CN101942189B - 无卤阻燃pc/pbt合金材料及其制备方法 - Google Patents
无卤阻燃pc/pbt合金材料及其制备方法 Download PDFInfo
- Publication number
- CN101942189B CN101942189B CN2010105181768A CN201010518176A CN101942189B CN 101942189 B CN101942189 B CN 101942189B CN 2010105181768 A CN2010105181768 A CN 2010105181768A CN 201010518176 A CN201010518176 A CN 201010518176A CN 101942189 B CN101942189 B CN 101942189B
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- China
- Prior art keywords
- fire retardant
- powdery
- resin
- pbt
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 164
- 239000000956 alloy Substances 0.000 title claims abstract description 46
- 229920006778 PC/PBT Polymers 0.000 title claims abstract description 35
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 229920005989 resin Polymers 0.000 claims abstract description 82
- 239000011347 resin Substances 0.000 claims abstract description 82
- 239000002270 dispersing agent Substances 0.000 claims abstract description 42
- 239000012745 toughening agent Substances 0.000 claims abstract description 36
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 25
- -1 polysiloxane Polymers 0.000 claims abstract description 24
- 238000002156 mixing Methods 0.000 claims abstract description 15
- 239000000654 additive Substances 0.000 claims abstract description 12
- 238000005461 lubrication Methods 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 35
- AZAXDEGLWYZTDO-UHFFFAOYSA-N 3-(benzenesulfonyl)benzenesulfonic acid;potassium Chemical compound [K].OS(=O)(=O)C1=CC=CC(S(=O)(=O)C=2C=CC=CC=2)=C1 AZAXDEGLWYZTDO-UHFFFAOYSA-N 0.000 claims description 26
- 239000003112 inhibitor Substances 0.000 claims description 25
- 230000003647 oxidation Effects 0.000 claims description 25
- 238000007254 oxidation reaction Methods 0.000 claims description 25
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 20
- 239000002131 composite material Substances 0.000 claims description 18
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 16
- 239000000194 fatty acid Substances 0.000 claims description 16
- 229930195729 fatty acid Natural products 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 15
- 238000005303 weighing Methods 0.000 claims description 15
- 229910052736 halogen Inorganic materials 0.000 claims description 14
- 150000002367 halogens Chemical class 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 14
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 12
- 210000003097 mucus Anatomy 0.000 claims description 12
- 229920000877 Melamine resin Polymers 0.000 claims description 11
- 229920000388 Polyphosphate Polymers 0.000 claims description 11
- 239000000314 lubricant Substances 0.000 claims description 11
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 11
- 239000001205 polyphosphate Substances 0.000 claims description 11
- 235000011176 polyphosphates Nutrition 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 10
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 9
- 238000009775 high-speed stirring Methods 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 7
- 150000003016 phosphoric acids Chemical class 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 4
- 238000013461 design Methods 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000004033 plastic Substances 0.000 abstract description 13
- 229920003023 plastic Polymers 0.000 abstract description 13
- 229910045601 alloy Inorganic materials 0.000 abstract description 9
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 229920001296 polysiloxane Polymers 0.000 abstract description 4
- 229910019142 PO4 Inorganic materials 0.000 abstract description 2
- 239000010452 phosphate Substances 0.000 abstract description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 abstract 2
- 230000003078 antioxidant effect Effects 0.000 abstract 2
- 230000001050 lubricating effect Effects 0.000 abstract 2
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 abstract 1
- 239000004417 polycarbonate Substances 0.000 description 26
- 229920001577 copolymer Polymers 0.000 description 13
- 238000012360 testing method Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 5
