WO2001041571A1 - Compositions microbicides - Google Patents
Compositions microbicides Download PDFInfo
- Publication number
- WO2001041571A1 WO2001041571A1 PCT/JP2000/008716 JP0008716W WO0141571A1 WO 2001041571 A1 WO2001041571 A1 WO 2001041571A1 JP 0008716 W JP0008716 W JP 0008716W WO 0141571 A1 WO0141571 A1 WO 0141571A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- salt
- surfactant
- acid
- aqueous solution
- component
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/08—Alkali metal chlorides; Alkaline earth metal chlorides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
Definitions
- hypochlorite sodium hypochlorite
- calcium hypochlorite sodium dichloroisocyanurate
- sodium dichloroisocyanurate sodium dichloroisocyanurate
- the preferred weight ratio (C) Z (A) in the aqueous solution is 2 to 1 to 15, particularly 1 to 1 to 15.
- the preferred pH of the aqueous solution is from 3 to 8, more preferably from 5 to 8, even more preferably from 5 to 7, particularly preferably from 5 to less than 7, more preferably from 6 to less than 7.
- the present invention comprises a product (IV) of a component containing hypochlorite ( ⁇ ), a product (V) of a component containing an aminoxide ( ⁇ ) and an organic acid or a salt thereof (C),
- the component (A) indicates the weight based on available chlorine.
- the product consists of a product (VI) containing a component containing hypochlorite (A) and an amine oxide (B) and a product (VII) containing a component containing an organic acid or its salt (C).
- A) / (B) a bactericide used as an aqueous solution containing a weight ratio of 10 / l to lZ10.
- This fungicide contains (A) component and (C) component at the time of use:
- (C) / (A) 5Zl ⁇ : LZ10, further 2Zl ⁇ lZ5, especially 1/1 ⁇ 15
- each product may contain optional components as long as stability and the like are not impaired. Further, it may be constituted by products (IV) to (VII) and further products other than these.
- the fungicidal composition of the present invention contains one or more surfactants (B).
- the surfactant can be selected from anionic surfactants, cationic surfactants, nonionic surfactants, and amphoteric surfactants, and those that are stable in an aqueous solution of hypochlorous acid are used. You. Of these, cationic surfactants and amphoteric surfactants are preferred, and amine oxides are particularly preferred. As the amine oxide, alkyldimethylamine oxide is preferable, and those having an alkyl group having 8 to 18 carbon atoms are particularly preferable.
- the germicidal composition of the present invention may contain a thickener, a fragrance, a coloring agent, and the like in addition to the components (I), (II), and (C).
- Examples include betaine-based amphoteric surfactants and imidazoline-based amphoteric surfactants such as imidazoline betaine.
- N-alkyl betaine is preferable, and N-alkyl betaine having an alkyl group having 12 to 18 carbon atoms is particularly preferable.
- the composition of the present invention has a pH at 20 ° C. of 3 to 8, more preferably 5 to 8, particularly preferably 5 to 7. It is preferable that the component (C) is used in such an amount as to fix the pH within this range.
- composition of the present invention can be stably blended with hypochlorous acid and / or a salt thereof, and can contain an anionic surfactant (F) to enhance the cleaning effect.
- the component (F) includes higher fatty acid salts, higher alcohol sulfates, higher alcohol sulfonates, sulfated fatty acid salts, sulfonated fatty acid salts, phosphate ester salts, fatty acid ester sulfate ester salts, and fatty acid ester sulfonic acid.
- the component (C) is as described in Embodiment R. Furthermore, citric acid, acetic acid, lactic acid, malic acid, tartaric acid, dalconic acid and the like can be mentioned. From the viewpoint of formulation stability, succinic acid or a salt thereof is particularly preferred.
- the component (C) is preferably at least one selected from acids and salts thereof described in the compendium of food additives.
- the component (C) is preferably one or more selected from acids having a carboxyl group and salts thereof.
