WO1992020857A1 - Verfahren zur delignifizierung von lignocellulosehaltigem material. bleiche und behandlung von abwässern mittels laccasen mit erweiterter wirksamkeit - Google Patents
Verfahren zur delignifizierung von lignocellulosehaltigem material. bleiche und behandlung von abwässern mittels laccasen mit erweiterter wirksamkeit Download PDFInfo
- Publication number
- WO1992020857A1 WO1992020857A1 PCT/EP1992/001086 EP9201086W WO9220857A1 WO 1992020857 A1 WO1992020857 A1 WO 1992020857A1 EP 9201086 W EP9201086 W EP 9201086W WO 9220857 A1 WO9220857 A1 WO 9220857A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- phenolic
- lignin
- added
- compounds
- laccase
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/005—Treatment of cellulose-containing material with microorganisms or enzymes
Definitions
- the present invention relates to a novel method for
- waste water in particular paper mill or pulp waste water.
- Pulp production Use of lignolytic enzymes: biopuiping.
- Processes include the sulfate and sulfite processes. With both processes, boiling and under pressure, cellulose ej-zeug: The sulfate process works with the active chemicals NaOH and Na 2 S. The sulfite process with Ca (HSO 3 ) 2 - SO 2 .
- the wood fabrication processes work with stone grinding (wood grinding) or with refiners (TMP). which the wood after
- wood pulps still contain a large part of the lignin and are mainly for printing newsprint or printing
- Biopulping is generally understood to mean using biological
- Cellulose or hemicellulose are dependent as a carbon source. This
- the main difficulty is the very slow one
- the rate of degradation of the lignin (days to weeks), so that in the in vivo process: wood chips + cellulase-less - mutants (Phanerochaete chrysosporium), among other things, at the screening of new ones better wild tribes works.
- the ultimate goal is to achieve faster and more effective lignin breakdown, especially the one above
- Phanerochaete chrysosporium Phanerochaete chrysosporium.
- Pulps used in the mechanical-thermal or chemo-mechanical or chemo-thermo-mechanical treatment of wood pulp Pulps used in the mechanical-thermal or chemo-mechanical or chemo-thermo-mechanical treatment of wood pulp
- the bleach is
- heme compounds e.g. also hemoglobin, which is quasi the active heme component in the
- the hemicellulases here u.a. the xylanases. are used as bleaching enzymes because one suspects an effect on the bonds between hemicelluloses (xyians) and the lignin.
- the enzyme has a long duration of action at relative
- lignolytic enzymes decolorization and detoxification of cellulose fabrication waste water and the oxidation and thus detoxification of chlorinated aromatics and others
- the present invention has now set itself the task.
- Oxidize lignin Oxidize lignin.
- German patent applications DE 3636208 (WO 88/03190).
- P 408894.4 describe the use of lignolytic enzymes with simultaneous addition of reduction and
- Laccase v.a. used by Coriolus versicoior This laccase is used together with laccase substrates
- Fig. 1 shows the mechanism of action of laccases on the
- the laccase catalyses the formation of a mesomeric aryloxy radical from phenol.
- Residual lignin content i.e. around 19% attempts to break down with the new one
- Residual lignin content i.e. by 41%, i.e. by more than double.
- the inventive method determined by means of a red-ox electrode and by means of a controller and actuator during the
- Reducing agents, salts and phenolic compounds are kept constant.
- Air, O 2 or hydrogen peroxide are preferably used as the oxidizing agent.
- Sodium bisulfite comes as a reducing agent.
- Metal salts are preferably used as salts. This is where FeSO 4 comes in. FeCl 3 . MnSO 4 . TiO 2 , CuSO 4 and Mn 3 acetate into consideration. It should also be noted that the addition of
- ethylenediamine tetraacetic acid EDTA
- EDTA ethylenediamine tetraacetic acid
- DTPA Diethylenetriamine-penta-acetic acid
- cathionic and ampholytic surfactants as well as glucans and
- Enzymes can also use hemicellulases and / or pectinases and / or lipases. The main difference to that in the work "Oxidation of non
- the system according to the Invention is either by means of laccase alone
- lignin peroxidases and / or manganese peroxidases from e.g.
