TWI272288B - Polyoxymethylene moldings having improved resistance to diesel fuel and aggressive gasoline - Google Patents
Polyoxymethylene moldings having improved resistance to diesel fuel and aggressive gasoline Download PDFInfo
- Publication number
- TWI272288B TWI272288B TW089110726A TW89110726A TWI272288B TW I272288 B TWI272288 B TW I272288B TW 089110726 A TW089110726 A TW 089110726A TW 89110726 A TW89110726 A TW 89110726A TW I272288 B TWI272288 B TW I272288B
- Authority
- TW
- Taiwan
- Prior art keywords
- weight
- fuel
- molding
- diesel fuel
- gasoline
- Prior art date
Links
- 239000002283 diesel fuel Substances 0.000 title claims abstract description 14
- 238000000465 moulding Methods 0.000 title claims abstract description 14
- 239000003502 gasoline Substances 0.000 title claims abstract description 11
- -1 Polyoxymethylene Polymers 0.000 title description 12
- 229920006324 polyoxymethylene Polymers 0.000 title description 10
- 229930040373 Paraformaldehyde Natural products 0.000 title description 5
- 239000000446 fuel Substances 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229920001515 polyalkylene glycol Polymers 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 6
- 229920012196 Polyoxymethylene Copolymer Polymers 0.000 claims abstract description 5
- 229920009382 Polyoxymethylene Homopolymer Polymers 0.000 claims abstract description 4
- 229920000642 polymer Polymers 0.000 claims description 5
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 3
- 230000002079 cooperative effect Effects 0.000 claims description 3
- 239000002828 fuel tank Substances 0.000 claims description 3
- 239000012779 reinforcing material Substances 0.000 claims description 3
- 238000009757 thermoplastic moulding Methods 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 4
- 230000000996 additive effect Effects 0.000 claims 1
- 239000000539 dimer Substances 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- 239000012758 reinforcing additive Substances 0.000 claims 1
- 230000007774 longterm Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000009864 tensile test Methods 0.000 description 4
- 229930182556 Polyacetal Natural products 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000004292 cyclic ethers Chemical class 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- UYVWNPAMKCDKRB-UHFFFAOYSA-N 1,2,4,5-tetraoxane Chemical compound C1OOCOO1 UYVWNPAMKCDKRB-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- 229960004256 calcium citrate Drugs 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000109 continuous material Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- TXSUIVPRHHQNTM-UHFFFAOYSA-N n'-(3-methylanilino)-n-phenyliminobenzenecarboximidamide Chemical compound CC1=CC=CC(NN=C(N=NC=2C=CC=CC=2)C=2C=CC=CC=2)=C1 TXSUIVPRHHQNTM-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000005704 oxymethylene group Chemical group [H]C([H])([*:2])O[*:1] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
- C08L59/02—Polyacetals containing polyoxymethylene sequences only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19925491A DE19925491A1 (de) | 1999-06-04 | 1999-06-04 | Polyoxymethylenformteile mit verbesserter Widerstandsfähigkeit gegen Dieselkraftstoff und agressiven Ottokraftstoff |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI272288B true TWI272288B (en) | 2007-02-01 |
Family
ID=7910152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW089110726A TWI272288B (en) | 1999-06-04 | 2000-06-01 | Polyoxymethylene moldings having improved resistance to diesel fuel and aggressive gasoline |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6489388B1 (enExample) |
| EP (1) | EP1057868B1 (enExample) |
