MX9307070A - Procedimiento para la elaboracion de 1,2- y 1,3-propandiol. - Google Patents
Procedimiento para la elaboracion de 1,2- y 1,3-propandiol.Info
- Publication number
- MX9307070A MX9307070A MX9307070A MX9307070A MX9307070A MX 9307070 A MX9307070 A MX 9307070A MX 9307070 A MX9307070 A MX 9307070A MX 9307070 A MX9307070 A MX 9307070A MX 9307070 A MX9307070 A MX 9307070A
- Authority
- MX
- Mexico
- Prior art keywords
- glycerol
- propanediol
- hydration
- stage
- reaction mixture
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/64—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of functional groups containing oxygen only in singly bound form
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
La invención se refiere a un procedimiento para la elaboración simultánea de 1,2- y 1,3-propandiol a partir de glicerina. El 1,2-propandiol usualmente se elabora a partir del óxido de propileno, el 1,3-propandiol por hidratación de la acroleína e hidrogenación subsiguiente. El procedimiento de acuerdo al invento abarca las etapas de reacción: (a) deshidratación de la glicerina por conducción de una mezcla glicerina-agua gaseosa con 10 hasta 40 por peso de glicerina a 250 hasta 340°C sobre un catalizador de sustancias sólidas con un valor H0 (función ácida de Hemmett) menor de 2, de preferencia entre -3 y -8,2, (b) hidratación de la acroleína contenida en la mezcla de reacción de la etapa (a) y (c) hidrogenación catalítica del 3-hidroxipropionaldehido y de la hidroacetona contenidas en la mezcla de reacción de la etapa (b). A partir de la glicerina pueden obtenerse en un procedimiento simple y simultáneo dos sustancias valiosas, el 1,2- y 1,3- propandiol, con elevado rendimiento total.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4238492A DE4238492C2 (de) | 1992-11-14 | 1992-11-14 | Verfahren zur Herstellung von 1,2- und 1,3-Propandiol |
Publications (1)
Publication Number | Publication Date |
---|---|
MX9307070A true MX9307070A (es) | 1994-05-31 |
Family
ID=6472888
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX9307070A MX9307070A (es) | 1992-11-14 | 1993-11-12 | Procedimiento para la elaboracion de 1,2- y 1,3-propandiol. |
Country Status (11)
Country | Link |
---|---|
US (1) | US5426249A (es) |
EP (1) | EP0598228B1 (es) |
JP (1) | JP3488491B2 (es) |
CN (1) | CN1053176C (es) |
AT (1) | ATE137729T1 (es) |
BR (1) | BR9304715A (es) |
DE (2) | DE4238492C2 (es) |
ES (1) | ES2086850T3 (es) |
MX (1) | MX9307070A (es) |
MY (1) | MY109072A (es) |
TW (1) | TW343963B (es) |
Families Citing this family (62)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5689016A (en) * | 1994-09-30 | 1997-11-18 | Shell Oil Company | Cobalt-catalyzed process for preparing alkanediols using a rhodium promoter |
US6180838B1 (en) | 1994-09-30 | 2001-01-30 | Shell Oil Company | Process for preparing alkanediols |
US6284930B1 (en) | 1999-07-30 | 2001-09-04 | E.I. Du Pont De Nemours And Company | Process for the preparation of 3-hydroxypropanal |
US6342646B1 (en) | 1999-07-30 | 2002-01-29 | E. I. Du Pont De Nemours And Company | Catalytic hydrogenation of 3-hydroxypropanal to 1,3-propanediol |
DE60101743T2 (de) | 2000-06-20 | 2004-12-09 | E.I. Du Pont De Nemours And Co., Wilmington | Katalytische dehydroxylation von diolen und polyolen |
US8017816B2 (en) * | 2002-04-22 | 2011-09-13 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
US8252961B2 (en) * | 2002-04-22 | 2012-08-28 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
MY140801A (en) * | 2002-10-03 | 2010-01-15 | Shell Int Research | Reduction of the viscosity of reactive heavy byproducts during the production of 1,3-propanediol |
BRPI0507874B1 (pt) * | 2004-03-25 | 2019-03-12 | Galen J. Suppes | Processos para converter glicerol em propileno glicol e também em acetol com seletividade elevada |
US7131446B2 (en) * | 2004-03-25 | 2006-11-07 | Tang Kenneth Y | Light-triggered tattoo process |
US7697020B2 (en) | 2004-11-04 | 2010-04-13 | Rohm Co., Ltd. | Thermal print head and method for manufacturing same |
DE102004060541A1 (de) * | 2004-12-15 | 2006-06-29 | Degussa Ag | Verfahren zur Herstellung von Alkandiolen und Alkantriolen mit einer vicinalen Diol-Gruppe |
FR2882052B1 (fr) * | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acroleine |
FR2882053B1 (fr) * | 2005-02-15 | 2007-03-23 | Arkema Sa | Procede de deshydratation du glycerol en acrolene |
TWI438187B (zh) * | 2005-02-28 | 2014-05-21 | Evonik Degussa Gmbh | 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法 |
JP4852266B2 (ja) * | 2005-06-30 | 2012-01-11 | 広栄化学工業株式会社 | モノヒドロキシアセトンの製造法 |
GB0514593D0 (en) * | 2005-07-15 | 2005-08-24 | Davy Process Techn Ltd | Process |
WO2007058221A1 (ja) * | 2005-11-15 | 2007-05-24 | Nippon Shokubai Co., Ltd. | 多価アルコールの脱水方法 |
JP2008088149A (ja) * | 2006-01-04 | 2008-04-17 | Nippon Shokubai Co Ltd | アクロレイン製造用触媒及びそれを用いたアクロレイン製造方法 |
FR2897058B1 (fr) * | 2006-02-07 | 2008-04-18 | Arkema Sa | Procede de preparation d'acroleine |
JP4041513B2 (ja) * | 2006-03-30 | 2008-01-30 | 株式会社日本触媒 | グリセリン脱水用触媒、グリセリン脱水用触媒の製造方法、アクロレインの製造方法、およびアクロレイン誘導体の製造方法 |
WO2007119528A1 (ja) * | 2006-03-30 | 2007-10-25 | Nippon Shokubai Co., Ltd. | アクロレインの製造方法 |
JP4041512B2 (ja) * | 2006-03-30 | 2008-01-30 | 株式会社日本触媒 | グリセリン脱水用触媒、グリセリン脱水用触媒の製造方法、アクロレインの製造方法、およびアクロレイン誘導体の製造方法 |
US7799957B2 (en) * | 2006-05-09 | 2010-09-21 | Kao Corporation | Process for producing product of hydrogenolysis of polyhydric alcohol |
JP5010963B2 (ja) * | 2006-05-09 | 2012-08-29 | 花王株式会社 | 多価アルコールの水素化分解物の製造方法 |
US7619119B2 (en) * | 2006-06-07 | 2009-11-17 | The Procter & Gamble Company | Processes for converting glycerol to amino alcohols |
US7619118B2 (en) | 2006-06-07 | 2009-11-17 | The Procter & Gamble Company | Process for the conversion of glycerol to propylene glycol and amino alcohols |
ES2402216T3 (es) * | 2006-06-07 | 2013-04-29 | The Procter & Gamble Company | Procesos para convertir glicerol en aminoalcoholes |
GB0614823D0 (en) * | 2006-07-26 | 2006-09-06 | Davy Process Techn Ltd | Process |
DE102006054519A1 (de) | 2006-11-20 | 2008-05-21 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Fettsäurealkylestern und Acrolein aus Triglyceriden |
EP2103590A4 (en) | 2006-12-01 | 2013-10-16 | Nippon Catalytic Chem Ind | METHOD FOR PRODUCING AN ACROLEINE AND GLYCERINE-CONTAINING COMPOSITION |
DE102007004350A1 (de) | 2007-01-29 | 2008-07-31 | Evonik Degussa Gmbh | Verfahren zur Regenerierung eines Katalysators |
DE102007004351A1 (de) | 2007-01-29 | 2008-07-31 | Evonik Degussa Gmbh | Neue Katalysatoren und Verfahren zur Dehydratisierung von Glycerin |
JP4991471B2 (ja) | 2007-05-16 | 2012-08-01 | 株式会社日本触媒 | グリセリン脱水用触媒、およびアクロレインの製造方法 |
EP2162416B8 (en) * | 2007-05-18 | 2018-12-19 | BioFuel-Solution i Malmö AB | Gas phase process for monoalcohol production from glycerol |
US20090054694A1 (en) * | 2007-08-24 | 2009-02-26 | Peterson Thomas H | Chemical production processes, systems, and catalyst compositions |
US20090054538A1 (en) * | 2007-08-24 | 2009-02-26 | Peterson Thomas H | Chemical production processes, systems, and catalyst compositions |
US7872159B2 (en) | 2007-08-24 | 2011-01-18 | Battelle Memorial Institute | Chemical production processes, systems, and catalyst compositions |
US7872158B2 (en) | 2007-08-24 | 2011-01-18 | Battelle Memorial Institute | Chemical production processes, systems, and catalyst compositions |
US20090088317A1 (en) * | 2007-09-28 | 2009-04-02 | Frye Jr John G | Multi-metal reduction catalysts and methods of producing reduction catalysts |
JP5081647B2 (ja) * | 2008-01-29 | 2012-11-28 | 昭和電工株式会社 | アクロレインの製造方法 |
AR072446A1 (es) | 2008-03-02 | 2010-09-01 | Dow Global Technologies Inc | Proceso de hidrogenacion mejorado |
WO2009138377A2 (de) | 2008-05-13 | 2009-11-19 | Basf Se | Verfahren zur herstellung von n,n-substituierten-1,3-propandiaminen |
JP2008280349A (ja) * | 2008-06-02 | 2008-11-20 | Nippon Shokubai Co Ltd | アクリル酸の製造方法、アクリル酸製造用装置、およびアクリル酸製造用組成物 |
JP5153462B2 (ja) * | 2008-06-05 | 2013-02-27 | 昭和電工株式会社 | アクロレインの製造方法及びアクリル酸の製造方法 |
EP2300400A4 (en) * | 2008-06-05 | 2012-03-21 | Huntsman Petrochemical Llc | PROCESS FOR PREPARING AND CLEANING PROPYLENE GLYCOL |
BRPI0806337A2 (pt) * | 2008-06-24 | 2010-03-09 | Suzano Petroquimica S A | preparação de catalisadores heterogêneos utilizados na hidrogenação seletiva de glicerina a propeno e processo para hidrogenação seletiva de glicerina a propeno |
BRPI0803898A2 (pt) * | 2008-07-30 | 2010-11-09 | Univ Rio De Janeiro | processo catalìtico para a transformação de glicerina em insumos para o setor petroquìmico |
JP5555867B2 (ja) * | 2008-08-04 | 2014-07-23 | 国立大学法人 千葉大学 | グリセリンからのグリコール及び1−プロパノールの製造方法 |
EP2179981A1 (en) * | 2008-10-24 | 2010-04-28 | Arkema France | Process for manufacturing acrolein from glycerol |
CN102203054B (zh) | 2008-11-05 | 2014-07-30 | 巴斯夫欧洲公司 | 生产n,n-取代的3-氨基丙-1-醇的方法 |
US8198477B2 (en) * | 2008-12-24 | 2012-06-12 | Rohm And Haas Company | Process for production of acrolein from glycerol |
CN102070422B (zh) * | 2009-11-20 | 2013-06-19 | 中国科学院大连化学物理研究所 | 丙三醇脱水、加氢制备丙酮醇及1,2-丙二醇的方法 |
KR101478887B1 (ko) | 2009-12-18 | 2015-01-02 | 바텔리 메모리얼 인스티튜트 | 멀티하이드릭 화합물 탈수 시스템, 촉매 조성물, 및 방법 |
WO2011159418A2 (en) * | 2010-06-16 | 2011-12-22 | Archer Daniels Midland Company | Processes for deodorizing renewable-sourced glycols |
CN102372602B (zh) * | 2010-08-25 | 2014-01-29 | 中国科学院大连化学物理研究所 | 一种甘油加氢制1,3-丙二醇的方法 |
JP5861024B2 (ja) | 2011-01-13 | 2016-02-16 | Jnc株式会社 | 多価アルコールからのグリコールの製造方法 |
EP2565175B1 (en) | 2011-08-31 | 2021-04-21 | Aristotle University of Thessaloniki | Catalytic process for the production of 1,2-propanediol from crude glycerol stream |
CN102344341B (zh) * | 2011-09-30 | 2014-03-12 | 东南大学 | 一种甘油一步氢解法制备1,3-丙二醇的方法 |
JP5755995B2 (ja) * | 2011-10-26 | 2015-07-29 | 株式会社日立製作所 | 超臨界水を用いた反応プロセス |
JP6008802B2 (ja) * | 2013-07-11 | 2016-10-19 | 三井化学株式会社 | フェノールの精製方法 |
CN107353180B (zh) * | 2017-06-22 | 2020-10-23 | 江苏飞翔化工股份有限公司 | 3-羟基丙醛水溶液加氢制备1,3-丙二醇联产1,2-丙二醇的方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR695931A (fr) * | 1929-06-15 | 1930-12-23 | Schering Kahlbaum Ag | Procédé de fabrication d'acroléine |
US1916743A (en) * | 1929-06-15 | 1933-07-04 | Schering Kahlbaum Ag | Production of acrolein |
US2042224A (en) * | 1934-06-27 | 1936-05-26 | Shell Dev | Process of converting a polyhydric alcohol to a carbonyl compound |
US2269935A (en) * | 1940-02-27 | 1942-01-13 | Du Pont | Process for producing hydroxy aldehydes and hydroxy ketones |
US2558520A (en) * | 1948-01-29 | 1951-06-26 | Us Ind Chemicals Inc | Production of acrolein from glycerol |
US4642394A (en) * | 1985-07-16 | 1987-02-10 | Celanese Corporation | Production of propanediols |
DE3818198A1 (de) * | 1988-05-28 | 1989-12-21 | Basf Ag | Verfahren zur herstellung niederer mehrwertiger alkohole |
DE3926136A1 (de) * | 1989-08-08 | 1991-02-14 | Degussa | Verfahren zur herstellung von 1,3-propandiol |
DE4038192A1 (de) * | 1990-11-30 | 1992-06-04 | Degussa | Verfahren zur herstellung von 1,3-propandiol |
DE4128692A1 (de) * | 1991-08-29 | 1993-03-04 | Henkel Kgaa | Verfahren zum herstellen von acetol |
DE4228487A1 (de) * | 1991-08-30 | 1993-03-04 | Kao Corp | Verfahren zur herstellung einer eine carbonyl- und/oder carboxylgruppe aufweisenden verbindung |
DE4138981A1 (de) * | 1991-11-27 | 1993-06-03 | Degussa | Verfahren zur herstellung von 3-hydroxyalkanalen |
DE4138982A1 (de) * | 1991-11-27 | 1993-06-03 | Degussa | Verfahren zur herstellung von 3-hydroxyalkanalen |
DE4218282A1 (de) * | 1992-06-03 | 1993-12-09 | Degussa | Verfahren zur Herstellung von 1,3-Propandiol |
-
1992
- 1992-11-14 DE DE4238492A patent/DE4238492C2/de not_active Expired - Fee Related
-
1993
- 1993-10-16 TW TW082108605A patent/TW343963B/zh active
- 1993-10-18 EP EP93116791A patent/EP0598228B1/de not_active Expired - Lifetime
- 1993-10-18 AT AT93116791T patent/ATE137729T1/de not_active IP Right Cessation
- 1993-10-18 ES ES93116791T patent/ES2086850T3/es not_active Expired - Lifetime
- 1993-10-18 DE DE59302507T patent/DE59302507D1/de not_active Expired - Fee Related
- 1993-11-12 JP JP28317793A patent/JP3488491B2/ja not_active Expired - Fee Related
- 1993-11-12 US US08/151,389 patent/US5426249A/en not_active Expired - Fee Related
- 1993-11-12 MX MX9307070A patent/MX9307070A/es not_active IP Right Cessation
- 1993-11-12 BR BR9304715A patent/BR9304715A/pt not_active IP Right Cessation
- 1993-11-12 MY MYPI93002377A patent/MY109072A/en unknown
- 1993-11-13 CN CN93114516A patent/CN1053176C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1053176C (zh) | 2000-06-07 |
DE4238492A1 (de) | 1994-05-19 |
ATE137729T1 (de) | 1996-05-15 |
EP0598228B1 (de) | 1996-05-08 |
ES2086850T3 (es) | 1996-07-01 |
MY109072A (en) | 1996-11-30 |
CN1090568A (zh) | 1994-08-10 |
JP3488491B2 (ja) | 2004-01-19 |
US5426249A (en) | 1995-06-20 |
TW343963B (en) | 1998-11-01 |
BR9304715A (pt) | 1994-11-01 |
DE59302507D1 (de) | 1996-06-13 |
JPH06192147A (ja) | 1994-07-12 |
EP0598228A1 (de) | 1994-05-25 |
DE4238492C2 (de) | 1995-06-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant or registration | ||
MM | Annulment or lapse due to non-payment of fees |