TW552257B - Process for the carbonylation of ethylene - Google Patents

Process for the carbonylation of ethylene Download PDF

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Publication number
TW552257B
TW552257B TW087103149A TW87103149A TW552257B TW 552257 B TW552257 B TW 552257B TW 087103149 A TW087103149 A TW 087103149A TW 87103149 A TW87103149 A TW 87103149A TW 552257 B TW552257 B TW 552257B
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TW
Taiwan
Prior art keywords
ethylene
carbon monoxide
catalyst system
group
carbonylation
Prior art date
Application number
TW087103149A
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English (en)
Inventor
Jean Margaret Pearson
Raymond Anthony Hadden
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Lucite Int Uk Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5027—Polyphosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Steroid Compounds (AREA)
  • Catalysts (AREA)
  • Polyethers (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Description

552257
(b)種二齒膦具通式（〗） R1 R12
其中 Μ是一個第三碳原子； R ’ R3 ’ R4，R5，R6，R7，r8，R9，R10 , R11 及 R12 久 二 、竭互是一個側選擇性取代有機基團其有一個 碳原子該基團經該碳原子連接至各該rG ; T 1 2 及L各獨互是一個連接基團選自一個選擇性取代低 伸燒基鍵連接各該磷原子至該基團X;及 — X是一個橋接基團含一個選擇性取代芳基分子磷原子 是連接至其可用的鄰接碳原子；及 (c) 一種陰離子其是基本上不與鈀離子配價及是衍生自 種p K a測疋於水溶液低於4之酸之一種組配。 8·根據申請專利範圍第7項之方法，其中該側選擇性取代 ____ _2- 本紙張尺度適用中國國家標準(CNS) A4規格(210 X 297公釐) 552257 A8 B8 C8
有機基團 R1 , R2，R3 , R4，R5，r6，r7，r8，r9 >
RlG ’ Rl1及Rl2是選擇性取代低烷基。 9·根據申請專利範圍第7項之方法，其中該有機基團r1， R2 ’ R3 ’ R4，R5，R6，R7，R8，R9，R10，Rll 及 R12是與其各別R〇碳原子缔合是以形成複合基團其是立 體阻至少如第三-丁基。 10·根據申請專利範圍第8項之方法，其中該有機基團r1， R2 , R3，R4，r5，r6，r7 , r8 , r9，Rl〇 ,尺"及 R疋與其各別R G碳原子缔合是以形成複合基團其是立 體阻至少如第三-丁基β 11.根據申凊專利範圍第7項之方法，其中該連接基團L i及 L2是伸甲基。 12·根據申請專利範圍第7項之方法，其中該二齒配位子是 選自α，α、二（二-第三-丁基膦基）_鄰-二甲苯，α，α，·二 (二新戊基膦基）-鄰-二甲苯及2,3-二（二-第三-丁基膦基 甲基）莕。 13· —種製造丙酸甲酯之方法，其包括以下步驟： (i)自乙婦進料流與一氧化碳進料流形成一個氣相； (i i)該氣相在一種包含甲醇，一種溶劑及一種催化劑 系統其含Ιε，或其一種化合物，及一種二齒膦配位子及 陰離子之一種來源之液相内與一種催化劑系統接觸；及 (i i i)在該甲醇及該催化劑系統之存在下該乙烯與該 一氧化碳反應； 特徵在於該乙晞進料流與一氧化碳進料流提供在該氣 _-3- 本紙張尺度適用中國國家標準(CNS) A4規格(210X 297公釐) 552257 as B8 C8 D8 六、申請專利範圍 相中乙稀對一氧化碳之莫耳比是大於1 : 1，及，該陰離 子是以一或多種於水溶液中測量為具有少於4之p K a值 之酸加入者。 -4- 本紙張尺度適用中國國家標準(CNS) A4規格(210X 297公釐)
TW087103149A 1997-03-19 1998-03-04 Process for the carbonylation of ethylene TW552257B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GBGB9705699.8A GB9705699D0 (en) 1997-03-19 1997-03-19 Process for the carbonylation of ethylene

Publications (1)

Publication Number Publication Date
TW552257B true TW552257B (en) 2003-09-11

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ID=10809517

Family Applications (1)

Application Number Title Priority Date Filing Date
TW087103149A TW552257B (en) 1997-03-19 1998-03-04 Process for the carbonylation of ethylene

