TWI471391B - 用於環氧樹脂系統之不含鹵素阻燃劑 - Google Patents
用於環氧樹脂系統之不含鹵素阻燃劑 Download PDFInfo
- Publication number
- TWI471391B TWI471391B TW98141391A TW98141391A TWI471391B TW I471391 B TWI471391 B TW I471391B TW 98141391 A TW98141391 A TW 98141391A TW 98141391 A TW98141391 A TW 98141391A TW I471391 B TWI471391 B TW I471391B
- Authority
- TW
- Taiwan
- Prior art keywords
- phosphate
- flame retardant
- coating composition
- epoxy resin
- group
- Prior art date
Links
- 239000003063 flame retardant Substances 0.000 title claims description 49
- 239000003822 epoxy resin Substances 0.000 title claims description 29
- 229920000647 polyepoxide Polymers 0.000 title claims description 29
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 title 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 41
- 150000003839 salts Chemical class 0.000 claims description 24
- 229910019142 PO4 Inorganic materials 0.000 claims description 22
- 239000010452 phosphate Substances 0.000 claims description 21
- 239000008199 coating composition Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 19
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 150000001768 cations Chemical class 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- -1 saccharide phosphate Chemical class 0.000 claims description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 7
- 239000004698 Polyethylene Substances 0.000 claims description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 6
- 150000001720 carbohydrates Chemical class 0.000 claims description 5
- 229920001187 thermosetting polymer Polymers 0.000 claims description 5
- 150000001719 carbohydrate derivatives Chemical class 0.000 claims description 4
- 150000002772 monosaccharides Chemical class 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000001736 Calcium glycerylphosphate Substances 0.000 claims description 3
- HXXFSFRBOHSIMQ-VFUOTHLCSA-N alpha-D-glucose 1-phosphate Chemical compound OC[C@H]1O[C@H](OP(O)(O)=O)[C@H](O)[C@@H](O)[C@@H]1O HXXFSFRBOHSIMQ-VFUOTHLCSA-N 0.000 claims description 3
- UHHRFSOMMCWGSO-UHFFFAOYSA-L calcium glycerophosphate Chemical compound [Ca+2].OCC(CO)OP([O-])([O-])=O UHHRFSOMMCWGSO-UHFFFAOYSA-L 0.000 claims description 3
- 229940095618 calcium glycerophosphate Drugs 0.000 claims description 3
- 235000019299 calcium glycerylphosphate Nutrition 0.000 claims description 3
- 235000001130 magnesium glycerophosphate Nutrition 0.000 claims description 3
- 239000011742 magnesium glycerophosphate Substances 0.000 claims description 3
- BHJKUVVFSKEBEX-UHFFFAOYSA-L magnesium;2,3-dihydroxypropyl phosphate Chemical compound [Mg+2].OCC(O)COP([O-])([O-])=O BHJKUVVFSKEBEX-UHFFFAOYSA-L 0.000 claims description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- 239000008103 glucose Substances 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000011572 manganese Substances 0.000 claims description 2
- 235000019830 sodium polyphosphate Nutrition 0.000 claims description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 claims 2
- 239000002552 dosage form Substances 0.000 claims 1
- AWUCVROLDVIAJX-UHFFFAOYSA-N glycerol 1-phosphate Chemical class OCC(O)COP(O)(O)=O AWUCVROLDVIAJX-UHFFFAOYSA-N 0.000 claims 1
- NJTGANWAUPEOAX-UHFFFAOYSA-N molport-023-220-454 Chemical compound OCC(O)CO.OCC(O)CO NJTGANWAUPEOAX-UHFFFAOYSA-N 0.000 claims 1
