ATE382725T1 - Fasern aus isotaktischen homopolymeren von propylen und ihre verwendung - Google Patents

Fasern aus isotaktischen homopolymeren von propylen und ihre verwendung

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Publication number
ATE382725T1
ATE382725T1 AT06016783T AT06016783T ATE382725T1 AT E382725 T1 ATE382725 T1 AT E382725T1 AT 06016783 T AT06016783 T AT 06016783T AT 06016783 T AT06016783 T AT 06016783T AT E382725 T1 ATE382725 T1 AT E382725T1
Authority
AT
Austria
Prior art keywords
propylene
fibers made
isotactic homopolymers
isotactic
homopolymers
Prior art date
Application number
AT06016783T
Other languages
English (en)
Inventor
James Stevens
Daniel D Vanderlende
Andy C Chang
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/139,786 external-priority patent/US6960635B2/en
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Application granted granted Critical
Publication of ATE382725T1 publication Critical patent/ATE382725T1/de

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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • C08L23/142Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • C08L23/147Copolymers of propene with monomers containing atoms other than carbon or hydrogen
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • D01F6/06Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/28Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/30Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds comprising olefins as the major constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00Indexing scheme relating to specific properties of organic compounds
    • C07B2200/11Compounds covalently bound to a solid support
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/02Cp or analog bridged to a non-Cp X anionic donor
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    • C08F2420/00Metallocene catalysts
    • C08F2420/06Cp analog where at least one of the carbon atoms of the non-coordinating part of the condensed ring is replaced by a heteroatom
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    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
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    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/12Polypropene
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10Homopolymers or copolymers of propene
    • C08J2323/14Copolymers of propene
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
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    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Ethylene-propylene or ethylene-propylene-diene copolymers
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    • C09K2200/00Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
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    • C09K2200/0615Macromolecular organic compounds, e.g. prepolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09K2200/0617Polyalkenes
    • C09K2200/062Polyethylene

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Artificial Filaments (AREA)
  • Nonwoven Fabrics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT06016783T 2001-11-06 2002-11-05 Fasern aus isotaktischen homopolymeren von propylen und ihre verwendung ATE382725T1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US33888101P 2001-11-06 2001-11-06
US38014802P 2002-05-05 2002-05-05
US10/139,786 US6960635B2 (en) 2001-11-06 2002-05-05 Isotactic propylene copolymers, their preparation and use

Publications (1)

Publication Number Publication Date
ATE382725T1 true ATE382725T1 (de) 2008-01-15

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AT06016783T ATE382725T1 (de) 2001-11-06 2002-11-05 Fasern aus isotaktischen homopolymeren von propylen und ihre verwendung
AT02802874T ATE361382T1 (de) 2001-11-06 2002-11-05 Fasern aus isotaktischem propylencopolymerisat, deren herstellung und verwendung

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AT02802874T ATE361382T1 (de) 2001-11-06 2002-11-05 Fasern aus isotaktischem propylencopolymerisat, deren herstellung und verwendung

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EP (2) EP1453994B1 (de)
AT (2) ATE382725T1 (de)
DE (2) DE60224463T2 (de)
DK (2) DK1453994T3 (de)
ES (2) ES2296252T3 (de)
WO (1) WO2003040442A1 (de)

