TW426980B - Wire bonding to copper - Google Patents
Wire bonding to copper Download PDFInfo
- Publication number
- TW426980B TW426980B TW088120537A TW88120537A TW426980B TW 426980 B TW426980 B TW 426980B TW 088120537 A TW088120537 A TW 088120537A TW 88120537 A TW88120537 A TW 88120537A TW 426980 B TW426980 B TW 426980B
- Authority
- TW
- Taiwan
- Prior art keywords
- layer
- copper
- barrier layer
- aluminum
- depositing
- Prior art date
Links
- 239000010949 copper Substances 0.000 title claims abstract description 43
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 43
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 230000004888 barrier function Effects 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 26
- 229910052782 aluminium Chemical group 0.000 claims abstract description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004065 semiconductor Substances 0.000 claims abstract description 11
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052737 gold Inorganic materials 0.000 claims abstract description 6
- 239000010931 gold Substances 0.000 claims abstract description 6
- 239000010410 layer Substances 0.000 claims description 125
- 239000011229 interlayer Substances 0.000 claims description 12
- 238000000151 deposition Methods 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000010936 titanium Substances 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims 2
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 claims 2
- 238000001465 metallisation Methods 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 description 27
- 239000002184 metal Substances 0.000 description 27
- 238000005516 engineering process Methods 0.000 description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000005253 cladding Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 238000005240 physical vapour deposition Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000004642 Polyimide Substances 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 229920002120 photoresistant polymer Polymers 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 208000019901 Anxiety disease Diseases 0.000 description 1
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- 229910001020 Au alloy Inorganic materials 0.000 description 1
- GPXJNWSHGFTCBW-UHFFFAOYSA-N Indium phosphide Chemical compound [In]#P GPXJNWSHGFTCBW-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- JCBNMVUSYPTHJY-UHFFFAOYSA-N [Ti].[Ar] Chemical compound [Ti].[Ar] JCBNMVUSYPTHJY-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000004964 aerogel Substances 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- QRJOYPHTNNOAOJ-UHFFFAOYSA-N copper gold Chemical compound [Cu].[Au] QRJOYPHTNNOAOJ-UHFFFAOYSA-N 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000003353 gold alloy Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical group N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000009865 steel metallurgy Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
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Landscapes
- Engineering & Computer Science (AREA)
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- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Wire Bonding (AREA)
Description
'五、發明說明(1) 一 發明範圍_ 本發明係關於製造積體電路,尤其是關於將金線互士 合到銅金屬敷層之方法。 Ί !發明背景 在半導體製造的發展中,持久性技術之一為線結合(弓丨 線鍵合或絲焊)。線結合用於將最早期積體電路站片互連 到引線框架(基座)上,以製造單個積體電路包(組合件)。 在芯片技術發展的同時,亦需要具有更高層次芯片積體的 ;更復雜包’如多片模塊,且需要將此等模塊彼此互連及支 持(電路)板。TAB結合及巨塊結合有效地用作此等包的互 丨連工藝’而線結合應用仍保持在普通I C (積體電路)製造 ;中。 ; 在IC互連技術發展_,早期銅被認定為1C互連的所需候 I選物。銅具有高導電性,亦為廉價,且銅的冶金發展良 好。但銅作為互連材料有早期不良經歷,銅電解性活躍, 且在半導體中產生遷移問題。在經線結合的包中,由於銅 易於與金線結合〉ttl合成合金,且銅—金合金使用不良,所 |以不犯使用銅金屬敷。由於鋼、紹的已知問題,所以次級 丨導體成為I c金屬敷的材料選擇。在此確立紹金屬,其它選 丨擇保留於背景中。 i 現在’ I c技術已推進到鋁導電性為丨c設計限制因素的程 度上°這使方法設計者拒絕金屬材料選擇。重又許可使用 的一種為銅。然而,將鋼冶金積成普通1(:處理為舊問題的 !重新翻版’此等之一為將結合金線結合到銅金屬敷。 —4269 b ο 五'發明說明(2) ' '— 發明概沭 我們開發了將金線結合到鋼金屬敷之方法,其包括在銅 上形成阻擋層,在該阻擋層上形成鋁襯墊。然後將金線熱 壓結合到鋁襯墊上。 μ 繪圖簡述 圖1 -24為進行本發明製程所用步驟之圖解說明。 發明詳述 爹号圖1,所示矽晶片丨1被部分切開,表明其為較大矽 晶片的一部分。應懂得,這些繪圖不成比例,為便於說 明’僅顯示了某些特徵口該矽材係用第一氧化層丨2 (一般 稱為場氧化膜)、金屬互連層13及中間介電層14 ( 一般為X 經沈積氧化物或其它適用的介電材料)覆蓋。低有機性材 料(如乾凝膠或氣凝膠)亦適用。且可使用旋上技術塗上。 此等要素為標準矽IC技術’不構成本發明部分。本發明將 用4基礎結構作為起始點描述’但熟諳此藝者將認識到,· 般積體電路具有三或四層金屬。金屬層13應認作與最 的金屬層鄰接’即使一般有其它層出現(未顯示)。 參考圖2,在該圖中,光刻掩蔽物1 6被加到介電層1 4 上’且以圖形形式暴露部分層間介電層,以製造中間互連 2。應僅得,雖然在此提到光刻或光刻掩蔽物,但可用其 匕刻製技術替代,如使用X-射線或電子束刻製。用抗光蝕 劑作為蝕刻掩蔽物,通過層間介電層形成窗丨8,以層間互 連金屬塊(15),如圖8所示。下一步,以適用的窗塞曰材3料 沈積到電介質及進入窗中,將層間窗1 8插塞。例如,在圖
第5頁 ‘498〇 五、發明說明(3) 4中,可使用雙層(如T i N和鎢),以層2 1和2 2表示。然後將 該晶片用化學機械研磨法(CMP)處理,以產生圖5所示之結 構。TiN/W層之CMP所用之技術描述於美國專利申請案序列 號第09/151,077號,該申請案歸檔於0 9/10/98。現在用金 屬塞23塞入窗中,使該結構物用於沈積下一個金屬敷層。 應瞭解,用圖5之CMP步驟除去不需要的金屬比使用更習用 之掩蔽物及蝕刻處理產生了更平面化的結構物,尤其是按 次序重複數次形成多重金屬層之情形《然而為實現本發明 意圖,可使用任何形成層間互連的的適用方法。 隨後,將蝕刻中斷層25覆蓋式沈積到層間電介質及層間 窗上。適用的蝕刻中斷層為四氮化三矽,該層一般能經受 氧化蝕刻處理(如R IE蝕刻方法),在形成時保護層間塞。 蝕刻中斷層之厚度一般為500-1500埃(Angst roms)。 在圖7中,介電層3 1被沈積到該結構物上,且以光刻掩 蔽物3 2掩蔽,如圖8所示。掩蔽物3 2經形成圖形在鶴塞2 3 上形成窗口 3 3。如圖9所示。較佳用RI E將經暴露氧化物餘 離,使窗3 3中的四氮化三矽蝕刻中斷物移開圖1 〇之結構 物。 在圖1 1中,阻擋層41被覆蓋式沈積到該結構物之表面 上,且進入所示之窗中。該層為界定銅互連層的第一步 驟,按次序描述,該層為1C中的最後或上部金屬層,且為 線結合欲製造的層次。在該結構物中亦可存在其它銅金屬 敷層,但本發明適合於最後金屬層,對該層經線結合製造 互連。阻擋層4 1所用之較佳材料為钽(Ta)、氮化纽