- Phanerochaete chrysosporium or other white rot fungi used together. With the latter. Lignin peroxidase (manganese peroxidases) + laccase. is worked at a pH around 4-5, at which both enzyme species are still active. The actual lignin breakdown. the bleach (with
- Oxidizing agents i.e. by intercepting lignin degradation
- Yeast cell walls originate in mixed cultures between
- an additional bleaching system such as formamidine sulfinic acid (FAS) / NaOH can also be important to compensate for the bleaching effect of NaOH / HO in the chemical system, and also as a collector the addition of soaps alone or in
- Oxidizing agents H 2 O 2. O 2 or atmospheric oxygen allow an almost complete polymerization of lignins contained in the wastewater, which go far (20-50%) above the values that can be achieved with laccases alone. This makes it possible for 70-90% of the lignin to become insoluble and thus loosen up, sediment,
- the pH is adjusted to 5 with 1N HCl.
- 0.1 - 1.5% H 2 O 2 are related to dry matter, approx. 0.1% ETDA or DTPA.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Paper (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU17933/92A AU663501B2 (en) | 1991-05-17 | 1992-05-18 | Process, using enhanced-action laccase enzymes, for the delignification or bleaching of lignocellulose-containing material or for the treatment of waste water |
JP4510402A JPH06508663A (ja) | 1991-05-17 | 1992-05-18 | 効率の高まったラッカーゼを用いた、リグノセルロースを含む材料の脱リグニン、漂白及び白水処理のための方法 |
BR9206013A BR9206013A (pt) | 1991-05-17 | 1992-05-18 | Processo para deslignificação de material contendo lignocelulose, alvejamento e tratamento de águas residuais por meio de lacases com eficiência melhorada. |
NO934148A NO934148L (no) | 1991-05-17 | 1993-11-16 | Fremgangsmaate for delignifisering av lignocelluloseholdige materiale, bleking og behandling av spillvann ved hjelp av laccaser med forbed ret virk-somhet |
FI935067A FI935067A (fi) | 1991-05-17 | 1993-11-16 | Foerfarande foer delignifiering eller blekning av lignosellulosahaltigt material och foer behandling av avfallsvatten med lackasenzymer, som har foerbaettrad effekt |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4116133 | 1991-05-17 | ||
DEP4116133.5 | 1991-05-17 | ||
DEP4137761.3 | 1991-11-16 | ||
DE19914137761 DE4137761A1 (de) | 1991-05-17 | 1991-11-16 | Verfahren zur delignifizierung von lignocellulosehaltigem material, bleiche und behandlung von abwaessern mittels laccasen mit erweiteter wirksamkeit |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1992020857A1 true WO1992020857A1 (de) | 1992-11-26 |
Family
ID=25903703
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1992/001086 WO1992020857A1 (de) | 1991-05-17 | 1992-05-18 | Verfahren zur delignifizierung von lignocellulosehaltigem material. bleiche und behandlung von abwässern mittels laccasen mit erweiterter wirksamkeit |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0584176A1 (de) |
JP (1) | JPH06508663A (de) |
CN (1) | CN1068161A (de) |
AU (1) | AU663501B2 (de) |
BR (1) | BR9206013A (de) |
CA (1) | CA2103260A1 (de) |
DE (1) | DE4137761A1 (de) |
FI (1) | FI935067A (de) |
NO (1) | NO934148L (de) |
WO (1) | WO1992020857A1 (de) |
Cited By (16)
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---|---|---|---|---|
WO1993023606A1 (en) * | 1992-05-18 | 1993-11-25 | Novo Nordisk A/S | Process for producing paper or paperboard with increased strength from mechanical pulp |
WO1994029510A1 (de) * | 1993-06-16 | 1994-12-22 | Lignozym Gmbh | Verfahren zur veränderung, abbau oder bleichen von lignin, ligninhaltigen materialien oder ähnlichen stoffen |
