TWI597886B - 鋰鎳錳氧正極材料之製法 - Google Patents
鋰鎳錳氧正極材料之製法 Download PDFInfo
- Publication number
- TWI597886B TWI597886B TW105125483A TW105125483A TWI597886B TW I597886 B TWI597886 B TW I597886B TW 105125483 A TW105125483 A TW 105125483A TW 105125483 A TW105125483 A TW 105125483A TW I597886 B TWI597886 B TW I597886B
- Authority
- TW
- Taiwan
- Prior art keywords
- precursor
- manganese oxide
- positive electrode
- lithium nickel
- nickel manganese
- Prior art date
Links
- FRMOHNDAXZZWQI-UHFFFAOYSA-N lithium manganese(2+) nickel(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Ni+2].[Li+] FRMOHNDAXZZWQI-UHFFFAOYSA-N 0.000 title claims description 47
- 239000010406 cathode material Substances 0.000 title claims description 41
- 238000000034 method Methods 0.000 title claims description 28
- 239000002243 precursor Substances 0.000 claims description 67
- 239000007774 positive electrode material Substances 0.000 claims description 46
- 239000000463 material Substances 0.000 claims description 45
- 238000000227 grinding Methods 0.000 claims description 32
- 239000002245 particle Substances 0.000 claims description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 21
- 239000012535 impurity Substances 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 229910003895 Li1.0Ni0.5Mn1.5O4 Inorganic materials 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 description 17
- 238000005245 sintering Methods 0.000 description 15
- 239000011572 manganese Substances 0.000 description 12
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 11
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 229910052748 manganese Inorganic materials 0.000 description 8
- 229910052744 lithium Inorganic materials 0.000 description 7
- 229910052759 nickel Inorganic materials 0.000 description 7
- 238000005498 polishing Methods 0.000 description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 229910000480 nickel oxide Inorganic materials 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 4
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 4
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 4
- 238000003746 solid phase reaction Methods 0.000 description 4
- 238000010671 solid-state reaction Methods 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 3
- KVGMATYUUPJFQL-UHFFFAOYSA-N manganese(2+) oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[Mn++].[Mn++].[Mn++] KVGMATYUUPJFQL-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 2
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910052808 lithium carbonate Inorganic materials 0.000 description 2
- 229940093474 manganese carbonate Drugs 0.000 description 2
- 235000006748 manganese carbonate Nutrition 0.000 description 2
- 239000011656 manganese carbonate Substances 0.000 description 2
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229940078494 nickel acetate Drugs 0.000 description 2
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000006104 solid solution Substances 0.000 description 2
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/52—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (Mn2O4)2-, e.g. Li2(NixMn2-x)O4 or Li2(MyNixMn2-x-y)O4
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/54—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (Mn2O4)-, e.g. Li(NixMn2-x)O4 or Li(MyNixMn2-x-y)O4
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462029117P | 2014-07-25 | 2014-07-25 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201640723A TW201640723A (zh) | 2016-11-16 |
| TWI597886B true TWI597886B (zh) | 2017-09-01 |
Family
ID=55162526
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW105125483A TWI597886B (zh) | 2014-07-25 | 2015-07-23 | 鋰鎳錳氧正極材料之製法 |
| TW104123839A TWI578601B (zh) | 2014-07-25 | 2015-07-23 | 鋰鎳錳氧正極材料之製法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW104123839A TWI578601B (zh) | 2014-07-25 | 2015-07-23 | 鋰鎳錳氧正極材料之製法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20170214044A1 (enExample) |