- 230000007812 deficiency Effects 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000012757 flame retardant agent Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 238000004500 asepsis Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- BBBXVLCJTNBOIV-UHFFFAOYSA-N fluoro butane-1-sulfonate Chemical compound CCCCS(=O)(=O)OF BBBXVLCJTNBOIV-UHFFFAOYSA-N 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical group C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- 206010010071 Coma Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000002964 excitative effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/919—Thermal treatment of the stream of extruded material, e.g. cooling using a bath, e.g. extruding into an open bath to coagulate or cool the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
Description
测试性能 | 性能指标 | 测试标准 | 实施例1 | 实施例2 | 实施例3 | 实施例4 |
抗冲击强度(缺口)/KJ·m-2 | ﹥65.0 | GB/T1043-93 | 70.4 | 71.2 | 72.1 | 73.5 |
弯曲强度/Mpa | ﹥70.0 | GB/T9341-2000 | 72.8 | 76.5 | 77.2 | 76.5 |
弯曲模量/Mpa | ﹥1700 | GB/T9341-2000 | 1720 | 1763 | 1800 | 1823 |
拉伸强度/Mpa | ﹥50.0 | GB/T1040-1992 | 52.8 | 55.9 | 56.6 | 58.5 |
断裂伸长率/% | ﹥30.0 | GB/T1040-1992 | 50 | 45 | 41.5 | 43.5 |
热变形温度/℃ | ﹥72.0 | GB/T1634.2-2004 | 75.1 | 72.5 | 73.1 | 72.9 |
熔体流动速率/g·10min-1 | ﹥4.0 | GB/T3682-2000 | 4.8 | 5.2 | 5.8 | 5.5 |
氧指数/% | ﹥29.0 | GB/T2406-1993 | 30.2 | 31.0 | 30.8 | 31.5 |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010105181768A CN101942189B (zh) | 2010-10-25 | 2010-10-25 | 无卤阻燃pc/pbt合金材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN2010105181768A CN101942189B (zh) | 2010-10-25 | 2010-10-25 | 无卤阻燃pc/pbt合金材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN101942189A CN101942189A (zh) | 2011-01-12 |
CN101942189B true CN101942189B (zh) | 2012-06-27 |
Family
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3659676A1 (en) * | 2018-11-27 | 2020-06-03 | SABIC Global Technologies B.V. | Rail interior compliant thermoplastic composite |
Families Citing this family (9)
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CN102276970B (zh) * | 2011-07-04 | 2013-04-10 | 四川中物材料有限责任公司 | 一种无卤阻燃薄膜级聚碳酸酯材料及其制备方法 |
CN104109367B (zh) * | 2014-08-04 | 2016-02-03 | 武汉理工大学 | 一种阻燃pc/pbt复合材料及其制备方法 |
CN105733237A (zh) * | 2016-05-12 | 2016-07-06 | 绵阳鸿琪新材料科技有限公司 | 一种高阻燃性pc合金的制备方法 |
CN106084751A (zh) * | 2016-07-28 | 2016-11-09 | 上海至正道化高分子材料股份有限公司 | 一种高性能高阻燃环保聚氨酯电缆料及制备方法 |
CN106336640A (zh) * | 2016-08-26 | 2017-01-18 | 青岛海尔新材料研发有限公司 | 一种pc/pbt合金改性材料及其制备方法 |
CN106496994A (zh) * | 2016-10-26 | 2017-03-15 | 东莞市宝化塑胶原料有限公司 | 注塑超薄产品的无卤阻燃聚碳酸酯母粒的改性配方及工艺 |
CN108342057B (zh) * | 2017-01-23 | 2020-09-22 | 汉达精密电子(昆山)有限公司 | 无卤阻燃pc/pbt合金及其产品 |
CN112029252B (zh) * | 2020-08-07 | 2022-11-11 | 青岛国恩科技股份有限公司 | 一种充电桩面板用耐候无卤阻燃光扩散pc/pbt材料及其制备方法 |
CN114525024B (zh) * | 2021-09-03 | 2023-09-29 | 广东泰塑新材料科技有限公司 | 一种阻燃的回收pc-pet合金的制备工艺 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004046235A1 (en) * | 2002-11-21 | 2004-06-03 | Ciba Specialty Chemicals Holding Inc. | Flame retardant composition comprising a phosphonic acid metal salt and a nitrogen-containing compound |
US20070191519A1 (en) * | 2006-02-14 | 2007-08-16 | General Electric Company | Halogen-free polycarbonate compositions and articles formed therefrom |
CN100564450C (zh) * | 2006-12-19 | 2009-12-02 | 嘉兴荣泰塑胶有限公司 | 一种阻燃性及耐冲击性优异的热塑性树脂组成物 |
CN101089045A (zh) * | 2007-06-08 | 2007-12-19 | 深圳市科聚新材料有限公司 | 无卤无磷阻燃pc/abs合金材料及其制备方法 |
CN101328304A (zh) * | 2007-06-22 | 2008-12-24 | 东丽纤维研究所(中国)有限公司 | 阻燃抗滴落性热塑性树脂组合物 |
DE102007041594A1 (de) * | 2007-09-01 | 2009-03-05 | Clariant International Limited | Flammwidrige Polyestercompounds |
CN101434743B (zh) * | 2007-11-14 | 2013-08-14 | 帝人化成株式会社 | 抗静电性优异的阻燃性聚碳酸酯树脂组合物 |
DE102007061760A1 (de) * | 2007-12-20 | 2009-06-25 | Bayer Materialscience Ag | Flammgeschützte schlagzähmodifizierte Polyalkylenterephthalat/Polycarbonat-Zusammensetzungen |
CN101469123B (zh) * | 2007-12-25 | 2011-06-15 | 比亚迪股份有限公司 | 一种塑料合金及其制备方法 |
CN101747609B (zh) * | 2008-12-22 | 2013-06-19 | 广州熵能聚合物技术有限公司 | 阻燃性聚碳酸酯组合物 |
CN101497742A (zh) * | 2009-03-09 | 2009-08-05 | 佛山市顺德区瑞能科技有限公司 | 一种无卤阻燃剂组合物及其用途 |
CN101792585B (zh) * | 2010-03-16 | 2011-12-14 | 广州市番禺区天宇塑料实业有限公司 | 一种阻燃聚碳酸酯组合物及其制备方法 |
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2010
- 2010-10-25 CN CN2010105181768A patent/CN101942189B/zh active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3659676A1 (en) * | 2018-11-27 | 2020-06-03 | SABIC Global Technologies B.V. | Rail interior compliant thermoplastic composite |
Also Published As
Publication number | Publication date |
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CN101942189A (zh) | 2011-01-12 |
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