TWI304105B - Polypropylene nonwoven fabric and use thereof - Google Patents

Polypropylene nonwoven fabric and use thereof Download PDF

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Publication number
TWI304105B
TWI304105B TW94141707A TW94141707A TWI304105B TW I304105 B TWI304105 B TW I304105B TW 94141707 A TW94141707 A TW 94141707A TW 94141707 A TW94141707 A TW 94141707A TW I304105 B TWI304105 B TW I304105B
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Taiwan
Prior art keywords
propylene
woven fabric
ethylene
nonwoven fabric
patent application
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TW94141707A
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English (en)
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TW200639284A (en
Inventor
Kenichi Suzuki
Akio Matsubara
Shigeyuki Motomura
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Mitsui Chemicals Inc
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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D04H1/4291—Olefin series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/49—Absorbent articles specially adapted to be worn around the waist, e.g. diapers
    • A61F13/49007—Form-fitting, self-adjusting disposable diapers
    • A61F13/49009—Form-fitting, self-adjusting disposable diapers with elastic means
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/49—Absorbent articles specially adapted to be worn around the waist, e.g. diapers
    • A61F13/49007—Form-fitting, self-adjusting disposable diapers
    • A61F13/49009—Form-fitting, self-adjusting disposable diapers with elastic means
    • A61F13/4902—Form-fitting, self-adjusting disposable diapers with elastic means characterised by the elastic material
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
    • A61F13/51456—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by its properties
    • A61F13/51464—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by its properties being stretchable or elastomeric
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/08—Melt spinning methods
    • D01D5/098—Melt spinning methods with simultaneous stretching
    • D01D5/0985—Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005—Synthetic yarns or filaments
    • D04H3/007—Addition polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00—Bandages or dressings; Absorbent pads
    • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
    • A61F13/513—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability
    • A61F2013/51322—Topsheet, i.e. the permeable cover or layer facing the skin characterised by its function or properties, e.g. stretchability, breathability, rewet, visual effect; having areas of different permeability being elastomeric or stretchable
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/249933—Fiber embedded in or on the surface of a natural or synthetic rubber matrix
    • Y10T428/249938—Composite or conjugate fiber [e.g., fiber contains more than one chemically different material in monofilament or multifilament form, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/681—Spun-bonded nonwoven fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/697—Containing at least two chemically different strand or fiber materials
    • Y10T442/698—Containing polymeric and natural strand or fiber materials

Description

1304105 九、發明說明： 【發明所屬之技術領域】 織布關異本;『小且具有優異觸感之不 物成形而形成之具有優異特性的不χ織寺定之聚丙烯組成 【先前技術】 丙烯由於廉價且剛性、耐濕 為良好，故利用如該特性而f w * θ j 亚且成形性亦 各種的用途。 W向錢成大1不織布，用於衛生材料等 ，由於聚丙烯具有雛高、及缺乏伸縮性的特性，於要 變要小的領域之中’不能使用由聚丙烯構成的 ί織ί田，，該伸縮性之部分，至今為正多使用； 聚氰基甲酸酯(專利文獻丨）。 ⑺…、」土 r玍之 可見旨f ί使用軟質的聚婦煙(專利文獻2)，雖然也
Ιϋ，4疋’於需要如上述伸縮性之用途中，會發 生成形體外觀差，且觸感不良的問題。 3 X 又，尚有藉自練質料短魏柄私赠料 ，3一用於彈性纖維類之例子，但是’並未明確地顯^質聚 烯煙/專規聚丙浠之混合比及對伸縮性之效果。 、 、 再者’將軟質聚烯烴/高MFR(250〜55〇)之讎度均聚 混合組成物加工為纖維等時，'能得到加工性•柔軟性(懸垂 利文獻4)然而，並未有伸縮性之記載。 另一方面，如果使用具有由苯乙烯所構成成分單位之並 物，則雖然伸縮性優異，但是不僅強度未充分地展現，且由取 烯烴構成之不織布或聚烯烴構成之膜的接著性不良，於作^ : 材料等使用之情形中，接著的問題成為障礙，產生不易由 計產品的問題。 x [專利文獻l]WO02/65679號小冊 1304105 [專利文獻2]W093/15251號小冊 [專利文獻3]W02003/040201號小冊 [專利文獻flWOOl/094462號小冊 【發明内容】 發明欲解決之問顳 本發明之目的為提供一種使用聚丙烯及丙烯，乙稀· α_婦炉 共聚物之新穎的不織布及其用途。 二 再者，本發明之目的為提供外觀良好而且伸縮性優異、殘留 巧變小，對聚烯烴具有優異接著性之聚烯烴系之不織布及其用途。 解決問題之方式 、 而成本發明之錢布係由包含下列㈣之聚_樹驗成物成形 等規聚丙烯(i):l〜4〇重量份，及 ㈣ί〜，〇1%、乙稀10〜25咖1%及礙數4〜20之α•婦 ^蜮里，、來δ而成之丙烯•乙烯· α_烯烴共聚 / 20之α-烯烴之共聚合量不超過3〇祕):6〇〜 钱4〜 以延織布於延伸倍^之條件加 理用:者吸生：，尿布、生 的手=明救護袍(_—、各醫療用用抱棄式 本發明之不織树酱:等«丙制ν 利材使用。 ^將既定量之丙烯、乙烯與視需要爱 乂一 ^丙烯•乙稀· α_稀烴共聚物⑼ 维而=馳共聚合而成 延伸後之不織布的殘留應以而^，為延伸性的， 不織布使用。而且，製造本發明之不^此作為具有彈力性之 域”造本㈣，不易產 1304105 伸縮性不織布不、 外:„且伸縮性優異’為殘留應變小之 布不同，當使用不織=月之不織布與聚氨基甲酸酯系之 著劑仍能非常良好地形狀時，即使用了聚稀煙系之^ 【實施方式】 的説明。 乙烯與視需要的其及將既定量丙烯、 物⑼，所構成的丙埽系^;22烯•乙烯·〜烯烴共聚 纖維而形成。 形成的树朐組成物進行紡紗形成的 説明 以下’對構成本發明之不_的丙烯系聚合物組成物 具體的 魏明—絲合触·所含的各齡(i)、⑼。 ^下述雜，射為均料烯 ===、要具 谈段=物，較佳為均聚丙烯或丙稀物、丙稀
織布成打面Awi ^°了下)只要是柄組成物後之娜尺在不 0.iM00g/10min 〇 x , , DSC _以上，較佳為聰以上，更佳=5^=私點通吊為 本發明使用之等規聚丙烯(i)為丙婦·α_婦煙無規共聚物之情形，

Claims (1)

1304105 申請專利範圍 ----一. | 1 » π m扣叫· ！F擎月4日修(得正本 成形^ ^ ^ 物 等規聚丙烯⑴：1〜20重量份，及 丙烯45〜89m〇l%、乙烯10〜25m〇1%及碳數4 ^ WOmol%共聚合成之丙烯·乙稀·續烴共聚物⑼二= 份。 乃直置 2.如申請專利範圍第丨項之不織布，其中，該 率1·之條件延倾之殘留紐低於观。、鱗以延伸倍 為纺利範圍第1項或第2項之不織布，其中，該不織布 4.如申請專利範圍帛j項之不，， 部之鱗熱量在气)之最场部，於該最大峰 任-材料，其特徵為··具有申請專利範圍第1至4項中 項中任-項之尿布’其特徵為··具有中料利顧第1至4 任-項之不織’其特徵為沒有巾請專職m第1至4項中 中任-項之ν!^^σπ，其特徵為··具有申請專利範圍第1至4項 項中任罩’其特徵為··具有申請專利範II第1至4 10·—種綷剑暮， -項之不織布。用/、特徵為··具有申請專利範圍第1至4項中任 11·一種貼布劑，斗 一項之不織布。/、寺敛為··具有申請專利範圍第1至4項中任 32 1304105 12. —種拋棄式的手術服，其特徵為:具有申請專利範圍第1至 4項中任一項之不織布。 13. —種救護袍，其特徵為:具有申請專利範圍第1至4項中任 一項之不織布。 14. 一種醫療用膜或者片材，其特徵為:具有申請專利範圍第1 至4項中任一項之不織布。 十一、圖式：
33
TW94141707A 2004-11-26 2005-11-28 Polypropylene nonwoven fabric and use thereof TWI304105B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004343200 2004-11-26

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TW200639284A TW200639284A (en) 2006-11-16
TWI304105B true TWI304105B (en) 2008-12-11

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Country Status (8)

Country Link
US (2) US7585796B2 (zh)
EP (2) EP2518194B1 (zh)
JP (2) JP4860483B2 (zh)
KR (1) KR20070086389A (zh)
CN (1) CN101065527A (zh)
DK (2) DK2518194T3 (zh)
TW (1) TWI304105B (zh)
WO (1) WO2006057369A1 (zh)

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TWI601858B (zh) * 2012-09-27 2017-10-11 三井化學股份有限公司 紡絲黏合不織布、不織布積層體及吸收物品

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ES2581598T3 (es) 2005-03-18 2016-09-06 Mitsui Chemicals, Inc. Composición polimérica de propileno, uso de la misma, y procedimiento para la producción de una composición polimérica termoplástica
KR101008358B1 (ko) * 2006-09-12 2011-01-14 코오롱글로텍주식회사 폴리올레핀계 조성물 및 이를 이용한 제품과 이의 제조방법
CN101622124A (zh) * 2007-03-02 2010-01-06 三井化学株式会社 非织造布层叠体
WO2008108230A1 (ja) * 2007-03-02 2008-09-12 Mitsui Chemicals, Inc. 混繊不織布積層体
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