- 150000004712 monophosphates Chemical class 0.000 claims 1
- OQZCJRJRGMMSGK-UHFFFAOYSA-M potassium metaphosphate Chemical compound [K+].[O-]P(=O)=O OQZCJRJRGMMSGK-UHFFFAOYSA-M 0.000 claims 1
- 235000019828 potassium polyphosphate Nutrition 0.000 claims 1
- 229920005989 resin Polymers 0.000 description 19
- 239000011347 resin Substances 0.000 description 19
- 235000021317 phosphate Nutrition 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 235000000346 sugar Nutrition 0.000 description 10
- 239000002253 acid Substances 0.000 description 7
- 229920000388 Polyphosphate Polymers 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 239000001205 polyphosphate Substances 0.000 description 5
- 235000011176 polyphosphates Nutrition 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- XYZZKVRWGOWVGO-UHFFFAOYSA-N Glycerol-phosphate Chemical compound OP(O)(O)=O.OCC(O)CO XYZZKVRWGOWVGO-UHFFFAOYSA-N 0.000 description 3
- 208000007976 Ketosis Diseases 0.000 description 3
- 150000001323 aldoses Chemical class 0.000 description 3
- 235000021474 generally recognized As safe (food) Nutrition 0.000 description 3
- 235000021473 generally recognized as safe (food ingredients) Nutrition 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 235000011009 potassium phosphates Nutrition 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000002009 diols Chemical class 0.000 description 2
- 150000002016 disaccharides Chemical class 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 150000002337 glycosamines Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 150000002584 ketoses Chemical class 0.000 description 2
- 230000036284 oxygen consumption Effects 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
- 235000019983 sodium metaphosphate Nutrition 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 150000005846 sugar alcohols Chemical class 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- SERLAGPUMNYUCK-DCUALPFSSA-N 1-O-alpha-D-glucopyranosyl-D-mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O SERLAGPUMNYUCK-DCUALPFSSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- GZCGUPFRVQAUEE-UHFFFAOYSA-N 2,3,4,5,6-pentahydroxyhexanal Chemical compound OCC(O)C(O)C(O)C(O)C=O GZCGUPFRVQAUEE-UHFFFAOYSA-N 0.000 description 1
- CQQGLXZHXDHSJD-UHFFFAOYSA-L 2,3-dihydroxypropyl phosphate;manganese(2+) Chemical compound [Mn+2].OCC(O)COP([O-])([O-])=O CQQGLXZHXDHSJD-UHFFFAOYSA-L 0.000 description 1
- MSWZFWKMSRAUBD-IVMDWMLBSA-N 2-amino-2-deoxy-D-glucopyranose Chemical compound N[C@H]1C(O)O[C@H](CO)[C@@H](O)[C@@H]1O MSWZFWKMSRAUBD-IVMDWMLBSA-N 0.000 description 1
- JNMKPXXKHWQWFB-UHFFFAOYSA-L 2-aminoacetate;manganese(2+) Chemical compound [Mn+2].NCC([O-])=O.NCC([O-])=O JNMKPXXKHWQWFB-UHFFFAOYSA-L 0.000 description 1
- AEMOLEFTQBMNLQ-UHFFFAOYSA-N 3,4,5,6-tetrahydroxyoxane-2-carboxylic acid Chemical compound OC1OC(C(O)=O)C(O)C(O)C1O AEMOLEFTQBMNLQ-UHFFFAOYSA-N 0.000 description 1
- 241000220479 Acacia Species 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 229920000945 Amylopectin Polymers 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- 229940122361 Bisphosphonate Drugs 0.000 description 1