- the component (A) is distinguished from the component (C).
- composition of the present invention is preferably used at an effective chlorine concentration of 1 to 5000 ppm, more preferably 5 to 2000 ppm, and especially 5 to LLOOOPM when used.
- hypochlorite (A) When an organic acid or a salt thereof (C) is used, it is preferable to mix it with hypochlorite (A).
- Specific examples include a product (IV) containing hypochlorite (A), an amine oxide (B), and a product (V) containing an organic acid or a salt thereof (C).
- a cleaning agent used as an aqueous solution containing (A) / (B) at a weight ratio of 1 OZl to 1Z10 when used is mentioned.
- the present invention provides a method for controlling pH, comprising: at least one selected from hypochlorite and hypochlorous acid (A); and at least one selected from amphoteric surfactants and cationic surfactants (B). And a deodorant composition containing the agent (C).
- the present invention relates to a method for sterilizing and cleaning a space in which the above-mentioned sterilizing composition for space of the present invention is discharged into a space in the form of foam or mist.
- the component (G) is preferably at least one selected from phosphoric acid, polyphosphoric acid, phosphonic acid and salts thereof, and the salt is preferably an alkali metal salt such as sodium or potassium.
- the deposited bacteria used in the following examples were all from Institute For Fermentation (OSAKA, IFO) located at 2-7-17-85, Jusanhoncho, I-ji, Osaka-shi, Osaka, Japan. Can be obtained. That it has been described in the 1 996-year version of Microorganisms 10 th List of Cultures.
- the value in parentheses indicates the effective chlorine concentration in the aqueous solution before dilution.
- composition was prepared from an aqueous solution of sodium hypochlorite (effective chlorine concentration: 600,000 p pm) and the components (B) and / or (F) are mixed in the specified amounts and diluted with ion-exchanged water to twice the final concentration and succinic acid up to twice the final concentration. It was obtained by mixing equal amounts of those diluted with ion-exchanged water.
- test spore bacterium solution Take 0.1 ml of the test spore bacterium solution, inoculate 10 ml of an aqueous solution (temperature: 25 ° C) diluted with sterilized ion-exchanged water, and inoculate the composition consisting of the components shown in Table T1 at room temperature. Acted for 3 minutes. Within 50 seconds, 50 ⁇ l of the bacterial contact solution was collected, and a micro Petri dish containing 0.2 ml of SCDL ⁇ ⁇ ⁇ medium (containing 3.3% sodium thiosulfate) for post-culture was used. -Cell Wells).
- Each test aqueous solution was prepared by mixing components (A) and (B) in a prescribed amount, diluted with ion-exchanged water to twice the final formulation concentration, and (C) component was added to the final formulation concentration. Equally mix the solution diluted with ion-exchanged water to twice the
