SI3036040T1 - A process for the conversion of sugars into lactic acid and 2-hydroxy-3-butenoic acid or esters thereof, comprising a metal-silicate material and a metal ion - Google Patents
A process for the conversion of sugars into lactic acid and 2-hydroxy-3-butenoic acid or esters thereof, comprising a metal-silicate material and a metal ion Download PDFInfo
- Publication number
- SI3036040T1 SI3036040T1 SI201430568T SI201430568T SI3036040T1 SI 3036040 T1 SI3036040 T1 SI 3036040T1 SI 201430568 T SI201430568 T SI 201430568T SI 201430568 T SI201430568 T SI 201430568T SI 3036040 T1 SI3036040 T1 SI 3036040T1
- Authority
- SI
- Slovenia
- Prior art keywords
- metal
- silicate material
- process according
- group
- metal ion
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 20
- 239000000463 material Substances 0.000 title claims abstract 16
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 title claims abstract 8
- 229910021645 metal ion Inorganic materials 0.000 title claims abstract 8
- 235000000346 sugar Nutrition 0.000 title claims abstract 6
- VBWPSWWDYVWZKA-UHFFFAOYSA-N 2-hydroxybut-3-enoic acid Chemical compound C=CC(O)C(O)=O VBWPSWWDYVWZKA-UHFFFAOYSA-N 0.000 title claims abstract 4
- 150000002148 esters Chemical class 0.000 title claims abstract 4
- 239000004310 lactic acid Substances 0.000 title claims abstract 4
- 235000014655 lactic acid Nutrition 0.000 title claims abstract 4
- 150000008163 sugars Chemical class 0.000 title claims 3
- 238000006243 chemical reaction Methods 0.000 title claims 2
- 239000002904 solvent Substances 0.000 claims abstract 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract 2
- 229910001414 potassium ion Inorganic materials 0.000 claims abstract 2
- 238000002360 preparation method Methods 0.000 claims abstract 2
- 229910001419 rubidium ion Inorganic materials 0.000 claims abstract 2
- 229910001415 sodium ion Inorganic materials 0.000 claims abstract 2
- 229910052914 metal silicate Inorganic materials 0.000 claims 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 3
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 claims 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 3
- UUFQTNFCRMXOAE-UHFFFAOYSA-N 1-methylmethylene Chemical compound C[CH] UUFQTNFCRMXOAE-UHFFFAOYSA-N 0.000 claims 2
- LPEKGGXMPWTOCB-UHFFFAOYSA-N 8beta-(2,3-epoxy-2-methylbutyryloxy)-14-acetoxytithifolin Natural products COC(=O)C(C)O LPEKGGXMPWTOCB-UHFFFAOYSA-N 0.000 claims 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 claims 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N Glycolaldehyde Chemical compound OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- ODQWQRRAPPTVAG-GZTJUZNOSA-N doxepin Chemical group C1OC2=CC=CC=C2C(=C/CCN(C)C)/C2=CC=CC=C21 ODQWQRRAPPTVAG-GZTJUZNOSA-N 0.000 claims 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 claims 2
- 229940057867 methyl lactate Drugs 0.000 claims 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 2
- YTBSYETUWUMLBZ-UHFFFAOYSA-N D-Erythrose Natural products OCC(O)C(O)C=O YTBSYETUWUMLBZ-UHFFFAOYSA-N 0.000 claims 1
- YTBSYETUWUMLBZ-IUYQGCFVSA-N D-erythrose Chemical compound OC[C@@H](O)[C@@H](O)C=O YTBSYETUWUMLBZ-IUYQGCFVSA-N 0.000 claims 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 claims 1
- 206010056474 Erythrosis Diseases 0.000 claims 1
- 229930091371 Fructose Natural products 0.000 claims 1
- 239000005715 Fructose Substances 0.000 claims 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims 1
- 229930006000 Sucrose Natural products 0.000 claims 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 claims 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 claims 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- -1 cesium ions Chemical class 0.000 claims 1
- 238000010924 continuous production Methods 0.000 claims 1
- 229940116333 ethyl lactate Drugs 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- 239000008103 glucose Substances 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- 150000003903 lactic acid esters Chemical class 0.000 claims 1