- YDNKGFDKKRUKPY-JHOUSYSJSA-N C16 ceramide Natural products CCCCCCCCCCCCCCCC(=O)N[C@@H](CO)[C@H](O)C=CCCCCCCCCCCCCC YDNKGFDKKRUKPY-JHOUSYSJSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- WQZGKKKJIJFFOK-CBPJZXOFSA-N D-Gulose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@H](O)[C@H]1O WQZGKKKJIJFFOK-CBPJZXOFSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- WQZGKKKJIJFFOK-WHZQZERISA-N D-aldose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-WHZQZERISA-N 0.000 description 1
- LKDRXBCSQODPBY-JDJSBBGDSA-N D-allulose Chemical compound OCC1(O)OC[C@@H](O)[C@@H](O)[C@H]1O LKDRXBCSQODPBY-JDJSBBGDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- AEMOLEFTQBMNLQ-AQKNRBDQSA-N D-glucopyranuronic acid Chemical compound OC1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-AQKNRBDQSA-N 0.000 description 1
- FBPFZTCFMRRESA-ZXXMMSQZSA-N D-iditol Chemical compound OC[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-ZXXMMSQZSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- HMFHBZSHGGEWLO-SOOFDHNKSA-N D-ribofuranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H]1O HMFHBZSHGGEWLO-SOOFDHNKSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-NQXXGFSBSA-N D-ribulose Chemical compound OC[C@@H](O)[C@@H](O)C(=O)CO ZAQJHHRNXZUBTE-NQXXGFSBSA-N 0.000 description 1
- UNXHWFMMPAWVPI-QWWZWVQMSA-N D-threitol Chemical compound OC[C@@H](O)[C@H](O)CO UNXHWFMMPAWVPI-QWWZWVQMSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-UHFFFAOYSA-N D-threo-2-Pentulose Natural products OCC(O)C(O)C(=O)CO ZAQJHHRNXZUBTE-UHFFFAOYSA-N 0.000 description 1
- ZAQJHHRNXZUBTE-WUJLRWPWSA-N D-xylulose Chemical compound OC[C@@H](O)[C@H](O)C(=O)CO ZAQJHHRNXZUBTE-WUJLRWPWSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- 241001427367 Gardena Species 0.000 description 1
- 229920002527 Glycogen Polymers 0.000 description 1
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VSOAQEOCSA-N L-altropyranose Chemical compound OC[C@@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-VSOAQEOCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 235000010643 Leucaena leucocephala Nutrition 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical group OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
- CRJGESKKUOMBCT-VQTJNVASSA-N N-acetylsphinganine Chemical compound CCCCCCCCCCCCCCC[C@@H](O)[C@H](CO)NC(C)=O CRJGESKKUOMBCT-VQTJNVASSA-N 0.000 description 1
- PYMYPHUHKUWMLA-LMVFSUKVSA-N Ribose Natural products OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 150000001320 aldopentoses Chemical class 0.000 description 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
- RNBGYGVWRKECFJ-ZXXMMSQZSA-N alpha-D-fructofuranose 1,6-bisphosphate Chemical group O[C@H]1[C@H](O)[C@](O)(COP(O)(O)=O)O[C@@H]1COP(O)(O)=O RNBGYGVWRKECFJ-ZXXMMSQZSA-N 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- SQVRNKJHWKZAKO-UHFFFAOYSA-N beta-N-Acetyl-D-neuraminic acid Natural products CC(=O)NC1C(O)CC(O)(C(O)=O)OC1C(O)C(O)CO SQVRNKJHWKZAKO-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004663 bisphosphonates Chemical class 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229940106189 ceramide Drugs 0.000 description 1
- ZVEQCJWYRWKARO-UHFFFAOYSA-N ceramide Natural products CCCCCCCCCCCCCCC(O)C(=O)NC(CO)C(O)C=CCCC=C(C)CCCCCCCCC ZVEQCJWYRWKARO-UHFFFAOYSA-N 0.000 description 1
- 238000004786 cone calorimetry Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229940025237 fructose 1,6-diphosphate Drugs 0.000 description 1
