TR200000456T2 - Glufosinatların ve ara ürünlerinin üretimine dair yöntem. - Google Patents
Glufosinatların ve ara ürünlerinin üretimine dair yöntem.Info
- Publication number
- TR200000456T2 TR200000456T2 TR2000/00456T TR200000456T TR200000456T2 TR 200000456 T2 TR200000456 T2 TR 200000456T2 TR 2000/00456 T TR2000/00456 T TR 2000/00456T TR 200000456 T TR200000456 T TR 200000456T TR 200000456 T2 TR200000456 T2 TR 200000456T2
- Authority
- TR
- Turkey
- Prior art keywords
- glufosinates
- compounds
- iii
- intermediates
- production
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000000543 intermediate Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 4
- 230000007062 hydrolysis Effects 0.000 abstract 2
- 238000006460 hydrolysis reaction Methods 0.000 abstract 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 1
- 125000005219 aminonitrile group Chemical group 0.000 abstract 1
- 235000019270 ammonium chloride Nutrition 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- -1 ketone compounds Chemical class 0.000 abstract 1
- MNWBNISUBARLIT-UHFFFAOYSA-N sodium cyanide Chemical compound [Na+].N#[C-] MNWBNISUBARLIT-UHFFFAOYSA-N 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/657163—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom
- C07F9/657172—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms the ring phosphorus atom being bound to at least one carbon atom the ring phosphorus atom and one oxygen atom being part of a (thio)phosphinic acid ester: (X = O, S)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/32—Esters thereof
- C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/3211—Esters of acyclic saturated acids which can have further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19736125A DE19736125A1 (de) | 1997-08-20 | 1997-08-20 | Verfahren zur Herstellung von Glufosinate und phosphorhaltige alpha-Aminonitrile als Zwischenprodukte |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TR200000456T2 true TR200000456T2 (tr) | 2000-07-21 |
Family
ID=7839559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TR2000/00456T TR200000456T2 (tr) | 1997-08-20 | 1998-08-08 | Glufosinatların ve ara ürünlerinin üretimine dair yöntem. |
Country Status (27)
| Country | Link |
|---|---|
| US (1) | US6359162B1 (enExample) |
| EP (1) | EP1005475B1 (enExample) |
| JP (1) | JP4519316B2 (enExample) |
| KR (1) | KR100674326B1 (enExample) |
| CN (1) | CN1261442C (enExample) |
| AR (1) | AR015932A1 (enExample) |
| AT (1) | ATE258180T1 (enExample) |
| AU (1) | AU756471B2 (enExample) |
| BR (1) | BR9811971B1 (enExample) |
| CA (1) | CA2301181C (enExample) |
| CO (1) | CO5031316A1 (enExample) |
| CZ (1) | CZ2000593A3 (enExample) |
| DE (2) | DE19736125A1 (enExample) |
| DK (1) | DK1005475T3 (enExample) |
| ES (1) | ES2214727T3 (enExample) |
| HU (1) | HUP0003501A3 (enExample) |
| IL (1) | IL134633A0 (enExample) |
| MY (1) | MY132853A (enExample) |
| PH (1) | PH11998002119A1 (enExample) |
| PL (1) | PL191587B1 (enExample) |
| PT (1) | PT1005475E (enExample) |
| RU (1) | RU2275376C2 (enExample) |
| TR (1) | TR200000456T2 (enExample) |
| TW (1) | TW530063B (enExample) |
| UA (1) | UA66806C2 (enExample) |
| WO (1) | WO1999009039A1 (enExample) |
| ZA (1) | ZA987465B (enExample) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100972717B1 (ko) * | 2002-03-21 | 2010-07-27 | 바이엘 쉐링 파마 악티엔게젤샤프트 | 혈장 카르복시펩티드분해효소 ｂ 억제제 |
| EP2065391B1 (en) * | 2006-09-20 | 2014-06-18 | Meiji Seika Pharma Co., Ltd. | Method for producing phosphorus-containing a-amino acid and production intermediate thereof |
| BR112012026205A2 (pt) | 2010-04-14 | 2015-11-03 | Strategic Enzyme Applic Inc | processo para produção enzimática de um produto de fosfinotricina ou um precursor do mesmo |
| CN102372738B (zh) * | 2010-08-14 | 2017-11-10 | 武汉工程大学 | Lj反应在制备维蒂希试剂和草铵膦中的应用 |
| US9255115B2 (en) | 2011-09-30 | 2016-02-09 | Meiji Seika Pharma Co. Ltd. | Method for producing glufosinate P free acid |
| CN102372739B (zh) * | 2011-12-05 | 2017-06-16 | 河北威远生化农药有限公司 | 一种草铵膦的合成方法 |
| CN102399239A (zh) * | 2011-12-27 | 2012-04-04 | 江苏优士化学有限公司 | 一种草铵膦及类似物的合成方法 |
| CN102399240A (zh) * | 2011-12-27 | 2012-04-04 | 江苏优士化学有限公司 | 一种改进的草铵膦及类似物的合成方法 |
| CN103183707B (zh) * | 2011-12-30 | 2016-06-15 | 中化蓝天集团有限公司 | 一种草胺膦的制备方法 |
| CN102584893B (zh) * | 2012-02-07 | 2015-03-04 | 浙江工业大学 | 一种草铵膦的制备方法 |
| CN103374030B (zh) * | 2012-04-13 | 2016-03-23 | 浙江新安化工集团股份有限公司 | 一种制备草铵膦的方法及其中间体的制备方法 |
| CN103483379A (zh) * | 2013-09-26 | 2014-01-01 | 江苏辉丰农化股份有限公司 | 一种草铵膦酸的制备方法 |
| MX2016014792A (es) * | 2014-05-13 | 2017-03-23 | Bayer Cropscience Ag | Proceso para preparar cianhidrinas que contienen fosforo. |
| CN104558033B (zh) * | 2014-12-19 | 2016-05-18 | 浙江工业大学 | 一种l-草铵膦-n-羧酸酐及其制备和应用 |
| EA039479B1 (ru) | 2015-04-27 | 2022-01-31 | Басф Се | Комбинации гербицидов, содержащие глюфосинат и индазифлам |
| MX2018002731A (es) | 2015-09-02 | 2018-04-13 | Bayer Cropscience Ag | Proceso para la elaboracion de esteres de cianohidrina que contienen fosforo. |
| WO2017037034A1 (de) | 2015-09-02 | 2017-03-09 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von phosphorhaltigen cyanhydrinestern |
| CN108026122B (zh) | 2015-09-02 | 2021-03-09 | 拜耳作物科学股份公司 | 制备含磷氰醇酯的方法 |
| KR20180048894A (ko) | 2015-09-02 | 2018-05-10 | 바이엘 크롭사이언스 악티엔게젤샤프트 | 인 함유 시아노하이드린 에스테르의 제조 방법 |
| US10501485B2 (en) | 2015-09-29 | 2019-12-10 | Basf Se | Process for producing phosphinates |
| CN107236001A (zh) * | 2016-04-06 | 2017-10-10 | 四川省乐山市福华通达农药科技有限公司 | 一种膦醛的合成方法 |
| CN107417721B (zh) * | 2016-05-24 | 2019-05-28 | 四川福思达生物技术开发有限责任公司 | 一种氢氰酸加成工艺 |
| WO2018108794A1 (de) | 2016-12-15 | 2018-06-21 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von d-glufosinat oder dessen salzen unter verwendung von ephedrin |
| WO2018108797A1 (de) | 2016-12-15 | 2018-06-21 | Bayer Cropscience Aktiengesellschaft | Verfahren zur herstellung von l-glufosinat oder dessen salzen unter verwendung von ephedrin |
| EP3392237B1 (de) | 2017-04-21 | 2019-10-02 | Evonik Degussa GmbH | Verfahren zur herstellung von acroleincyanhydrinen |
| US11634442B2 (en) * | 2017-07-18 | 2023-04-25 | Basf Se | Methods for the purification of L-glufosinate |
| MX393530B (es) | 2017-07-21 | 2025-03-24 | Basf Se | Produccion de glufosinato mediante la reaccion de acetato de 3-[n-butoxi(metil)fosforil]-1-cianopropilo para obtener una mezcla de n-butil (3-amino-3-cianopropil)metilfosfinato y sales de amonio de acido (3-amino-3-cianopropil)metilfosfinico. |
| EP3728278B1 (de) | 2017-12-19 | 2022-11-30 | Basf Se | Verfahren zur herstellung von phosphorhaltigen aminonitrilen und glufosinat |
| CN109134534B (zh) * | 2018-08-08 | 2020-09-08 | 江苏好收成韦恩农化股份有限公司 | 一种3,3-二烷氧基丙基甲基膦酸酯简易制备方法 |
| KR102131687B1 (ko) * | 2018-09-10 | 2020-07-08 | 주식회사 휴런 | 파킨슨 병 진단 장치 및 방법 |
| BR112021013261B1 (pt) | 2019-01-11 | 2024-02-20 | Cj Cheiljedang Corporation | Método para produzir l-glufosinato |
| CN111662324B (zh) * | 2019-03-05 | 2023-02-24 | 利尔化学股份有限公司 | 一种制备l-草铵膦的方法 |
| CN111662325B (zh) * | 2019-03-05 | 2023-03-24 | 利尔化学股份有限公司 | 一种制备l-草铵膦的方法 |
| CN111662326B (zh) * | 2019-03-05 | 2023-03-24 | 利尔化学股份有限公司 | 一种制备l-草铵膦的方法 |
| CN110003269B (zh) * | 2019-04-29 | 2022-04-05 | 利尔化学股份有限公司 | 低能耗生产草铵膦的方法 |
| CN110590836B (zh) * | 2019-09-30 | 2022-07-26 | 江苏七洲绿色化工股份有限公司 | 一种草铵膦中间体的合成方法 |
| CN112898338A (zh) * | 2019-12-04 | 2021-06-04 | 利尔化学股份有限公司 | 草铵膦中间体及草铵膦的制备方法 |
| CN111659330B (zh) * | 2020-04-23 | 2021-05-07 | 河北威远生物化工有限公司 | 一种连续化生产草铵膦的工艺与设备 |
| CN112358499A (zh) * | 2020-11-12 | 2021-02-12 | 江苏春江润田农化有限公司 | 一种草铵膦的合成方法 |
| JP7728880B2 (ja) | 2021-04-01 | 2025-08-25 | エボニック オペレーションズ ゲーエムベーハー | Ｌ－グルホシネートおよびそのホスホエステルを産生するための酵素的方法 |
| EP4105335A1 (en) | 2021-06-16 | 2022-12-21 | Evonik Operations GmbH | Enzymatic method for the production of l-glufosinate p-alkyl esters |
| EP4219512B1 (en) * | 2021-07-20 | 2024-08-28 | Lier Chemical Co., Ltd. | Method for preparing glufosinate or analog thereof |
| EP4151643A1 (en) | 2021-09-16 | 2023-03-22 | Evonik Operations GmbH | Improved process for production of phosphoesters of glufosinate precursors |
| CN114163472B (zh) * | 2021-11-27 | 2024-08-09 | 永农生物科学有限公司 | 醇溶剂下合成α-氨基腈的方法及草铵膦的合成方法 |
| EP4493709A1 (en) | 2022-03-14 | 2025-01-22 | Evonik Operations GmbH | Enzymatic method for the production of l-glufosinate p-esters |
| CN116041387B (zh) * | 2022-11-17 | 2023-07-14 | 永农生物科学有限公司 | 一种草铵膦的制备方法 |
| KR20250152064A (ko) | 2023-02-23 | 2025-10-22 | 바스프 에스이 | 시안히드린 또는 시안히드린 유도체로부터 l-글루포시네이트의 제조 방법 |
| CN121335908A (zh) | 2023-06-13 | 2026-01-13 | 巴斯夫欧洲公司 | 使用基于酰胺酶的工艺的草铵膦合成 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5484529A (en) * | 1977-12-19 | 1979-07-05 | Meiji Seika Kaisha Ltd | Production of d,l-2-amino-4-methylphosphinobutyric acid |
| DE2849003A1 (de) | 1978-11-11 | 1980-08-21 | Hoechst Ag | Phosphorhaltige cyanhydrinderivate und verfahren zu ihrer herstellung |
| DE3508573A1 (de) * | 1985-03-11 | 1986-09-11 | Hoechst Ag, 6230 Frankfurt | Phosphorhaltige (alpha)-aminonitrile und verfahren zu ihrer herstellung |
| JP2615777B2 (ja) * | 1987-05-26 | 1997-06-04 | 日産化学工業株式会社 | ホスフィニルアミノ酸誘導体の製造方法 |
| RU2024536C1 (ru) * | 1992-01-09 | 1994-12-15 | Институт элементоорганических соединений РАН | 4-триметилсилоксиметилфосфинил -2- триметилсилокси -2-бутеннитрил в качестве полупродукта синтеза 4-метилгидроксифосфинил-2- кетобутановой кислоты, обладающей гербицидной активностью, и способы его получения |
-
1997
- 1997-08-20 DE DE19736125A patent/DE19736125A1/de not_active Withdrawn
-
1998
- 1998-08-08 PT PT98945195T patent/PT1005475E/pt unknown
- 1998-08-08 CZ CZ2000593A patent/CZ2000593A3/cs unknown
- 1998-08-08 UA UA2000031510A patent/UA66806C2/uk unknown
- 1998-08-08 RU RU2000107139/04A patent/RU2275376C2/ru not_active IP Right Cessation
- 1998-08-08 DE DE59810636T patent/DE59810636D1/de not_active Expired - Lifetime
- 1998-08-08 IL IL13463398A patent/IL134633A0/xx not_active IP Right Cessation
- 1998-08-08 EP EP98945195A patent/EP1005475B1/de not_active Expired - Lifetime
- 1998-08-08 CN CNB988082616A patent/CN1261442C/zh not_active Expired - Lifetime
- 1998-08-08 BR BRPI9811971-0A patent/BR9811971B1/pt not_active IP Right Cessation
- 1998-08-08 AU AU92598/98A patent/AU756471B2/en not_active Ceased
- 1998-08-08 JP JP2000509718A patent/JP4519316B2/ja not_active Expired - Lifetime
- 1998-08-08 WO PCT/EP1998/005053 patent/WO1999009039A1/de not_active Ceased
- 1998-08-08 ES ES98945195T patent/ES2214727T3/es not_active Expired - Lifetime
- 1998-08-08 TR TR2000/00456T patent/TR200000456T2/xx unknown
- 1998-08-08 HU HU0003501A patent/HUP0003501A3/hu unknown
- 1998-08-08 US US09/486,031 patent/US6359162B1/en not_active Expired - Lifetime
- 1998-08-08 CA CA002301181A patent/CA2301181C/en not_active Expired - Fee Related
- 1998-08-08 DK DK98945195T patent/DK1005475T3/da active
- 1998-08-08 PL PL338855A patent/PL191587B1/pl not_active IP Right Cessation
- 1998-08-08 AT AT98945195T patent/ATE258180T1/de not_active IP Right Cessation
- 1998-08-08 KR KR1020007001687A patent/KR100674326B1/ko not_active Expired - Lifetime
- 1998-08-18 CO CO98046950A patent/CO5031316A1/es unknown
- 1998-08-18 TW TW087113567A patent/TW530063B/zh not_active IP Right Cessation
- 1998-08-18 MY MYPI98003746A patent/MY132853A/en unknown
- 1998-08-18 AR ARP980104072A patent/AR015932A1/es active IP Right Grant
- 1998-08-19 ZA ZA987465A patent/ZA987465B/xx unknown
- 1998-08-19 PH PH11998002119A patent/PH11998002119A1/en unknown
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| UA66806C2 (uk) | Спосіб одержання глюфозинату, проміжні продукти та спосіб одержання проміжних продуктів | |
| CA1261854A (en) | METHOD FOR THE PREPARATION OF 4-PHENYLPYRROLE DERIVATIVES | |
| AU7551096A (en) | Process for the synthesis of curcumin-related compounds | |
| RU94042224A (ru) | Способ получения олигонуклеотидов и соответствующие промежуточные соединения | |
| GEP20001938B (en) | Intermediary Compounds for the Hemisynthesis of Taxanes and Preparation Processes Therefor | |
| CA2248953A1 (en) | Novel benzofuranone derivatives and process for producing the same | |
| DE69813792D1 (de) | Zwischenprodukte und verfahren zu ihrer herstellung | |
| PH30922A (en) | Process for cyclic amino acid anticonvulsant compound. | |
| IT1282023B1 (it) | Procedimento per la produzione di uretani aromatici | |
| NO20002214D0 (no) | FremgangsmÕte for syntese av pyrrolaminer | |
| MY110796A (en) | Process for the manufacture of aminomethanephosphonic acid | |
| MXPA03005279A (es) | Proceso mejorado para producir cianhidrina de acetona. | |
| DE69513408D1 (de) | Ein verbessertes verfahren für die herstellung von seitenketten-derivaten von cyclohexapeptidyl-lipopeptiden | |
| AU4502097A (en) | Process for the production of cyanocinnamamides | |
| EP0739885A4 (en) | METHOD FOR PRODUCING 3-ISOXAZOLE CARBONIC ACID | |
| NO985775L (no) | FremgangsmÕte til fremstilling av aminocyanacetamid | |
| AU4264799A (en) | Method for stereoselective production of substituted cyclohexylcyanhydrins | |
| DE69914493D1 (de) | Verfahren zur herstellung von 2-hydroxy-6-trifluormethylpyridin | |
| NZ332245A (en) | Substituted benzo-oxazolol carboxylic acid derivatives, process for their production and medicaments containing them | |
| AU5925498A (en) | Processes for producing 3-cyanopyridine from 2-methyl-1,5-pentanediamine | |
| IL126554A0 (en) | Gamma-oxo-homophenylalanine derivatives and process for producing homophenylalanine derivatives by reducing the same | |
| ATE253553T1 (de) | Verfahren zur herstellung von 2- alkylthiobenzonitril-derivaten | |
| AU5681100A (en) | Method for producing 4,6-dichloropyrimidine | |
| ES2179517T3 (es) | Procedimiento para la obtencion de 2,4,5-trifluor-benzonitrilo. | |
| WO1996003401A3 (en) | Process for the production of aminoazobicycloalkanes from oximes |