- 229910052808 lithium carbonate Inorganic materials 0.000 claims 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims 1
- 235000011056 potassium acetate Nutrition 0.000 claims 1
- 229910000027 potassium carbonate Inorganic materials 0.000 claims 1
- 235000015320 potassium carbonate Nutrition 0.000 claims 1
- PHZLMBHDXVLRIX-UHFFFAOYSA-M potassium lactate Chemical compound [K+].CC(O)C([O-])=O PHZLMBHDXVLRIX-UHFFFAOYSA-M 0.000 claims 1
- 239000001521 potassium lactate Substances 0.000 claims 1
- 235000011085 potassium lactate Nutrition 0.000 claims 1
- 229960001304 potassium lactate Drugs 0.000 claims 1
- 235000010333 potassium nitrate Nutrition 0.000 claims 1
- 229910000026 rubidium carbonate Inorganic materials 0.000 claims 1
- WPFGFHJALYCVMO-UHFFFAOYSA-L rubidium carbonate Chemical compound [Rb+].[Rb+].[O-]C([O-])=O WPFGFHJALYCVMO-UHFFFAOYSA-L 0.000 claims 1
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 1
- 235000017550 sodium carbonate Nutrition 0.000 claims 1
- 239000005720 sucrose Substances 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 229910001417 caesium ion Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/7057—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/088—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13181069 | 2013-08-20 | ||
| EP14752847.5A EP3036040B1 (en) | 2013-08-20 | 2014-08-15 | Process for the conversion of sugars to lactic acid and 2-hydroxy-3-butenoic acid or esters thereof comprising a metallo-silicate material and a metal ion |
| PCT/EP2014/067475 WO2015024875A1 (en) | 2013-08-20 | 2014-08-15 | Process for the conversion of sugars to lactic acid and 2-hydroxy-3-butenoic acid or esters thereof comprising a metallo-silicate material and a metal ion |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SI3036040T1 true SI3036040T1 (en) | 2018-02-28 |
Family
ID=48986058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SI201430568T SI3036040T1 (en) | 2013-08-20 | 2014-08-15 | A process for the conversion of sugars into lactic acid and 2-hydroxy-3-butenoic acid or esters thereof, comprising a metal-silicate material and a metal ion |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US9573123B2 (https=) |
| EP (2) | EP3284535A1 (https=) |
| JP (1) | JP6431913B2 (https=) |
| KR (1) | KR101919030B1 (https=) |
| CN (2) | CN108465483A (https=) |
| BR (1) | BR112016003585B1 (https=) |
| DK (1) | DK3036040T3 (https=) |
| ES (1) | ES2657987T3 (https=) |
| HU (1) | HUE036409T2 (https=) |
| LT (1) | LT3036040T (https=) |
| MX (1) | MX352954B (https=) |
| NO (1) | NO3036040T3 (https=) |
| PL (1) | PL3036040T3 (https=) |
| SG (1) | SG11201600206SA (https=) |
| SI (1) | SI3036040T1 (https=) |
| TW (1) | TWI642478B (https=) |
| WO (1) | WO2015024875A1 (https=) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2015352840B2 (en) | 2014-11-28 | 2020-01-02 | Haldor Topsøe A/S | Process for preparing esters of lactic acid, and 2-hydroxy-3-butenoic acid or alfa-hydroxy methionine analogues from sugars |
| KR102558113B1 (ko) | 2015-02-12 | 2023-07-24 | 바스프 에스이 | Bea 골격 구조를 갖는 탈알루미늄화된 제올라이트 물질의 제조 방법 |
| JP6908529B2 (ja) | 2015-04-30 | 2021-07-28 | ハルドール・トプサー・アクチエゼルスカベット | 糖およびその誘導体からのメチオニンα−ヒドロキシ類似体の製造方法 |
| EP3106452A1 (en) | 2015-06-18 | 2016-12-21 | Haldor Topsøe A/S | Preparation of 2,5,6-trihydroxy-3-hexenoic acid and 2,5-dihydroxy-3-pentenoic acid and esters thereof from c6 and c5 sugars |
| JP6871873B2 (ja) * | 2015-06-18 | 2021-05-19 | ハルドール・トプサー・アクチエゼルスカベット | Ｃ６およびｃ５糖からの２，５，６−トリヒドロキシ−３−ヘキセン酸および２，５−ジヒドロキシ−３−ペンテン酸ならびにそれらのエステル類の製造 |
| US10252251B2 (en) * | 2015-08-28 | 2019-04-09 | Board Of Regents Of The Nevada System Of Higher Education, On Behalf Of The University Of Nevada, Reno | Production of organic materials using solid catalysts |
| ES2899827T3 (es) * | 2015-12-08 | 2022-03-14 | Basf Se | Material zeolítico que contiene estaño y que tiene una estructura de marco BEA |
| SE1600025A1 (en) * | 2016-01-28 | 2017-06-27 | Perstorp Ab | Radiation curing composition |
| CN111683922B (zh) | 2018-02-09 | 2023-05-30 | 托普索公司 | α-羟基化合物的生产方法及其用途 |
| CN109289909B (zh) * | 2018-10-16 | 2021-03-19 | 郑州大学 | 一种催化复杂糖转化制备乳酸酯的催化剂 |
| CN111253249B (zh) * | 2018-11-30 | 2022-10-21 | 中国石油化工股份有限公司 | 一种制备乳酸酯的方法 |
| CN111116344B (zh) * | 2019-12-22 | 2021-08-31 | 上海交通大学 | 一种光催化转化单糖生物质制备乳酸的方法 |
| CN116199712A (zh) * | 2023-02-03 | 2023-06-02 | 嘉兴学院 | 一种金属-膦杂化材料及其制备方法与应用方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4933161A (en) | 1987-02-04 | 1990-06-12 | Exxon Research And Engineering Company | Tin substitution into zeolite frameworks |
| US5968473A (en) | 1998-12-18 | 1999-10-19 | Uop Llc | Stannosilicate molecular sieves |
| CN1175089C (zh) * | 2001-04-28 | 2004-11-10 | 中国石油化工股份有限公司 | 一种含分子筛的重整催化剂 |
| DE102004020259A1 (de) * | 2004-04-26 | 2005-11-10 | Hte Ag The High Throughput Experimentation Company | Oxidationskatalysator für die simultane Entfernung von Kohlenmonoxid und Kohlenwasserstoffen aus sauerstoffreichen Abgasen und Verfahren zu seiner Herstellung |
| EP2186411A1 (en) * | 2008-09-17 | 2010-05-19 | Taminco | Antimicrobial composition |
| EP2184270B1 (en) | 2008-11-11 | 2013-02-13 | Haldor Topsoe A/S | Zeolite-catalyzed preparation of alpha-hydroxy carboxylic acid compounds and esters thereof |
| WO2011125882A1 (ja) * | 2010-03-31 | 2011-10-13 | 株式会社日本触媒 | 炭水化物含有原料から乳酸類を製造する方法 |
| MY157001A (en) | 2010-03-31 | 2016-04-15 | Nippon Catalytic Chem Ind | Method for producing lactic acids from carbohydrate -containing raw material |
| LV14490B (lv) * | 2011-12-23 | 2012-05-20 | Rīgas Tehniskā Universitāte | Selektīvi katalizatori pienskābes iegūšanai no glicerīna |
| CN103058869B (zh) * | 2013-02-01 | 2015-04-08 | 郑州大学 | 一种催化糖转化制备乳酸及乳酸酯的方法 |
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2014
- 2014-08-15 JP JP2016535434A patent/JP6431913B2/ja active Active
- 2014-08-15 CN CN201810238215.5A patent/CN108465483A/zh active Pending
- 2014-08-15 NO NO14752847A patent/NO3036040T3/no unknown
- 2014-08-15 DK DK14752847.5T patent/DK3036040T3/en active
- 2014-08-15 EP EP17193723.8A patent/EP3284535A1/en not_active Withdrawn
- 2014-08-15 HU HUE14752847A patent/HUE036409T2/hu unknown
- 2014-08-15 KR KR1020167001535A patent/KR101919030B1/ko active Active
- 2014-08-15 ES ES14752847.5T patent/ES2657987T3/es active Active
- 2014-08-15 MX MX2016001863A patent/MX352954B/es active IP Right Grant
- 2014-08-15 US US14/910,319 patent/US9573123B2/en active Active
- 2014-08-15 CN CN201480045946.8A patent/CN105473227B/zh active Active
- 2014-08-15 SI SI201430568T patent/SI3036040T1/en unknown
- 2014-08-15 TW TW103128069A patent/TWI642478B/zh active
- 2014-08-15 WO PCT/EP2014/067475 patent/WO2015024875A1/en not_active Ceased
- 2014-08-15 BR BR112016003585-2A patent/BR112016003585B1/pt active IP Right Grant
- 2014-08-15 PL PL14752847T patent/PL3036040T3/pl unknown
- 2014-08-15 SG SG11201600206SA patent/SG11201600206SA/en unknown
- 2014-08-15 EP EP14752847.5A patent/EP3036040B1/en active Active
- 2014-08-15 LT LTEP14752847.5T patent/LT3036040T/lt unknown
-
2017
- 2017-02-17 US US15/435,758 patent/US9975113B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| MX352954B (es) | 2017-12-15 |
| BR112016003585A2 (pt) | 2018-05-02 |
| US9975113B2 (en) | 2018-05-22 |
| DK3036040T3 (en) | 2018-01-08 |
| KR101919030B1 (ko) | 2018-11-15 |
| TW201517983A (zh) | 2015-05-16 |
| CN105473227A (zh) | 2016-04-06 |
| KR20160045675A (ko) | 2016-04-27 |
| NO3036040T3 (https=) | 2018-04-07 |
| WO2015024875A1 (en) | 2015-02-26 |
| US9573123B2 (en) | 2017-02-21 |
| ES2657987T3 (es) | 2018-03-07 |
| JP6431913B2 (ja) | 2018-11-28 |
| EP3036040A1 (en) | 2016-06-29 |
| US20160175822A1 (en) | 2016-06-23 |
| EP3284535A1 (en) | 2018-02-21 |
| JP2016536324A (ja) | 2016-11-24 |
| CN105473227B (zh) | 2018-04-27 |
| LT3036040T (lt) | 2018-02-12 |
| EP3036040B1 (en) | 2017-11-08 |
| HUE036409T2 (hu) | 2018-07-30 |
| PL3036040T3 (pl) | 2018-04-30 |
| MX2016001863A (es) | 2016-05-16 |
| TWI642478B (zh) | 2018-12-01 |
| CN108465483A (zh) | 2018-08-31 |
| BR112016003585B1 (pt) | 2020-12-01 |
| SG11201600206SA (en) | 2016-02-26 |
| US20170173570A1 (en) | 2017-06-22 |
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