TWI465516B - 耐火性之衝擊經改質的聚伸烷基對酞酸酯/聚碳酸酯組成物 - Google Patents
耐火性之衝擊經改質的聚伸烷基對酞酸酯/聚碳酸酯組成物 Download PDFInfo
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- TWI465516B TWI465516B TW097149563A TW97149563A TWI465516B TW I465516 B TWI465516 B TW I465516B TW 097149563 A TW097149563 A TW 097149563A TW 97149563 A TW97149563 A TW 97149563A TW I465516 B TWI465516 B TW I465516B
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- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- VULHYRAYXYTONQ-UHFFFAOYSA-N n-phenylmethanimine Chemical compound C=NC1=CC=CC=C1 VULHYRAYXYTONQ-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical group C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- RUOPINZRYMFPBF-UHFFFAOYSA-N pentane-1,3-diol Chemical compound CCC(O)CCO RUOPINZRYMFPBF-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- NARVIWMVBMUEOG-UHFFFAOYSA-N prop-1-en-2-ol Chemical class CC(O)=C NARVIWMVBMUEOG-UHFFFAOYSA-N 0.000 description 1
- DSNYFFJTZPIKFZ-UHFFFAOYSA-N propoxybenzene Chemical group CCCOC1=CC=CC=C1 DSNYFFJTZPIKFZ-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Polymers OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007061760A DE102007061760A1 (de) | 2007-12-20 | 2007-12-20 | Flammgeschützte schlagzähmodifizierte Polyalkylenterephthalat/Polycarbonat-Zusammensetzungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200946592A TW200946592A (en) | 2009-11-16 |
| TWI465516B true TWI465516B (zh) | 2014-12-21 |
Family
ID=40457020
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW097149563A TWI465516B (zh) | 2007-12-20 | 2008-12-19 | 耐火性之衝擊經改質的聚伸烷基對酞酸酯/聚碳酸酯組成物 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20090215945A1 (OSRAM) |
| EP (1) | EP2225320B1 (OSRAM) |
| JP (1) | JP5485908B2 (OSRAM) |
| KR (1) | KR101530405B1 (OSRAM) |
| CN (1) | CN101945935B (OSRAM) |
| BR (1) | BRPI0821317A2 (OSRAM) |
| CA (1) | CA2709951A1 (OSRAM) |
| DE (1) | DE102007061760A1 (OSRAM) |
| ES (1) | ES2416379T3 (OSRAM) |
| RU (1) | RU2504563C2 (OSRAM) |
| TW (1) | TWI465516B (OSRAM) |
| WO (1) | WO2009080244A1 (OSRAM) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007061758A1 (de) * | 2007-12-20 | 2009-06-25 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
| DE102007061761A1 (de) * | 2007-12-20 | 2009-06-25 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
| DE102007061762A1 (de) * | 2007-12-20 | 2009-06-25 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen |
| US20110159232A1 (en) * | 2009-12-30 | 2011-06-30 | E. I. Du Pont De Nemours And Company | Flame retardant poly(trimethylene terephthalate) compositions |
| DE102010013991A1 (de) | 2010-04-07 | 2011-10-13 | Bayer Materialscience Ag | Flammgeschützte Polycarbonat-Zusammensetzungen |
| CN101942189B (zh) * | 2010-10-25 | 2012-06-27 | 江苏技术师范学院 | 无卤阻燃pc/pbt合金材料及其制备方法 |
| WO2012113145A1 (en) * | 2011-02-24 | 2012-08-30 | Rhodia (China) Co., Ltd. | Flame retardant polymer compositions comprising stabilized hypophosphite salts |
| EP2599822B1 (en) * | 2011-12-02 | 2018-10-31 | Bemis Company, Inc | Packaging sheet with improved cutting properties |
| WO2013087584A1 (de) * | 2011-12-13 | 2013-06-20 | Bayer Intellectual Property Gmbh | Flammgeschützte polyalkylenterephthalat/polycarbonat-zusammensetzungen |
| ES2637641T3 (es) * | 2011-12-29 | 2017-10-16 | Covestro Deutschland Ag | Composiciones poliméricas con adherencia mejorada |
