TWI251002B - Hyperbranched copolyamide, composition based on this hyperbranched copolyamide and process for obtaining it - Google Patents
Hyperbranched copolyamide, composition based on this hyperbranched copolyamide and process for obtaining it Download PDFInfo
- Publication number
- TWI251002B TWI251002B TW089108528A TW89108528A TWI251002B TW I251002 B TWI251002 B TW I251002B TW 089108528 A TW089108528 A TW 089108528A TW 89108528 A TW89108528 A TW 89108528A TW I251002 B TWI251002 B TW I251002B
- Authority
- TW
- Taiwan
- Prior art keywords
- patent application
- highly branched
- copolyamine
- monomer
- acid
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 238000000034 method Methods 0.000 title claims description 21
- 239000000178 monomer Substances 0.000 claims abstract description 72
- 229920000642 polymer Polymers 0.000 claims abstract description 62
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 22
- 239000000654 additive Substances 0.000 claims abstract description 18
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 10
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 10
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 3
- 229920000768 polyamine Polymers 0.000 claims description 25
- 125000000524 functional group Chemical group 0.000 claims description 24
- 150000001412 amines Chemical class 0.000 claims description 22
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 claims description 17
- 125000003118 aryl group Chemical group 0.000 claims description 17
- 239000006185 dispersion Substances 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 14
- -1 amine salt Chemical class 0.000 claims description 14
- 238000000465 moulding Methods 0.000 claims description 13
- 230000000996 additive effect Effects 0.000 claims description 12
- 230000000694 effects Effects 0.000 claims description 11
- 238000009987 spinning Methods 0.000 claims description 11
- 238000001125 extrusion Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 9
- 238000007334 copolymerization reaction Methods 0.000 claims description 8
- 239000012071 phase Substances 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 239000006254 rheological additive Substances 0.000 claims description 7
- 239000003381 stabilizer Substances 0.000 claims description 7
- 239000004416 thermosoftening plastic Substances 0.000 claims description 7
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims description 6
- 150000001413 amino acids Chemical class 0.000 claims description 5
- 125000003277 amino group Chemical group 0.000 claims description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 5
- 230000000930 thermomechanical effect Effects 0.000 claims description 5
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 238000007306 functionalization reaction Methods 0.000 claims description 4
- 125000005842 heteroatom Chemical group 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- RJGDLRCDCYRQOQ-UHFFFAOYSA-N anthrone Chemical group C1=CC=C2C(=O)C3=CC=CC=C3CC2=C1 RJGDLRCDCYRQOQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000003607 modifier Substances 0.000 claims description 3
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 claims description 2