- FBPFZTCFMRRESA-GUCUJZIJSA-N galactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-GUCUJZIJSA-N 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229960002442 glucosamine Drugs 0.000 description 1
- 229940097043 glucuronic acid Drugs 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 229940096919 glycogen Drugs 0.000 description 1
- 150000002402 hexoses Chemical class 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 150000002454 idoses Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000000905 isomalt Substances 0.000 description 1
- 235000010439 isomalt Nutrition 0.000 description 1
- HPIGCVXMBGOWTF-UHFFFAOYSA-N isomaltol Natural products CC(=O)C=1OC=CC=1O HPIGCVXMBGOWTF-UHFFFAOYSA-N 0.000 description 1
- BJHIKXHVCXFQLS-PQLUHFTBSA-N keto-D-tagatose Chemical compound OC[C@@H](O)[C@H](O)[C@H](O)C(=O)CO BJHIKXHVCXFQLS-PQLUHFTBSA-N 0.000 description 1
- 150000002581 ketopentoses Chemical class 0.000 description 1
- 239000000832 lactitol Substances 0.000 description 1
- 235000010448 lactitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-JVCRWLNRSA-N lactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-JVCRWLNRSA-N 0.000 description 1
- 229960003451 lactitol Drugs 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- VVGIYYKRAMHVLU-UHFFFAOYSA-N newbouldiamide Natural products CCCCCCCCCCCCCCCCCCCC(O)C(O)C(O)C(CO)NC(=O)CCCCCCCCCCCCCCCCC VVGIYYKRAMHVLU-UHFFFAOYSA-N 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- ATGAWOHQWWULNK-UHFFFAOYSA-I pentapotassium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [K+].[K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ATGAWOHQWWULNK-UHFFFAOYSA-I 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- SQVRNKJHWKZAKO-OQPLDHBCSA-N sialic acid Chemical compound CC(=O)N[C@@H]1[C@@H](O)C[C@@](O)(C(O)=O)OC1[C@H](O)[C@H](O)CO SQVRNKJHWKZAKO-OQPLDHBCSA-N 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- BWAUQTFFVCLSOS-UHFFFAOYSA-N sodiosodium hydrate Chemical compound O.[Na].[Na] BWAUQTFFVCLSOS-UHFFFAOYSA-N 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12052308P | 2008-12-08 | 2008-12-08 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201033303A TW201033303A (en) | 2010-09-16 |
| TWI471391B true TWI471391B (zh) | 2015-02-01 |
Family
ID=41786466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW98141391A TWI471391B (zh) | 2008-12-08 | 2009-12-03 | 用於環氧樹脂系統之不含鹵素阻燃劑 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8710122B2 (OSRAM) |
| EP (1) | EP2358805B1 (OSRAM) |
| JP (1) | JP5769629B2 (OSRAM) |
| KR (1) | KR101699988B1 (OSRAM) |
| CN (1) | CN102300916B (OSRAM) |
| BR (1) | BRPI0922176A2 (OSRAM) |
| CA (1) | CA2745245A1 (OSRAM) |
| MX (1) | MX2011005592A (OSRAM) |
| RU (1) | RU2488615C2 (OSRAM) |
| TW (1) | TWI471391B (OSRAM) |
| WO (1) | WO2010077493A1 (OSRAM) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105531038B (zh) * | 2013-07-31 | 2018-06-26 | 英派尔科技开发有限公司 | 耐火印刷电路板组件 |
| WO2015148314A1 (en) * | 2014-03-25 | 2015-10-01 | 3M Innovative Properties Company | Flame retardant, pressure-sensitive adhesive, and curable composition |
| RU2616943C1 (ru) * | 2016-04-22 | 2017-04-18 | К5 Лтд | Автономное средство пожаротушения |
| RU2630530C1 (ru) * | 2016-04-22 | 2017-09-11 | К5 Лтд | Комбинированный газовый огнетушащий состав |
| RU2628375C1 (ru) * | 2016-04-22 | 2017-08-16 | К5 Лтд | Микрокапсулированный огнетушащий агент и способ его получения |