第6頁 4^69Q〇 五、發明說明(4) ! . ! (TaN)、鈦(Ti )或氬化鈦(TiN),亦可使用其它材料。該阻 擋層可通過化學氣相沈積(CVD)或物理氣相沈積(PVD)洗 積。適於使用100-1000埃層。 I 隨後經PVD覆蓋式沈積銅接觸層42,如圖1 2所示。鋼接 觸層之厚度可恰好足以提供用於覆蓋式電解性沈積表面上 之晶種層。如1 0 0 0 -2 0 0 0埃。該銅晶種層42使得能夠經標 準技術電解性沈積銅層4 3。層4 3之厚度應足以完全將窗口 (33)(圖12)塞住,如圖13所示,且較佳為窗口高度的 1. 2-1. 6倍。下一步,用前述CMP方法將表面平面化,以產
生圖1 4所示之結構物,該結構物具有側部和底部由阻擒層 i 45包圍的銅塞44。 S
J 為封閉銅塞4 4的頂部,在圖1 5所示之結構物上覆蓋式.、尤 積第二阻擋層51。該阻擋層基本具有與阻擋層41相同的規 定,並保證封閉銅金屬敷層的所有側面,防止銅在丨c中遷 移。 然後對銅金屬敷層進行線結合接觸,如圖丨6 — 2 〇所示。 在圖16中’薄阻擋層51由厚鋁層52覆蓋。該鋁層52可經 i CVD或PVD沈積,且較佳具有〇· n 〇微米之厚度。 、二 ! 然後使光刻掩蔽物5 3覆於银刻層5 1和5 2上,以界定紹钟 合襯墊,如圖1 7所示。此等層的不需要部分用習用技術^ 蝕分離,以產生結合襯墊5 6,該襯墊5 6與銅塞經阻擋層5 5 隔離,如圖18所示。在該層上通常有很多結合襯墊,隨後 |以習用鈍化層58覆蓋IC。該覆蓋層可以為四氮化三矽 (SINCAPS)或聚合物(如聚醯亞胺)。該覆蓋層較佳為可光
!' " "— -------------------- i五、發明說明(5) —---—-- ;界定性聚醯亞胺。如果為光界定性’那麼使 圖:,或者掩蔽及浸"成窗59,且暴露…襯塾f6 之表面,如圖丨9所示。可用標準抗光触 γ ,, s蜊及Ίά刻技術使四 亂化二矽形成圖形。如果層58為光界定性,可省略抗光蝕 劑’使該層經曝光及顯影自身形成圖形。 在圖20中,線61經熱壓(TC)結合結合到鋁襯墊“上。該 線較佳為金’或具有少量金屬添加劑之合金,以利於硬化 等,如使用金-鈹。該線之直徑一般為〇, 5 —2密耳(mi丨), 較佳1-1.2密耳。該铭結合概替之面積一般為1〇〇〇 4〇〇〇〇 平方微求’較佳50 00-2500 0平方微米。標準使用TC結合操 作。用力可以為15-60克’較佳40-60克。超聲頻率為 *' 40-20 0千赫茲(kHz),較佳為60- 1 2 0千赫茲,電源為 20-20 0毫伏’較佳50- 1 00毫伏,此等參數適用於不同的結 合工具’如K&S線結合裝置。 對上述製程最後數步的一種替代性方法顯示於圖 2卜24。以圖14之結構起始,覆蓋層72在鋁結合襯墊層之 前覆上。在圖21中’窗71顯示於覆蓋層72中。窗71暴露了 ;銅金屬敷層44。如圖22所示,阻擋層73及鋁層74被覆蓋式 I沈積到覆蓋層72上,且進入窗中與銅金屬敷層接觸。然後 !如圖22所示,用掩蔽物76掩蔽鋁層74,將層74和73浸蝕, I形成圊23所示的鋁結合襯墊77。在圖24中,掩蔽物被移 I去,且施加金TC (熱壓)線結合物7 8,完成互連。 I在上述發明之具體實施例仲,最後金屬圖形為銅,所述 阻擋層用於將銅隔離,並防止其遷移到下面的不同冶金學
第8頁 Q q —----- ^ ------- --- '-, 五、發明說明(6) 區域。然而’如果位於下方的層亦包括以銅金屬敷化的最 後層,那麼圖中所示層不需在金屬敷層之間具有阻擋層。 但有時在最後銅結合區域及紹線結合概塾之間存在有效的 阻播仍很重要。 雖然上述方法被開發用於石夕C Μ 0 S (互補型-金屬-氧化物 I -半導體)積體電路’但亦可同樣用於其它類型的積體電 i路,如ΠΙ-ν光性積體電路。此等積體電路一般具有砷化 鎵(GaAs)或磷化銦(InP)基片及多層III-V三元和/或四元 層形成的有源器件。但某些應用中,其互連可與石夕積體電 |路技術相似。此等電路一般在很高速度下操作,為銅金屬 j敷帶來清晰的益處。 i I 今天製造的大多數矽積體電路具有晶體管器件所用的多 晶發柵,該第一層金屬一般為多晶矽,以形成柵及形成這 些柵所用之互連。在第一層後形成的金屬互連層一般為 铭,且一般使用一至三層鋁。其中的一層或多層可用本發 明上述教示方法以銅替代。至少有一層銅層具有線結合部 位’以根據本發明轉變為鋁結合部位.引用第一金屬敷層 或第二金屬敷層應懂得,所述第一層或第二層不必為I c結 構中的第一層或第二層。 | 热請此藝者可對本發明作出各種其它改進。根據基本原 理及等價方法對技藝所作改進對該說明書具體教示方法產 生的偏差,應合理認作在本發明描述及申請之範圍内。
第9頁
Claims (1)