- XFDUHJPVQKIXHO-UHFFFAOYSA-N 3-aminobenzoic acid Chemical compound NC1=CC=CC(C(O)=O)=C1 XFDUHJPVQKIXHO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005711 Benzoic acid Substances 0.000 claims description 2
- 239000004472 Lysine Substances 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 238000011835 investigation Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000007790 solid phase Substances 0.000 claims description 2
- 235000001014 amino acid Nutrition 0.000 claims 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 2
- IHWDSEPNZDYMNF-UHFFFAOYSA-N 1H-indol-2-amine Chemical compound C1=CC=C2NC(N)=CC2=C1 IHWDSEPNZDYMNF-UHFFFAOYSA-N 0.000 claims 1
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical group OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 claims 1
- 235000003704 aspartic acid Nutrition 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims 1
- 239000012535 impurity Substances 0.000 claims 1
- MLQPXAQSJNFRRZ-UHFFFAOYSA-N n-decyldodecan-1-amine Chemical compound CCCCCCCCCCCCNCCCCCCCCCC MLQPXAQSJNFRRZ-UHFFFAOYSA-N 0.000 claims 1
- 150000002923 oximes Chemical class 0.000 claims 1
- 239000000052 vinegar Substances 0.000 claims 1
- 235000021419 vinegar Nutrition 0.000 claims 1
- 230000000007 visual effect Effects 0.000 claims 1
- CDBAMNGURPMUTG-UHFFFAOYSA-N 4-[2-(4-hydroxycyclohexyl)propan-2-yl]cyclohexan-1-ol Chemical class C1CC(O)CCC1C(C)(C)C1CCC(O)CC1 CDBAMNGURPMUTG-UHFFFAOYSA-N 0.000 abstract description 15
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- KBZFDRWPMZESDI-UHFFFAOYSA-N 5-aminobenzene-1,3-dicarboxylic acid Chemical compound NC1=CC(C(O)=O)=CC(C(O)=O)=C1 KBZFDRWPMZESDI-UHFFFAOYSA-N 0.000 abstract description 7
- UENRXLSRMCSUSN-UHFFFAOYSA-N 3,5-diaminobenzoic acid Chemical compound NC1=CC(N)=CC(C(O)=O)=C1 UENRXLSRMCSUSN-UHFFFAOYSA-N 0.000 abstract description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract 2
- 150000003951 lactams Chemical class 0.000 abstract 1
- 239000004034 viscosity adjusting agent Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 50
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000002609 medium Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 239000004952 Polyamide Substances 0.000 description 5
- 239000000412 dendrimer Substances 0.000 description 5
- 229920000736 dendritic polymer Polymers 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 229920002647 polyamide Polymers 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920000265 Polyparaphenylene Polymers 0.000 description 3
- 229940024606 amino acid Drugs 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000004305 biphenyl Substances 0.000 description 3
- 235000010290 biphenyl Nutrition 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
- 229920002098 polyfluorene Polymers 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 230000002194 synthesizing effect Effects 0.000 description 3
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 206010036790 Productive cough Diseases 0.000 description 2
- 229920006090 Sniamid® Polymers 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000006267 biphenyl group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 210000003802 sputum Anatomy 0.000 description 2