| CN103013081B (zh) * | 2012-12-17 | 2015-12-09 | 上海冠旗电子新材料股份有限公司 | 耐高温耐刮伤无卤阻燃聚碳酸酯薄膜 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4866123A (en) * | 1987-08-27 | 1989-09-12 | Bayer Aktiengesellschaft | Molding compositions of polycarbonate and polyalkylene terephthalate showing improved joint line strength |
Family Cites Families (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2891920A (en) | 1955-01-26 | 1959-06-23 | Dow Corning | Polymerization of organopolysiloxanes in aqueous emulsion |
| DE1007996B (de) | 1955-03-26 | 1957-05-09 | Bayer Ag | Verfahren zur Herstellung thermoplastischer Kunststoffe |
| DE1031512B (de) | 1955-12-21 | 1958-06-04 | Bayer Ag | Verfahren zur Herstellung von hochmolekularen faser- und filmbildenden Polycarbonaten |
| US2991273A (en) | 1956-07-07 | 1961-07-04 | Bayer Ag | Process for manufacture of vacuum moulded parts of high molecular weight thermoplastic polycarbonates |
| US3148172A (en) | 1956-07-19 | 1964-09-08 | Gen Electric | Polycarbonates of dihydroxyaryl ethers |
| US2999846A (en) | 1956-11-30 | 1961-09-12 | Schnell Hermann | High molecular weight thermoplastic aromatic sulfoxy polycarbonates |
| US3062781A (en) | 1958-07-02 | 1962-11-06 | Bayer Ag | Process for the production of polycarbonates |
| US2999835A (en) | 1959-01-02 | 1961-09-12 | Gen Electric | Resinous mixture comprising organo-polysiloxane and polymer of a carbonate of a dihydric phenol, and products containing same |
| US3028635A (en) | 1959-04-17 | 1962-04-10 | Schlumberger Cie N | Advancing screw for gill box |
| US3288864A (en) | 1962-05-11 | 1966-11-29 | Union Carbide Corp | Reaction products of isopropenyl phenols and of linear dimers thereof |
| GB1024024A (en) | 1963-04-08 | 1966-03-30 | Dow Corning | Improvements in or relating to polymerising or co-polymerising organosilicon compounds |
| GB1122003A (en) | 1964-10-07 | 1968-07-31 | Gen Electric | Improvements in aromatic polycarbonates |
| US3442864A (en) | 1965-06-30 | 1969-05-06 | Diamond Alkali Co | Formals of norbornane-2,7-diols and copolymers thereof with trioxane |
| NL152889B (nl) | 1967-03-10 | 1977-04-15 | Gen Electric | Werkwijze ter bereiding van een lineair polycarbonaatcopolymeer, alsmede orienteerbare textielvezel van dit copolymeer. |
| FR1580834A (OSRAM) | 1968-01-04 | 1969-09-12 | ||
| US3644574A (en) | 1969-07-17 | 1972-02-22 | Eastman Kodak Co | Shaped articles of blends of polyesters and polyvinyls |
| DE2036052A1 (en) | 1970-07-21 | 1972-01-27 | Milchwirtschafthche Forschungs und Untersuchungs Gesellschaft mbH, 2100 Hamburg | Working up of additives in fat and protein - contng foodstuffs |
| DE2063050C3 (de) | 1970-12-22 | 1983-12-15 | Bayer Ag, 5090 Leverkusen | Verseifungsbeständige Polycarbonate, Verfahren zu deren Herstellung und deren Verwendung |
| US4013613A (en) | 1971-10-01 | 1977-03-22 | General Electric Company | Reinforced intercrystalline thermoplastic polyester compositions |
| DE2211956A1 (de) | 1972-03-11 | 1973-10-25 | Bayer Ag | Verfahren zur herstellung verseifungsstabiler blockcopolycarbonate |
| JPS5039599B2 (OSRAM) | 1973-03-30 | 1975-12-18 | ||
| JPS5437632B2 (OSRAM) * | 1973-10-19 | 1979-11-16 | ||
| DE2407776A1 (de) | 1974-02-19 | 1975-09-04 | Licentia Gmbh | Schaltung zur regelung der betriebsspannung fuer die transistor-zeilenendstufe eines fernsehempfaengers |
| DE2715932A1 (de) | 1977-04-09 | 1978-10-19 | Bayer Ag | Schnellkristallisierende poly(aethylen/alkylen)-terephthalate |
| US4334106A (en) | 1981-02-05 | 1982-06-08 | The Upjohn Company | Process for the preparation of hydroxyphenyl-indanols |
| JPS6035150A (ja) | 1983-08-05 | 1985-02-22 | Aisan Ind Co Ltd | エンジンのアイドル回転数制御方法 |
| JPS6162039A (ja) | 1984-09-04 | 1986-03-29 | Fuji Xerox Co Ltd | 電子写真用感光体 |
| JPS6162040A (ja) | 1984-09-04 | 1986-03-29 | Fuji Xerox Co Ltd | 電子写真用感光体 |
| JPS61105550A (ja) | 1984-10-29 | 1986-05-23 | Fuji Xerox Co Ltd | 電子写真用感光体 |
| US4686256A (en) * | 1985-12-17 | 1987-08-11 | General Electric Company | Thermoplastically moldable compositions |
| DE3631540A1 (de) | 1986-09-17 | 1988-03-24 | Bayer Ag | Thermoplastische formmassen mit hoher alterungsbestaendigkeit und guter tieftemperaturzaehigkeit |
| DE3631539A1 (de) | 1986-09-17 | 1988-03-24 | Bayer Ag | Alterungsbestaendige thermoplastische formmassen mit guter zaehigkeit |
| DE3704655A1 (de) | 1987-02-14 | 1988-08-25 | Bayer Ag | Teilchenfoermige mehrphasenpolymerisate |
| DE3704657A1 (de) | 1987-02-14 | 1988-08-25 | Bayer Ag | Teilchenfoermige mehrphasenpolymerisate |
| CA1321431C (en) | 1987-09-21 | 1993-08-17 | Masafumi Hongo | Polycarbonate resin composition |
| DE3738143A1 (de) | 1987-11-10 | 1989-05-18 | Bayer Ag | Verwendung von redoxpfropfpolymerisaten zur verbesserung der benzinbestaendigkeit von thermoplastischen, aromatischen polycarbonat- und/oder polyestercarbonat-formmassen |
| DE3832396A1 (de) | 1988-08-12 | 1990-02-15 | Bayer Ag | Dihydroxydiphenylcycloalkane, ihre herstellung und ihre verwendung zur herstellung von hochmolekularen polycarbonaten |
| NO170326C (no) | 1988-08-12 | 1992-10-07 | Bayer Ag | Dihydroksydifenylcykloalkaner |
| EP0430134B1 (en) | 1989-11-27 | 1996-07-31 | Mitsubishi Rayon Co., Ltd. | High impact graft copolymers and resin compositions |
| DE4312390A1 (de) | 1993-04-16 | 1994-10-20 | Bayer Ag | Zweistufen-Verfahren zur Herstellung von thermoplastischem Polycarbonat |
| US5807914A (en) | 1995-07-05 | 1998-09-15 | Mitsubishi Engineering-Plastics Corporation | Glass fiber-reinforced polycarbonate resin composition |
| DE19539290A1 (de) | 1995-10-23 | 1997-04-24 | Bayer Ag | Verfahren zur Herstellung von Poly-(diorganosiloxan)-Polycarbonat-Blockcopolymeren |
| JPH10310694A (ja) * | 1997-05-14 | 1998-11-24 | Daicel Chem Ind Ltd | 熱可塑性樹脂組成物 |
| DE19742868A1 (de) | 1997-09-29 | 1999-04-01 | Bayer Ag | Polycarbonat-ABS-Formmassen |
| JPH11116791A (ja) * | 1997-10-14 | 1999-04-27 | Daicel Chem Ind Ltd | 熱可塑性樹脂組成物 |
| DE19820398A1 (de) * | 1998-05-07 | 1999-11-11 | Basf Ag | Flammgeschützte Polyesterformmassen |
| DE19820399A1 (de) | 1998-05-07 | 1999-11-11 | Basf Ag | Flammgeschützte Polyesterformmassen |
| DE19853105A1 (de) | 1998-11-18 | 2000-05-25 | Bayer Ag | Flammwidrige Polycarbonat-ABS-Formmassen |
| DE19904814A1 (de) | 1999-02-05 | 2000-08-10 | Basf Ag | Flammgeschützte Polyester/Polycarbonatblends |
| NL1013105C2 (nl) * | 1999-09-21 | 2001-03-22 | Dsm Nv | Vlamdovend mengsel. |
| JP2001261973A (ja) | 2000-03-16 | 2001-09-26 | Daicel Chem Ind Ltd | 熱可塑性樹脂組成物 |
| JP2001335699A (ja) | 2000-05-30 | 2001-12-04 | Daicel Chem Ind Ltd | 難燃性樹脂組成物 |
| JP5255169B2 (ja) | 2000-11-24 | 2013-08-07 | 株式会社ダイセル | 難燃性樹脂組成物 |