- 六、申請專利範圍 _ 1. 一種製造半導體積體電路之方法’其中該上部互連層 包括銅,該方法包括: a)將阻擋層沈積到該上部互連層之經選擇部分上 該阻擋層為選自钽(Ta)、氮化钽(TaN)、鈦(Ti)或氮化鈦 (T i N )及其組合之群之材料; b) 將鋁層沈積到該阻擋層上,及 c) 將導電性線互連結合到該鋁層上。 2.根據申請專利範圍第1項之方法,其中該半導體積體 電路之半導體為矽。 3.根據申請專利範圍第2項之方法,其中該線包括金, ;且用熱壓結合方法結合。 ; 4.根據申請專利範圍第1項之方法,其在步驟a)前包括 !附加步驟,該附加步驟將覆蓋層沈積到該上部互連層,在 I該覆蓋層中形成窗,然後進行步驟a)至c )。 5.根據申請專利範圍第1項之方法,其在步驟c)前包括 ;附加步驟,該附加步驟將覆蓋層沈積到該上部互連層,在 該覆蓋層中形成窗,以暴露該部分鋁層,.然後進行步驟 c) ° 6, —種製造半導體積體電路之方法,其包括以下步驟: a) 在半導體基材上形成銅互連層; b) 將介電層沈積到該銅互連層上; c) 在該介電層上形成多重窗口 ,以留下該銅互連層 ί之經暴露部分; j I d)將阻擋層沈積到該介電層上以及該銅互連層之經 六、申名分 曝露部 e) 將鋁層沈積到該阻擋層上; f) 浸蝕分離該阻擋層及該鋁層之經選擇部分,以將 丨阻擋層襯墊及鋁襯墊留在該第二導電性互連層之經暴露部 !分上: g) 將導線熱壓結合到該鋁襯墊上。 7. 根據申請專利範圍第6項之方法,其中該阻擋層包括 選自鈕(Ta)、氮化鈕(TaN)、鈦(Ti)、氮化鈦(TiN)及其組 合之群之材料。 8. —種製造半導體積體電路之方法,其包括以下步驟: a) 在半導體基材上形成第一導電性互連層,其中該 第一導電性互連層具有第一互連圖形; b) 將第一介電層沈積到該第一導電性互連層上; i c)在該第一介電層形成至少一個層間窗口,以暴露 I 一部分該第一導電性互連層; d) 將第一阻擋層沈積到該第一介電層上,且進入該 層間窗口; e) 將銅層電鍍到該第一阻擋層上,該銅層具有足夠 I厚度,以填充該層間窗口; I ! f)除去部分該第一阻擋層及該銅層,留下阻擋層及 I填充該層間窗口之銅塞; g) 將阻擋層沈積到該第一介電層及該銅塞上; h) 將鋁層沈積到該阻擋層上;第11頁第12頁
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JPS63128634A (ja) * | 1986-11-18 | 1988-06-01 | Nec Corp | 半導体装置の製造方法 |
JPH0727921B2 (ja) * | 1987-07-31 | 1995-03-29 | 日本電気株式会社 | 半導体装置の製造方法 |
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JP3906522B2 (ja) * | 1997-06-10 | 2007-04-18 | ソニー株式会社 | 半導体装置の製造方法 |
US6197688B1 (en) * | 1998-02-12 | 2001-03-06 | Motorola Inc. | Interconnect structure in a semiconductor device and method of formation |
US5968333A (en) * | 1998-04-07 | 1999-10-19 | Advanced Micro Devices, Inc. | Method of electroplating a copper or copper alloy interconnect |
US6117769A (en) * | 1998-08-11 | 2000-09-12 | Advanced Micro Devices, Inc. | Pad structure for copper interconnection and its formation |
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1999
- 1999-11-24 TW TW088120537A patent/TW426980B/zh not_active IP Right Cessation
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2000
- 2000-01-13 EP EP00300208A patent/EP1022776B1/en not_active Expired - Lifetime
- 2000-01-13 DE DE60039800T patent/DE60039800D1/de not_active Expired - Lifetime
- 2000-01-17 JP JP2000007951A patent/JP3575676B2/ja not_active Expired - Lifetime
- 2000-01-22 KR KR1020000003060A patent/KR100659801B1/ko active IP Right Grant
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JP3575676B2 (ja) | 2004-10-13 |
EP1022776A3 (en) | 2000-09-13 |
JP2000216191A (ja) | 2000-08-04 |
KR100659801B1 (ko) | 2006-12-19 |
US6472304B2 (en) | 2002-10-29 |
KR20000057792A (ko) | 2000-09-25 |
US20010036716A1 (en) | 2001-11-01 |
EP1022776B1 (en) | 2008-08-13 |
DE60039800D1 (de) | 2008-09-25 |
EP1022776A2 (en) | 2000-07-26 |
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