- 208000024794 sputum Diseases 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 150000003628 tricarboxylic acids Chemical class 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- WTFAGPBUAGFMQX-UHFFFAOYSA-N 1-[2-[2-(2-aminopropoxy)propoxy]propoxy]propan-2-amine Chemical compound CC(N)COCC(C)OCC(C)OCC(C)N WTFAGPBUAGFMQX-UHFFFAOYSA-N 0.000 description 1
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 1
- LDOMKUVUXZRECL-UHFFFAOYSA-N 2-aminobenzene-1,3-dicarboxylic acid Chemical compound NC1=C(C(O)=O)C=CC=C1C(O)=O LDOMKUVUXZRECL-UHFFFAOYSA-N 0.000 description 1
- IHXWECHPYNPJRR-UHFFFAOYSA-N 3-hydroxycyclobut-2-en-1-one Chemical compound OC1=CC(=O)C1 IHXWECHPYNPJRR-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- CYQNLOGQMXTRSY-UHFFFAOYSA-N 6-aminoundecanedioic acid Chemical compound OC(=O)CCCCC(N)CCCCC(O)=O CYQNLOGQMXTRSY-UHFFFAOYSA-N 0.000 description 1
- 241000208140 Acer Species 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 241000284156 Clerodendrum quadriloculare Species 0.000 description 1
- 239000007818 Grignard reagent Substances 0.000 description 1
- 101100264174 Mus musculus Xiap gene Proteins 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000208422 Rhododendron Species 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 101100002079 Schizosaccharomyces pombe (strain 972 / ATCC 24843) arb2 gene Proteins 0.000 description 1
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229940009098 aspartate Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- ZADPBFCGQRWHPN-UHFFFAOYSA-N boronic acid Chemical compound OBO ZADPBFCGQRWHPN-UHFFFAOYSA-N 0.000 description 1
- 229920005605 branched copolymer Polymers 0.000 description 1
- 238000007707 calorimetry Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000012738 dissolution medium Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229930004069 diterpene Natural products 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 238000009730 filament winding Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 150000004795 grignard reagents Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229960001915 hexamidine Drugs 0.000 description 1
- OQLKNTOKMBVBKV-UHFFFAOYSA-N hexamidine Chemical compound C1=CC(C(=N)N)=CC=C1OCCCCCCOC1=CC=C(C(N)=N)C=C1 OQLKNTOKMBVBKV-UHFFFAOYSA-N 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- AWKZQVYCCQCKBH-UHFFFAOYSA-N hydrazine 1-methylpyrrolidin-2-one Chemical compound CN1C(CCC1)=O.NN AWKZQVYCCQCKBH-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- RTWNYYOXLSILQN-UHFFFAOYSA-N methanediamine Chemical compound NCN RTWNYYOXLSILQN-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229930003658 monoterpene Natural products 0.000 description 1
- 235000002577 monoterpenes Nutrition 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- FWWQKRXKHIRPJY-UHFFFAOYSA-N octadecyl aldehyde Natural products CCCCCCCCCCCCCCCCCC=O FWWQKRXKHIRPJY-UHFFFAOYSA-N 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 229940105131 stearamine Drugs 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/002—Dendritic macromolecules