- Emazol O-10 manufactured by Kao Corporation
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00980019A EP1236398A4 (en) | 1999-12-10 | 2000-12-08 | MICROBICIDAL COMPOSITIONS |
US10/149,147 US6793846B2 (en) | 1999-12-10 | 2000-12-08 | Microbicide compositions |
Applications Claiming Priority (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP35221799 | 1999-12-10 | ||
JP11-352217 | 1999-12-10 | ||
JP2000-41092 | 2000-02-18 | ||
JP2000041092A JP3607555B2 (ja) | 1999-12-10 | 2000-02-18 | 殺菌剤組成物 |
JP2000066815A JP3607559B2 (ja) | 2000-03-10 | 2000-03-10 | 殺菌剤組成物 |
JP2000-66815 | 2000-03-10 | ||
JP2000130276A JP2001311095A (ja) | 2000-04-28 | 2000-04-28 | 殺菌洗浄剤組成物 |
JP2000-130276 | 2000-04-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001041571A1 true WO2001041571A1 (fr) | 2001-06-14 |
Family
ID=27480719
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2000/008716 WO2001041571A1 (fr) | 1999-12-10 | 2000-12-08 | Compositions microbicides |
Country Status (5)
Country | Link |
---|---|
US (1) | US6793846B2 (ja) |
EP (1) | EP1236398A4 (ja) |
KR (1) | KR100737951B1 (ja) |
CN (1) | CN1433270A (ja) |
WO (1) | WO2001041571A1 (ja) |
Families Citing this family (30)
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US20030138498A1 (en) * | 1999-12-10 | 2003-07-24 | Kiyoaki Yoshikawa | Methods of sterilization |
JP2007530731A (ja) * | 2004-03-23 | 2007-11-01 | ザ・クロロックス・カンパニー | 次亜塩素酸塩希釈方法 |
US20050232847A1 (en) * | 2004-04-20 | 2005-10-20 | Bromberg Steven E | Method for diluting hypochlorite |
BRPI0609429B8 (pt) * | 2005-03-23 | 2021-07-20 | Invekra S A P I De C V | uso de uma solução aquosa com potencial de oxirredução (orp) |
US20070015683A1 (en) * | 2005-07-14 | 2007-01-18 | Harris Research, Inc. | Textile cleaning composition and method of use |
BRPI0706676B8 (pt) | 2006-01-20 | 2021-05-25 | Oculus Innovative Sciences Inc | uso de uma solução aquosa com potencial de oxirredução |
US20070227930A1 (en) * | 2006-03-28 | 2007-10-04 | Bromberg Steven E | Antimicrobial Product Combination |
EP2046688B1 (en) * | 2006-06-27 | 2012-09-12 | Poolrite Research PTY Ltd. | Improved water treatment method |
DE102007048205A1 (de) * | 2007-10-08 | 2009-04-09 | Actides Gmbh | Verfahren zur Herstellung eines Desinfektionsmittels auf der Basis einer wäßrigen HCIO-Lösung |
US20090148342A1 (en) * | 2007-10-29 | 2009-06-11 | Bromberg Steven E | Hypochlorite Technology |
WO2010148004A1 (en) | 2009-06-15 | 2010-12-23 | Oculus Innovative Sciences, Inc. | Solution containing hypochlorous acid and methods of using same |
AU2011100255B4 (en) | 2010-04-29 | 2011-08-25 | Zodiac Group Australia Pty Limited | Method for water treatment |
GB2488838A (en) * | 2011-03-11 | 2012-09-12 | Biomimetics Health Ind Ltd | A stable antimicrobial aqueous hypochlorous acid solution |
US9220272B2 (en) * | 2012-04-23 | 2015-12-29 | Lonza, Inc | Active halogen antimicrobial composition and method of use |
EP2999341B1 (en) * | 2013-05-22 | 2018-11-28 | Sonoma Pharmaceuticals, Inc. | Stabilized hypochlorous acid solution and use thereof |
