TW343963B - Process for the production of 1,2- and 1,3-propanediol - Google Patents

Process for the production of 1,2- and 1,3-propanediol

Info

Publication number
TW343963B
TW343963B TW082108605A TW82108605A TW343963B TW 343963 B TW343963 B TW 343963B TW 082108605 A TW082108605 A TW 082108605A TW 82108605 A TW82108605 A TW 82108605A TW 343963 B TW343963 B TW 343963B
Authority
TW
Taiwan
Prior art keywords
stage
propanediol
glycerol
product stream
acrolein
Prior art date
Application number
TW082108605A
Other languages
English (en)
Inventor
Thomas Haas
Armin Neher
Dietrich Arntz
Herbert Klenk
Walter Girke
Original Assignee
Degussa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa filed Critical Degussa
Application granted granted Critical
Publication of TW343963B publication Critical patent/TW343963B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/64—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of functional groups containing oxygen only in singly bound form
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
TW082108605A 1992-11-14 1993-10-16 Process for the production of 1,2- and 1,3-propanediol TW343963B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4238492A DE4238492C2 (de) 1992-11-14 1992-11-14 Verfahren zur Herstellung von 1,2- und 1,3-Propandiol

Publications (1)

Publication Number Publication Date
TW343963B true TW343963B (en) 1998-11-01

Family

ID=6472888

Family Applications (1)

Application Number Title Priority Date Filing Date
TW082108605A TW343963B (en) 1992-11-14 1993-10-16 Process for the production of 1,2- and 1,3-propanediol

Country Status (11)

Country Link
US (1) US5426249A (zh)
EP (1) EP0598228B1 (zh)
JP (1) JP3488491B2 (zh)
CN (1) CN1053176C (zh)
AT (1) ATE137729T1 (zh)
BR (1) BR9304715A (zh)
DE (2) DE4238492C2 (zh)
ES (1) ES2086850T3 (zh)
MX (1) MX9307070A (zh)
MY (1) MY109072A (zh)
TW (1) TW343963B (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI403495B (zh) * 2006-07-26 2013-08-01 Davy Process Techn Ltd 方法