- C08G83/005—Hyperbranched macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/04—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/28—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/005—Dendritic macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyamides (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- External Artificial Organs (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9905885A FR2793252B1 (fr) | 1999-05-05 | 1999-05-05 | Copolyamide hyperbranche, composition a base de ce copolyamide hyperbranche et procede d'obtention de ce dernier |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI251002B true TWI251002B (en) | 2006-03-11 |
Family
ID=9545376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW089108528A TWI251002B (en) | 1999-05-05 | 2000-05-04 | Hyperbranched copolyamide, composition based on this hyperbranched copolyamide and process for obtaining it |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US6872800B1 (enExample) |
| EP (1) | EP1183301B1 (enExample) |
| JP (1) | JP3766595B2 (enExample) |
| KR (1) | KR100507419B1 (enExample) |
| CN (1) | CN1174029C (enExample) |
| AT (1) | ATE253612T1 (enExample) |
| AU (1) | AU4414000A (enExample) |
| BR (1) | BR0011196B1 (enExample) |
| CA (1) | CA2373024A1 (enExample) |
| CZ (1) | CZ20013958A3 (enExample) |
| DE (1) | DE60006383T2 (enExample) |
| ES (1) | ES2204577T3 (enExample) |
| FR (1) | FR2793252B1 (enExample) |
| HU (1) | HUP0201073A2 (enExample) |
| IL (2) | IL146295A0 (enExample) |
| PL (1) | PL351817A1 (enExample) |
| RU (1) | RU2223287C2 (enExample) |
| SK (1) | SK16002001A3 (enExample) |
| TR (1) | TR200200166T2 (enExample) |
| TW (1) | TWI251002B (enExample) |
| WO (1) | WO2000068298A1 (enExample) |
Families Citing this family (70)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2812868B1 (fr) * | 2000-08-09 | 2003-03-07 | Rhodianyl | Materiau de construction comprenant un renfort fibreux ou filamentaire |
| FR2831189B1 (fr) * | 2001-10-23 | 2003-12-12 | Rhodianyl | Procede de fabrication de fils, fibres et filaments |
| PL211893B1 (pl) * | 2001-02-22 | 2012-07-31 | Rhodia Polyamide Intermediates | Sposób wytwarzania syntetycznych przędz, włókien i włókien ciągłych na bazie poliamidu oraz przędze, włókna i włókna ciągłe możliwe do otrzymania tym sposobem |
| FR2821088B1 (fr) * | 2001-02-22 | 2003-04-11 | Rhodianyl | Procede de fabrication de fils, fibres et filaments |
| DE10158149A1 (de) * | 2001-11-28 | 2003-06-18 | Bayer Ag | Silangruppen enthaltende Polymere |
| FR2833603A1 (fr) * | 2001-12-17 | 2003-06-20 | Rhodianyl | Composition polymere thermoplastique comprenant un copolyamide hyperbranche, et articles realises a partir de cette composition |
| WO2003051993A1 (fr) * | 2001-12-17 | 2003-06-26 | Rhodianyl | Composition thermoplastique comprenant un additif polymere hyperbranche, articles realises a partir de ce materiau |
| FR2833604B1 (fr) * | 2001-12-17 | 2004-03-12 | Rhodianyl | Composition polymere thermoplastique comprenant un copolyamide hyperbranche, et articles realises a partir de cette composition |
| KR20040111512A (ko) * | 2002-04-15 | 2004-12-31 | 디에스엠 아이피 어셋츠 비.브이. | 블로우 성형된 다층 필름과 이의 제조 방법 |
| FR2840622B1 (fr) * | 2002-06-11 | 2004-07-23 | Rhodia Chimie Sa | Composition pour le traitement des articles en fibres textiles comprenant un polymere dendritique |