Families Citing this family (114)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
EP1699882B1 (de) 2003-12-24 2009-09-09 Dow Global Technologies Inc. Radikalinitiierung in gegenwart eines stabilen organischen radikals und zugehörige zusammensetzungen
EP1942152A1 (de) 2003-12-24 2008-07-09 Dow Gloval Technologies Inc. Polymerverbindung
US7504347B2 (en) 2004-03-17 2009-03-17 Dow Global Technologies Inc. Fibers made from copolymers of propylene/α-olefins
US7622179B2 (en) 2004-03-17 2009-11-24 Dow Global Technologies Inc. Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof
US7803728B2 (en) 2004-03-17 2010-09-28 Dow Global Technologies Inc. Fibers made from copolymers of ethylene/α-olefins
US7101623B2 (en) 2004-03-19 2006-09-05 Dow Global Technologies Inc. Extensible and elastic conjugate fibers and webs having a nontacky feel
AU2005224677A1 (en) * 2004-03-19 2005-09-29 Dow Global Technologies Inc. Propylene-based copolymers, a method of making the fibers and articles made from the fibers
US7645829B2 (en) 2004-04-15 2010-01-12 Exxonmobil Chemical Patents Inc. Plasticized functionalized propylene copolymer adhesive composition
DE602005010230D1 (de) * 2004-04-19 2008-11-20 Dow Global Technologies Inc Zusammensetzung für einseitige, geräuscharme stretchclingfolie und daraus hergestellte folien
CN100577898C (zh) * 2004-04-30 2010-01-06 陶氏环球技术公司 改进的无纺织物和纤维
WO2005111282A1 (en) * 2004-04-30 2005-11-24 Dow Global Technologies Inc. Improved nonwoven fabric and fibers
KR20070086389A (ko) * 2004-11-26 2007-08-27 미쯔이카가쿠 가부시기가이샤 폴리프로필렌의 부직포 및 그 용도
US7319077B2 (en) 2004-12-17 2008-01-15 Exxonmobil Chemical Patents Inc. Polymer blends and nonwoven articles therefrom
ATE467658T1 (de) 2004-12-17 2010-05-15 Exxonmobil Chem Patents Inc Homogenes polymerblend und artikel daraus
ATE435887T1 (de) 2004-12-17 2009-07-15 Exxonmobil Chem Patents Inc Folien aus polymerblends
JP2008524388A (ja) 2004-12-17 2008-07-10 エクソンモービル・ケミカル・パテンツ・インク 不均一ポリマーブレンド及びそれらを用いた成形製品
US7833917B2 (en) 2004-12-30 2010-11-16 Kimberly-Clark Worldwide, Inc. Extensible and stretch laminates with comparably low cross-machine direction tension and methods of making same
EP1858944B1 (de) * 2005-03-17 2011-07-20 Dow Global Technologies LLC Aus Ethylen/alpha-Olefin-Interpolymeren hergestellte dreidimensionale Strukturen mit zufälligen Schlingen und Verwendungen dafür
EP1859083B1 (de) 2005-03-17 2012-01-18 Dow Global Technologies LLC Aus copolymeren von ethylen/alpha-olefinen hergestellte fasern
CN101351582B (zh) * 2005-03-17 2015-02-25 陶氏环球技术有限责任公司 由丙烯/α-烯烃共聚体制造的纤维
CN101248133B (zh) 2005-06-24 2012-11-21 埃克森美孚化学专利公司 官能化丙烯共聚物粘合剂组合物
US7695812B2 (en) 2005-09-16 2010-04-13 Dow Global Technologies, Inc. Fibers made from copolymers of ethylene/α-olefins
KR20080068043A (ko) 2005-10-05 2008-07-22 다우 글로벌 테크놀로지스 인크. 폴리올레핀 기반의 박리가능 시일
RU2426650C2 (ru) 2005-10-26 2011-08-20 Дау Глобал Текнолоджиз Инк. Многослойные предварительно вытянутые эластичные изделия
US7820010B2 (en) 2005-12-15 2010-10-26 Kimberly-Clark Worldwide, Inc. Treated tissue products having increased strength
US7879188B2 (en) 2005-12-15 2011-02-01 Kimberly-Clark Worldwide, Inc. Additive compositions for treating various base sheets
US7837832B2 (en) 2005-12-15 2010-11-23 Dow Global Technologies, Inc. Additive compositions for treating various base sheets
EP1963573B1 (de) 2005-12-15 2016-02-17 Dow Global Technologies LLC Verbesserte zelluloseartikel mit einer zusatzzusammensetzung
US7842163B2 (en) 2005-12-15 2010-11-30 Kimberly-Clark Worldwide, Inc. Embossed tissue products
US7879189B2 (en) 2005-12-15 2011-02-01 Kimberly-Clark Worldwide, Inc. Additive compositions for treating various base sheets