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5689016A (en) * 1994-09-30 1997-11-18 Shell Oil Company Cobalt-catalyzed process for preparing alkanediols using a rhodium promoter
US6180838B1 (en) 1994-09-30 2001-01-30 Shell Oil Company Process for preparing alkanediols
US6284930B1 (en) 1999-07-30 2001-09-04 E.I. Du Pont De Nemours And Company Process for the preparation of 3-hydroxypropanal
US6342646B1 (en) 1999-07-30 2002-01-29 E. I. Du Pont De Nemours And Company Catalytic hydrogenation of 3-hydroxypropanal to 1,3-propanediol
DE60101743T2 (de) 2000-06-20 2004-12-09 E.I. Du Pont De Nemours And Co., Wilmington Katalytische dehydroxylation von diolen und polyolen
US8017816B2 (en) * 2002-04-22 2011-09-13 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
US8252961B2 (en) * 2002-04-22 2012-08-28 The Curators Of The University Of Missouri Method of producing lower alcohols from glycerol
MY140801A (en) * 2002-10-03 2010-01-15 Shell Int Research Reduction of the viscosity of reactive heavy byproducts during the production of 1,3-propanediol
BRPI0507874B1 (pt) * 2004-03-25 2019-03-12 Galen J. Suppes Processos para converter glicerol em propileno glicol e também em acetol com seletividade elevada
US7131446B2 (en) * 2004-03-25 2006-11-07 Tang Kenneth Y Light-triggered tattoo process
US7697020B2 (en) 2004-11-04 2010-04-13 Rohm Co., Ltd. Thermal print head and method for manufacturing same
DE102004060541A1 (de) * 2004-12-15 2006-06-29 Degussa Ag Verfahren zur Herstellung von Alkandiolen und Alkantriolen mit einer vicinalen Diol-Gruppe
FR2882052B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acroleine
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
TWI438187B (zh) * 2005-02-28 2014-05-21 Evonik Degussa Gmbh 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法
JP4852266B2 (ja) * 2005-06-30 2012-01-11 広栄化学工業株式会社 モノヒドロキシアセトンの製造法
GB0514593D0 (en) * 2005-07-15 2005-08-24 Davy Process Techn Ltd Process
WO2007058221A1 (ja) * 2005-11-15 2007-05-24 Nippon Shokubai Co., Ltd. 多価アルコールの脱水方法
JP2008088149A (ja) * 2006-01-04 2008-04-17 Nippon Shokubai Co Ltd アクロレイン製造用触媒及びそれを用いたアクロレイン製造方法
FR2897058B1 (fr) * 2006-02-07 2008-04-18 Arkema Sa Procede de preparation d'acroleine
JP4041513B2 (ja) * 2006-03-30 2008-01-30 株式会社日本触媒 グリセリン脱水用触媒、グリセリン脱水用触媒の製造方法、アクロレインの製造方法、およびアクロレイン誘導体の製造方法
WO2007119528A1 (ja) * 2006-03-30 2007-10-25 Nippon Shokubai Co., Ltd. アクロレインの製造方法
JP4041512B2 (ja) * 2006-03-30 2008-01-30 株式会社日本触媒 グリセリン脱水用触媒、グリセリン脱水用触媒の製造方法、アクロレインの製造方法、およびアクロレイン誘導体の製造方法
US7799957B2 (en) * 2006-05-09 2010-09-21 Kao Corporation Process for producing product of hydrogenolysis of polyhydric alcohol
JP5010963B2 (ja) * 2006-05-09 2012-08-29 花王株式会社 多価アルコールの水素化分解物の製造方法
US7619119B2 (en) * 2006-06-07 2009-11-17 The Procter & Gamble Company Processes for converting glycerol to amino alcohols
US7619118B2 (en) 2006-06-07 2009-11-17 The Procter & Gamble Company Process for the conversion of glycerol to propylene glycol and amino alcohols
ES2402216T3 (es) * 2006-06-07 2013-04-29 The Procter & Gamble Company Procesos para convertir glicerol en aminoalcoholes
DE102006054519A1 (de) 2006-11-20 2008-05-21 Evonik Degussa Gmbh Verfahren zur Herstellung von Fettsäurealkylestern und Acrolein aus Triglyceriden
EP2103590A4 (en) 2006-12-01 2013-10-16 Nippon Catalytic Chem Ind METHOD FOR PRODUCING AN ACROLEINE AND GLYCERINE-CONTAINING COMPOSITION
DE102007004350A1 (de) 2007-01-29 2008-07-31 Evonik Degussa Gmbh Verfahren zur Regenerierung eines Katalysators
DE102007004351A1 (de) 2007-01-29 2008-07-31 Evonik Degussa Gmbh Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin
JP4991471B2 (ja) 2007-05-16 2012-08-01 株式会社日本触媒 グリセリン脱水用触媒、およびアクロレインの製造方法
EP2162416B8 (en) * 2007-05-18 2018-12-19 BioFuel-Solution i Malmö AB Gas phase process for monoalcohol production from glycerol
US20090054694A1 (en) * 2007-08-24 2009-02-26 Peterson Thomas H Chemical production processes, systems, and catalyst compositions
US20090054538A1 (en) * 2007-08-24 2009-02-26 Peterson Thomas H Chemical production processes, systems, and catalyst compositions
