 may be formed such that it is formed over exposed portions of gate dielectric layer 18 (e.g. within region 12) and over none or only a portion of first metal layer 26 in region 14. Note that second metal layer 28 is in direct contact with gate dielectric layer 18 in region 12. Therefore, in region 12, second metal layer 28 is in direct contact with gate dielectric layer 18, and in region 14, first metal layer 26 is in direct contact with gate dielectric layer 18. This will therefore allow for different work functions for devices formed in each of regions 12 and 14. Still referring to FIG.
- a polysilicon gate layer 30 (also referred to as polycrystalline silicon gate layer 30) is formed overlying second metal layer 28.
- an antireflective coating (ARC) layer is formed overlying polysilicon gate layer 30. Note that in alternate embodiments, more, fewer, or different layers may be formed over second metal layer 28. For example, any number of different layers may be used instead of or in addition to polysilicon layer 30. Also, note that ARC layer 32 is optional, depending on the subsequent photolithography processes used.
- a patterned masking layer 34 is formed overlying ARC layer 30 (where patterned masking layer 34 may be formed using conventional processes).
- patterned masking layer 34 defines a gate electrode stack of a first device in region 12 and a gate electrode stack of a second device in region 14.
- patterned masking layer 34 may be used to define any number of gate stacks depending on the number of devices desired.
- polysilicon layer 30 and ARC layer 32 may not be present such that patterned masking layer 34 is formed directly over second metal-containing layer 28.
- patterned masking layer 34 may be formed directly over second metal layer 28 in region 12 and first metal layer 26 in region 14.
- the gate electrode stack defined by patterned masking layer 34 in region 12 corresponds to a PMOS type gate electrode stack and the gate electrode stack defined by patterned masking layer 34 in region 14 corresponds to an NMOS type gate electrode stack.
- first metal layer 26 may include, for example, titanium nitride, iridium, iridium oxide, ruthenium, ruthenium oxide, tantalum nitride, etc.
- second metal layer 28 may include, for example, tantalum silicon nitride, tantalum carbide, a metal boride, a metal silicon nitride, a metal carbide, etc.
- different metals or combination of metals may be used within first metal layer 26 and second metal layer 28 depending on the devices being formed.
- the gate electrode stack defined by patterned masking layer 34 in region 12 may correspond to an NMOS device and the gate electrode stack defined by patterned masking layer 34 in region 14 may correspond to a PMOS device, and the materials of the first and second metal layers may be selected accordingly.
- the thicknesses of first metal layer 26 and second metal layer 28 range between approximately 30 Angstroms to 500 Angstroms.
- FIG. 7 illustrates semiconductor structure 11 after formation of gate electrode stack 36 overlying gate dielectric layer 18 in region 12 and gate electrode stack 40 overlying gate dielectric layer 18 in region 14. Therefore, after formation of patterned masking layer 34, conventional etch processes may be used to form gate electrode stacks 36 and 40. Patterned masking layer 34 is then removed. As illustrated in FIG.
- gate electrode stack 36 includes a first metal layer 38 formed from second metal layer 28, a polysilicon gate layer 41 formed from polysilicon gate layer 30, and an ARC layer 43 formed from ARC layer 32.
- Gate electrode stack 40 includes a first metal layer 42 formed from first metal layer 26, a second metal layer 44 formed from second metal layer 28, a polysilicon gate layer 46 formed from polysilicon gate layer 30, and an ARC layer 48 formed from ARC layer 32. Therefore, note that each of gate electrode stacks 36 and 40 include different metal layers (38 and 42, respectively) in direct contact with gate dielectric layer 18 in regions 12 and 14, respectively, thus resulting in different work functions.
- gate electrode stacks 36 and 40 may include any number of layers, where the illustrated embodiment provides just one example of gate stacks 36 and 40.
- each of gate electrode stacks 36 and 40 may include a single gate layer (such as, for example, gate layer 38 and gate layer 42, without gate layers 41, 43, 44, 46, and 48) or each of gate electrode layers 36 and 40 may include any number of gate layers.
- other types of gate electrode stacks may be formed. FIG.
- Device 8 illustrates semiconductor structure 11 after formation of substantially completed device 66 in region 12 and device 68 in region 14 where the subsequent processing may be performed using conventional techniques.
- devices 66 and 68 may be referred to as transistors 66 and 68.
- Device 66 includes sidewall spacers 50 adjacent sidewalls of gate electrode stack 36 and source/drain regions 54 and 56 extending laterally within substrate 10 and underlying portions of gate dielectric 52 (formed from gate dielectric layer 18).
