TWI396316B - 氧化還原梭添加物與非水電解質生命週期的還原抑制劑以及包含相同抑制劑的二次電池 - Google Patents
氧化還原梭添加物與非水電解質生命週期的還原抑制劑以及包含相同抑制劑的二次電池 Download PDFInfo
- Publication number
- TWI396316B TWI396316B TW095139158A TW95139158A TWI396316B TW I396316 B TWI396316 B TW I396316B TW 095139158 A TW095139158 A TW 095139158A TW 95139158 A TW95139158 A TW 95139158A TW I396316 B TWI396316 B TW I396316B
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- Prior art keywords
- carbon atoms
- redox shuttle
- electrolyte
- shuttle additive
- inhibitor
- Prior art date
Links
- 239000000654 additive Substances 0.000 title claims description 56
- 230000000996 additive effect Effects 0.000 title claims description 55
- 239000011255 nonaqueous electrolyte Substances 0.000 title claims description 22
- 239000003112 inhibitor Substances 0.000 title claims description 19
- 230000009467 reduction Effects 0.000 title claims description 9
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 47
- 239000003792 electrolyte Substances 0.000 claims description 40
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 20
- 229910052736 halogen Inorganic materials 0.000 claims description 15
- 150000002367 halogens Chemical class 0.000 claims description 15
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- -1 cyclic sulfites Chemical class 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 11
- 150000008053 sultones Chemical class 0.000 claims description 11
- 239000003125 aqueous solvent Substances 0.000 claims description 10
- 125000004122 cyclic group Chemical group 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 150000001491 aromatic compounds Chemical class 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 4
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- 239000002904 solvent Substances 0.000 claims description 4
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- 125000005805 dimethoxy phenyl group Chemical group 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 23
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 19
- 238000004519 manufacturing process Methods 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- 229910052744 lithium Inorganic materials 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 229910013870 LiPF 6 Inorganic materials 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- IFDLFCDWOFLKEB-UHFFFAOYSA-N 2-methylbutylbenzene Chemical compound CCC(C)CC1=CC=CC=C1 IFDLFCDWOFLKEB-UHFFFAOYSA-N 0.000 description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000006722 reduction reaction Methods 0.000 description 6
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 5
- 229910001416 lithium ion Inorganic materials 0.000 description 5
- 230000033116 oxidation-reduction process Effects 0.000 description 5
- 239000011572 manganese Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- WWAOVLXLTJXDGS-UHFFFAOYSA-N 1,2-difluoro-4,5-dimethoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1OC WWAOVLXLTJXDGS-UHFFFAOYSA-N 0.000 description 3
