TWI606632B - 具有低敲緊密度之過渡金屬前驅物及具有高粒子強度之鋰過渡金屬氧化物 - Google Patents

具有低敲緊密度之過渡金屬前驅物及具有高粒子強度之鋰過渡金屬氧化物 Download PDF

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TWI606632B
TWI606632B TW103104590A TW103104590A TWI606632B TW I606632 B TWI606632 B TW I606632B TW 103104590 A TW103104590 A TW 103104590A TW 103104590 A TW103104590 A TW 103104590A TW I606632 B TWI606632 B TW I606632B
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Taiwan
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transition metal
lithium
metal oxide
precursor
metal precursor
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TW103104590A
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Chinese (zh)
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TW201448332A (zh
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林振鎣
張誠均
張元碩
朴信英
申昊錫
吳賢真
韓貞敏
嚴仁晟
鄭王謨
李東勳
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Ｌｇ化學股份有限公司
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
    • C01G53/84—Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • C01G53/502—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 containing lithium and cobalt
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/60—Other road transportation technologies with climate change mitigation effect
    • Y02T10/70—Energy storage systems for electromobility, e.g. batteries

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
TW103104590A 2013-02-13 2014-02-12 具有低敲緊密度之過渡金屬前驅物及具有高粒子強度之鋰過渡金屬氧化物 TWI606632B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020130015206A KR101575024B1 (ko) 2013-02-13 2013-02-13 낮은 탭 밀도를 갖는 전이금속 전구체 및 높은 입자 강도를 가진 리튬 전이금속 산화물

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TW201448332A TW201448332A (zh) 2014-12-16
TWI606632B true TWI606632B (zh) 2017-11-21

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TW103104590A TWI606632B (zh) 2013-02-13 2014-02-12 具有低敲緊密度之過渡金屬前驅物及具有高粒子強度之鋰過渡金屬氧化物

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US (2) US11577969B2 (enExample)
EP (1) EP2902364B1 (enExample)
JP (1) JP6224125B2 (enExample)
KR (1) KR101575024B1 (enExample)
CN (1) CN104884390B (enExample)
BR (1) BR112015013932B8 (enExample)
IN (1) IN2015DN03943A (enExample)
TW (1) TWI606632B (enExample)
WO (1) WO2014126373A1 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102233772B1 (ko) 2016-09-13 2021-03-30 삼성에스디아이 주식회사 리튬이차전지용 산화코발트, 그 제조방법, 이로부터 형성된 리튬이차전지용 리튬코발트산화물 및 이를 포함한 양극을 구비한 리튬이차전지
JP7262230B2 (ja) * 2019-01-22 2023-04-21 株式会社田中化学研究所 非水電解質二次電池用複合水酸化物小粒子
KR102930413B1 (ko) * 2021-02-17 2026-02-23 에스케이온 주식회사 리튬 이차 전지용 양극 활물질 및 이를 포함하는 리튬 이차 전지

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001106534A (ja) 1999-10-06 2001-04-17 Tanaka Chemical Corp 非水電解液電池活物質用原料複合金属水酸化物及び活物質リチウム複合金属酸化物
JP4359092B2 (ja) * 2003-08-21 2009-11-04 Ａｇｃセイミケミカル株式会社 二次電池正極用のリチウムコバルト複合酸化物の製造方法
JP4683527B2 (ja) * 2004-07-22 2011-05-18 日本化学工業株式会社 改質リチウムマンガンニッケル系複合酸化物、その製造方法、リチウム二次電池正極活物質及びリチウム二次電池
EP2162396A1 (en) 2007-06-29 2010-03-17 Umicore High density lithium cobalt oxide for rechargeable batteries
DE102007039471A1 (de) 2007-08-21 2009-02-26 H.C. Starck Gmbh Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Lithium-Sekundärbatterien
DE102007049108A1 (de) 2007-10-12 2009-04-16 H.C. Starck Gmbh Pulverförmige Verbindungen, Verfahren zu deren Herstellung sowie deren Verwendung in Batterien
KR101147604B1 (ko) * 2007-10-12 2012-05-23 주식회사 엘지화학 젤리-롤형 전극조립체의 변형을 억제하기 위한 제조방법
KR101234965B1 (ko) 2007-11-06 2013-02-20 파나소닉 주식회사 비수전해질 이차전지용 양극 활물질 및 그것을 이용한 비수전해질 이차전지
EP2314545B1 (en) 2008-03-28 2018-03-07 Toda Kogyo Corp. Oxycobalt hydroxide particulate powder and manufacturing method therefor, as well as lithium cobaltate particulate powder and non-aqueous electrolyte secondary battery using the same
US8394299B2 (en) * 2008-04-03 2013-03-12 Lg Chem, Ltd. Precursor for the preparation of a lithium composite transition metal oxide
JP5651937B2 (ja) * 2008-09-10 2015-01-14 住友金属鉱山株式会社 非水系電解質二次電池用正極活物質およびその製造方法、ならびにこれを用いた非水系電解質二次電池
EP2399311B1 (en) 2009-02-20 2013-05-29 Umicore Non-homogeneous positive electrode materials combining high safety and high power in a li rechargeable battery
CN102574700A (zh) * 2009-10-22 2012-07-11 户田工业株式会社 镍-钴-锰类化合物颗粒粉末及其制造方法、锂复合氧化物颗粒粉末及其制造方法和非水电解质二次电池
EP2544280B1 (en) 2010-03-05 2018-06-06 JX Nippon Mining & Metals Corporation Positive-electrode active material for lithium ion battery, positive electrode for lithium battery, and lithium ion battery
KR101286761B1 (ko) 2010-06-01 2013-07-16 주식회사 엘앤에프신소재 전이금속 화합물 전구체, 이를 이용한 리튬 전이금속 화합물, 상기 리튬 전이금속 화합물을 포함하는 양극 활물질 및 상기 양극 활물질을 포함하는 리튬 이온 이차전지
JP2012038562A (ja) * 2010-08-06 2012-02-23 Tdk Corp 前駆体、活物質の製造方法及びリチウムイオン二次電池
CA2806915C (en) 2010-09-22 2018-10-09 Omg Kokkola Chemicals Oy Mixed metal oxidized hydroxide and method for production
WO2012095381A2 (de) * 2011-01-10 2012-07-19 Basf Se Verfahren zur herstellung von übergangsmetallhydroxiden
JP6310698B2 (ja) * 2011-10-11 2018-04-11 株式会社Ｇｓユアサ 非水電解質二次電池および非水電解質二次電池の製造方法
KR101689214B1 (ko) * 2011-10-28 2016-12-26 삼성에스디아이 주식회사 리튬 이차 전지용 니켈 복합 수산화물, 이로부터 형성된 리튬 이차 전지용 리튬 복합 산화물, 그 제조방법, 이를 포함하는 리튬 이차 전지용 양극 및 이를 구비한 리튬 이차 전지
JP2013144625A (ja) 2012-01-16 2013-07-25 Tanaka Chemical Corp ニッケルコバルトマンガン複合水酸化物及びその製造方法、非水電解質二次電池用の正極活物質、並びに非水電解質二次電池
KR101954119B1 (ko) 2013-10-31 2019-03-06 주식회사 엘지화학 리튬 이차전지용 양극 활물질 조성물 및 그 제조방법

Also Published As

Publication number Publication date
EP2902364A1 (en) 2015-08-05
TW201448332A (zh) 2014-12-16
WO2014126373A1 (ko) 2014-08-21
CN104884390B (zh) 2018-01-23
JP6224125B2 (ja) 2017-11-01
BR112015013932B1 (pt) 2021-11-23
IN2015DN03943A (enExample) 2015-10-02
US20220135428A1 (en) 2022-05-05
KR101575024B1 (ko) 2015-12-07
US11577969B2 (en) 2023-02-14
JP2016500048A (ja) 2016-01-07
KR20140102367A (ko) 2014-08-22
BR112015013932A2 (pt) 2017-07-11
US20160002063A1 (en) 2016-01-07
CN104884390A (zh) 2015-09-02
EP2902364B1 (en) 2018-06-06
EP2902364A4 (en) 2016-06-29
BR112015013932B8 (pt) 2023-01-17

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