| FR2841253B1 (fr) * | 2002-06-21 | 2004-10-22 | Rhodia Polyamide Intermediates | Composition polyamide expansible et mousse polyamide obtenue a partir de cette composition |
| DE10251294B4 (de) * | 2002-11-04 | 2007-05-16 | Ems Chemie Ag | Polyamidformmasse und deren Verwendung |
| FR2847902B1 (fr) | 2002-11-29 | 2007-02-16 | Rhodia Eng Plastics Srl | Composition a base de matrice thermoplastique |
| FR2851252B1 (fr) * | 2003-02-14 | 2007-03-09 | Rhodianyl | Composition comprenant une matrice polymerique et un additif fonctionnalise et articles realises a partir de cette composition |
| EP1667636A2 (fr) * | 2003-09-29 | 2006-06-14 | Rhodia Chimie | Emulsions comprenant un polymere dendritique et utilisation d'un polymere dendritique comme agent d emulsification |
| WO2005032498A2 (fr) * | 2003-09-29 | 2005-04-14 | Rhodia Chimie | Composition aqueuse comprenant un polymere dentrique polyonique et un agent tensioactif ionique |
| WO2006040443A1 (fr) * | 2004-10-08 | 2006-04-20 | Rhodia Chimie | Procede de preparation de particules a base de polymere thermoplastique et poudre ainsi obtenue. |
| US7224050B2 (en) * | 2005-05-25 | 2007-05-29 | Intel Corporation | Plastic materials including dendrimers or hyperbranched polymers for integrated circuit packaging |
| FR2899591B1 (fr) * | 2006-04-10 | 2008-05-23 | Rhodia Recherches & Tech | Procede de preparation de particules a base de polymere thermoplastique et poudre ainsi obtenue |
| CN100532420C (zh) * | 2006-11-30 | 2009-08-26 | 中国科学院长春应用化学研究所 | 一种采用超支化聚合物改性聚乳酸的方法 |
| JP4992610B2 (ja) * | 2007-08-23 | 2012-08-08 | 東レ株式会社 | 繊維 |
| EP2265673B1 (en) | 2008-03-14 | 2019-05-08 | 3D Systems, Inc. | Powder compositions and methods of manufacturing articles therefrom |
| US20100113669A1 (en) * | 2008-10-30 | 2010-05-06 | E.I. Du Pont De Nemours And Company | Thermoplastic composition including hyperbranched aromatic polyamide |
| FR2944288B1 (fr) | 2009-04-10 | 2012-08-17 | Rhodia Operations | Materiau polyamide a proprietes barrieres aux fluides elevees |
| FR2947278B1 (fr) | 2009-06-30 | 2012-06-22 | Rhodia Operations | Composition polyamide modifiee comprenant au moins un compose phenolique |
| BRPI1010218B1 (pt) | 2009-07-03 | 2020-10-13 | Performance Polyamides, Sas | poliamida funcionalizada com sulfonato, processo de preparação da poliamida funcionalizada, composição de polímero termoplástico e artigo |
| FR2947556B1 (fr) | 2009-07-03 | 2011-07-15 | Rhodia Operations | Composition polyamide modifiee |
| FR2950626B1 (fr) * | 2009-09-30 | 2013-11-08 | Rhodia Operations | Polyamides a fluidite elevee |
| FR2951452B1 (fr) | 2009-10-16 | 2012-07-27 | Rhodia Operations | Article moule ignifuge a base de polyamide comprenant un revetement intumescent |
| FR2951451B1 (fr) | 2009-10-20 | 2012-10-19 | Rhodia Operations | Composition polyamide modifiee comprenant au moins un compose phenolique |
| CN101693749B (zh) * | 2009-10-22 | 2011-10-05 | 浙江大学 | 一种制备超支化乙烯基或丙烯基酰胺类聚合物的方法 |
| FR2953849B1 (fr) | 2009-12-16 | 2012-11-16 | Rhodia Operations | Composition polyamide de faible conductivite thermique |
| FR2958296B1 (fr) * | 2010-04-06 | 2013-08-16 | Rhodia Operations | Composition polyamide de haute viscosite |
| FR2958652B1 (fr) | 2010-04-13 | 2013-09-06 | Rhodia Operations | Composition thermoplastique a base de polyamide et de polycetone. |