| CN106189850A (zh) * | 2016-08-24 | 2016-12-07 | 安徽徽明建设集团有限公司 | 一种防水保温屋顶涂料 |
| US10421910B2 (en) | 2017-08-16 | 2019-09-24 | International Business Machines Corporation | Sorbitol, glucaric acid, and gluconic acid based flame-retardants |
| US10611897B2 (en) * | 2017-11-07 | 2020-04-07 | International Business Machines Corporation | Arabitol and xylitol based flame retardants |
| US10597584B2 (en) * | 2017-11-08 | 2020-03-24 | International Business Machines Corporation | Levoglucosan-based flame retardant compounds |
| CN108467654A (zh) * | 2018-04-24 | 2018-08-31 | 常州五荣化工有限公司 | 一种建筑用防火涂料 |
| JP7121149B2 (ja) * | 2019-02-15 | 2022-08-17 | 島田 誠之 | コーティング剤、薄膜、薄膜付き基材、および薄膜の製造方法 |
| WO2020247780A1 (en) * | 2019-06-07 | 2020-12-10 | Frs Group, Llc | Long-term fire retardant with an organophosphate and methods for making and using same |
| WO2020247775A2 (en) | 2019-06-07 | 2020-12-10 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| US11958938B2 (en) * | 2020-04-28 | 2024-04-16 | 3M Innovative Properties Company | Curable composition |
| KR20210158504A (ko) * | 2020-06-24 | 2021-12-31 | 공석태 | Frp 난연첨가제 |
| CA3200497A1 (en) | 2020-12-15 | 2022-06-23 | Dennis Hulbert | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
| SE2151389A1 (en) * | 2021-11-15 | 2023-05-16 | Larsson Anna Carin | Flame retardant composition |
| US11975231B2 (en) | 2022-03-31 | 2024-05-07 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
| WO2025181577A1 (en) * | 2024-02-29 | 2025-09-04 | 3M Innovative Properties Company | Curable adhesive composition comprising epoxy, initiator and metal compound, articles and methods |
| CN119390723B (zh) * | 2024-12-31 | 2025-08-26 | 安徽艾立德制药有限公司 | 一种甘油磷酸镁的无定型物及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09310070A (ja) * | 1996-05-20 | 1997-12-02 | Shigenobu Sakata | 不燃・難燃液とその製造法 |
| US20040099178A1 (en) * | 2000-11-01 | 2004-05-27 | Jones William H. | Novel fire retardant materials and method for producing same |
| TW200732448A (en) * | 2006-02-23 | 2007-09-01 | Pont Taiwan Ltd Du | Non-halogen adhesive containing polyphosphate compounds |
Family Cites Families (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE661824A (OSRAM) | 1964-03-31 | |||
| US3811992A (en) * | 1966-01-14 | 1974-05-21 | Adachi Plywood Co Ltd | Fire-proof laminated plywood core |
| US3819518A (en) | 1972-07-31 | 1974-06-25 | Apex Chem Co Inc | Scorch-resistant water-soluble flame-retardants for cellulose |
| US3973074A (en) | 1973-02-20 | 1976-08-03 | Macmillan Bloedel Limited | Flame-proof cellulosic product |
| AR206903A1 (es) | 1973-11-12 | 1976-08-31 | Stauffer Chemical Co | Producto de copolicondensacion de un tris-beta-haloalquilfosfato y un dialquil fosfonato util como agente retardador del fuego |
| US4311634A (en) | 1974-09-27 | 1982-01-19 | E. I. Du Pont De Nemours And Company | Heat stable polymer coating composition with antioxidant |
| US4122226A (en) | 1974-09-27 | 1978-10-24 | E. I. Du Pont De Nemours And Company | Heat-stable polymer coating composition with oxidation catalyst |
| US4165411A (en) | 1975-06-18 | 1979-08-21 | W. R. Grace & Co. | Flame retardant urethane and method |
| US4199534A (en) | 1978-04-20 | 1980-04-22 | Stauffer Chemical Company | Poly (oxyorganophosphate/phosphonate) and process for preparing |