US7879191B2 (en) 2005-12-15 2011-02-01 Kimberly-Clark Worldwide, Inc. Wiping products having enhanced cleaning abilities
US8444811B2 (en) 2005-12-15 2013-05-21 Kimberly-Clark Worldwide, Inc. Process for increasing the basis weight of sheet materials
US7837831B2 (en) 2005-12-15 2010-11-23 Kimberly-Clark Worldwide, Inc. Tissue products containing a polymer dispersion
WO2008156454A1 (en) 2007-06-21 2008-12-24 Kimberly-Clark Worldwide, Inc. Wiping products having enhanced oil absorbency
US7883604B2 (en) 2005-12-15 2011-02-08 Kimberly-Clark Worldwide, Inc. Creping process and products made therefrom
US7807023B2 (en) 2005-12-15 2010-10-05 Kimberly-Clark Worldwide, Inc. Process for increasing the basis weight of sheet materials
CA2642462A1 (en) 2006-02-15 2007-08-30 Dow Global Technologies Inc. Crosslinked polyethylene elastic fibers
EP2016217A2 (de) 2006-05-03 2009-01-21 Dow Global Technologies Inc. Dehnbare faser für schwimmbekleidungen
US7585382B2 (en) 2006-06-30 2009-09-08 Kimberly-Clark Worldwide, Inc. Latent elastic nonwoven composite
WO2008016518A2 (en) 2006-08-02 2008-02-07 Exxonmobil Chemical Patents Inc. Propylene-based polymer article
US7582178B2 (en) 2006-11-22 2009-09-01 Kimberly-Clark Worldwide, Inc. Nonwoven-film composite with latent elasticity
US7938921B2 (en) 2006-11-22 2011-05-10 Kimberly-Clark Worldwide, Inc. Strand composite having latent elasticity
US7785443B2 (en) 2006-12-07 2010-08-31 Kimberly-Clark Worldwide, Inc. Process for producing tissue products
US8143352B2 (en) 2006-12-20 2012-03-27 Exxonmobil Research And Engineering Company Process for fluid phase in-line blending of polymers
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
US7951732B2 (en) 2007-01-26 2011-05-31 Exxonmobil Chemical Patents Inc. Elastomeric laminates for consumer products
US8080610B2 (en) 2007-03-06 2011-12-20 Exxonmobil Research And Engineering Company Monomer recycle process for fluid phase in-line blending of polymers
US7910795B2 (en) 2007-03-09 2011-03-22 Kimberly-Clark Worldwide, Inc. Absorbent article containing a crosslinked elastic film
US7588662B2 (en) 2007-03-22 2009-09-15 Kimberly-Clark Worldwide, Inc. Tissue products containing non-fibrous polymeric surface structures and a topically-applied softening composition
US8241753B2 (en) 2007-06-04 2012-08-14 Exxonmobil Chemical Patents Inc. Composite thermoplastic elastomer structures with high adhesion performance and uses for the same
US8038364B2 (en) 2007-08-07 2011-10-18 Saint-Gobain Technical Fabrics America, Inc. Reinforcement for asphaltic paving, method of paving, and process for making a grid with the coating for asphaltic paving
GB0717376D0 (en) 2007-09-07 2007-10-17 Exxonmobil Chem Patents Inc Composition and manufacture thereof
WO2009035579A1 (en) 2007-09-13 2009-03-19 Exxonmobil Research And Engineering Company In-line blending of plasticizers with a base polymer
CN101855249B (zh) 2007-09-13 2013-02-13 埃克森美孚研究工程公司 在线生产增塑聚合物和增塑聚合物共混物的方法
WO2009043946A1 (es) 2007-10-02 2009-04-09 Dow Global Technologies Inc. Métodos para la reducción de aditivos polares necesarios para uso en poliolefinas
BRPI0721999A2 (pt) 2007-10-19 2014-03-18 Dow Global Technologies Inc Vedação de proteção
US8609772B2 (en) 2007-10-23 2013-12-17 Exxonmobil Chemical Patents Inc. Elastic films having improved mechanical and elastic properties and methods for making the same
WO2009067337A1 (en) * 2007-11-19 2009-05-28 Dow Global Technologies Inc. Long chain branched propylene-alpha-olefin copolymers
EP2450403A1 (de) 2007-12-20 2012-05-09 ExxonMobil Research and Engineering Company Polypropylen-Ethylen-Propylen-Copolymer-Mischungen und Inline-Verfahren zu deren Herstellung