| EP (1) | EP3174142A4 (enExample) |
| JP (1) | JP2017522702A (enExample) |
| KR (1) | KR20170030559A (enExample) |
| CN (1) | CN106575759A (enExample) |
| CA (1) | CA2956380A1 (enExample) |
| TW (2) | TWI597886B (enExample) |
| WO (1) | WO2016011962A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201916198D0 (en) * | 2019-11-07 | 2019-12-25 | Johnson Matthey Plc | Cathode material and process |
| KR102168640B1 (ko) * | 2020-04-21 | 2020-10-21 | (주)탑전지 | 스피넬 복합고용체 산화물을 포함하는 양극 활물질, 이의 제조 방법, 및 이를 포함하는 리튬 이차 전지 |
| US20230411694A1 (en) * | 2020-11-30 | 2023-12-21 | Panasonic Intellectual Property Management Co., Ltd. | Non-aqueous electrolyte secondary battery |
| US20240145700A1 (en) * | 2021-03-18 | 2024-05-02 | Panasonic Intellectual Property Management Co., Ltd. | Non-aqueous electrolyte secondary battery |
| JP7838884B2 (ja) * | 2022-09-15 | 2026-04-01 | エルジー・ケム・リミテッド | 正極活物質前駆体の製造方法 |
| EP4774773A2 (en) * | 2023-09-08 | 2026-07-15 | Li Industries, Inc. | Systems and methods for combined electrode material synthesis |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4092950B2 (ja) * | 2001-05-17 | 2008-05-28 | 三菱化学株式会社 | リチウムニッケルマンガン複合酸化物の製造方法 |
| JP4299065B2 (ja) * | 2003-06-19 | 2009-07-22 | 株式会社クレハ | リチウム二次電池用正極材およびその製造方法 |
| FR2879822B1 (fr) * | 2004-12-21 | 2009-05-22 | Commissariat Energie Atomique | Materiau d'electrode positive optimise pour accumulateurs au lithium, procede pour sa realisation, electrode, accumulateur et batterie mettant en oeuvre ce materiau |
| CN1801508A (zh) * | 2005-01-06 | 2006-07-12 | 中南大学 | 高电压锂离子电池正极材料锂镍锰氧的制备方法 |
| JP2007039266A (ja) * | 2005-08-02 | 2007-02-15 | Sumitomo Metal Mining Co Ltd | リチウムマンガンニッケル複合酸化物の製造方法および非水系電解質二次電池用正極活物質 |
| FR2890241B1 (fr) * | 2005-08-25 | 2009-05-22 | Commissariat Energie Atomique | Materiau d'electrode positive haute tension de structure spinelle a base de nickel et de manganese pour accumulateurs au lithium |
| JP4591716B2 (ja) * | 2006-04-07 | 2010-12-01 | 三菱化学株式会社 | リチウム二次電池正極材料用リチウム遷移金属系化合物粉体、その製造方法、噴霧乾燥体、および焼成前駆体、並びにそれを用いたリチウム二次電池用正極及びリチウム二次電池 |
| CN101148263A (zh) * | 2006-09-19 | 2008-03-26 | 上海杉杉新材料研究院有限责任公司 | 高电压锂离子电池正极材料锂镍锰氧的制备方法 |
| US20130032753A1 (en) * | 2010-02-23 | 2013-02-07 | Manabu Yamamoto | Positive electrode active substance precursor particles, positive electrode active substance particles and non-aqueous electrolyte secondary battery |
| JP2012033279A (ja) * | 2010-07-28 | 2012-02-16 | Nec Energy Devices Ltd | リチウムイオン二次電池 |
| WO2012127919A1 (ja) * | 2011-03-18 | 2012-09-27 | 株式会社 村田製作所 | 二次電池用電極活物質およびそれを備えた二次電池 |
| CN103456932A (zh) * | 2012-05-27 | 2013-12-18 | 湖南省正源储能材料与器件研究所 | 一种储能材料的制备方法 |
| WO2014077277A1 (ja) * | 2012-11-13 | 2014-05-22 | 日揮触媒化成株式会社 | リチウム複合酸化物およびその製造方法、そのリチウム複合酸化物を含む二次電池用正極活物質、それを含む二次電池用正極、ならびにそれを正極として用いるリチウムイオン二次電池 |
-
2015
- 2015-07-23 WO PCT/CN2015/084908 patent/WO2016011962A1/zh not_active Ceased
- 2015-07-23 TW TW105125483A patent/TWI597886B/zh active
- 2015-07-23 US US15/328,575 patent/US20170214044A1/en not_active Abandoned
- 2015-07-23 CN CN201580037867.7A patent/CN106575759A/zh active Pending
- 2015-07-23 EP EP15825046.4A patent/EP3174142A4/en not_active Withdrawn
- 2015-07-23 KR KR1020177003145A patent/KR20170030559A/ko not_active Ceased
- 2015-07-23 TW TW104123839A patent/TWI578601B/zh active
- 2015-07-23 CA CA2956380A patent/CA2956380A1/en active Pending
- 2015-07-23 JP JP2017503913A patent/JP2017522702A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| TW201640723A (zh) | 2016-11-16 |
| TW201605108A (zh) | 2016-02-01 |
| EP3174142A1 (en) | 2017-05-31 |
| US20170214044A1 (en) | 2017-07-27 |
| KR20170030559A (ko) | 2017-03-17 |
| TWI578601B (zh) | 2017-04-11 |
| WO2016011962A1 (zh) | 2016-01-28 |
| CN106575759A (zh) | 2017-04-19 |
| JP2017522702A (ja) | 2017-08-10 |
| CA2956380A1 (en) | 2016-01-28 |
| EP3174142A4 (en) | 2018-04-04 |
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