| FR2960545B1 (fr) | 2010-05-28 | 2014-11-28 | Rhodia Operations | Polyamide modifie sulfonate aux proprietes barrieres ameliorees |
| FR2969160B1 (fr) | 2010-12-16 | 2014-04-18 | Rhodia Operations | Copolymere polyamide-polyolefine |
| FR2969162B1 (fr) | 2010-12-21 | 2014-04-18 | Rhodia Operations | Article ignifuge a base de polyamide comprenant un revetement par traitement plasma |
| CN103764765B (zh) | 2011-08-26 | 2018-09-18 | 罗地亚运作公司 | 聚酰胺与聚酯树脂混合物的阻燃组合物 |
| FR2988394B1 (fr) | 2012-03-26 | 2015-12-11 | Rhodia Operations | Agent fluidifiant et procede utilisant cet agent |
| FR2993270B1 (fr) | 2012-07-12 | 2015-08-07 | Rhodia Operations | Procede de moussage chimique en presence de charges de renfort |
| FR2996556A1 (fr) * | 2012-10-10 | 2014-04-11 | Rhodia Operations | Liner pour reservoir cng |
| WO2014056887A1 (en) | 2012-10-10 | 2014-04-17 | Rhodia Operations | Gas storage tank |
| CN104884504B (zh) * | 2012-12-31 | 2017-08-29 | 可隆工业株式会社 | 交联聚合物、聚合物树脂组合物以及聚合物膜 |
| WO2014121842A1 (fr) | 2013-02-08 | 2014-08-14 | Rhodia Operations | Composition d'un alliage de resines de polyamide et de polyester |
| AU2013204225A1 (en) * | 2013-04-12 | 2014-10-30 | Steripak Pty Ltd | Degradable and biodegradable plastic material and a method for making it |
| FR3006318A1 (fr) | 2013-06-03 | 2014-12-05 | Rhodia Operations | Charges en tant qu'agent permettant de diminuer la deterioration de proprietes barrieres |
| EP2848652A1 (en) | 2013-09-17 | 2015-03-18 | Rhodia Operations | Polyamide based composition containing polyketone and rubber |
| FR3030548B1 (fr) | 2014-12-22 | 2018-03-30 | Rhodia Operations | Composition thermoplastique a haute fluidite |
| WO2017110918A1 (ja) * | 2015-12-25 | 2017-06-29 | 東レ株式会社 | 末端変性ポリアミド樹脂およびその製造方法 |
| CN107474351A (zh) * | 2016-06-07 | 2017-12-15 | 中国石油化工股份有限公司 | 高密度聚乙烯组合物及其制备方法 |
| FR3053696B1 (fr) * | 2016-07-11 | 2018-07-06 | Arkema France | Composition de polyamide semi-cristallin de haute temperature de transition vitreuse pour materiau composite, son procede de fabrication et ses utilisations |
| KR102436777B1 (ko) | 2016-07-13 | 2022-08-26 | 퍼포먼스 폴리아미드 에스에이에스 | 폴리아미드 조성물의 할로겐-함유 산화제에 대한 내성을 증가시키는 방법 |
| CN107083030A (zh) * | 2017-06-02 | 2017-08-22 | 浙江华杰材料科技有限公司 | 一种低翘曲高强度玻纤增强pbt/asa合金材料及其制备方法 |
| CN108559074B (zh) * | 2018-03-26 | 2020-09-25 | 中国石油化工股份有限公司 | 一种支化尼龙6的连续聚合工艺及其产品 |
| CN108586729B (zh) * | 2018-03-26 | 2020-09-22 | 中国石油化工股份有限公司 | 一种支化尼龙的制备方法、复合薄膜及其制备方法 |
| CN109694478A (zh) * | 2018-12-28 | 2019-04-30 | 上海华谊树脂有限公司 | 一种超支化聚酰胺及其制备方法和用途 |
| CN113906007A (zh) | 2019-03-26 | 2022-01-07 | 银杏生物制品公司 | 10-亚甲基脂质的衍生物，该类衍生物的制备方法及其用途 |
| CN113493938B (zh) * | 2020-04-01 | 2023-06-06 | 苏州合祥纺织科技有限公司 | 一种γ-PGA纳米纤维的制备方法 |
| KR102220037B1 (ko) * | 2020-06-24 | 2021-02-25 | 주식회사 성진테크윈 | 덴드리머고분자 제조방법 |
| JP7596733B2 (ja) * | 2020-11-16 | 2024-12-10 | 東レ株式会社 | ポリアミド樹脂粉粒体、その製造方法、およびポリアミド樹脂粉粒体を用いた三次元造形物の製造方法 |
| CN112745672B (zh) * | 2020-12-16 | 2022-06-14 | 金发科技股份有限公司 | 一种聚酰胺模塑组合物及其制备方法和应用 |
| CN114106320B (zh) * | 2021-04-12 | 2023-09-19 | 惠生(中国)投资有限公司 | 一种全芳香族耐高温尼龙及其制备方法和用途 |
| CN116157472A (zh) * | 2021-07-13 | 2023-05-23 | 东丽先端材料研究开发（中国）有限公司 | 末端改性聚酰胺树脂、其制备方法、组合物及成型品 |
