TWI550136B - 在電解法中適於釋氧之電極及其製法和從水溶液電極沈積金屬之方法 - Google Patents
在電解法中適於釋氧之電極及其製法和從水溶液電極沈積金屬之方法 Download PDFInfo
- Publication number
- TWI550136B TWI550136B TW101115023A TW101115023A TWI550136B TW I550136 B TWI550136 B TW I550136B TW 101115023 A TW101115023 A TW 101115023A TW 101115023 A TW101115023 A TW 101115023A TW I550136 B TWI550136 B TW I550136B
- Authority
- TW
- Taiwan
- Prior art keywords
- electrode
- solution
- titanium
- range
- molar ratio
- Prior art date
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 21
- 229910052760 oxygen Inorganic materials 0.000 title claims description 21
- 239000001301 oxygen Substances 0.000 title claims description 21
- 239000000243 solution Substances 0.000 claims description 29
- 229910052751 metal Inorganic materials 0.000 claims description 26
- 239000002184 metal Substances 0.000 claims description 26
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 22
- 229910052719 titanium Inorganic materials 0.000 claims description 22
- 239000010936 titanium Substances 0.000 claims description 22
- 239000000758 substrate Substances 0.000 claims description 15
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 14
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 239000011241 protective layer Substances 0.000 claims description 11
- 229910052707 ruthenium Inorganic materials 0.000 claims description 11
- 239000010410 layer Substances 0.000 claims description 10
- 238000005868 electrolysis reaction Methods 0.000 claims description 9
- 239000002243 precursor Substances 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 229910052797 bismuth Inorganic materials 0.000 claims description 5
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 239000013081 microcrystal Substances 0.000 claims description 5
- 238000000151 deposition Methods 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 3
- 229910052746 lanthanum Inorganic materials 0.000 claims 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 3
- 229910052684 Cerium Inorganic materials 0.000 claims 2
- 229910001069 Ti alloy Inorganic materials 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 14
- 238000000576 coating method Methods 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 9
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 8
- 238000000354 decomposition reaction Methods 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 229910052762 osmium Inorganic materials 0.000 description 7
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000003792 electrolyte Substances 0.000 description 5
- -1 fluoride ions Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000005272 metallurgy Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 238000005979 thermal decomposition reaction Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052758 niobium Inorganic materials 0.000 description 3
- 239000010955 niobium Substances 0.000 description 3
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910001887 tin oxide Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000012327 Ruthenium complex Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 239000002320 enamel (paints) Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910000487 osmium oxide Inorganic materials 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- JIWAALDUIFCBLV-UHFFFAOYSA-N oxoosmium Chemical compound [Os]=O JIWAALDUIFCBLV-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/093—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Metals (AREA)
- Inert Electrodes (AREA)
- Vending Machines For Individual Products (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT001132A ITMI20111132A1 (it) | 2011-06-22 | 2011-06-22 | Anodo per evoluzione di ossigeno |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201300576A TW201300576A (zh) | 2013-01-01 |
| TWI550136B true TWI550136B (zh) | 2016-09-21 |
Family
ID=44515177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW101115023A TWI550136B (zh) | 2011-06-22 | 2012-04-27 | 在電解法中適於釋氧之電極及其製法和從水溶液電極沈積金屬之方法 |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US11001935B2 (https=) |
| EP (1) | EP2723918B1 (https=) |
| JP (1) | JP5932028B2 (https=) |
| KR (1) | KR101894706B1 (https=) |
| CN (1) | CN103597124B (https=) |
| AP (1) | AP2013007339A0 (https=) |
| AR (1) | AR086725A1 (https=) |
| AU (1) | AU2012274018B2 (https=) |
| BR (1) | BR112013029743B1 (https=) |
| CA (1) | CA2835233C (https=) |
| CL (1) | CL2013003326A1 (https=) |
| EA (1) | EA024916B1 (https=) |
| ES (1) | ES2558179T3 (https=) |
| IN (1) | IN2014DN00250A (https=) |
| IT (1) | ITMI20111132A1 (https=) |
| MX (1) | MX350803B (https=) |
| PE (1) | PE20140885A1 (https=) |
| PL (1) | PL2723918T3 (https=) |
| TW (1) | TWI550136B (https=) |
| WO (1) | WO2012175673A1 (https=) |
| ZA (1) | ZA201308554B (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20130991A1 (it) * | 2013-06-17 | 2014-12-18 | Industrie De Nora Spa | Sistema per la misurazione di correnti presenti sugli elettrodi in celle elettrolitiche interconnesse. |
| WO2015029367A1 (ja) * | 2013-08-30 | 2015-03-05 | Ｊｘ日鉱日石エネルギー株式会社 | 電気化学還元装置 |
| US10415146B2 (en) * | 2014-10-21 | 2019-09-17 | Evoqua Water Technologies Llc | Electrode with two layer coating, method of use, and preparation thereof |
| US10407784B2 (en) * | 2015-06-23 | 2019-09-10 | Industrie De Nora S.P.A. | Electrode for electrolytic processes |
| AU2016363676B2 (en) | 2015-11-30 | 2022-08-18 | Newsouth Innovations Pty Limited | Method for improving catalytic activity |
| CN106676618A (zh) * | 2017-03-22 | 2017-05-17 | 苏州市汉宜化学有限公司 | 一种改良的枪色电镀网状阳极 |
| KR102403412B1 (ko) * | 2019-09-06 | 2022-05-31 | 한국재료연구원 | 입체 나노시트 구조를 갖는 촉매를 포함하는 수전해전극, 그 제조방법 및 그를 포함하는 수전해장치 |
| CN112921354B (zh) * | 2021-01-25 | 2022-07-01 | 深圳市飞猫电器有限公司 | 一种阳极及其制备方法和应用、臭氧发生系统和食品净化器 |
| CN114272920B (zh) * | 2021-11-22 | 2023-10-03 | 广东省科学院资源利用与稀土开发研究所 | 一种有机污染物降解用复合氧化物涂层电极及其制备方法 |
| CN114645295B (zh) * | 2022-03-31 | 2023-06-02 | 华南理工大学 | 一种用于电解水的阳极催化剂的制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200307061A (en) * | 2002-05-24 | 2003-12-01 | De Nora Elettrodi Spa | Electrode for gas evolution and method for its production |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0774470B2 (ja) * | 1990-03-20 | 1995-08-09 | ダイソー株式会社 | 酸素発生用陽極の製法 |
| JP3212327B2 (ja) * | 1991-08-30 | 2001-09-25 | ペルメレック電極株式会社 | 電解用電極 |
| NL9101753A (nl) * | 1991-10-21 | 1993-05-17 | Magneto Chemie Bv | Anodes met verlengde levensduur en werkwijzen voor hun vervaardiging. |
| JP3231556B2 (ja) * | 1994-07-29 | 2001-11-26 | ペルメレック電極株式会社 | ジスルフィド化合物の電解還元方法 |
| JP3507278B2 (ja) * | 1997-06-03 | 2004-03-15 | ペルメレック電極株式会社 | 電気めっき方法 |
| IT1294749B1 (it) * | 1997-09-17 | 1999-04-12 | Nora De | Anodo per evoluzione di ossigeno in elettroliti contenenti manganese e fluoruri |
| IT1302581B1 (it) | 1998-10-01 | 2000-09-29 | Nora De | Anodo con migliorato rivestimento per la reazione di evoluzione diossigeno in elettroliti contenenti manganese. |
| ITMI20031543A1 (it) | 2003-07-28 | 2005-01-29 | De Nora Elettrodi Spa | Elettrodo per processi elettrochimici e metodo per il suo ottenimento |
| ITMI20041006A1 (it) * | 2004-05-20 | 2004-08-20 | De Nora Elettrodi Spa | Anodo per sviluppo ossigeno |
| JP4961825B2 (ja) * | 2006-05-09 | 2012-06-27 | アタカ大機株式会社 | 電気化学反応用陽極 |
| JP4972991B2 (ja) * | 2006-05-09 | 2012-07-11 | アタカ大機株式会社 | 酸素発生用電極 |
| CN1995464A (zh) * | 2006-11-28 | 2007-07-11 | 北京科技大学 | 一种纳米晶铱系氧化物涂层电极制备方法 |
| IT1391767B1 (it) * | 2008-11-12 | 2012-01-27 | Industrie De Nora Spa | Elettrodo per cella elettrolitica |
-
2011
- 2011-06-22 IT IT001132A patent/ITMI20111132A1/it unknown
-
2012
- 2012-04-27 TW TW101115023A patent/TWI550136B/zh active
- 2012-06-22 IN IN250DEN2014 patent/IN2014DN00250A/en unknown
- 2012-06-22 CN CN201280029073.2A patent/CN103597124B/zh active Active
- 2012-06-22 EP EP12731378.1A patent/EP2723918B1/en active Active
- 2012-06-22 BR BR112013029743-3A patent/BR112013029743B1/pt active IP Right Grant
- 2012-06-22 EA EA201301175A patent/EA024916B1/ru not_active IP Right Cessation
- 2012-06-22 AR ARP120102246A patent/AR086725A1/es active IP Right Grant
- 2012-06-22 US US14/116,882 patent/US11001935B2/en active Active
- 2012-06-22 AU AU2012274018A patent/AU2012274018B2/en active Active
- 2012-06-22 PE PE2013002521A patent/PE20140885A1/es active IP Right Grant
- 2012-06-22 MX MX2013013412A patent/MX350803B/es active IP Right Grant
- 2012-06-22 AP AP2013007339A patent/AP2013007339A0/xx unknown
- 2012-06-22 KR KR1020137031371A patent/KR101894706B1/ko active Active
- 2012-06-22 WO PCT/EP2012/062088 patent/WO2012175673A1/en not_active Ceased
- 2012-06-22 ES ES12731378.1T patent/ES2558179T3/es active Active
- 2012-06-22 PL PL12731378T patent/PL2723918T3/pl unknown
- 2012-06-22 JP JP2014516365A patent/JP5932028B2/ja active Active
- 2012-06-22 CA CA2835233A patent/CA2835233C/en active Active
-
2013
- 2013-11-13 ZA ZA2013/08554A patent/ZA201308554B/en unknown
- 2013-11-19 CL CL2013003326A patent/CL2013003326A1/es unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW200307061A (en) * | 2002-05-24 | 2003-12-01 | De Nora Elettrodi Spa | Electrode for gas evolution and method for its production |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2723918A1 (en) | 2014-04-30 |
| CA2835233C (en) | 2019-11-12 |
| ES2558179T3 (es) | 2016-02-02 |
| JP5932028B2 (ja) | 2016-06-08 |
| BR112013029743B1 (pt) | 2020-07-07 |
| AR086725A1 (es) | 2014-01-15 |
| MX2013013412A (es) | 2013-12-12 |
| AP2013007339A0 (en) | 2013-12-31 |
| KR101894706B1 (ko) | 2018-10-24 |
| JP2014517158A (ja) | 2014-07-17 |
| ZA201308554B (en) | 2015-02-25 |
| AU2012274018A1 (en) | 2014-01-09 |
| CN103597124B (zh) | 2016-08-17 |
| EA201301175A1 (ru) | 2014-04-30 |
| US11001935B2 (en) | 2021-05-11 |
| PE20140885A1 (es) | 2014-08-22 |
| BR112013029743A2 (pt) | 2017-01-17 |
| PL2723918T3 (pl) | 2016-06-30 |
| ITMI20111132A1 (it) | 2012-12-23 |
| EA024916B1 (ru) | 2016-11-30 |
| TW201300576A (zh) | 2013-01-01 |
| US20140311915A1 (en) | 2014-10-23 |
| MX350803B (es) | 2017-09-25 |
| CA2835233A1 (en) | 2012-12-27 |
| CL2013003326A1 (es) | 2014-05-09 |
| WO2012175673A1 (en) | 2012-12-27 |
| CN103597124A (zh) | 2014-02-19 |
| EP2723918B1 (en) | 2015-12-09 |
| IN2014DN00250A (https=) | 2015-06-05 |
| AU2012274018B2 (en) | 2017-03-09 |
| KR20140021673A (ko) | 2014-02-20 |
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