US7872159B2 (en) 2007-08-24 2011-01-18 Battelle Memorial Institute Chemical production processes, systems, and catalyst compositions
US7872158B2 (en) 2007-08-24 2011-01-18 Battelle Memorial Institute Chemical production processes, systems, and catalyst compositions
US20090088317A1 (en) * 2007-09-28 2009-04-02 Frye Jr John G Multi-metal reduction catalysts and methods of producing reduction catalysts
JP5081647B2 (ja) * 2008-01-29 2012-11-28 昭和電工株式会社 アクロレインの製造方法
AR072446A1 (es) 2008-03-02 2010-09-01 Dow Global Technologies Inc Proceso de hidrogenacion mejorado
WO2009138377A2 (de) 2008-05-13 2009-11-19 Basf Se Verfahren zur herstellung von n,n-substituierten-1,3-propandiaminen
JP2008280349A (ja) * 2008-06-02 2008-11-20 Nippon Shokubai Co Ltd アクリル酸の製造方法、アクリル酸製造用装置、およびアクリル酸製造用組成物
JP5153462B2 (ja) * 2008-06-05 2013-02-27 昭和電工株式会社 アクロレインの製造方法及びアクリル酸の製造方法
EP2300400A4 (en) * 2008-06-05 2012-03-21 Huntsman Petrochemical Llc PROCESS FOR PREPARING AND CLEANING PROPYLENE GLYCOL
BRPI0806337A2 (pt) * 2008-06-24 2010-03-09 Suzano Petroquimica S A preparação de catalisadores heterogêneos utilizados na hidrogenação seletiva de glicerina a propeno e processo para hidrogenação seletiva de glicerina a propeno
BRPI0803898A2 (pt) * 2008-07-30 2010-11-09 Univ Rio De Janeiro processo catalìtico para a transformação de glicerina em insumos para o setor petroquìmico
JP5555867B2 (ja) * 2008-08-04 2014-07-23 国立大学法人 千葉大学 グリセリンからのグリコール及び１−プロパノールの製造方法
EP2179981A1 (en) * 2008-10-24 2010-04-28 Arkema France Process for manufacturing acrolein from glycerol
CN102203054B (zh) 2008-11-05 2014-07-30 巴斯夫欧洲公司 生产n，n-取代的3-氨基丙-1-醇的方法
US8198477B2 (en) * 2008-12-24 2012-06-12 Rohm And Haas Company Process for production of acrolein from glycerol
CN102070422B (zh) * 2009-11-20 2013-06-19 中国科学院大连化学物理研究所 丙三醇脱水、加氢制备丙酮醇及1,2-丙二醇的方法
KR101478887B1 (ko) 2009-12-18 2015-01-02 바텔리 메모리얼 인스티튜트 멀티하이드릭 화합물 탈수 시스템, 촉매 조성물, 및 방법
WO2011159418A2 (en) * 2010-06-16 2011-12-22 Archer Daniels Midland Company Processes for deodorizing renewable-sourced glycols
CN102372602B (zh) * 2010-08-25 2014-01-29 中国科学院大连化学物理研究所 一种甘油加氢制1,3-丙二醇的方法
JP5861024B2 (ja) 2011-01-13 2016-02-16 Jnc株式会社 多価アルコールからのグリコールの製造方法
EP2565175B1 (en) 2011-08-31 2021-04-21 Aristotle University of Thessaloniki Catalytic process for the production of 1,2-propanediol from crude glycerol stream
CN102344341B (zh) * 2011-09-30 2014-03-12 东南大学 一种甘油一步氢解法制备1,3-丙二醇的方法
JP5755995B2 (ja) * 2011-10-26 2015-07-29 株式会社日立製作所 超臨界水を用いた反応プロセス
JP6008802B2 (ja) * 2013-07-11 2016-10-19 三井化学株式会社 フェノールの精製方法
CN107353180B (zh) * 2017-06-22 2020-10-23 江苏飞翔化工股份有限公司 3-羟基丙醛水溶液加氢制备1,3-丙二醇联产1,2-丙二醇的方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR695931A (fr) * 1929-06-15 1930-12-23 Schering Kahlbaum Ag Procédé de fabrication d'acroléine
US1916743A (en) * 1929-06-15 1933-07-04 Schering Kahlbaum Ag Production of acrolein
US2042224A (en) * 1934-06-27 1936-05-26 Shell Dev Process of converting a polyhydric alcohol to a carbonyl compound
US2269935A (en) * 1940-02-27 1942-01-13 Du Pont Process for producing hydroxy aldehydes and hydroxy ketones
US2558520A (en) * 1948-01-29 1951-06-26 Us Ind Chemicals Inc Production of acrolein from glycerol
US4642394A (en) * 1985-07-16 1987-02-10 Celanese Corporation Production of propanediols
DE3818198A1 (de) * 1988-05-28 1989-12-21 Basf Ag Verfahren zur herstellung niederer mehrwertiger alkohole
DE3926136A1 (de) * 1989-08-08 1991-02-14 Degussa Verfahren zur herstellung von 1,3-propandiol
DE4038192A1 (de) * 1990-11-30 1992-06-04 Degussa Verfahren zur herstellung von 1,3-propandiol
DE4128692A1 (de) * 1991-08-29 1993-03-04 Henkel Kgaa Verfahren zum herstellen von acetol
DE4228487A1 (de) * 1991-08-30 1993-03-04 Kao Corp Verfahren zur herstellung einer eine carbonyl- und/oder carboxylgruppe aufweisenden verbindung
DE4138981A1 (de) * 1991-11-27 1993-06-03 Degussa Verfahren zur herstellung von 3-hydroxyalkanalen
DE4138982A1 (de) * 1991-11-27 1993-06-03 Degussa Verfahren zur herstellung von 3-hydroxyalkanalen
DE4218282A1 (de) * 1992-06-03 1993-12-09 Degussa Verfahren zur Herstellung von 1,3-Propandiol

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI403495B (zh) * 2006-07-26 2013-08-01 Davy Process Techn Ltd 方法

Also Published As

Publication number Publication date
CN1053176C (zh) 2000-06-07
DE4238492A1 (de) 1994-05-19
ATE137729T1 (de) 1996-05-15
EP0598228B1 (de) 1996-05-08
ES2086850T3 (es) 1996-07-01
MY109072A (en) 1996-11-30
CN1090568A (zh) 1994-08-10
JP3488491B2 (ja) 2004-01-19
US5426249A (en) 1995-06-20
BR9304715A (pt) 1994-11-01
DE59302507D1 (de) 1996-06-13
JPH06192147A (ja) 1994-07-12
EP0598228A1 (de) 1994-05-25
MX9307070A (es) 1994-05-31
DE4238492C2 (de) 1995-06-14

Similar Documents

Publication Publication Date Title
TW343963B (en) Process for the production of 1,2- and 1,3-propanediol
US5210354A (en) Propylene oxide-styrene monomer process
CA2100229A1 (en) Process for the preparation of 1,3-propanediol
ATE142999T1 (de) Verfahren zur herstellung von acrolein
AU2001271684B2 (en) Glycol purification
KR920007872B1 (ko) 메타크릴산의 회수 방법
JPH09509941A (ja) シクロヘキシルアジペートおよびアジピン酸の製造方法
JPS60115532A (ja) ブタジエンの製造方法
JP4427189B2 (ja) 高濃度モノエチレングリコールの製造方法
US3922314A (en) Process for the preparation of ethylene glycol
DE3260280D1 (en) Process for the preparation of isosorbid-5-nitrate
US4873391A (en) Process for producing isobutylene
KR100868601B1 (ko) 수용액으로부터의 포름산의 제거 방법
JPH0748346A (ja) ジ第三ブチルペルオキシドの統合した製造方法
JPH08208544A (ja) フェノールタール廃棄物減少法
CN110882722A (zh) 一种酸碱复合催化剂以及使用其制备甲基丙烯醛的方法
US4461676A (en) Process for refining tetrahydrofuran
US5321155A (en) Process for the production of cyclohexyladipates and adipic acid
US2704298A (en) Manufacture of alkoxy-aldehydes
US2552513A (en) Separation of aldehydes and ketones
CA1132612A (en) Process for the purification of benzaldehyde
CN115353447B (zh) 一种低水含量甲醛溶液制备不饱和羧酸或羧酸酯的方法
SU1006425A1 (ru) Способ получени концентрированных водных растворов формальдегида
CN115286505A (zh) 一种气相浓甲醛制备不饱和羧酸或羧酸酯的方法
RU2063958C1 (ru) Способ выделения кротонового альдегида