| CN114921224B (zh) * | 2022-02-07 | 2023-06-13 | 浙江大学杭州国际科创中心 | 一种基于超支化聚合物的黏合剂的制备方法 |
| CN115926134B (zh) * | 2022-11-14 | 2023-11-10 | 百达联康生物科技(深圳)有限公司 | 一种阳离子聚酯及其制备方法和应用 |
| CN115975378B (zh) * | 2022-12-14 | 2023-11-28 | 苏州优利金新材料有限公司 | 一种耐高温的二氧化硅改性尼龙材料的制备方法和应用 |
| CN117024731B (zh) * | 2023-08-10 | 2025-12-02 | 会通新材料(上海)有限公司 | 一种四臂星形结构长链聚酰胺及其制备方法 |
| CN117229497B (zh) * | 2023-09-28 | 2024-03-29 | 中国科学院宁波材料技术与工程研究所 | 一种超支化聚酰胺树脂及其制备方法和应用 |
| CN117247539B (zh) * | 2023-09-28 | 2024-03-22 | 中国科学院宁波材料技术与工程研究所 | 一种超支化聚酯酰胺多元醇及其制备方法和应用 |
| CN118292136B (zh) * | 2024-06-05 | 2024-08-30 | 烟台泰和新材高分子新材料研究院有限公司 | 一种提高日晒牢度的改性间位芳纶纤维及制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0558556B1 (en) * | 1990-11-19 | 1997-04-23 | Cornell Research Foundation, Inc. | Hyperbranched polyesters |
| US5264543A (en) * | 1991-10-30 | 1993-11-23 | E. I. Du Pont De Nemours And Company | Hyperbranched aramid |
| BE1007260A3 (nl) * | 1993-07-08 | 1995-05-02 | Dsm Nv | Werkwijze voor het bereiden van een dendritisch macromolekuul. |
| US5493000A (en) * | 1992-02-21 | 1996-02-20 | Alliedsignal Inc. | Fractal polymers and graft copolymers formed from same |
| US5480944A (en) | 1993-08-23 | 1996-01-02 | Alliedsignal Inc. | Interpenetrating blends of linear polymers and compatible fractal polymers |
| US5587441A (en) * | 1994-11-08 | 1996-12-24 | Cornell Research Foundation, Inc. | Hyperbranched polymers from AB monomers |
| CA2208840C (en) * | 1995-10-27 | 2001-06-19 | Mitsui Petrochemical Industries, Ltd. | Semiaromatic polyamides, processes for preparing the same and compositions containing the same |
| FR2766197B1 (fr) * | 1997-07-17 | 1999-09-03 | Nyltech Italia | Copolyamide thermoplastique, composition a base de ce copolyamide thermoplastique |
| US6541599B1 (en) * | 2001-07-31 | 2003-04-01 | Eastman Kodak Company | Process for manufacture of soluble highly branched polyamides, and at least partially aliphatic highly branched polyamides obtained therefrom |
-
1999
- 1999-05-05 FR FR9905885A patent/FR2793252B1/fr not_active Expired - Fee Related
-
2000
- 2000-05-04 TW TW089108528A patent/TWI251002B/zh not_active IP Right Cessation
- 2000-05-05 IL IL14629500A patent/IL146295A0/xx unknown
- 2000-05-05 CA CA002373024A patent/CA2373024A1/fr not_active Abandoned
- 2000-05-05 DE DE60006383T patent/DE60006383T2/de not_active Expired - Lifetime
- 2000-05-05 SK SK1600-2001A patent/SK16002001A3/sk unknown
- 2000-05-05 CN CNB008085587A patent/CN1174029C/zh not_active Expired - Fee Related
- 2000-05-05 CZ CZ20013958A patent/CZ20013958A3/cs unknown
- 2000-05-05 ES ES00925407T patent/ES2204577T3/es not_active Expired - Lifetime
- 2000-05-05 WO PCT/FR2000/001229 patent/WO2000068298A1/fr not_active Ceased
- 2000-05-05 TR TR2002/00166T patent/TR200200166T2/xx unknown
- 2000-05-05 HU HU0201073A patent/HUP0201073A2/hu unknown
- 2000-05-05 JP JP2000616267A patent/JP3766595B2/ja not_active Expired - Fee Related
- 2000-05-05 AU AU44140/00A patent/AU4414000A/en not_active Abandoned
- 2000-05-05 KR KR10-2001-7014120A patent/KR100507419B1/ko not_active Expired - Fee Related
- 2000-05-05 EP EP00925407A patent/EP1183301B1/fr not_active Expired - Lifetime
- 2000-05-05 PL PL00351817A patent/PL351817A1/xx not_active IP Right Cessation