WO1995001426A1 (en) * | 1993-06-29 | 1995-01-12 | Novo Nordisk A/S | Enhancement of laccase reactions |
WO1995014807A1 (en) * | 1993-11-23 | 1995-06-01 | Novo Nordisk A/S | Deinking of waste paper by treatment with starch degrading enzyme e.g. amylase |
WO1997029237A1 (en) * | 1996-02-08 | 1997-08-14 | Novo Nordisk A/S | Process for increasing the charge on a lignocellulosic material, product obtainable by the process, and use of the product in the preparation of a lignocellulose-based product |
US5691193A (en) * | 1993-02-25 | 1997-11-25 | Pulp And Paper Research Institute Of Canada | Non-chlorine bleaching of kraft pulp |
WO1998005818A1 (de) * | 1996-08-01 | 1998-02-12 | Consortium für elektrochemische Industrie GmbH | Mehrkomponentensystem zum verändern, abbau oder bleichen von lignin, ligninhaltigen materialien oder ähnlichen stoffen sowie verfahren zu seiner anwendung |
WO1998031763A1 (en) * | 1997-01-14 | 1998-07-23 | Neste Chemicals Oy | Lignin-based adhesives and a process for the preparation thereof |
WO1998031762A1 (en) * | 1997-01-14 | 1998-07-23 | Neste Chemicals Oy | A new adhesive for fiber boards |
WO1998031761A1 (en) * | 1997-01-14 | 1998-07-23 | Neste Chemicals Oy | Adhesives for fiber boards and a process for the preparation thereof |
WO1998031764A1 (en) * | 1997-01-14 | 1998-07-23 | Neste Chemicals Oy | Lignin-based adhesives for particle board manufacture |
EP0881326A1 (de) * | 1997-05-30 | 1998-12-02 | Papierfabrik, Schoeller & Hoesch GmbH | Verfahren zur Herstellung von gebleichten Spezialzellstoffen |
WO1999001607A2 (de) * | 1997-06-20 | 1999-01-14 | Call, Krimhild | Enzymatisches oxidationssystem mit neuen enzymwirkungsverstärkenden verbindungen |
US5885412A (en) * | 1993-12-23 | 1999-03-23 | Bim Kemi Ab | Inhibition of hydrogen peroxide decomposing enzymes during bleaching of cellulose fibers |
US5888787A (en) * | 1996-07-02 | 1999-03-30 | North Carolina State University | Selective enzymatic oxidation of aromatic methyl groups to aldehydes by oxygen in the presence of a laccase-mediator catalyst |
RU2488445C1 (ru) * | 2012-04-26 | 2013-07-27 | Общество с ограниченной ответственностью "Целлокорм" | Синтез многофункционального катализатора окислительного крекинга органического сырья и способ жидкофазного низкотемпературного окислительного крекинга органического сырья (варианты) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5770418A (en) * | 1994-06-24 | 1998-06-23 | Novo Nordisk A/S | Purified polyporus laccases and nucleic acids encoding same |
BR9508113A (pt) * | 1994-06-24 | 1998-07-14 | Novo Nordisk Biotech Inc | Construção de dna enzima vetor recombinante célula hospedeira recombinante processos para obter uma enzima de lacase para polimerizar um substrato de lingnina ou lingossulfato em solução para despolimerizar in situ pasta kraft para oxidar corantes ou precursores de corante para tingir cabelo e para polimerizar ou oxidar um composto fenólico ou anilina composição de corante e recipiente |
CN1053242C (zh) * | 1995-12-11 | 2000-06-07 | 山东大学 | 利用木聚糖酶改善草浆性能的工艺 |
DE19820947B4 (de) * | 1997-05-12 | 2005-12-01 | Call, Krimhild | Enzymatisches Bleichsystem mit neuen enzymwirkungsverstärkenden Verbindungen zum Verändern, Abbau oder Bleichen von Lignin, ligninhaltigen Materialien oder Verändern oder Abbau von Kohle sowie Verfahren unter Verwendung des Bleichsystems |
CN1100176C (zh) * | 2000-02-03 | 2003-01-29 | 华南理工大学 | 一种阔叶木硫酸盐浆的全无氯漂白方法 |
FI113879B (fi) | 2000-05-23 | 2004-06-30 | Valtion Teknillinen | Uusi lakkaasientsyymi |
DE10064064A1 (de) * | 2000-12-21 | 2002-07-18 | Fraunhofer Ges Forschung | Verfahren zur Beschleunigung biokatalytischer und/oder hormoneller Prozesse und dessen Verwendung |
FI122278B (fi) * | 2009-09-11 | 2011-11-15 | Upm Kymmene Corp | Menetelmä inkjetmustepitoisten suspensioiden siistaamiseksi |
WO2014058581A1 (en) * | 2012-10-10 | 2014-04-17 | Buckman Laboratories International, Inc. | Fixation of mineral oil in paper food packaging with laccase to prevent mineral oil migration into food |
CN103031297B (zh) * | 2012-12-21 | 2014-03-12 | 青岛蔚蓝生物集团有限公司 | 一种漂白浆磨浆用复合酶及其应用工艺 |
CN105019289B (zh) * | 2015-07-11 | 2016-06-08 | 湖北欧华达纤维科技股份有限公司 | 利用金孢展齿革菌降解木质素的纸浆生产方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1988003190A1 (en) * | 1986-10-24 | 1988-05-05 | Call Hans Peter | Process for producing cellulose from lignin-containing raw materials |
EP0429422A1 (de) * | 1989-11-17 | 1991-05-29 | Enso-Gutzeit Oy | Verfahren zur Herstellung von Zellstoff |
EP0447673A1 (de) * | 1990-03-20 | 1991-09-25 | LIGNOZYM GESELLSCHAFT ZUR HERSTELLUNG UND ZUM VERTRIEB VON ENZYMEN mbH | Verfahren zum enzymatischen Bleichen von Zellstoffen |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3713103A1 (de) * | 1987-04-16 | 1988-11-03 | Aloys Prof Dr Huettermann | Verfahren zur entfernung von phenolen bzw. chloraromaten aus abwaessern der zellstoffindustrie |
-
1991
- 1991-11-16 DE DE19914137761 patent/DE4137761A1/de not_active Withdrawn
-
1992
- 1992-05-16 CN CN 92104549 patent/CN1068161A/zh active Pending
- 1992-05-18 EP EP19920910456 patent/EP0584176A1/de not_active Withdrawn
- 1992-05-18 JP JP4510402A patent/JPH06508663A/ja active Pending
- 1992-05-18 AU AU17933/92A patent/AU663501B2/en not_active Ceased
- 1992-05-18 WO PCT/EP1992/001086 patent/WO1992020857A1/de not_active Application Discontinuation
- 1992-05-18 CA CA 2103260 patent/CA2103260A1/en not_active Abandoned
- 1992-05-18 BR BR9206013A patent/BR9206013A/pt not_active Application Discontinuation
-
1993
- 1993-11-16 NO NO934148A patent/NO934148L/no unknown
- 1993-11-16 FI FI935067A patent/FI935067A/fi not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1988003190A1 (en) * | 1986-10-24 | 1988-05-05 | Call Hans Peter | Process for producing cellulose from lignin-containing raw materials |
EP0429422A1 (de) * | 1989-11-17 | 1991-05-29 | Enso-Gutzeit Oy | Verfahren zur Herstellung von Zellstoff |
EP0447673A1 (de) * | 1990-03-20 | 1991-09-25 | LIGNOZYM GESELLSCHAFT ZUR HERSTELLUNG UND ZUM VERTRIEB VON ENZYMEN mbH | Verfahren zum enzymatischen Bleichen von Zellstoffen |
Non-Patent Citations (1)
Title |
---|
PAPIER, DAS. Bd. 44, Nr. 10A, Oktober 1990, DARMSTADT DE Seiten V33 - V41 CALL, H.P. ET AL. 'Einsatz von lignolytischen Enzymen bei der Zellstoff und Papierherstellung (Biopulping, Biobleaching).' * |
Cited By (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6207009B1 (en) | 1992-05-18 | 2001-03-27 | Novo Nordisk Biochem North America, Inc. | Method of treating mechanical pulp with a phenol-oxidizing enzyme system |
WO1993023606A1 (en) * | 1992-05-18 | 1993-11-25 | Novo Nordisk A/S | Process for producing paper or paperboard with increased strength from mechanical pulp |
US5691193A (en) * | 1993-02-25 | 1997-11-25 | Pulp And Paper Research Institute Of Canada | Non-chlorine bleaching of kraft pulp |
WO1994029510A1 (de) * | 1993-06-16 | 1994-12-22 | Lignozym Gmbh | Verfahren zur veränderung, abbau oder bleichen von lignin, ligninhaltigen materialien oder ähnlichen stoffen |
CN1043913C (zh) * | 1993-06-16 | 1999-06-30 | 里格诺金姆有限公司 | 木质素、含木质素的材料或类似物质的改性、降解或漂白的方法 |
US5795855A (en) * | 1993-06-29 | 1998-08-18 | Novo Nordisk A/S | Enhancement of laccase reactions |
WO1995001426A1 (en) * | 1993-06-29 | 1995-01-12 | Novo Nordisk A/S | Enhancement of laccase reactions |
KR100336177B1 (ko) * | 1993-06-29 | 2002-10-04 | 노보자임스 에이/에스 | 락카제반응의증강법및증강제 |
CN1074790C (zh) * | 1993-06-29 | 2001-11-14 | 诺沃奇梅兹有限公司 | 漆酶反应的增强作用 |
US5885304A (en) * | 1993-06-29 | 1999-03-23 | Novo Nordisk A/S | Enhancement of laccase reactions |
US5879509A (en) * | 1993-11-23 | 1999-03-09 | Novo Nordisk A/S | Deinking of starch-coated printed paper by treatment with starch degrading enzyme |
WO1995014807A1 (en) * | 1993-11-23 | 1995-06-01 | Novo Nordisk A/S | Deinking of waste paper by treatment with starch degrading enzyme e.g. amylase |
US5885412A (en) * | 1993-12-23 | 1999-03-23 | Bim Kemi Ab | Inhibition of hydrogen peroxide decomposing enzymes during bleaching of cellulose fibers |
WO1997029237A1 (en) * | 1996-02-08 | 1997-08-14 | Novo Nordisk A/S | Process for increasing the charge on a lignocellulosic material, product obtainable by the process, and use of the product in the preparation of a lignocellulose-based product |
US6187136B1 (en) | 1996-02-08 | 2001-02-13 | Novo Nordisk A/S | Process for increasing the charge on a lignocellulosic material |
US5888787A (en) * | 1996-07-02 | 1999-03-30 | North Carolina State University | Selective enzymatic oxidation of aromatic methyl groups to aldehydes by oxygen in the presence of a laccase-mediator catalyst |
WO1998005818A1 (de) * | 1996-08-01 | 1998-02-12 | Consortium für elektrochemische Industrie GmbH | Mehrkomponentensystem zum verändern, abbau oder bleichen von lignin, ligninhaltigen materialien oder ähnlichen stoffen sowie verfahren zu seiner anwendung |
WO1998031763A1 (en) * | 1997-01-14 | 1998-07-23 | Neste Chemicals Oy | Lignin-based adhesives and a process for the preparation thereof |
WO1998031764A1 (en) * | 1997-01-14 | 1998-07-23 | Neste Chemicals Oy | Lignin-based adhesives for particle board manufacture |
WO1998031762A1 (en) * | 1997-01-14 | 1998-07-23 | Neste Chemicals Oy | A new adhesive for fiber boards |
WO1998031761A1 (en) * | 1997-01-14 | 1998-07-23 | Neste Chemicals Oy | Adhesives for fiber boards and a process for the preparation thereof |
AU731726B2 (en) * | 1997-01-14 | 2001-04-05 | Neste Chemicals Oy | A new adhesive for fiber boards |
US6287708B1 (en) | 1997-01-14 | 2001-09-11 | Neste Chemicals Oy | Adhesive for fiber boards |
EP0881326A1 (de) * | 1997-05-30 | 1998-12-02 | Papierfabrik, Schoeller & Hoesch GmbH | Verfahren zur Herstellung von gebleichten Spezialzellstoffen |
WO1999001607A3 (de) * | 1997-06-20 | 1999-06-24 | Call Krimhild | Enzymatisches oxidationssystem mit neuen enzymwirkungsverstärkenden verbindungen |
WO1999001607A2 (de) * | 1997-06-20 | 1999-01-14 | Call, Krimhild | Enzymatisches oxidationssystem mit neuen enzymwirkungsverstärkenden verbindungen |
RU2488445C1 (ru) * | 2012-04-26 | 2013-07-27 | Общество с ограниченной ответственностью "Целлокорм" | Синтез многофункционального катализатора окислительного крекинга органического сырья и способ жидкофазного низкотемпературного окислительного крекинга органического сырья (варианты) |
WO2013162421A1 (ru) * | 2012-04-26 | 2013-10-31 | Общество с ограниченной ответственностью "Целлокорм" | Синтез многофункционального катализатора и способ жидкофазного низкотемпературного окислительного крекинга органического сырья |
Also Published As
Publication number | Publication date |
---|---|
NO934148D0 (no) | 1993-11-16 |
NO934148L (no) | 1994-01-04 |
AU1793392A (en) | 1992-12-30 |
CA2103260A1 (en) | 1992-11-18 |
FI935067A (fi) | 1993-12-03 |
CN1068161A (zh) | 1993-01-20 |
JPH06508663A (ja) | 1994-09-29 |
DE4137761A1 (de) | 1992-11-19 |
AU663501B2 (en) | 1995-10-12 |
BR9206013A (pt) | 1994-11-15 |
EP0584176A1 (de) | 1994-03-02 |
FI935067A0 (fi) | 1993-11-16 |
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