| DE10213431A1 (de) * | 2002-03-26 | 2003-10-09 | Bayer Ag | Schlagzähmodifizierte Polymer-Zusammensetzung |
| DE10234420A1 (de) * | 2002-07-29 | 2004-02-12 | Bayer Ag | Schlagzähmodifizierte Polycarbonat Blends |
| ES2307988T3 (es) * | 2003-11-07 | 2008-12-01 | Italmatch Chemicals S.P.A. | Composiciones de policarbonato retardadoras de llama libres de halogenos. |
| DE102004049342A1 (de) * | 2004-10-08 | 2006-04-13 | Basf Ag | Fließfähige Thermoplaste mit halogenfreiem Flammschutz |
| US20060287422A1 (en) * | 2005-06-16 | 2006-12-21 | General Electric Company | Thermoplastic polycarbonate compositions with improved mechanical properties, articles made therefrom and method of manufacture |
| DE112006001824T5 (de) * | 2005-07-08 | 2008-05-15 | Polyplastics Co. Ltd. | Flammenhemmende Harzzusammensetzung |
| FR2893031B1 (fr) * | 2005-11-04 | 2008-02-08 | Coatex Sas | Procede de fabrication d'une resine thermoplastique avec une resistance a l'impact amelioree mettant en oeuvre un polymere peigne avec au moins une fonction greffee oxyde de polyalkylene et resines obtenues. |
| US20070129489A1 (en) * | 2005-12-01 | 2007-06-07 | Bayer Materialscience Llc | Thermoplastic composition and articles having high impact strength and good appearance |
| KR100767428B1 (ko) * | 2006-04-14 | 2007-10-17 | 제일모직주식회사 | 내스크래치성을 갖는 난연성 열가소성 수지 조성물 |
| DE102006020984A1 (de) * | 2006-05-04 | 2007-11-08 | Lanxess Deutschland Gmbh | Leichtbauteil in Hybridbauweise |
-
2007
- 2007-12-20 DE DE102007061760A patent/DE102007061760A1/de not_active Withdrawn
-
2008
- 2008-12-16 RU RU2010129711/05A patent/RU2504563C2/ru not_active IP Right Cessation
- 2008-12-16 KR KR1020107013536A patent/KR101530405B1/ko not_active Expired - Fee Related
- 2008-12-16 EP EP08864043.8A patent/EP2225320B1/de not_active Not-in-force
- 2008-12-16 JP JP2010538435A patent/JP5485908B2/ja not_active Expired - Fee Related
- 2008-12-16 ES ES08864043T patent/ES2416379T3/es active Active
- 2008-12-16 BR BRPI0821317-8A patent/BRPI0821317A2/pt not_active IP Right Cessation
- 2008-12-16 WO PCT/EP2008/010694 patent/WO2009080244A1/de not_active Ceased
- 2008-12-16 CN CN2008801271380A patent/CN101945935B/zh not_active Expired - Fee Related
- 2008-12-16 CA CA2709951A patent/CA2709951A1/en not_active Abandoned
- 2008-12-18 US US12/338,270 patent/US20090215945A1/en not_active Abandoned
- 2008-12-19 TW TW097149563A patent/TWI465516B/zh not_active IP Right Cessation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4866123A (en) * | 1987-08-27 | 1989-09-12 | Bayer Aktiengesellschaft | Molding compositions of polycarbonate and polyalkylene terephthalate showing improved joint line strength |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2009080244A1 (de) | 2009-07-02 |
| CN101945935B (zh) | 2013-03-20 |
| JP5485908B2 (ja) | 2014-05-07 |
| US20090215945A1 (en) | 2009-08-27 |
| KR20100096188A (ko) | 2010-09-01 |
| ES2416379T3 (es) | 2013-07-31 |
| KR101530405B1 (ko) | 2015-06-19 |
| TW200946592A (en) | 2009-11-16 |
| BRPI0821317A2 (pt) | 2015-06-16 |
| CA2709951A1 (en) | 2009-07-02 |
| DE102007061760A1 (de) | 2009-06-25 |
| EP2225320A1 (de) | 2010-09-08 |
| RU2010129711A (ru) | 2012-01-27 |
| JP2011506704A (ja) | 2011-03-03 |
| RU2504563C2 (ru) | 2014-01-20 |
| CN101945935A (zh) | 2011-01-12 |
| EP2225320B1 (de) | 2013-05-08 |
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