- 2000-05-05 BR BRPI0011196-1A patent/BR0011196B1/pt not_active IP Right Cessation
- 2000-05-05 US US09/959,710 patent/US6872800B1/en not_active Expired - Lifetime
- 2000-05-05 RU RU2001132726/04A patent/RU2223287C2/ru not_active IP Right Cessation
- 2000-05-05 AT AT00925407T patent/ATE253612T1/de not_active IP Right Cessation
-
2001
- 2001-11-01 IL IL146295A patent/IL146295A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| RU2001132726A (ru) | 2004-02-20 |
| SK16002001A3 (sk) | 2002-05-09 |
| PL351817A1 (en) | 2003-06-16 |
| ES2204577T3 (es) | 2004-05-01 |
| DE60006383D1 (de) | 2003-12-11 |
| KR20020016784A (ko) | 2002-03-06 |
| CA2373024A1 (fr) | 2000-11-16 |
| AU4414000A (en) | 2000-11-21 |
| JP2002544307A (ja) | 2002-12-24 |
| CN1174029C (zh) | 2004-11-03 |
| FR2793252A1 (fr) | 2000-11-10 |
| BR0011196B1 (pt) | 2010-03-09 |
| IL146295A0 (en) | 2002-07-25 |
| JP3766595B2 (ja) | 2006-04-12 |
| EP1183301B1 (fr) | 2003-11-05 |
| CN1354767A (zh) | 2002-06-19 |
| KR100507419B1 (ko) | 2005-08-11 |
| TR200200166T2 (tr) | 2002-04-22 |
| DE60006383T2 (de) | 2004-09-16 |
| RU2223287C2 (ru) | 2004-02-10 |
| EP1183301A1 (fr) | 2002-03-06 |
| CZ20013958A3 (cs) | 2002-04-17 |
| HUP0201073A2 (en) | 2002-07-29 |
| FR2793252B1 (fr) | 2001-07-20 |
| IL146295A (en) | 2010-05-31 |
| BR0011196A (pt) | 2002-02-19 |
| WO2000068298A1 (fr) | 2000-11-16 |
| US6872800B1 (en) | 2005-03-29 |
| ATE253612T1 (de) | 2003-11-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI251002B (en) | Hyperbranched copolyamide, composition based on this hyperbranched copolyamide and process for obtaining it | |
| TWI270564B (en) | Thermoplastic polymer composition comprising a hyperbranched polymer, and articles from this composition | |
| TWI280966B (en) | Thermoplastic composition comprising a hyperbranched polymer additive bearing incompatible functions, and articles made from this material | |
| CN103635510B (zh) | 具有不同嵌段的支链聚酰胺 | |
| CN102203166B (zh) | 增强聚酰胺组合物 | |
| EP2451864A1 (fr) | Article polyamide composite | |
| JPH04227632A (ja) | 新規なポリエーテルアミド及びその製法 | |
| CN104411742A (zh) | 水分散性聚酰胺粉末 | |
| JPH0286623A (ja) | 熱互変性芳香族コポリエステルアミドの製造方法 | |
| CN103172855B (zh) | 一种乳酸-氨基酸共聚聚酯酰胺及其制备方法 | |
| JP2004519532A (ja) | 溶融性ポリエステルの製造方法 | |
| WO2019121824A1 (en) | Piperidine-containing semi-aromatic copolyamide | |
| TW534897B (en) | Building material comprising a fibrous or filamentary reinforcement | |
| TWI222476B (en) | Process for manufacturing yarns, fibres and filaments | |
| US20230203308A1 (en) | Preparation method of branched polyamide (pa) copolymer with ultra-high toughness, pa copolymer prepared using the method, and use of the pa copolymer | |
| CN102884104B (zh) | 制备pa-4x的方法和通过该方法可得的pa-410 | |
| JP4824911B2 (ja) | ヒドロゲル、架橋ヒドロゲル及びそれらの製造方法 | |
| EP0994157A1 (en) | Molecular reinforced polymeric composition | |
| JPH02115226A (ja) | 固相後縮合による分枝鎖状（コ）ポリアミド類の製造方法 | |
| CA2444904A1 (en) | Polyamide molding materials for producing transparent films | |
| CN100584875C (zh) | 复合材料前体和复合材料,它们的制造方法和用途 | |
| JPS59197429A (ja) | ポリエステル−ポリアミドブロツク重合体類の製造方法 | |
| MXPA01011205A (en) | Hyperbranched copolyamide, composition based on said hyperbranched copolyamide and method for obtaining same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |