TW200834944A - Doping techniques for group IB III AVIA compound layers - Google Patents
Doping techniques for group IB III AVIA compound layers Download PDFInfo
- Publication number
- TW200834944A TW200834944A TW096146909A TW96146909A TW200834944A TW 200834944 A TW200834944 A TW 200834944A TW 096146909 A TW096146909 A TW 096146909A TW 96146909 A TW96146909 A TW 96146909A TW 200834944 A TW200834944 A TW 200834944A
- Authority
- TW
- Taiwan
- Prior art keywords
- layer
- dopant
- group
- film
- metal precursor
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 68
- 150000001875 compounds Chemical class 0.000 title description 18
- 239000000463 material Substances 0.000 claims abstract description 173
- 239000002019 doping agent Substances 0.000 claims abstract description 165
- 239000002243 precursor Substances 0.000 claims abstract description 153
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 37
- 239000006096 absorbing agent Substances 0.000 claims abstract description 36
- 229910052738 indium Inorganic materials 0.000 claims abstract description 29
- 229910052802 copper Inorganic materials 0.000 claims abstract description 19
- 239000010410 layer Substances 0.000 claims description 491
- 229910052751 metal Inorganic materials 0.000 claims description 96
- 239000002184 metal Substances 0.000 claims description 96
- 239000000758 substrate Substances 0.000 claims description 74
- 239000010949 copper Substances 0.000 claims description 57
- 239000011669 selenium Substances 0.000 claims description 57
- 238000000151 deposition Methods 0.000 claims description 43
- 239000011734 sodium Substances 0.000 claims description 43
- 230000008569 process Effects 0.000 claims description 37
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 238000000137 annealing Methods 0.000 claims description 17
- 229910052711 selenium Inorganic materials 0.000 claims description 15
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- 238000009713 electroplating Methods 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000011247 coating layer Substances 0.000 claims description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 2
- 229910052797 bismuth Inorganic materials 0.000 claims 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 4
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 238000003618 dip coating Methods 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
- 239000010408 film Substances 0.000 description 73
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 42
- 238000010521 absorption reaction Methods 0.000 description 35
- 210000004027 cell Anatomy 0.000 description 31
- 239000011775 sodium fluoride Substances 0.000 description 20
- 235000013024 sodium fluoride Nutrition 0.000 description 20
- 230000008021 deposition Effects 0.000 description 16
- 239000000203 mixture Substances 0.000 description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 11
- 239000012535 impurity Substances 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- 239000002250 absorbent Substances 0.000 description 8
- 230000002745 absorbent Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 239000004065 semiconductor Substances 0.000 description 8
- 239000000956 alloy Substances 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 238000004070 electrodeposition Methods 0.000 description 7
- 239000011888 foil Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 238000004544 sputter deposition Methods 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- 230000004888 barrier function Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 229910052746 lanthanum Inorganic materials 0.000 description 5
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 5
- 229910052707 ruthenium Inorganic materials 0.000 description 5
- 239000010409 thin film Substances 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- 206010028980 Neoplasm Diseases 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229910052762 osmium Inorganic materials 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 229910052741 iridium Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- 238000001878 scanning electron micrograph Methods 0.000 description 3
- SPVXKVOXSXTJOY-UHFFFAOYSA-N selane Chemical compound [SeH2] SPVXKVOXSXTJOY-UHFFFAOYSA-N 0.000 description 3
- 229910000058 selane Inorganic materials 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- 229910052714 tellurium Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910017612 Cu(In,Ga)Se2 Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910002056 binary alloy Inorganic materials 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 239000000039 congener Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000011257 shell material Substances 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 102000040717 Alpha family Human genes 0.000 description 1
- 108091071248 Alpha family Proteins 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- 108091006629 SLC13A2 Proteins 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- FQZRHZYQHIYASI-UHFFFAOYSA-N [N-]=[N+]=[N-].[N-]=[N+]=[N-].[NH5+2] Chemical compound [N-]=[N+]=[N-].[N-]=[N+]=[N-].[NH5+2] FQZRHZYQHIYASI-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 210000003323 beak Anatomy 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000010549 co-Evaporation Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- HVMJUDPAXRRVQO-UHFFFAOYSA-N copper indium Chemical compound [Cu].[In] HVMJUDPAXRRVQO-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- BVTBRVFYZUCAKH-UHFFFAOYSA-L disodium selenite Chemical compound [Na+].[Na+].[O-][Se]([O-])=O BVTBRVFYZUCAKH-UHFFFAOYSA-L 0.000 description 1
- VDQVEACBQKUUSU-UHFFFAOYSA-M disodium;sulfanide Chemical compound [Na+].[Na+].[SH-] VDQVEACBQKUUSU-UHFFFAOYSA-M 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 229910001325 element alloy Inorganic materials 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- BVSHTEBQPBBCFT-UHFFFAOYSA-N gallium(iii) sulfide Chemical compound [S-2].[S-2].[S-2].[Ga+3].[Ga+3] BVSHTEBQPBBCFT-UHFFFAOYSA-N 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000005247 gettering Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000001540 jet deposition Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000002488 metal-organic chemical vapour deposition Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- NALMPLUMOWIVJC-UHFFFAOYSA-N n,n,4-trimethylbenzeneamine oxide Chemical compound CC1=CC=C([N+](C)(C)[O-])C=C1 NALMPLUMOWIVJC-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005289 physical deposition Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 229940091258 selenium supplement Drugs 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229940001593 sodium carbonate Drugs 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011697 sodium iodate Substances 0.000 description 1
- 229940032753 sodium iodate Drugs 0.000 description 1
- 235000015281 sodium iodate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- VPQBLCVGUWPDHV-UHFFFAOYSA-N sodium selenide Chemical compound [Na+].[Na+].[Se-2] VPQBLCVGUWPDHV-UHFFFAOYSA-N 0.000 description 1
- 239000011781 sodium selenite Substances 0.000 description 1
- 229960001471 sodium selenite Drugs 0.000 description 1
- 235000015921 sodium selenite Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- -1 sodium tetrafluoroborate Chemical compound 0.000 description 1
- 229910001495 sodium tetrafluoroborate Inorganic materials 0.000 description 1
- SYXYWTXQFUUWLP-UHFFFAOYSA-N sodium;butan-1-olate Chemical compound [Na+].CCCC[O-] SYXYWTXQFUUWLP-UHFFFAOYSA-N 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 229910002058 ternary alloy Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F19/00—Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules
- H10F19/30—Integrated devices, or assemblies of multiple devices, comprising at least one photovoltaic cell covered by group H10F10/00, e.g. photovoltaic modules comprising thin-film photovoltaic cells
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/12—Active materials
- H10F77/126—Active materials comprising only Group I-III-VI chalcopyrite materials, e.g. CuInSe2, CuGaSe2 or CuInGaSe2 [CIGS]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F10/00—Individual photovoltaic cells, e.g. solar cells
- H10F10/10—Individual photovoltaic cells, e.g. solar cells having potential barriers
- H10F10/16—Photovoltaic cells having only PN heterojunction potential barriers
- H10F10/167—Photovoltaic cells having only PN heterojunction potential barriers comprising Group I-III-VI materials, e.g. CdS/CuInSe2 [CIS] heterojunction photovoltaic cells
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F77/00—Constructional details of devices covered by this subclass
- H10F77/10—Semiconductor bodies
- H10F77/12—Active materials
- H10F77/126—Active materials comprising only Group I-III-VI chalcopyrite materials, e.g. CuInSe2, CuGaSe2 or CuInGaSe2 [CIGS]
- H10F77/1265—Active materials comprising only Group I-III-VI chalcopyrite materials, e.g. CuInSe2, CuGaSe2 or CuInGaSe2 [CIGS] characterised by the dopants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/541—CuInSe2 material PV cells
Landscapes
- Photovoltaic Devices (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86927606P | 2006-12-08 | 2006-12-08 | |
| US87082706P | 2006-12-19 | 2006-12-19 | |
| US11/852,980 US20080169025A1 (en) | 2006-12-08 | 2007-09-10 | Doping techniques for group ibiiiavia compound layers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200834944A true TW200834944A (en) | 2008-08-16 |
Family
ID=39616847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW096146909A TW200834944A (en) | 2006-12-08 | 2007-12-07 | Doping techniques for group IB III AVIA compound layers |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20080169025A1 (enExample) |
| EP (1) | EP2097930A2 (enExample) |
| JP (1) | JP2010512647A (enExample) |
| KR (1) | KR20090106513A (enExample) |
| CN (1) | CN101589472B (enExample) |
| TW (1) | TW200834944A (enExample) |
| WO (1) | WO2008127449A2 (enExample) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI405347B (zh) * | 2010-07-02 | 2013-08-11 | Gcsol Tech Co Ltd | Cigs太陽能電池 |
| TWI463685B (zh) * | 2012-12-17 | 2014-12-01 | Ind Tech Res Inst | 多層堆疊的光吸收薄膜與其製造方法及太陽能電池 |
| TWI500170B (zh) * | 2011-11-22 | 2015-09-11 | Lu Chung Hsin | 製造摻雜Bi之IB-IIIA-VIA化合物之光吸收層的方法與包含其之太陽能電池 |
| TWI559560B (zh) * | 2013-08-13 | 2016-11-21 | 呂宗昕 | 光吸收層、包含光吸收層的太陽能電池、用以製備光吸收層的前驅物溶液及製造光吸收層的方法 |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070163640A1 (en) * | 2004-02-19 | 2007-07-19 | Nanosolar, Inc. | High-throughput printing of semiconductor precursor layer by use of chalcogen-rich chalcogenides |
| US7892413B2 (en) * | 2006-09-27 | 2011-02-22 | Solopower, Inc. | Electroplating methods and chemistries for deposition of copper-indium-gallium containing thin films |
| US8066865B2 (en) * | 2008-05-19 | 2011-11-29 | Solopower, Inc. | Electroplating methods and chemistries for deposition of group IIIA-group via thin films |
| US20100140098A1 (en) * | 2008-05-15 | 2010-06-10 | Solopower, Inc. | Selenium containing electrodeposition solution and methods |
| US8409418B2 (en) * | 2009-02-06 | 2013-04-02 | Solopower, Inc. | Enhanced plating chemistries and methods for preparation of group IBIIIAVIA thin film solar cell absorbers |
| US8425753B2 (en) * | 2008-05-19 | 2013-04-23 | Solopower, Inc. | Electroplating methods and chemistries for deposition of copper-indium-gallium containing thin films |
| US20090283411A1 (en) * | 2008-05-15 | 2009-11-19 | Serdar Aksu | Selenium electroplating chemistries and methods |
| IT1391802B1 (it) * | 2008-11-21 | 2012-01-27 | Consiglio Nazionale Ricerche | Metodo di realizzazione di celle solari multistrato a film sottile |
| EP2399295B1 (en) * | 2009-02-20 | 2019-04-10 | Beijing Apollo Ding rong Solar Technology Co., Ltd. | Protective layer for large-scale production of thin-film solar cells |
| US8709856B2 (en) * | 2009-03-09 | 2014-04-29 | Zetta Research and Development LLC—AQT Series | Enhancement of semiconducting photovoltaic absorbers by the addition of alkali salts through solution coating techniques |
| DE102009013903A1 (de) * | 2009-03-19 | 2010-09-23 | Clariant International Limited | Solarzellen mit einer Barriereschicht auf Basis von Polysilazan |
| US7897020B2 (en) * | 2009-04-13 | 2011-03-01 | Miasole | Method for alkali doping of thin film photovoltaic materials |
| WO2010126699A2 (en) | 2009-04-29 | 2010-11-04 | Hunter Douglas Industries B.V. | Architectural panels with organic photovoltaic interlayers and methods of forming the same |
| US8277894B2 (en) * | 2009-07-16 | 2012-10-02 | Rohm And Haas Electronic Materials Llc | Selenium ink and methods of making and using same |
| US20110048493A1 (en) * | 2009-09-02 | 2011-03-03 | Electronics And Telecommunications Research Institute | Solar cell |
| KR101306913B1 (ko) * | 2009-09-02 | 2013-09-10 | 한국전자통신연구원 | 태양 전지 |
| US20110067998A1 (en) * | 2009-09-20 | 2011-03-24 | Miasole | Method of making an electrically conductive cadmium sulfide sputtering target for photovoltaic manufacturing |
| TW201124544A (en) * | 2009-11-24 | 2011-07-16 | Applied Quantum Technology Llc | Chalcogenide absorber layers for photovoltaic applications and methods of manufacturing the same |
| CN102656701B (zh) * | 2009-12-15 | 2016-05-04 | 第一太阳能有限公司 | 光伏窗口层 |
| CN102859046A (zh) * | 2009-12-18 | 2013-01-02 | 索罗能源公司 | Ib/iiia/via族薄膜太阳能吸收器的镀覆化学物 |
| TWI520367B (zh) * | 2010-02-09 | 2016-02-01 | 陶氏全球科技公司 | 具透明導電阻擋層之光伏打裝置 |
| US8048707B1 (en) | 2010-10-19 | 2011-11-01 | Miasole | Sulfur salt containing CIG targets, methods of making and methods of use thereof |
| US7935558B1 (en) | 2010-10-19 | 2011-05-03 | Miasole | Sodium salt containing CIG targets, methods of making and methods of use thereof |
| US9169548B1 (en) | 2010-10-19 | 2015-10-27 | Apollo Precision Fujian Limited | Photovoltaic cell with copper poor CIGS absorber layer and method of making thereof |
| US20120132281A1 (en) * | 2010-11-26 | 2012-05-31 | Nexpower Technology Corporation | Thin-film solar cell and manufacturing method thereof |
| US8404512B1 (en) * | 2011-03-04 | 2013-03-26 | Solopower, Inc. | Crystallization methods for preparing group IBIIIAVIA thin film solar absorbers |
| TWI538235B (zh) | 2011-04-19 | 2016-06-11 | 弗里松股份有限公司 | 薄膜光伏打裝置及製造方法 |
| FR2977078B1 (fr) | 2011-06-27 | 2013-06-28 | Saint Gobain | Substrat conducteur pour cellule photovoltaique |
| US8436445B2 (en) * | 2011-08-15 | 2013-05-07 | Stion Corporation | Method of manufacture of sodium doped CIGS/CIGSS absorber layers for high efficiency photovoltaic devices |
| KR101896951B1 (ko) * | 2011-10-13 | 2018-09-12 | 엘지이노텍 주식회사 | 태양전지 및 이의 제조방법 |
| US10043921B1 (en) | 2011-12-21 | 2018-08-07 | Beijing Apollo Ding Rong Solar Technology Co., Ltd. | Photovoltaic cell with high efficiency cigs absorber layer with low minority carrier lifetime and method of making thereof |
| CN103258899A (zh) * | 2012-02-17 | 2013-08-21 | 任丘市永基光电太阳能有限公司 | 一种柔性不锈钢衬底上cigs吸收层制备方法 |
| US20130213478A1 (en) * | 2012-02-21 | 2013-08-22 | Aqt Solar, Inc. | Enhancing the Photovoltaic Response of CZTS Thin-Films |
| CN103296130A (zh) * | 2012-03-05 | 2013-09-11 | 任丘市永基光电太阳能有限公司 | 一种柔性不锈钢衬底上CIGS吸收层的Na掺杂方法 |
| KR20130105325A (ko) * | 2012-03-12 | 2013-09-25 | 한국에너지기술연구원 | Na 무함유 기판을 이용한 CIGS계 박막 태양전지의 제조방법 및 이에 따라 제조된 태양전지 |
| JP5878416B2 (ja) * | 2012-03-30 | 2016-03-08 | 本田技研工業株式会社 | カルコパイライト型太陽電池及びその製造方法 |
| US20140090710A1 (en) * | 2012-09-29 | 2014-04-03 | Precursor Energetics, Inc. | Ink deposition processes for thin film cigs absorbers |
| CN104704617B (zh) | 2012-12-21 | 2018-03-20 | 弗立泽姆公司 | 制造添加有钾的薄膜光电装置 |
| KR101450426B1 (ko) * | 2013-01-09 | 2014-10-14 | 연세대학교 산학협력단 | 칼코겐화물 흡수층용 나트륨 도핑 용액 및 이를 이용한 박막태양전지 제조방법 |
| KR101458427B1 (ko) * | 2013-03-12 | 2014-11-10 | 한국에너지기술연구원 | 성능이 향상된 ci(g)s 박막 제조 방법과 이를 이용한 태양전지. |
| CN103710674B (zh) * | 2013-11-26 | 2017-10-20 | 山东希格斯新能源有限责任公司 | 一种制备cigs薄膜太阳能电池工艺方法 |
| KR101485009B1 (ko) * | 2013-12-20 | 2015-01-26 | 한국생산기술연구원 | Cigs계 박막 태양 전지의 제조 방법 및 이에 따른 태양 전지 |
| TWI677105B (zh) | 2014-05-23 | 2019-11-11 | 瑞士商弗里松股份有限公司 | 製造薄膜光電子裝置之方法及可藉由該方法獲得的薄膜光電子裝置 |
| TWI661991B (zh) | 2014-09-18 | 2019-06-11 | 瑞士商弗里松股份有限公司 | 用於製造薄膜裝置之自組裝圖案化 |
| US10516069B2 (en) * | 2014-10-20 | 2019-12-24 | Taiwan Semiconductor Manufacturing Co., Ltd. | Absorber surface modification |
| WO2017137271A1 (en) | 2016-02-11 | 2017-08-17 | Flisom Ag | Self-Assembly Patterning for Fabricating Thin-Film Devices |
| EP3414780B1 (en) | 2016-02-11 | 2020-12-02 | Flisom AG | Fabricating thin-film optoelectronic devices with added rubidium and/or cesium |
| CN105742412A (zh) * | 2016-04-28 | 2016-07-06 | 中国科学院上海微系统与信息技术研究所 | 一种薄膜太阳能电池吸收层碱金属掺入方法 |
| EP3627564A1 (de) * | 2018-09-22 | 2020-03-25 | (CNBM) Bengbu Design & Research Institute for Glass Industry Co., Ltd. | Verfahren zur nachbehandlung einer absorberschicht |
| CN111326602A (zh) * | 2018-12-17 | 2020-06-23 | 北京铂阳顶荣光伏科技有限公司 | 一种铜铟镓硒太阳能薄膜的退火工艺、装置及制备方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4581108A (en) * | 1984-01-06 | 1986-04-08 | Atlantic Richfield Company | Process of forming a compound semiconductive material |
| US4547622A (en) * | 1984-04-27 | 1985-10-15 | Massachusetts Institute Of Technology | Solar cells and photodetectors |
| US4798660A (en) * | 1985-07-16 | 1989-01-17 | Atlantic Richfield Company | Method for forming Cu In Se2 films |
| US5730852A (en) * | 1995-09-25 | 1998-03-24 | Davis, Joseph & Negley | Preparation of cuxinygazsen (X=0-2, Y=0-2, Z=0-2, N=0-3) precursor films by electrodeposition for fabricating high efficiency solar cells |
| JP3249408B2 (ja) * | 1996-10-25 | 2002-01-21 | 昭和シェル石油株式会社 | 薄膜太陽電池の薄膜光吸収層の製造方法及び製造装置 |
| US6339013B1 (en) * | 1997-05-13 | 2002-01-15 | The Board Of Trustees Of The University Of Arkansas | Method of doping silicon, metal doped silicon, method of making solar cells, and solar cells |
| JP4208281B2 (ja) * | 1998-02-26 | 2009-01-14 | キヤノン株式会社 | 積層型光起電力素子 |
| JP2001044464A (ja) * | 1999-07-28 | 2001-02-16 | Asahi Chem Ind Co Ltd | Ib―IIIb―VIb2族化合物半導体層の形成方法、薄膜太陽電池の製造方法 |
| US6441301B1 (en) * | 2000-03-23 | 2002-08-27 | Matsushita Electric Industrial Co., Ltd. | Solar cell and method of manufacturing the same |
| US7842882B2 (en) * | 2004-03-01 | 2010-11-30 | Basol Bulent M | Low cost and high throughput deposition methods and apparatus for high density semiconductor film growth |
| AU2003207295A1 (en) * | 2002-02-14 | 2003-09-04 | Honda Giken Kogyo Kabushiki Kaisha | Light absorbing layer forming method |
| US20050056863A1 (en) * | 2003-09-17 | 2005-03-17 | Matsushita Electric Industrial Co., Ltd. | Semiconductor film, method for manufacturing the semiconductor film, solar cell using the semiconductor film and method for manufacturing the solar cell |
| US7374963B2 (en) * | 2004-03-15 | 2008-05-20 | Solopower, Inc. | Technique and apparatus for depositing thin layers of semiconductors for solar cell fabrication |
| CN100463230C (zh) * | 2004-05-11 | 2009-02-18 | 本田技研工业株式会社 | 黄铜矿型薄膜太阳能电池的制造方法 |
| WO2006053128A2 (en) * | 2004-11-10 | 2006-05-18 | Daystar Technologies, Inc. | Pallet based system for forming thin-film solar cells |
| JP4471855B2 (ja) * | 2005-01-25 | 2010-06-02 | 本田技研工業株式会社 | カルコパイライト型薄膜太陽電池の製造方法 |
-
2007
- 2007-09-10 US US11/852,980 patent/US20080169025A1/en not_active Abandoned
- 2007-12-03 CN CN2007800502716A patent/CN101589472B/zh not_active Expired - Fee Related
- 2007-12-03 JP JP2009540413A patent/JP2010512647A/ja active Pending
- 2007-12-03 EP EP07873652A patent/EP2097930A2/en not_active Withdrawn
- 2007-12-03 WO PCT/US2007/086300 patent/WO2008127449A2/en not_active Ceased
- 2007-12-03 KR KR1020097014297A patent/KR20090106513A/ko not_active Ceased
- 2007-12-07 TW TW096146909A patent/TW200834944A/zh unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI405347B (zh) * | 2010-07-02 | 2013-08-11 | Gcsol Tech Co Ltd | Cigs太陽能電池 |
| TWI500170B (zh) * | 2011-11-22 | 2015-09-11 | Lu Chung Hsin | 製造摻雜Bi之IB-IIIA-VIA化合物之光吸收層的方法與包含其之太陽能電池 |
| TWI463685B (zh) * | 2012-12-17 | 2014-12-01 | Ind Tech Res Inst | 多層堆疊的光吸收薄膜與其製造方法及太陽能電池 |
| TWI559560B (zh) * | 2013-08-13 | 2016-11-21 | 呂宗昕 | 光吸收層、包含光吸收層的太陽能電池、用以製備光吸收層的前驅物溶液及製造光吸收層的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20090106513A (ko) | 2009-10-09 |
| JP2010512647A (ja) | 2010-04-22 |
| WO2008127449A2 (en) | 2008-10-23 |
| CN101589472A (zh) | 2009-11-25 |
| CN101589472B (zh) | 2012-09-05 |
| EP2097930A2 (en) | 2009-09-09 |
| WO2008127449A3 (en) | 2009-01-15 |
| US20080169025A1 (en) | 2008-07-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TW200834944A (en) | Doping techniques for group IB III AVIA compound layers | |
| US8188367B2 (en) | Multilayer structure to form absorber layers for solar cells | |
| CN101443920B (zh) | 制备用于薄膜太阳能电池制造及其相应装置的前体膜和化合物层的技术 | |
| US8026122B1 (en) | Metal species surface treatment of thin film photovoltaic cell and manufacturing method | |
| US20080023336A1 (en) | Technique for doping compound layers used in solar cell fabrication | |
| JP6096790B2 (ja) | 光電池のための導電性基材 | |
| US20070178620A1 (en) | Method of Forming Copper Indium Gallium Containing Precursors And Semiconductor Compound Layers | |
| JP5956397B2 (ja) | 銅・インジウム・ガリウム・セレニウム(cigs)または銅・亜鉛・錫・硫黄(czts)系薄膜型太陽電池及びその製造方法 | |
| JP4110515B2 (ja) | 薄膜太陽電池およびその製造方法 | |
| WO2003069684A1 (fr) | Procédé de formation de couche absorbant la lumière | |
| JP5928612B2 (ja) | 化合物半導体太陽電池 | |
| JP2008520102A (ja) | アルカリ含有層を用いた方法及び光起電力素子 | |
| US20130104972A1 (en) | Se OR S BASED THIN FILM SOLAR CELL AND METHOD OF MANUFACTURING THE SAME | |
| US9391231B2 (en) | Method for preparing a thin layer of an absorber made of copper, zinc and tin sulfide(s), annealed thin layer and photovoltaic device thus obtained | |
| Li et al. | Sputtering of molybdenum as a promising back electrode candidate for superstrate structured Sb2S3 solar cells | |
| JP4055064B2 (ja) | 薄膜太陽電池の製造方法 | |
| CN107078180A (zh) | 一种光伏电池及其制造方法 | |
| CN103620792A (zh) | 太阳能电池及其制备方法 | |
| KR101160487B1 (ko) | 후막형 cigs 태양전지 및 그 제조방법 | |
| TW201106497A (en) | Method for manufacturing solar cell component | |
| CN117641950A (zh) | 一种钙钛矿太阳电池及其制备方法、光伏组件 | |
| CN121174774A (en) | Solar cell, preparation method thereof and photovoltaic module | |
| Hossain et al. | Nano Materials Science | |
| Romanyuk et al. | Article type: Feature Article All solution-processed chalcogenide solar cells–from single functional layers towards a 13.8% efficient CIGS device | |
| TW201607054A (zh) | 薄膜太陽能電池及其製作方法 |