| JP (1) | JP4746170B2 (enExample) |
| KR (1) | KR100737172B1 (enExample) |
| BR (1) | BR0002565A (enExample) |
| DE (2) | DE19925491A1 (enExample) |
| ES (1) | ES2234479T3 (enExample) |
| TW (1) | TWI272288B (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19943178A1 (de) * | 1999-09-09 | 2001-03-15 | Ticona Gmbh | Polyoxymethylen mit verbesserter Stabilität gegen Säuren und seine Verwendung |
| WO2001052675A2 (en) * | 2000-01-18 | 2001-07-26 | Stryker Instruments | Air filtration system including a helmet assembly |
| DE10030632A1 (de) * | 2000-06-29 | 2002-01-10 | Basf Ag | Antistatische Polyoxymethylenformmassen |
| DE10030553A1 (de) * | 2000-06-29 | 2002-01-10 | Basf Ag | Stabilisierte thermoplastische Formmassen |
| DE10129535A1 (de) * | 2001-06-21 | 2003-01-09 | Basf Ag | Dieselkraftstoffbeständige Formteile |
| US20030105199A1 (en) * | 2001-11-16 | 2003-06-05 | Mitsubishi Gas Chemical Company, Inc. | Polyoxymethylene resin composition and molded article thereof |
| KR20040061720A (ko) * | 2002-12-31 | 2004-07-07 | 주식회사 코오롱 | 폴리옥시메틸렌 수지 조성물 |
| US20050131124A1 (en) * | 2003-12-15 | 2005-06-16 | Jean-Michel Philippoz | High temperature diesel-resistant polyacetal molded articles |
| KR100523361B1 (ko) * | 2003-12-22 | 2005-10-24 | 한국엔지니어링플라스틱 주식회사 | 내연료성이 우수한 폴리옥시메틸렌 조성물과 이의 성형품 |
| US7625969B2 (en) | 2004-01-21 | 2009-12-01 | Asahi Kasei Chemicals Corporation | Polyacetal resin composition |
| US7396492B2 (en) * | 2006-03-30 | 2008-07-08 | Kenneth Leon Price | Electrically conductive resin compounds based on polyoxymethylene and highly structured carbon black |
| US8128845B2 (en) * | 2006-11-22 | 2012-03-06 | E.I. Du Pont De Nemours And Company | Static dissipative polyacetal compositions |
| BRPI1008523A2 (pt) | 2009-02-11 | 2016-03-08 | Basf Se | "material termoplástico para moldagem, uso dos materiais termoplásticos para moldagem,e, fibras ou peça moldada de qualquer espécie". |
| US8840976B2 (en) | 2010-10-14 | 2014-09-23 | Ticona Llc | VOC or compressed gas containment device made from a polyoxymethylene polymer |
| EP2505609B1 (en) | 2011-04-01 | 2015-01-21 | Ticona GmbH | High impact resistant polyoxymethylene for extrusion blow molding |
| WO2013101624A1 (en) | 2011-12-30 | 2013-07-04 | Ticona Llc | Printable molded articles made from a polyoxymethylene polymer composition |
| DE102012001878A1 (de) * | 2012-02-01 | 2013-08-01 | Veritas Ag | Betriebsstoffleitung mit wenigstens einer Schicht mit Polyoxymethylen |
| US9991021B2 (en) | 2012-12-13 | 2018-06-05 | Ticona Llc | Laser-weldable electrostatically dissipative polyoxymethylene based on stainless steel fibers |
| EP2938673B1 (en) | 2012-12-27 | 2018-10-03 | Ticona LLC | Conductive polyoxymethylene based on stainless steel fibers |
| US9745467B2 (en) | 2012-12-27 | 2017-08-29 | Ticona, Llc | Impact modified polyoxymethylene composition and articles made therefrom that are stable when exposed to ultraviolet light |
| US10030208B2 (en) * | 2013-10-21 | 2018-07-24 | Celanese Sales Germany Gmbh | Intrinsic low friction polyoxymethylene |
| JP5814419B1 (ja) | 2014-04-25 | 2015-11-17 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物、及びこのポリアセタール樹脂組成物の成形品を備える硫黄燃料接触体 |
| WO2016104255A1 (ja) * | 2014-12-22 | 2016-06-30 | 三菱瓦斯化学株式会社 | ポリアセタール樹脂組成物及びその成形体 |
| US10196577B2 (en) | 2015-09-30 | 2019-02-05 | Celanese Sales Germany Gmbh | Low friction squeak free assembly |
| WO2018163098A1 (en) | 2017-03-10 | 2018-09-13 | Celanese Sales Germany Gmbh | Polyester polymer compositions |
| JP6386124B1 (ja) * | 2017-03-31 | 2018-09-05 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物 |
| CN110769729A (zh) * | 2017-05-05 | 2020-02-07 | 提克纳有限责任公司 | 耐化学性的聚甲醛聚合物组合物 |
| WO2020013184A1 (ja) * | 2018-07-11 | 2020-01-16 | 三菱エンジニアリングプラスチックス株式会社 | ポリアセタール樹脂組成物、および、成形品 |
| JP2022150444A (ja) * | 2021-03-26 | 2022-10-07 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物、及びこのポリアセタール樹脂組成物の成形品を備える硫黄燃料接触体 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES485447A0 (es) * | 1978-11-02 | 1980-12-16 | Hoechst Ag | Perfeccionamientos en tuberias de combustible hechas de un sistema compuesto de plasticos. |
| DE2947490A1 (de) | 1979-11-24 | 1981-06-04 | Hoechst Ag, 6000 Frankfurt | Polyoxymethylenfibride und verfahren zu ihrer herstellung |
| DE3303760A1 (de) * | 1983-02-04 | 1984-08-09 | Hoechst Ag, 6230 Frankfurt | Schlagzaeh modifiziertes polyoxymethylen und daraus hergestellte formkoerper |
| US5063263A (en) * | 1989-06-15 | 1991-11-05 | E. I. Du Pont De Nemours And Company | Polyacetal compositions containing a non-meltable polymer stabilizer improved with a minor amount of at least one meltable co-stabilizer and at least one primary antioxidant |
| JP2965660B2 (ja) * | 1990-10-25 | 1999-10-18 | 旭化成工業株式会社 | ポリアセタール樹脂製ガソリンタンク |
| JP2606542B2 (ja) * | 1993-01-20 | 1997-05-07 | 旭化成工業株式会社 | ポリオキシメチレン樹脂組成物 |
| JP3341789B2 (ja) * | 1993-05-12 | 2002-11-05 | 三菱瓦斯化学株式会社 | ポリアセタール樹脂組成物 |
| JP3188082B2 (ja) * | 1993-12-02 | 2001-07-16 | ポリプラスチックス株式会社 | ポリアセタール樹脂製自動車関連部材 |
| JP3140626B2 (ja) * | 1994-02-22 | 2001-03-05 | ポリプラスチックス株式会社 | ポリオキシメチレン組成物及びその成形品 |
| KR970011955A (ko) * | 1995-08-12 | 1997-03-29 | 곽정소 | 고속 응답용 액정표시소자 |
| DE19681504B4 (de) * | 1995-09-06 | 2005-12-29 | Asahi Kasei Kabushiki Kaisha | Polyacetalharzzusammensetzung mit hoher mechanischer Festigkeitsbeständigkeit |
| US6077908A (en) * | 1995-09-07 | 2000-06-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyoxymethylene resin composition |
| JP3285501B2 (ja) * | 1996-10-25 | 2002-05-27 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物 |
| JP3357552B2 (ja) * | 1996-10-25 | 2002-12-16 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物 |
| WO1998021280A1 (en) * | 1996-11-13 | 1998-05-22 | Asahi Kasei Kogyo Kabushiki Kaisha | Resin composition |
| DE19702425A1 (de) | 1997-01-24 | 1998-07-30 | Basf Ag | Dieselkraftstoffbeständige Formteile |
| US5919530A (en) * | 1997-06-30 | 1999-07-06 | Basf Corporation | Process for producing customized thermoplastic resins |
| JPH11130935A (ja) * | 1997-10-30 | 1999-05-18 | Polyplastics Co | 共重合ポリアセタール樹脂組成物及びその成形品 |
| EP0957128B1 (en) * | 1998-05-14 | 2002-10-09 | Mitsubishi Gas Chemical Company, Inc. | Polyoxymethylene resin composition |
-
1999
- 1999-06-04 DE DE19925491A patent/DE19925491A1/de not_active Withdrawn
-
2000
- 2000-05-31 ES ES00111610T patent/ES2234479T3/es not_active Expired - Lifetime
- 2000-05-31 DE DE50009075T patent/DE50009075D1/de not_active Expired - Lifetime
- 2000-05-31 EP EP00111610A patent/EP1057868B1/de not_active Expired - Lifetime
- 2000-06-01 TW TW089110726A patent/TWI272288B/zh not_active IP Right Cessation
- 2000-06-02 JP JP2000166021A patent/JP4746170B2/ja not_active Expired - Fee Related
- 2000-06-02 KR KR1020000030282A patent/KR100737172B1/ko not_active Expired - Lifetime
- 2000-06-02 BR BR0002565-8A patent/BR0002565A/pt not_active IP Right Cessation
- 2000-06-02 US US09/586,036 patent/US6489388B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2001011284A (ja) | 2001-01-16 |
| ES2234479T3 (es) | 2005-07-01 |
| DE50009075D1 (de) | 2005-02-03 |
| JP4746170B2 (ja) | 2011-08-10 |
| EP1057868A2 (de) | 2000-12-06 |
| DE19925491A1 (de) | 2000-12-14 |
| KR100737172B1 (ko) | 2007-07-10 |
| US6489388B1 (en) | 2002-12-03 |
| BR0002565A (pt) | 2001-01-02 |
| EP1057868B1 (de) | 2004-12-29 |
| KR20010039632A (ko) | 2001-05-15 |
| EP1057868A3 (de) | 2001-02-07 |
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