| JPS54141823A (en) * | 1978-04-26 | 1979-11-05 | Hitachi Cable Ltd | Fire resistant coating composition |
| JPS57123221A (en) * | 1981-01-23 | 1982-07-31 | Okura Ind Co Ltd | Metal-containing curable resin composition containing ionic bond |
| DE3628560A1 (de) * | 1986-08-22 | 1988-03-03 | Basf Ag | Polyoximethylen-formmassen mit verbesserter thermischer stabilitaet, verfahren zu deren herstellung und deren verwendung |
| US5091608A (en) * | 1988-07-27 | 1992-02-25 | Minnesota Mining And Manufacturing Company | Flame retardant splicing system |
| JPH02172847A (ja) * | 1988-12-23 | 1990-07-04 | Shinto Paint Co Ltd | 膨張型耐火被覆組成物 |
| JPH03119017A (ja) | 1989-09-29 | 1991-05-21 | Hitachi Chem Co Ltd | 発泡用樹脂組成物，発泡体および構造体 |
| JPH0728994A (ja) | 1992-06-13 | 1995-01-31 | Kanebo Ltd | 濃度階調補正装置 |
| US5268393A (en) * | 1992-07-17 | 1993-12-07 | Blount David H | Flame-retardant polyurethane foam produced without additional blowing agents |
| JPH0728994U (ja) * | 1993-10-22 | 1995-05-30 | 桂助 上野 | 無機フアイバーマット |
| US5656709A (en) * | 1994-05-24 | 1997-08-12 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Hybrid material and process for producing the same |
| US5587448A (en) * | 1994-12-29 | 1996-12-24 | Minnesota Mining And Manufacturing | Reaction system for producing a polyurethane and method of using same to seal a surface |
| EP0742261B1 (en) | 1995-04-10 | 2000-08-02 | Shin-Etsu Chemical Co., Ltd. | Semiconductor encapsulating epoxy resin compositions suitable for semiconductor encapsulation, their manufacture and use, semiconductor devices encapsulated therewith |
| US5723515A (en) | 1995-12-29 | 1998-03-03 | No Fire Technologies, Inc. | Intumescent fire-retardant composition for high temperature and long duration protection |
| JPH1017796A (ja) | 1996-07-05 | 1998-01-20 | Dainippon Toryo Co Ltd | 発泡型耐火被覆剤 |
| US6362279B2 (en) | 1996-09-27 | 2002-03-26 | The United States Of America As Represented By The Secretary Of The Air Force | Preceramic additives as fire retardants for plastics |
| US6001270A (en) * | 1998-03-16 | 1999-12-14 | The United States Of America As Represented By The Secretary Of The Army | Sticky high water content gels for extinguishers |
| US6171702B1 (en) * | 1998-07-17 | 2001-01-09 | Xerox Corporation | Coated substrates |
| JP3461125B2 (ja) | 1998-08-18 | 2003-10-27 | 出光石油化学株式会社 | 難燃性ポリカーボネート樹脂組成物及びブロー成形品 |
| JP2002057442A (ja) | 2000-05-30 | 2002-02-22 | Fujikura Ltd | フレキシブルプリント基板の絶縁構造及び製造方法 |
| US6551417B1 (en) * | 2000-09-20 | 2003-04-22 | Ge Betz, Inc. | Tri-cation zinc phosphate conversion coating and process of making the same |
| US6518357B1 (en) | 2000-10-04 | 2003-02-11 | General Electric Company | Flame retardant polycarbonate-silsesquioxane compositions, method for making and articles made thereby |
| JP2002201344A (ja) | 2000-11-06 | 2002-07-19 | Toray Ind Inc | 液晶性樹脂組成物、その製造方法および成形品 |
| US20030166765A1 (en) | 2000-11-17 | 2003-09-04 | Shinichi Sugihara | Coating responding to a visible light, coating film and article |
| KR100425376B1 (ko) | 2001-10-29 | 2004-03-30 | 국도화학 주식회사 | 인 및 실리콘 변성 난연성 에폭시수지 |
| GB0216356D0 (en) | 2002-07-13 | 2002-08-21 | Chance & Hunt Ltd | Flame retardant product |
| DE10244578A1 (de) * | 2002-09-25 | 2004-04-08 | Clariant Gmbh | Flammwidrige duroplastische Massen |
| KR100484175B1 (ko) * | 2002-11-08 | 2005-04-18 | 삼성전자주식회사 | 고효율 플라즈마 디스플레이 패널 구동 장치 및 방법 |
| JP2005097352A (ja) * | 2003-09-22 | 2005-04-14 | Dainippon Ink & Chem Inc | エポキシ樹脂組成物、半導体封止材料及び半導体装置 |
| US6982049B1 (en) | 2003-12-03 | 2006-01-03 | No-Burn Investments, L.L.C. | Fire retardant with mold inhibitor |
| JP2005236273A (ja) | 2004-01-20 | 2005-09-02 | Showa Denko Kk | ソルダーレジスト用難燃組成物、その硬化方法及び用途 |
| PL1716201T3 (pl) | 2004-02-18 | 2017-08-31 | Huntsman Advanced Materials Licensing (Switzerland) Gmbh | Kompozycja obniżająca palność z zastosowaniem siloksanów |
| ITMI20040588A1 (it) | 2004-03-25 | 2004-06-25 | Walter Navarrini | Composizioni per materiali porosi |
| US20050215670A1 (en) * | 2004-03-29 | 2005-09-29 | Akihiko Shimasaki | Coating composition and article coated therewith |
| US20050236606A1 (en) | 2004-04-26 | 2005-10-27 | Certainteed Corporation | Flame resistant fibrous insulation and methods of making the same |
| US7700680B2 (en) | 2004-06-10 | 2010-04-20 | Italmatch Chemicals S.P.A. | Polyester compositions flame retarded with halogen-free additives |
| US7820079B2 (en) * | 2004-06-14 | 2010-10-26 | Nissin Chemical Industry Co., Ltd. | Vehicle interior material coating composition and vehicle interior material |
| US20070244229A1 (en) | 2004-06-17 | 2007-10-18 | Hong Sang H | Flameproof Thermoplastic Resin Composition |
| US20050287362A1 (en) | 2004-06-23 | 2005-12-29 | 3M Innovative Properties Company | Halogen free tapes & method of making same |
| WO2006022219A1 (ja) | 2004-08-25 | 2006-03-02 | Kawashima Selkon Textiles Co., Ltd. | ポリリン酸系難燃剤 |
| JP4984451B2 (ja) * | 2005-07-20 | 2012-07-25 | Ｄｉｃ株式会社 | エポキシ樹脂組成物及びその硬化物 |
| EP1945724A2 (en) * | 2005-11-08 | 2008-07-23 | Laxmi C. Gupta | Methods for applying fire retardant systems, compositions and uses |
| US8197338B2 (en) | 2006-02-24 | 2012-06-12 | Wms Gaming Inc. | Suspending wagering game play on wagering game machines |
| CN100360543C (zh) * | 2006-04-11 | 2008-01-09 | 四川师范大学 | 一种环己五醇磷酸酯胺盐的制备方法 |
| JP2007302762A (ja) | 2006-05-10 | 2007-11-22 | Gun Ei Chem Ind Co Ltd | 発泡用樹脂組成物及びその発泡体 |
| US7405358B2 (en) * | 2006-10-17 | 2008-07-29 | Quick Connectors, Inc | Splice for down hole electrical submersible pump cable |
| US20090104444A1 (en) | 2007-10-19 | 2009-04-23 | 3M Innovative Properties Company | Halogen-free flame retardant adhesive compositions and article containing same |
| US20090124734A1 (en) | 2007-11-05 | 2009-05-14 | 3M Innovative Properties Company | Halogen-free flame retardant resin composition |
| WO2010042422A2 (en) | 2008-10-07 | 2010-04-15 | 3M Innovative Properties Company | Composition, method of making the same, and use thereof |
| US7915436B2 (en) | 2008-11-03 | 2011-03-29 | 3M Innovative Properties Company | Phosphorus-containing silsesquioxane derivatives as flame retardants |
-
2009
- 2009-11-24 MX MX2011005592A patent/MX2011005592A/es active IP Right Grant
- 2009-11-24 WO PCT/US2009/065624 patent/WO2010077493A1/en not_active Ceased
- 2009-11-24 US US13/128,846 patent/US8710122B2/en active Active
- 2009-11-24 KR KR1020117015506A patent/KR101699988B1/ko not_active Expired - Fee Related
- 2009-11-24 RU RU2011120267/05A patent/RU2488615C2/ru not_active IP Right Cessation
- 2009-11-24 CA CA2745245A patent/CA2745245A1/en not_active Abandoned
- 2009-11-24 JP JP2011539590A patent/JP5769629B2/ja not_active Expired - Fee Related