US7910679B2 (en) 2007-12-20 2011-03-22 Exxonmobil Research And Engineering Company Bulk homogeneous polymerization process for ethylene propylene copolymers
WO2009082463A1 (en) 2007-12-20 2009-07-02 Exxonmobil Research And Engineering Company In-line process to produce pellet-stable polyolefins
EP2093315A1 (de) * 2008-02-22 2009-08-26 Total Petrochemicals Research Feluy Aus Polypropylen hergestellte Fasern und Vliese mit hohem Dispersitätsindex
US8067512B2 (en) 2008-04-10 2011-11-29 Exxonmobil Research And Engineering Company Monomer/solvent separation and recycle process for propylene containing polymers
US8709191B2 (en) 2008-05-15 2014-04-29 Kimberly-Clark Worldwide, Inc. Latent elastic composite formed from a multi-layered film
US7939610B2 (en) 2008-05-22 2011-05-10 Exxonmobil Research And Engineering Company Polymerization processes for broadened molecular weight distribution
US8383246B2 (en) * 2008-05-22 2013-02-26 Exxonmobil Oil Corporation Polypropylene-based shrink films
US7867433B2 (en) 2008-05-30 2011-01-11 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked articles
US8765832B2 (en) 2011-10-14 2014-07-01 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked compositions and methods of making them
WO2009158100A2 (en) 2008-06-27 2009-12-30 Exxonmobil Chemical Patents Inc. High shrinkage propylene-based films
CN102171318A (zh) 2008-08-08 2011-08-31 埃克森美孚化学专利公司 用于机油粘度改进的经改善的烯属共聚物组合物
US8399586B2 (en) 2008-09-05 2013-03-19 Exxonmobil Research And Engineering Company Process for feeding ethylene to polymerization reactors
US8105463B2 (en) 2009-03-20 2012-01-31 Kimberly-Clark Worldwide, Inc. Creped tissue sheets treated with an additive composition according to a pattern
PL2416961T3 (pl) 2009-04-10 2023-01-09 Dow Global Technologies Llc Współwytłaczana dwuosiowo orientowana folia polipropylenowa o ulepszonych właściwościach zgrzewania
US8975334B2 (en) 2009-07-23 2015-03-10 Exxonmobil Chemical Patents Inc. Crosslinkable propylene-based copolymers, methods for preparing the same, and articles made therefrom
CN102762785A (zh) 2009-12-23 2012-10-31 英威达技术有限公司 聚烯烃弹性纤维
EP2516709A4 (de) 2009-12-23 2013-11-06 Invista Tech Sarl Stoff mit elastischer polyolefinfaser
CN107411883A (zh) 2009-12-23 2017-12-01 英威达技术有限公司 包括聚烯烃弹性纤维的弹力制品
KR101996322B1 (ko) 2009-12-23 2019-07-05 인비스타 테크놀러지스 에스.에이 알.엘. 점착 방지 첨가제를 함유하는 탄성 섬유
US8900719B2 (en) 2010-04-14 2014-12-02 Avery Dennison Corporation Blends of ethylene copolymers and propylene based plastomers in multilayer films for low noise and RF welding
US8940839B2 (en) 2011-03-25 2015-01-27 Exxonmobil Chemical Patents Inc. Diblock copolymers prepared by cross metathesis
US8841397B2 (en) 2011-03-25 2014-09-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8835563B2 (en) 2011-03-25 2014-09-16 Exxonmobil Chemical Patents Inc. Block copolymers from silylated vinyl terminated macromers
US8399724B2 (en) 2011-03-25 2013-03-19 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin copolymers and methods to produce thereof
US8623974B2 (en) 2011-03-25 2014-01-07 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
CN103747958B (zh) * 2011-08-17 2018-07-03 阿科玛法国公司 多层聚合物结构
US20130165354A1 (en) 2011-12-22 2013-06-27 Exxonmobil Research And Engineering Company Method for improving engine fuel efficiency
WO2013096078A1 (en) 2011-12-22 2013-06-27 Avery Dennison Corporation Flexible barrier films containing cyclic olefins
ES2639287T3 (es) 2011-12-28 2017-10-26 Dow Global Technologies Llc Sellados de apertura fácil esterilizables para películas de envasado