Country Status (20)

Country Link
US (1) US6284919B1 (zh)
EP (1) EP0970038B2 (zh)
JP (1) JP4143133B2 (zh)
KR (1) KR100540952B1 (zh)
CN (1) CN1245371C (zh)
AT (1) ATE215928T1 (zh)
AU (1) AU737772C (zh)
BR (1) BR9808354A (zh)
CA (1) CA2282515C (zh)
CZ (1) CZ295078B6 (zh)
DE (1) DE69804776T3 (zh)
ES (1) ES2172114T5 (zh)
GB (1) GB9705699D0 (zh)
HU (1) HU226818B1 (zh)
ID (1) ID24681A (zh)
MY (1) MY124656A (zh)
PT (1) PT970038E (zh)
TW (1) TW552257B (zh)
WO (1) WO1998041495A1 (zh)
ZA (1) ZA981982B (zh)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8445711B2 (en) 2006-04-13 2013-05-21 Lucite International Uk Limited Metal complexes
TWI415682B (zh) * 2005-08-12 2013-11-21 Lucite Int Uk Ltd 經改良之催化劑系統
US8816113B2 (en) 2008-07-04 2014-08-26 Lucite International Uk Limited Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporating such ligands
US8969560B2 (en) 2010-01-05 2015-03-03 Lucite International Uk Limited Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporating such ligands
US9040445B2 (en) 2004-02-18 2015-05-26 Lucite International Uk Limited Catalyst system
TWI487569B (zh) * 2005-11-17 2015-06-11 Lucite Int Uk Ltd 乙烯系不飽和化合物之羰基化作用
TWI506017B (zh) * 2009-12-15 2015-11-01 Lucite Int Uk Ltd 乙烯羰基化之連續製程
US9809611B2 (en) 2006-12-02 2017-11-07 Lucite International Uk Limited Carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds

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US6489506B2 (en) * 1997-03-19 2002-12-03 Lucite International Uk Limited Process for the palladium and phosphine ligand catalyzed carbonylation of ethylene
GB9918229D0 (en) * 1999-08-04 1999-10-06 Ici Plc Improvements relating to metal-compound catalysed processes
JP2002019268A (ja) * 2000-07-03 2002-01-23 Nippon Aerosil Co Ltd インクジェット記録媒体のインク吸収層形成用超微粒セラミック粉末凝集体分散水
TWI301481B (en) * 2002-08-10 2008-10-01 Lucite Int Uk Ltd A catalyst system
JP2007516197A (ja) 2003-07-03 2007-06-21 ルーサイト インターナショナル ユーケー リミテッド エチレン性不飽和化合物のヒドロホルミル化方法
EP1656336B1 (en) * 2003-07-25 2007-08-15 DSM IP Assets B.V. Process for the carbonylation of conjugated dienes using a palladium catalyst system
GB0411951D0 (en) * 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
GB0625518D0 (en) * 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
EP2025660A3 (en) * 2007-08-14 2009-03-04 Rohm and Haas Company Processes for producing ethylene and carbon monoxide mixtures from ethane
JP5058915B2 (ja) * 2007-09-20 2012-10-24 ローム アンド ハース カンパニー エタンからエチレン及び一酸化炭素の混合物を製造するための触媒プロセス
EP2165997A1 (en) * 2008-09-18 2010-03-24 Rohm and Haas Company Improved process for the oxidative dehydrogenation of ethane
GB0921876D0 (en) * 2009-12-15 2010-01-27 Lucite Int Uk Ltd Improved carbonylation process
DE102010002809A1 (de) 2010-03-12 2011-11-17 Evonik Degussa Gmbh Verfahren zur Herstellung von linearen alpha,omega-Dicarbonsäurediestern
BR112014004595A2 (pt) * 2011-09-01 2017-03-21 Dsm Ip Assets Bv processo para a carbonilação de alquenos opcionalmente funcionalizados
GB201122054D0 (en) * 2011-12-21 2012-02-01 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
US9273020B2 (en) * 2012-05-02 2016-03-01 Haldor Topsoe A/S Process for the production of chemical compounds from carbon dioxide
CN105636928B (zh) 2013-09-30 2018-11-27 陶氏环球技术有限责任公司 链烷酸烷基酯的气相生产
ES2709386T3 (es) 2014-06-24 2019-04-16 Dow Global Technologies Llc Proceso para producir agentes coalescentes con contenidos bajos de COV
TW201634430A (zh) * 2015-03-26 2016-10-01 陶氏全球科技責任有限公司 烷酸烷酯之氣相產生
CN108003022B (zh) * 2016-11-02 2020-01-07 中国科学院大连化学物理研究所 一种制备酯类化合物的方法
CN108003024B (zh) * 2016-11-02 2019-10-18 中国科学院大连化学物理研究所 一种丙酸甲酯的制备方法
CN108003023B (zh) * 2016-11-02 2019-10-18 中国科学院大连化学物理研究所 一种制备丙酸甲酯的方法
CN111087306B (zh) 2019-12-27 2021-08-03 南京诚志清洁能源有限公司 芳基双齿膦配体组合催化制备有机羧酸酯的方法
CN114618521B (zh) * 2020-12-11 2023-05-09 中国科学院大连化学物理研究所 一种负载型双金属核壳结构催化剂制备丙酸甲酯的方法

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KR880007426A (ko) * 1986-12-24 1988-08-27 오노 알버어스 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법
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EP0495547B1 (en) † 1991-01-15 1996-04-24 Shell Internationale Researchmaatschappij B.V. Carbonylation of olefins
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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9040445B2 (en) 2004-02-18 2015-05-26 Lucite International Uk Limited Catalyst system
US9802185B2 (en) 2004-02-18 2017-10-31 Lucite International Uk Limited Catalyst system
TWI415682B (zh) * 2005-08-12 2013-11-21 Lucite Int Uk Ltd 經改良之催化劑系統
US8604236B2 (en) 2005-08-12 2013-12-10 Lucite International Uk Limited Catalyst system
TWI487569B (zh) * 2005-11-17 2015-06-11 Lucite Int Uk Ltd 乙烯系不飽和化合物之羰基化作用
US9334227B2 (en) 2005-11-17 2016-05-10 Lucite International Uk Limited Carbonylation of ethylenically unsaturated compounds
US8445711B2 (en) 2006-04-13 2013-05-21 Lucite International Uk Limited Metal complexes
US9809611B2 (en) 2006-12-02 2017-11-07 Lucite International Uk Limited Carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
US8816113B2 (en) 2008-07-04 2014-08-26 Lucite International Uk Limited Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporating such ligands
TWI506017B (zh) * 2009-12-15 2015-11-01 Lucite Int Uk Ltd 乙烯羰基化之連續製程
US8969560B2 (en) 2010-01-05 2015-03-03 Lucite International Uk Limited Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporating such ligands
US9381503B2 (en) 2010-01-05 2016-07-05 Lucite International Uk Limited Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporating such ligands

Also Published As

Publication number Publication date
AU737772B2 (en) 2001-08-30
AU737772C (en) 2005-08-18
EP0970038A1 (en) 2000-01-12
US6284919B1 (en) 2001-09-04
DE69804776D1 (de) 2002-05-16
PT970038E (pt) 2002-07-31
CN1250434A (zh) 2000-04-12
HUP0000772A3 (en) 2000-11-28
CN1245371C (zh) 2006-03-15
ID24681A (id) 2000-07-27
EP0970038B1 (en) 2002-04-10
DE69804776T3 (de) 2006-03-23
DE69804776T2 (de) 2002-09-26
JP4143133B2 (ja) 2008-09-03
BR9808354A (pt) 2000-05-23
HU226818B1 (en) 2009-11-30
KR20000076427A (ko) 2000-12-26
WO1998041495A1 (en) 1998-09-24
CA2282515A1 (en) 1998-09-24
MY124656A (en) 2006-06-30
EP0970038B2 (en) 2005-09-07
ES2172114T5 (es) 2006-04-01
CZ295078B6 (cs) 2005-05-18
ATE215928T1 (de) 2002-04-15
KR100540952B1 (ko) 2006-01-12
ES2172114T3 (es) 2002-09-16
HUP0000772A2 (en) 2000-07-28
CA2282515C (en) 2007-05-01
JP2001517218A (ja) 2001-10-02
AU6628698A (en) 1998-10-12
GB9705699D0 (en) 1997-05-07
ZA981982B (en) 1998-09-21
CZ326999A3 (cs) 2000-01-12

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