- 2009-11-24 CN CN200980155941.XA patent/CN102300916B/zh not_active Expired - Fee Related
- 2009-11-24 EP EP09795840.9A patent/EP2358805B1/en active Active
- 2009-11-24 BR BRPI0922176A patent/BRPI0922176A2/pt not_active Application Discontinuation
- 2009-12-03 TW TW98141391A patent/TWI471391B/zh not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09310070A (ja) * | 1996-05-20 | 1997-12-02 | Shigenobu Sakata | 不燃・難燃液とその製造法 |
| US20040099178A1 (en) * | 2000-11-01 | 2004-05-27 | Jones William H. | Novel fire retardant materials and method for producing same |
| TW200732448A (en) * | 2006-02-23 | 2007-09-01 | Pont Taiwan Ltd Du | Non-halogen adhesive containing polyphosphate compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201033303A (en) | 2010-09-16 |
| RU2488615C2 (ru) | 2013-07-27 |
| WO2010077493A1 (en) | 2010-07-08 |
| RU2011120267A (ru) | 2012-11-27 |
| KR20110096149A (ko) | 2011-08-29 |
| CN102300916B (zh) | 2014-11-12 |
| JP5769629B2 (ja) | 2015-08-26 |
| CA2745245A1 (en) | 2010-07-08 |
| US8710122B2 (en) | 2014-04-29 |
| MX2011005592A (es) | 2011-06-16 |
| KR101699988B1 (ko) | 2017-01-26 |
| EP2358805B1 (en) | 2016-09-21 |
| BRPI0922176A2 (pt) | 2018-05-22 |
| US20110224331A1 (en) | 2011-09-15 |
| JP2012511083A (ja) | 2012-05-17 |
| EP2358805A1 (en) | 2011-08-24 |
| CN102300916A (zh) | 2011-12-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI471391B (zh) | 用於環氧樹脂系統之不含鹵素阻燃劑 | |
| Deng et al. | Solidifying process and flame retardancy of epoxy resin cured with boron-containing phenolic resin | |
| Gérard et al. | Reaction to fire of an intumescent epoxy resin: Protection mechanisms and synergy | |
| JPS6147875B2 (OSRAM) | ||
| Rong et al. | Synergistic effect of phenyl phosphoric acid derivatives and DOPO on multifunctional epoxy resin: Fire safety, mechanical properties, transparency and hydrophobicity | |
| US20060113513A1 (en) | Fire retardant and a method for production thereof | |
| EP2505607B1 (en) | Thermoplastic ABS resin compositions having flame retardancy | |
| Liu et al. | Low-melting phosphate glasses as flame-retardant synergists to epoxy: Barrier effects vs flame retardancy | |
| US4061605A (en) | Reaction products of benzenephosphonic acid and melamine as flame-retardant additives | |
| TW200524981A (en) | Halogen-free flame-retardant resin composition and prepreg and laminate using the same | |
| CN114591616A (zh) | 一种阻燃聚碳酸酯组合物及其制备方法与应用 | |
| CN101974140B (zh) | 酚醛树脂的制备方法 | |
| US4265806A (en) | Flame retardant thermoplastic synthetic resin | |
| CA1107047A (en) | Chemical retardants for forest fires | |
| CN103333320B (zh) | 一种磷氮协效阻燃柔韧型环氧树脂的合成方法 | |
| Chen et al. | Study on flame retardance of co-microencapsulated ammonium polyphosphate and pentaerythritol in polypropylene | |
| JPS62149752A (ja) | 難燃性ポリマ−組成物 | |
| CN113462020A (zh) | 具有双峰热失重分解特征的基于亚磷酸铝的复合体及其制备和应用 | |
| Olcay et al. | Synergism in nitrogen-and phosphorus-based flame retardants | |
| Brostow et al. | Fire resistance of polymers | |
| RU2726212C1 (ru) | Композиция для получения жесткого пенополиуретана пониженной горючести | |
| CN108124864A (zh) | 一种稳定型复硝酚钠及其制备方法 | |
| JP2007246874A (ja) | 難燃性熱硬化エポキシ樹脂組成物 | |
| JPS6138745B2 (OSRAM) | ||
| CN108485193A (zh) | 一种可用于电子封装材料的阻燃型环氧树脂组合物及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |