EA024916B1 - Анод для выделения кислорода - Google Patents
Анод для выделения кислорода Download PDFInfo
- Publication number
- EA024916B1 EA024916B1 EA201301175A EA201301175A EA024916B1 EA 024916 B1 EA024916 B1 EA 024916B1 EA 201301175 A EA201301175 A EA 201301175A EA 201301175 A EA201301175 A EA 201301175A EA 024916 B1 EA024916 B1 EA 024916B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- valve metal
- electrode according
- oxides
- titanium
- molar ratio
- Prior art date
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 19
- 239000001301 oxygen Substances 0.000 title claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 30
- 239000002184 metal Substances 0.000 claims abstract description 30
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000010936 titanium Substances 0.000 claims abstract description 21
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 19
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000758 substrate Substances 0.000 claims abstract description 18
- 230000003197 catalytic effect Effects 0.000 claims abstract description 17
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 15
- 150000002739 metals Chemical class 0.000 claims abstract description 13
- 229910052715 tantalum Inorganic materials 0.000 claims abstract description 11
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 10
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 10
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 6
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 6
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 5
- 239000010955 niobium Substances 0.000 claims abstract description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 27
- 238000000354 decomposition reaction Methods 0.000 claims description 13
- 239000010410 layer Substances 0.000 claims description 12
- 239000011241 protective layer Substances 0.000 claims description 10
- 238000005275 alloying Methods 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 5
- 229910001936 tantalum oxide Inorganic materials 0.000 claims description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 5
- 238000004070 electrodeposition Methods 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 229910001069 Ti alloy Inorganic materials 0.000 claims 1
- 238000005363 electrowinning Methods 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 description 22
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 13
- 239000000203 mixture Substances 0.000 description 10
- 239000002243 precursor Substances 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- -1 fluoride ions Chemical class 0.000 description 6
- 229910000457 iridium oxide Inorganic materials 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 239000003792 electrolyte Substances 0.000 description 5
- 238000005979 thermal decomposition reaction Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000009849 deactivation Effects 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- YJZATOSJMRIRIW-UHFFFAOYSA-N [Ir]=O Chemical class [Ir]=O YJZATOSJMRIRIW-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 229910001437 manganese ion Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 102100028672 C-type lectin domain family 4 member D Human genes 0.000 description 1
- 101100368700 Caenorhabditis elegans tac-1 gene Proteins 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 101000766905 Homo sapiens C-type lectin domain family 4 member D Proteins 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910021569 Manganese fluoride Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000004210 cathodic protection Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000010285 flame spraying Methods 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical class [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/093—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D17/00—Constructional parts, or assemblies thereof, of cells for electrolytic coating
- C25D17/10—Electrodes, e.g. composition, counter electrode
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Metals (AREA)
- Inert Electrodes (AREA)
- Vending Machines For Individual Products (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT001132A ITMI20111132A1 (it) | 2011-06-22 | 2011-06-22 | Anodo per evoluzione di ossigeno |
| PCT/EP2012/062088 WO2012175673A1 (en) | 2011-06-22 | 2012-06-22 | Anode for oxygen evolution |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA201301175A1 EA201301175A1 (ru) | 2014-04-30 |
| EA024916B1 true EA024916B1 (ru) | 2016-11-30 |
Family
ID=44515177
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA201301175A EA024916B1 (ru) | 2011-06-22 | 2012-06-22 | Анод для выделения кислорода |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US11001935B2 (https=) |
| EP (1) | EP2723918B1 (https=) |
| JP (1) | JP5932028B2 (https=) |
| KR (1) | KR101894706B1 (https=) |
| CN (1) | CN103597124B (https=) |
| AP (1) | AP2013007339A0 (https=) |
| AR (1) | AR086725A1 (https=) |
| AU (1) | AU2012274018B2 (https=) |
| BR (1) | BR112013029743B1 (https=) |
| CA (1) | CA2835233C (https=) |
| CL (1) | CL2013003326A1 (https=) |
| EA (1) | EA024916B1 (https=) |
| ES (1) | ES2558179T3 (https=) |
| IN (1) | IN2014DN00250A (https=) |
| IT (1) | ITMI20111132A1 (https=) |
| MX (1) | MX350803B (https=) |
| PE (1) | PE20140885A1 (https=) |
| PL (1) | PL2723918T3 (https=) |
| TW (1) | TWI550136B (https=) |
| WO (1) | WO2012175673A1 (https=) |
| ZA (1) | ZA201308554B (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20130991A1 (it) * | 2013-06-17 | 2014-12-18 | Industrie De Nora Spa | Sistema per la misurazione di correnti presenti sugli elettrodi in celle elettrolitiche interconnesse. |
| WO2015029367A1 (ja) * | 2013-08-30 | 2015-03-05 | Ｊｘ日鉱日石エネルギー株式会社 | 電気化学還元装置 |
| US10415146B2 (en) * | 2014-10-21 | 2019-09-17 | Evoqua Water Technologies Llc | Electrode with two layer coating, method of use, and preparation thereof |
| US10407784B2 (en) * | 2015-06-23 | 2019-09-10 | Industrie De Nora S.P.A. | Electrode for electrolytic processes |
| AU2016363676B2 (en) | 2015-11-30 | 2022-08-18 | Newsouth Innovations Pty Limited | Method for improving catalytic activity |
| CN106676618A (zh) * | 2017-03-22 | 2017-05-17 | 苏州市汉宜化学有限公司 | 一种改良的枪色电镀网状阳极 |
| KR102403412B1 (ko) * | 2019-09-06 | 2022-05-31 | 한국재료연구원 | 입체 나노시트 구조를 갖는 촉매를 포함하는 수전해전극, 그 제조방법 및 그를 포함하는 수전해장치 |
| CN112921354B (zh) * | 2021-01-25 | 2022-07-01 | 深圳市飞猫电器有限公司 | 一种阳极及其制备方法和应用、臭氧发生系统和食品净化器 |
| CN114272920B (zh) * | 2021-11-22 | 2023-10-03 | 广东省科学院资源利用与稀土开发研究所 | 一种有机污染物降解用复合氧化物涂层电极及其制备方法 |
| CN114645295B (zh) * | 2022-03-31 | 2023-06-02 | 华南理工大学 | 一种用于电解水的阳极催化剂的制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2291887A (en) * | 1994-07-29 | 1996-02-07 | Permelec Electrode Ltd | Use of insoluble electrode comprising an iridium oxide-containing coating as anode in electrolytic reduction of a disulphide compound |
| WO2003100135A2 (en) * | 2002-05-24 | 2003-12-04 | De Nora Elettrodi S.P.A. | Electrode for gas evolution and method for its production |
| US20080116064A1 (en) * | 2006-05-09 | 2008-05-22 | Daiki Ataka Engineering Co., Ltd. | Oxygen evolution electrode |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0774470B2 (ja) * | 1990-03-20 | 1995-08-09 | ダイソー株式会社 | 酸素発生用陽極の製法 |
| JP3212327B2 (ja) * | 1991-08-30 | 2001-09-25 | ペルメレック電極株式会社 | 電解用電極 |
| NL9101753A (nl) * | 1991-10-21 | 1993-05-17 | Magneto Chemie Bv | Anodes met verlengde levensduur en werkwijzen voor hun vervaardiging. |
| JP3507278B2 (ja) * | 1997-06-03 | 2004-03-15 | ペルメレック電極株式会社 | 電気めっき方法 |
| IT1294749B1 (it) * | 1997-09-17 | 1999-04-12 | Nora De | Anodo per evoluzione di ossigeno in elettroliti contenenti manganese e fluoruri |
| IT1302581B1 (it) | 1998-10-01 | 2000-09-29 | Nora De | Anodo con migliorato rivestimento per la reazione di evoluzione diossigeno in elettroliti contenenti manganese. |
| ITMI20031543A1 (it) | 2003-07-28 | 2005-01-29 | De Nora Elettrodi Spa | Elettrodo per processi elettrochimici e metodo per il suo ottenimento |
| ITMI20041006A1 (it) * | 2004-05-20 | 2004-08-20 | De Nora Elettrodi Spa | Anodo per sviluppo ossigeno |
| JP4961825B2 (ja) * | 2006-05-09 | 2012-06-27 | アタカ大機株式会社 | 電気化学反応用陽極 |
| CN1995464A (zh) * | 2006-11-28 | 2007-07-11 | 北京科技大学 | 一种纳米晶铱系氧化物涂层电极制备方法 |
| IT1391767B1 (it) * | 2008-11-12 | 2012-01-27 | Industrie De Nora Spa | Elettrodo per cella elettrolitica |
-
2011
- 2011-06-22 IT IT001132A patent/ITMI20111132A1/it unknown
-
2012
- 2012-04-27 TW TW101115023A patent/TWI550136B/zh active
- 2012-06-22 IN IN250DEN2014 patent/IN2014DN00250A/en unknown
- 2012-06-22 CN CN201280029073.2A patent/CN103597124B/zh active Active
- 2012-06-22 EP EP12731378.1A patent/EP2723918B1/en active Active
- 2012-06-22 BR BR112013029743-3A patent/BR112013029743B1/pt active IP Right Grant
- 2012-06-22 EA EA201301175A patent/EA024916B1/ru not_active IP Right Cessation
- 2012-06-22 AR ARP120102246A patent/AR086725A1/es active IP Right Grant
- 2012-06-22 US US14/116,882 patent/US11001935B2/en active Active
- 2012-06-22 AU AU2012274018A patent/AU2012274018B2/en active Active
- 2012-06-22 PE PE2013002521A patent/PE20140885A1/es active IP Right Grant
- 2012-06-22 MX MX2013013412A patent/MX350803B/es active IP Right Grant
- 2012-06-22 AP AP2013007339A patent/AP2013007339A0/xx unknown
- 2012-06-22 KR KR1020137031371A patent/KR101894706B1/ko active Active
- 2012-06-22 WO PCT/EP2012/062088 patent/WO2012175673A1/en not_active Ceased
- 2012-06-22 ES ES12731378.1T patent/ES2558179T3/es active Active
- 2012-06-22 PL PL12731378T patent/PL2723918T3/pl unknown
- 2012-06-22 JP JP2014516365A patent/JP5932028B2/ja active Active
- 2012-06-22 CA CA2835233A patent/CA2835233C/en active Active
-
2013
- 2013-11-13 ZA ZA2013/08554A patent/ZA201308554B/en unknown
- 2013-11-19 CL CL2013003326A patent/CL2013003326A1/es unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2291887A (en) * | 1994-07-29 | 1996-02-07 | Permelec Electrode Ltd | Use of insoluble electrode comprising an iridium oxide-containing coating as anode in electrolytic reduction of a disulphide compound |
| WO2003100135A2 (en) * | 2002-05-24 | 2003-12-04 | De Nora Elettrodi S.P.A. | Electrode for gas evolution and method for its production |
| US20080116064A1 (en) * | 2006-05-09 | 2008-05-22 | Daiki Ataka Engineering Co., Ltd. | Oxygen evolution electrode |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2723918A1 (en) | 2014-04-30 |
| CA2835233C (en) | 2019-11-12 |
| ES2558179T3 (es) | 2016-02-02 |
| JP5932028B2 (ja) | 2016-06-08 |
| BR112013029743B1 (pt) | 2020-07-07 |
| AR086725A1 (es) | 2014-01-15 |
| MX2013013412A (es) | 2013-12-12 |
| AP2013007339A0 (en) | 2013-12-31 |
| KR101894706B1 (ko) | 2018-10-24 |
| JP2014517158A (ja) | 2014-07-17 |
| ZA201308554B (en) | 2015-02-25 |
| AU2012274018A1 (en) | 2014-01-09 |
| CN103597124B (zh) | 2016-08-17 |
| EA201301175A1 (ru) | 2014-04-30 |
| US11001935B2 (en) | 2021-05-11 |
| PE20140885A1 (es) | 2014-08-22 |
| BR112013029743A2 (pt) | 2017-01-17 |
| PL2723918T3 (pl) | 2016-06-30 |
| TWI550136B (zh) | 2016-09-21 |
| ITMI20111132A1 (it) | 2012-12-23 |
| TW201300576A (zh) | 2013-01-01 |
| US20140311915A1 (en) | 2014-10-23 |
| MX350803B (es) | 2017-09-25 |
| CA2835233A1 (en) | 2012-12-27 |
| CL2013003326A1 (es) | 2014-05-09 |
| WO2012175673A1 (en) | 2012-12-27 |
| CN103597124A (zh) | 2014-02-19 |
| EP2723918B1 (en) | 2015-12-09 |
| IN2014DN00250A (https=) | 2015-06-05 |
| AU2012274018B2 (en) | 2017-03-09 |
| KR20140021673A (ko) | 2014-02-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG TJ TM |