US10897905B2 (en) | 2016-01-26 | 2021-01-26 | Metrex Research, LLC | Hypochlorite based hard surface disinfectants |
KR102197921B1 (ko) * | 2016-04-26 | 2021-01-04 | 오르가노 코포레이션 | 수처리제 조성물 및 수처리 방법 |
KR102588218B1 (ko) * | 2017-09-22 | 2023-10-13 | 가부시키가이샤 후지미인코퍼레이티드 | 표면 처리 조성물, 표면 처리 조성물의 제조 방법, 표면 처리 방법 및 반도체 기판의 제조 방법 |
US10986841B2 (en) | 2018-11-06 | 2021-04-27 | The Clorox Company | Bleach compositions |
KR102200507B1 (ko) * | 2019-12-11 | 2021-01-08 | 주식회사 아워홈 | 바이러스 소독용 조성물 |
KR102330342B1 (ko) * | 2020-03-02 | 2021-11-23 | 경희대학교 산학협력단 | 감염성 호흡기 바이러스 차단용 조성물 및 이의 용도 |
KR20210122169A (ko) | 2020-03-30 | 2021-10-08 | 김종덕 | 풀빅산을 포함하는 살균제 조성물 |
CN111481723B (zh) * | 2020-04-17 | 2022-02-01 | 重庆有艾生物科技有限公司 | 一种运用弱酸性次氯酸消毒液在聚集性场所进行空气动态消毒的集成技术与方法 |
US11845916B2 (en) | 2020-06-24 | 2023-12-19 | The Clorox Company | Burstable sporicidal cleaning wipe system containing stabilized hypochlorite |
KR102208456B1 (ko) * | 2020-08-07 | 2021-01-27 | 주식회사 세니젠 | 과채류 세척용 항균제 조성물 |
KR102313318B1 (ko) * | 2020-08-31 | 2021-10-15 | 에코텍 주식회사 | 식물 살균 및 성장 촉진이 우수한 장기 보존성 차아염소산수 및 그 제조 방법 |
CN113693954B (zh) * | 2021-09-05 | 2024-02-20 | 诗乐氏实业(深圳)有限公司 | 一种抗菌洗手液 |
CN113749982B (zh) * | 2021-09-05 | 2024-01-12 | 江西展宏医疗器械有限公司 | 一种抗菌洗手液的制备方法 |
KR102447491B1 (ko) * | 2022-01-17 | 2022-09-27 | 주식회사 세니젠 | 차아염소산과 피트산을 포함하는 내생포자 사멸용 조성물 |
CN114849463A (zh) * | 2022-03-25 | 2022-08-05 | 广州市番禺环境科学研究所有限公司 | 一种除臭剂及其制备方法 |
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-
2000
- 2000-12-08 WO PCT/JP2000/008716 patent/WO2001041571A1/ja active Application Filing
- 2000-12-08 KR KR1020027007411A patent/KR100737951B1/ko active IP Right Grant
- 2000-12-08 CN CN00818808A patent/CN1433270A/zh active Pending
- 2000-12-08 EP EP00980019A patent/EP1236398A4/en not_active Withdrawn
- 2000-12-08 US US10/149,147 patent/US6793846B2/en not_active Expired - Fee Related
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JPH04360672A (ja) * | 1991-06-07 | 1992-12-14 | Juichiro Yagi | 食品除菌殺菌剤 |
JPH08164189A (ja) * | 1994-12-15 | 1996-06-25 | Morinaga Milk Ind Co Ltd | 殺菌方法 |
JPH09154922A (ja) * | 1995-12-04 | 1997-06-17 | Tomey Technol Corp | コンタクトレンズの消毒洗浄方法 |
JPH1149619A (ja) * | 1997-08-01 | 1999-02-23 | Tosoh Corp | 晒粉組成物 |
JPH11148098A (ja) * | 1997-11-14 | 1999-06-02 | Kao Corp | 硬質体用の固形殺菌洗浄剤 |
JPH11148097A (ja) * | 1997-11-14 | 1999-06-02 | Kao Corp | 生鮮食品用の固形殺菌洗浄剤 |
JPH11188083A (ja) * | 1997-12-25 | 1999-07-13 | Yoshiya Okazaki | 殺菌水製造方法及び装置 |
JPH11228316A (ja) * | 1998-02-19 | 1999-08-24 | Clean Chemical Kk | 殺菌消毒用製剤 |
Non-Patent Citations (1)
Title |
---|
See also references of EP1236398A4 * |
Also Published As
Publication number | Publication date |
---|---|
EP1236398A4 (en) | 2004-04-07 |
KR20020065900A (ko) | 2002-08-14 |
US6793846B2 (en) | 2004-09-21 |
CN1433270A (zh) | 2003-07-30 |
KR100737951B1 (ko) | 2007-07-13 |
EP1236398A1 (en) | 2002-09-04 |
US20030155549A1 (en) | 2003-08-21 |
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