US11607869B2 (en) * 2012-04-13 2023-03-21 Trinseo Europe Gmbh Multilayer polymeric structure
EP2669086A1 (de) 2012-05-28 2013-12-04 Dow Global Technologies LLC Gusssilageschicht mit verbesserten Haftungseigenschaften
AU2013331046B2 (en) 2012-10-19 2015-08-13 Saint-Gobain Adfors Canada, Ltd. Composite tack film
US20170152377A1 (en) * 2014-06-26 2017-06-01 Dow Global Technologies Llc Breathable films and articles incorporating same
WO2016069089A1 (en) 2014-10-29 2016-05-06 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions for elastic applications
WO2016076969A1 (en) 2014-11-12 2016-05-19 Exxonmobil Chemical Patents Inc. Purification of plasticizer and use thereof in a polymer production process and plant
RU2689784C2 (ru) * 2014-11-18 2019-05-29 Кимберли-Кларк Ворлдвайд, Инк. Мягкое и долговечное нетканое полотно
US10155364B2 (en) 2015-05-01 2018-12-18 Avery Dennison Corporation High optics machine direction oriented label facestock
EP3112150A1 (de) 2015-06-30 2017-01-04 Dow Global Technologies LLC Verfahren zur herstellung einer abziehbaren siegelschicht
JP6883025B2 (ja) 2015-09-10 2021-06-02 ダウ キミカ メキシカーナ エセ・アー・デ・セ・ウベ 多層フィルム及び該多層フィルムから作製される物品
WO2017222892A1 (en) 2016-06-22 2017-12-28 Dow Global Technologies Llc Multilayer films, and methods for making said multilayer films
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
US10584297B2 (en) 2016-12-13 2020-03-10 Afton Chemical Corporation Polyolefin-derived dispersants
US10221267B2 (en) 2016-12-13 2019-03-05 Afton Chemical Corporation Microstructure-controlled copolymers of ethylene and C3-C10 alpha-olefins
ES2988126T3 (es) 2018-02-12 2024-11-19 Exxonmobil Chemical Patents Inc Sistema de alimentación de catalizador de metaloceno para procesos de polimerización en solución
WO2019190705A1 (en) * 2018-03-29 2019-10-03 Dow Global Technologies Llc Bicomponent fiber and polymer composition thereof
EP3550321A1 (de) * 2018-04-03 2019-10-09 Centre National de la Recherche Scientifique (CNRS) Materialien mit hoher dielektrizitätskonstante für magnetresonanzbildgebung
WO2020205311A1 (en) 2019-04-05 2020-10-08 Exxonmobil Chemical Patents Inc. Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
US11530279B2 (en) 2019-04-05 2022-12-20 Exxonmobil Chemicals Patents Inc. Broad molecular weight distribution polymer product from loop reactors with intentional thermal gradients
SG11202110447SA (en) 2019-04-05 2021-10-28 Exxonmobil Chemical Patents Inc Controlling molecular weight distribution and chemical composition distribution of a polyolefin product
WO2021034471A1 (en) 2019-08-16 2021-02-25 Exxonmobil Chemical Patents Inc. Producing blocks of block copolymer in a separator downstream of a reactor
WO2021080803A1 (en) 2019-10-22 2021-04-29 Exxonmobil Chemical Patents Inc. Impact copolymer compositions
US20220306849A1 (en) 2019-10-22 2022-09-29 Celanese International Corporation Thermoplastic Vulcanizate Compositions and Processes for the Production Thereof
US11492427B2 (en) 2019-10-29 2022-11-08 ExxonMobile Chemicals Patents Inc. Production of gradient copolymers using monomer and comonomer concentration gradients in a loop reactor
WO2024137004A1 (en) 2022-12-21 2024-06-27 Exxonmobil Chemical Patents Inc. Enhanced polymer devolatilization via controlled foaming

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10298824A (ja) * 1997-04-22 1998-11-10 Chisso Corp 繊維およびそれを用いた繊維成形体
MXPA01011548A (es) * 1999-05-13 2002-07-02 Exxon Chemical Patents Inc Fibras elasticas y articulos hechos de las mismas, incluyendo polimeros de propileno crsitalinos y cristalizables.

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