- spacers 50 and source/drain regions 54 and 56 may be formed using conventional processes.
- spacers 50 may include a single material or may include multiple materials.
- source/drain regions 54 and 56 include extension regions and deep implant regions; however, in alternate embodiments, different types of source/drain regions may be formed.
- Device 68 in region 14 includes sidewall spacers 58 adjacent sidewalls of gate electrode stack 40 and source/drain regions 62 and 64 extending laterally within substrate 10 and underlying portions of gate dielectric 60 (formed from gate dielectric layer 18). Note that spacers 58 and source/drain regions 62 and 64 may be formed using conventional processes. For example, spacers 58 may include a single material or may include multiple materials.
- source/drain regions 62 and 64 include extension regions and deep implant regions; however, in alternate embodiments, different types of source/drain regions may be formed.
- devices 66 and 68 may be formed having different resulting structures using different methods than those illustrated and described in reference to FIG. 8, while still using the selective deposition of first metal layer 26 described above. Therefore, it can be appreciated how the selective formation of first metal layer 26 through the use of inhibitor layer 24 (which may be selectively formed) allows for dual metal gate integration while avoiding the problems presented by prior art methods. That is, unlike the prior art solutions described above, the selective formation of first metal layer 26 may . prevent the need to etch away portions of a metal-containing gate layer overlying gate dielectric layer 18. This may prevent the dangers of overetching gate dielectric layer 18.
- the embodiments described herein may allow for improved dual metal gate integration where devices requiring different metals in direct contact with the gate dielectric layer may be formed.
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Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05728396.2A EP1776715B1 (en) | 2004-04-19 | 2005-03-22 | Method for forming a gate electrode having a metal |
| JP2007508363A JP4757867B2 (ja) | 2004-04-19 | 2005-03-22 | 金属からなるゲート電極を形成するための方法 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/827,202 US7030001B2 (en) | 2004-04-19 | 2004-04-19 | Method for forming a gate electrode having a metal |
| US10/827,202 | 2004-04-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2005106938A1 true WO2005106938A1 (en) | 2005-11-10 |
Family
ID=35096814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2005/009620 Ceased WO2005106938A1 (en) | 2004-04-19 | 2005-03-22 | Method for forming a gate electrode having a metal |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7030001B2 (enExample) |
| EP (1) | EP1776715B1 (enExample) |
| JP (1) | JP4757867B2 (enExample) |
| KR (1) | KR20070014152A (enExample) |
| CN (1) | CN100437939C (enExample) |
| WO (1) | WO2005106938A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007165414A (ja) * | 2005-12-09 | 2007-06-28 | Toshiba Corp | 半導体装置及びその製造方法 |
| JP2009517872A (ja) * | 2005-12-01 | 2009-04-30 | インターナショナル・ビジネス・マシーンズ・コーポレーション | 結合されたステッパおよび堆積ツール(堆積装置および堆積層の形成方法) |
| JP2009538542A (ja) * | 2006-05-26 | 2009-11-05 | フリースケール セミコンダクター インコーポレイテッド | 中間層を有する半導体素子の形成方法及びその構造 |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4040602B2 (ja) * | 2004-05-14 | 2008-01-30 | Necエレクトロニクス株式会社 | 半導体装置 |
| US20060011949A1 (en) * | 2004-07-18 | 2006-01-19 | Chih-Wei Yang | Metal-gate cmos device and fabrication method of making same |
| JP2006156807A (ja) * | 2004-11-30 | 2006-06-15 | Toshiba Corp | 半導体装置およびその製造方法 |
| JP4764030B2 (ja) * | 2005-03-03 | 2011-08-31 | 株式会社東芝 | 半導体装置及びその製造方法 |
| KR100639073B1 (ko) * | 2005-05-10 | 2006-10-30 | 한국과학기술원 | 선택적 다마신을 이용한 반도체 금속 배선의 형성방법 |
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Also Published As
| Publication number | Publication date |
|---|---|
| EP1776715A1 (en) | 2007-04-25 |
| CN1947230A (zh) | 2007-04-11 |
| JP4757867B2 (ja) | 2011-08-24 |
| US7030001B2 (en) | 2006-04-18 |
| EP1776715B1 (en) | 2013-06-19 |
| EP1776715A4 (en) | 2009-05-06 |
| CN100437939C (zh) | 2008-11-26 |
| US20050233562A1 (en) | 2005-10-20 |
| KR20070014152A (ko) | 2007-01-31 |
| JP2007533156A (ja) | 2007-11-15 |
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