- ATGCJUULFWEWPY-UHFFFAOYSA-N 1,4-ditert-butyl-2,5-dimethoxybenzene Chemical compound COC1=CC(C(C)(C)C)=C(OC)C=C1C(C)(C)C ATGCJUULFWEWPY-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 238000006479 redox reaction Methods 0.000 description 3
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- WDXYVJKNSMILOQ-UHFFFAOYSA-N 1,3,2-dioxathiolane 2-oxide Chemical compound O=S1OCCO1 WDXYVJKNSMILOQ-UHFFFAOYSA-N 0.000 description 2
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical group O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 description 2
- BJWMSGRKJIOCNR-UHFFFAOYSA-N 4-ethenyl-1,3-dioxolan-2-one Chemical compound C=CC1COC(=O)O1 BJWMSGRKJIOCNR-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
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- 229910013716 LiNi Inorganic materials 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000006183 anode active material Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000006182 cathode active material Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 150000005676 cyclic carbonates Chemical class 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- VUPKGFBOKBGHFZ-UHFFFAOYSA-N dipropyl carbonate Chemical compound CCCOC(=O)OCCC VUPKGFBOKBGHFZ-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 230000002687 intercalation Effects 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
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- 230000009257 reactivity Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- ZXDQTQYRMDJIDZ-UHFFFAOYSA-N 1,3-difluoro-2,5-dimethoxybenzene Chemical compound COC1=CC(F)=C(OC)C(F)=C1 ZXDQTQYRMDJIDZ-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- QNQUBUBFPGHXAL-UHFFFAOYSA-N 1,4-difluoro-2,5-dimethoxybenzene Chemical compound COC1=CC(F)=C(OC)C=C1F QNQUBUBFPGHXAL-UHFFFAOYSA-N 0.000 description 1
- OXHNLMTVIGZXSG-UHFFFAOYSA-N 1-Methylpyrrole Chemical compound CN1C=CC=C1 OXHNLMTVIGZXSG-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- VUAXHMVRKOTJKP-UHFFFAOYSA-M 2,2-dimethylbutanoate Chemical compound CCC(C)(C)C([O-])=O VUAXHMVRKOTJKP-UHFFFAOYSA-M 0.000 description 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 description 1
- SSPIBMWEJNSGAF-UHFFFAOYSA-N 4,5-diethyl-1,3-dioxol-2-one Chemical compound CCC=1OC(=O)OC=1CC SSPIBMWEJNSGAF-UHFFFAOYSA-N 0.000 description 1
- QYIOFABFKUOIBV-UHFFFAOYSA-N 4,5-dimethyl-1,3-dioxol-2-one Chemical compound CC=1OC(=O)OC=1C QYIOFABFKUOIBV-UHFFFAOYSA-N 0.000 description 1
- GTIHXJAINLJNOQ-UHFFFAOYSA-N 4,5-dipropyl-1,3-dioxol-2-one Chemical compound CCCC=1OC(=O)OC=1CCC GTIHXJAINLJNOQ-UHFFFAOYSA-N 0.000 description 1
- QBBPWNDLJSXLJF-UHFFFAOYSA-N 4-(fluoromethyl)-1,3-dioxol-2-one Chemical compound FCC1=COC(=O)O1 QBBPWNDLJSXLJF-UHFFFAOYSA-N 0.000 description 1
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 1
- DAUVWNSVSAPZET-UHFFFAOYSA-N 4-butyl-1,3-dioxol-2-one Chemical compound CCCCC1=COC(=O)O1 DAUVWNSVSAPZET-UHFFFAOYSA-N 0.000 description 1
- GKLGPTLXQVBSDY-UHFFFAOYSA-N 4-ethyl-1,3,2-dioxathiolane 2-oxide Chemical compound CCC1COS(=O)O1 GKLGPTLXQVBSDY-UHFFFAOYSA-N 0.000 description 1
- IXIDQWJXRMPFRX-UHFFFAOYSA-N 4-ethyl-1,3-dioxol-2-one Chemical compound CCC1=COC(=O)O1 IXIDQWJXRMPFRX-UHFFFAOYSA-N 0.000 description 1
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical compound FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 description 1
- IEOVPNZQPZGDRI-UHFFFAOYSA-N 4-propyl-1,3-dioxol-2-one Chemical compound CCCC1=COC(=O)O1 IEOVPNZQPZGDRI-UHFFFAOYSA-N 0.000 description 1
- 229910020366 ClO 4 Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000002000 Electrolyte additive Substances 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910011281 LiCoPO 4 Inorganic materials 0.000 description 1
- 229910010707 LiFePO 4 Inorganic materials 0.000 description 1
- 229910052493 LiFePO4 Inorganic materials 0.000 description 1
- 229910015645 LiMn Inorganic materials 0.000 description 1
- 229910015644 LiMn 2 - z Ni Inorganic materials 0.000 description 1
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 1
- 229910014689 LiMnO Inorganic materials 0.000 description 1
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 description 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000006256 anode slurry Substances 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- AWAAXGSYKBMTQM-UHFFFAOYSA-N but-2-ene;carbonic acid Chemical compound CC=CC.OC(O)=O AWAAXGSYKBMTQM-UHFFFAOYSA-N 0.000 description 1
- 239000006257 cathode slurry Substances 0.000 description 1
- 229910052798 chalcogen Inorganic materials 0.000 description 1
- 150000001787 chalcogens Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009831 deintercalation Methods 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002641 lithium Chemical class 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920005735 poly(methyl vinyl ketone) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- CFJRPNFOLVDFMJ-UHFFFAOYSA-N titanium disulfide Chemical compound S=[Ti]=S CFJRPNFOLVDFMJ-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Heterocyclic Compounds Containing Sulfur Atoms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20050100000 | 2005-10-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200731599A TW200731599A (en) | 2007-08-16 |
| TWI396316B true TWI396316B (zh) | 2013-05-11 |
Family
ID=37967966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5317390B2 (ja) * | 2006-02-09 | 2013-10-16 | 三洋電機株式会社 | 非水電解質二次電池 |
| JP5095179B2 (ja) * | 2006-11-10 | 2012-12-12 | 株式会社東芝 | 非水電解質電池、リチウムチタン複合酸化物および電池パック |
| CN101779325B (zh) * | 2007-08-16 | 2013-11-13 | 株式会社Lg化学 | 非水电解质锂二次电池 |
| CN101803099B (zh) * | 2007-09-12 | 2016-06-29 | 株式会社Lg化学 | 非水性电解质锂二次电池 |
| EP2206189B1 (en) * | 2007-09-19 | 2014-10-22 | Lg Chem, Ltd. | Non-aqueous electrolyte lithium secondary battery |
| KR20100137447A (ko) * | 2008-02-12 | 2010-12-30 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 고전압 캐소드용 산화환원 셔틀 |
| JP2009218065A (ja) * | 2008-03-10 | 2009-09-24 | Hitachi Ltd | リチウム二次電池及びその製造方法 |
| US8968940B2 (en) * | 2010-05-25 | 2015-03-03 | Uchicago Argonne, Llc | Redox shuttles for high voltage cathodes |
| CN103098284A (zh) * | 2010-09-10 | 2013-05-08 | 巴斯夫欧洲公司 | 生产具有低水含量的溶剂混合物 |
| US20130216910A1 (en) | 2010-11-09 | 2013-08-22 | 3M Innovative Properties Company | High capacity alloy anodes and lithium-ion electrochemical cells containing same |
| JP2012138327A (ja) * | 2010-12-28 | 2012-07-19 | Hitachi Ltd | 非水電解液及びこれを用いた非水二次電池 |
| CN102208683B (zh) * | 2011-05-16 | 2013-09-25 | 湖州创亚动力电池材料有限公司 | 一种改善锂离子二次电池高温存储性能的电解液 |
| CN103988355B (zh) | 2011-12-08 | 2017-03-08 | 巴斯夫欧洲公司 | 电化学电池及其用途 |
| US9160032B2 (en) | 2011-12-08 | 2015-10-13 | Basf Se | Electrochemical cells and use thereof |
| KR20140110916A (ko) * | 2011-12-08 | 2014-09-17 | 바스프 에스이 | 혼합물 및 이의 리튬 이온 배터리에서의 용도 |
| US9774057B2 (en) | 2011-12-08 | 2017-09-26 | Basf Se | Mixtures and use thereof in lithium ion batteries |
| US9966625B2 (en) * | 2012-02-28 | 2018-05-08 | Uchicago Argonne, Llc | Organic non-aqueous cation-based redox flow batteries |
| JP5664685B2 (ja) * | 2012-03-27 | 2015-02-04 | Tdk株式会社 | 非水電解質溶液およびリチウムイオン二次電池 |
| JP5931572B2 (ja) * | 2012-04-27 | 2016-06-08 | 旭化成株式会社 | 非水系二次電池用レドックスシャトル剤、非水系二次電池用電解液及び非水系二次電池 |
| JP5977573B2 (ja) * | 2012-04-27 | 2016-08-24 | 旭化成株式会社 | 非水系二次電池 |
| WO2013166074A1 (en) * | 2012-05-01 | 2013-11-07 | Altairnano, Inc. | Improved lithium titanate cell |
| WO2014012980A1 (en) | 2012-07-20 | 2014-01-23 | Basf Se | Electrochemical cells |
| US20140134501A1 (en) * | 2012-11-12 | 2014-05-15 | Novolyte Technologies, Inc. | Non-Aqueous Electrolytic Solutions And Electrochemical Cells Comprising Same |
| US20160056418A1 (en) * | 2014-08-21 | 2016-02-25 | Ford Global Technologies, Llc | Li-ion monoblock battery for stop/start applications |
| JP6597629B2 (ja) | 2014-10-21 | 2019-10-30 | 日本電気株式会社 | 二次電池およびその製造方法 |
| CN105161757B (zh) * | 2015-07-24 | 2017-08-22 | 张家港市国泰华荣化工新材料有限公司 | 一种含有氧化还原型防过充添加剂的锂离子电池电解液 |
| US10374239B2 (en) | 2016-12-29 | 2019-08-06 | Uchicago Argonne, Llc | Aqueous pyridinium cation-based redox flow batteries |
| US10553890B2 (en) | 2017-06-23 | 2020-02-04 | Uchicago Argonne, Llc | Aqueous redox flow batteries |
| US10622676B2 (en) | 2017-06-29 | 2020-04-14 | Uchicago Argonne, Llc | Functional organic salt for lithium-ion batteries |
| EP3651240A4 (en) * | 2017-07-07 | 2021-03-10 | Murata Manufacturing Co., Ltd. | SECONDARY BATTERY, BATTERY PACK, ELECTRIC VEHICLE, POWER STORAGE SYSTEM, ELECTRIC TOOL AND ELECTRONIC DEVICE |
| US10424805B2 (en) | 2017-08-15 | 2019-09-24 | Uchicago Argonne, Llc | Benzothiophene-based redox molecules for flow battery |
| US11271237B2 (en) | 2019-07-29 | 2022-03-08 | Uchicago Argonne, Llc | Organic redox molecules for flow batteries |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1398013A (zh) * | 2001-07-12 | 2003-02-19 | 日本电池株式会社 | 非水系二次电池 |
| CN1498438A (zh) * | 2001-01-24 | 2004-05-19 | ��˲���ʽ���� | 非水电解液和锂二次电池 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4857423A (en) | 1987-11-30 | 1989-08-15 | Eic Labotatories, Inc. | Overcharge protection of secondary, non-aqueous batteries |
| JP3809657B2 (ja) | 1994-03-07 | 2006-08-16 | ソニー株式会社 | 非水電解液二次電池 |
| JP3669024B2 (ja) | 1995-05-26 | 2005-07-06 | ソニー株式会社 | 非水電解液二次電池 |
| CA2156800C (en) | 1995-08-23 | 2003-04-29 | Huanyu Mao | Polymerizable aromatic additives for overcharge protection in non-aqueous rechargeable lithium batteries |
| US5882812A (en) | 1997-01-14 | 1999-03-16 | Polyplus Battery Company, Inc. | Overcharge protection systems for rechargeable batteries |
| GB9717220D0 (en) * | 1997-08-15 | 1997-10-22 | Aea Technology Plc | Eklectrolyte for a rechargeable cell |
| JP3823683B2 (ja) * | 1999-05-24 | 2006-09-20 | 宇部興産株式会社 | 非水電解液およびそれを用いたリチウム二次電池 |
| JP4411691B2 (ja) | 1999-06-30 | 2010-02-10 | パナソニック株式会社 | 非水電解液二次電池および非水電解液二次電池の充電制御システムおよびこれを用いた機器 |
| WO2001029920A1 (en) * | 1999-10-18 | 2001-04-26 | The Regents Of The University Of California | Shutdown and redox shuttle additives for batteries |
| JP4762411B2 (ja) * | 2000-06-26 | 2011-08-31 | パナソニック株式会社 | 二次電池用非水電解液およびこれを用いた非水電解液二次電池 |
| KR100326468B1 (ko) | 2000-07-25 | 2002-02-28 | 김순택 | 리튬 설퍼 전지용 전해액 |
| JP4352622B2 (ja) | 2001-03-06 | 2009-10-28 | 宇部興産株式会社 | 非水電解液およびそれを用いたリチウム二次電池 |
| JP3797197B2 (ja) * | 2001-11-01 | 2006-07-12 | 株式会社ジーエス・ユアサコーポレーション | 非水電解質二次電池 |
| JP4281895B2 (ja) | 2001-12-28 | 2009-06-17 | 三井化学株式会社 | 非水電解液およびそれを用いたリチウム二次電池 |
| JP4127355B2 (ja) * | 2002-01-18 | 2008-07-30 | 三菱化学株式会社 | 非水系電解液及びそれを用いたリチウム二次電池 |
| JP4229615B2 (ja) * | 2002-01-24 | 2009-02-25 | 三菱化学株式会社 | 非水系電解液及びそれを用いたリチウム二次電池 |
| KR100661680B1 (ko) * | 2002-07-25 | 2006-12-26 | 가부시끼가이샤 도시바 | 비수전해질 이차 전지 |
| JP4056346B2 (ja) * | 2002-09-30 | 2008-03-05 | 三洋電機株式会社 | 非水電解質二次電池 |
| JP2004158213A (ja) * | 2002-11-01 | 2004-06-03 | Toshiba Corp | 非水電解質二次電池の製造方法 |
| JP2004281218A (ja) * | 2003-03-14 | 2004-10-07 | Yuasa Corp | 非水電解質及び非水電解質電池 |
| JP4283598B2 (ja) * | 2003-05-29 | 2009-06-24 | Ｔｄｋ株式会社 | 非水電解質溶液及びリチウムイオン２次電池 |
| JP4690643B2 (ja) * | 2003-09-25 | 2011-06-01 | 株式会社東芝 | 非水電解質二次電池 |
| JP4580662B2 (ja) * | 2004-02-27 | 2010-11-17 | 三井化学株式会社 | 非水電解質および非水電解質二次電池 |
| DE602005025200D1 (de) | 2004-04-01 | 2011-01-20 | 3M Innovative Properties Co | Redox-shuttle für eine wiederaufladbare lithiumionenzelle |
-
2006
- 2006-10-20 KR KR1020060102449A patent/KR100812056B1/ko active Active
- 2006-10-23 JP JP2008536514A patent/JP5323487B2/ja active Active
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1498438A (zh) * | 2001-01-24 | 2004-05-19 | ��˲���ʽ���� | 非水电解液和锂二次电池 |
| CN1398013A (zh) * | 2001-07-12 | 2003-02-19 | 日本电池株式会社 | 非水系二次电池 |
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| KR20070044361A (ko) | 2007-04-27 |
| US8481216B2 (en) | 2013-07-09 |
| CN101297433A (zh) | 2008-10-29 |
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| CN101297433B (zh) | 2011-12-21 |
| EP1952476B1 (en) | 2010-09-15 |
| KR100812056B1 (ko) | 2008-03-07 |
| JP5738342B2 (ja) | 2015-06-24 |
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| US8673507B2 (en) | 2014-03-18 |
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| EP1952476A1 (en) | 2008-08-06 |
| JP2009514149A (ja) | 2009-04-02 |
| EP1952476A4 (en) | 2009-03-18 |
| DE602006016979D1 (de) | 2010-10-28 |
| US20130216898A1 (en) | 2013-08-22 |
| US20070092802A1 (en) | 2007-04-26 |
| JP2013219035A (ja) | 2013-10-24 |
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