RU2662959C2 - Способ и каталитическая система для получения полимеров и блок-сополимеров - Google Patents

Способ и каталитическая система для получения полимеров и блок-сополимеров Download PDF

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RU2662959C2
RU2662959C2 RU2015150307A RU2015150307A RU2662959C2 RU 2662959 C2 RU2662959 C2 RU 2662959C2 RU 2015150307 A RU2015150307 A RU 2015150307A RU 2015150307 A RU2015150307 A RU 2015150307A RU 2662959 C2 RU2662959 C2 RU 2662959C2
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RU2015150307A
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Шарлотт Кэтрин УИЛЛЬЯМС
Чарльз РОМЭЙН
Майкл КЕМБЕР
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Империал Инновейшнз Лимитед
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/18—Block or graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/40—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
    • C08G63/42—Cyclic ethers; Cyclic carbonates; Cyclic sulfites; Cyclic orthoesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
    • C08G64/20—General preparatory processes
    • C08G64/32—General preparatory processes using carbon dioxide
    • C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
RU2015150307A 2013-05-17 2014-05-16 Способ и каталитическая система для получения полимеров и блок-сополимеров RU2662959C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1308978.4 2013-05-17
GBGB1308978.4A GB201308978D0 (en) 2013-05-17 2013-05-17 Method for producing polymers and block copolymers
PCT/GB2014/051511 WO2014184578A2 (en) 2013-05-17 2014-05-16 Method and catalyst system for preparing polymers and block copolymers

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RU2015150307A RU2015150307A (ru) 2017-06-22
RU2015150307A3 RU2015150307A3 (enExample) 2018-01-25
RU2662959C2 true RU2662959C2 (ru) 2018-07-31

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EP (2) EP3461853A1 (enExample)
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KR (2) KR102036213B1 (enExample)
CN (2) CN107686552A (enExample)
AU (2) AU2014267009B2 (enExample)
BR (1) BR112015028582A2 (enExample)
ES (1) ES2702899T3 (enExample)
GB (1) GB201308978D0 (enExample)
HK (1) HK1245984A1 (enExample)
MX (1) MX376960B (enExample)
PL (1) PL2997071T3 (enExample)
PT (1) PT2997071T (enExample)
RU (2) RU2662959C2 (enExample)
SA (1) SA515370156B1 (enExample)
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Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0807607D0 (en) 2008-04-25 2008-06-04 Imp Innovations Ltd Catalyst
GB201308978D0 (en) 2013-05-17 2013-07-03 Imp Innovations Ltd Method for producing polymers and block copolymers
KR101767310B1 (ko) 2015-07-10 2017-08-10 국민대학교산학협력단 전자끄는기를 포함하는 에폭사이드, 이산화탄소 및 전자끄는기를 포함하지 않는 에폭사이드의 삼원중합체 제조방법
GB201514506D0 (en) * 2015-08-14 2015-09-30 Imp Innovations Ltd Multi-block copolymers
GB201515350D0 (en) 2015-08-28 2015-10-14 Econic Technologies Ltd Method for preparing polyols
JP6713534B2 (ja) * 2016-07-05 2020-06-24 日東化成株式会社 ポリエステル重合用触媒、ポリエステル樹脂の製造方法
PL3538588T3 (pl) 2016-11-11 2023-04-11 Dow Global Technologies Llc Poliole na bazie poliwęglanu
CN111051357B (zh) 2017-09-04 2023-03-31 国立大学法人东京农工大学 新型高分子引发剂及其制造方法、以及嵌段共聚物的制造方法
CN109679077B (zh) * 2018-12-09 2021-03-16 中山大学 一种用（硫）脲/有机碱催化环氧化物与环状酸酐开环共聚制备聚酯的方法
WO2020159669A1 (en) 2019-01-31 2020-08-06 Dow Global Technologies Llc Purification process for polyether-carbonate polyols
CN110511336B (zh) * 2019-09-02 2020-07-10 华中科技大学 一种一氧化碳调控的脂肪族聚酯嵌段共聚物的合成方法
CN111909366B (zh) * 2020-08-13 2021-08-31 天津大学 一种由乙酸钾催化环酐/环氧化物开环交替共聚合制备聚酯的方法
GB202017531D0 (en) 2020-11-05 2020-12-23 Econic Tech Limited (poly)ol block copolymer
CN113072691B (zh) * 2021-04-13 2023-08-01 上海华峰新材料研发科技有限公司 一种聚碳酸环己烯酯共聚物及其制备方法
CN114377726B (zh) * 2021-08-05 2023-03-24 清华大学 一种使用双核金属配合物催化剂进行的塑料水解方法
CN114308120B (zh) * 2021-12-30 2024-10-01 青岛科技大学 一种磷盐两亲性双功能化有机催化剂及其制备方法和应用
CN114456366B (zh) * 2022-01-27 2022-11-11 四川大学 低烟低热本征阻燃共聚碳酸酯及制备方法和应用
CN114456363B (zh) * 2022-02-25 2022-11-01 中国科学院长春应用化学研究所 一种催化体系和多嵌段共聚物的合成方法
CN114891194B (zh) * 2022-06-17 2023-08-29 中国科学院长春应用化学研究所 一种合成聚酯的双功能高分子催化剂及其应用
CN115477744B (zh) * 2022-10-18 2023-09-22 佛山科学技术学院 一种可降解聚酯双子表面活性剂及其制备方法
CN122145775A (zh) * 2026-05-11 2026-06-05 中国科学院长春应用化学研究所 一种光致变色多元共聚酯、光致变色生物可降解聚酯薄膜及其制备与应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4565845A (en) * 1984-09-05 1986-01-21 Hitachi Chemical Company, Ltd. Process for producing polyester and block copolymer thereof
US4665134A (en) * 1984-09-05 1987-05-12 Hitachi Chemical Company Ltd. Process for producing block copolymer
US20120172566A1 (en) * 2010-08-13 2012-07-05 Zhejiang University Metal cyanide complex catalyst and its preparation and application
WO2013034750A2 (en) * 2011-09-08 2013-03-14 Imperial Innovations Limited Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6164724A (ja) * 1984-09-05 1986-04-03 Hitachi Chem Co Ltd ブロツクコポリマ−の製造法
US20060223973A1 (en) 2005-03-29 2006-10-05 Basf Corporation Method of forming a polyethercarbonate polyol
CN100484983C (zh) * 2007-02-12 2009-05-06 江苏中科金龙化工股份有限公司 一种聚酯多元醇的制备方法
RU2355694C2 (ru) * 2007-04-20 2009-05-20 Игорь Леонидович Федюшкин Катализатор получения полилактидов и способ его синтеза
CN101139436B (zh) * 2007-10-18 2010-05-19 吉林大学 胺亚胺锌催化剂的用途
GB0807607D0 (en) 2008-04-25 2008-06-04 Imp Innovations Ltd Catalyst
BRPI0911886B1 (pt) 2008-05-09 2019-09-24 Cornell University Métodos de sintetização de um polímero de poli(carbonato de etileno) e complexos metálicos
KR102089887B1 (ko) 2008-09-08 2020-03-16 사우디 아람코 테크놀로지스 컴퍼니 폴리카보네이트 폴리올 조성물
EP2196486A1 (en) * 2008-12-12 2010-06-16 Total Petrochemicals Research Feluy Process to prepare di- and multiblock copolymers
WO2010110460A1 (ja) * 2009-03-27 2010-09-30 国立大学法人名古屋大学 ラクチド・ε－カプロラクトン共重合体の製造方法
ES2587257T3 (es) 2010-03-24 2016-10-21 Covestro Deutschland Ag Procedimiento para la preparación de polioletercarbonatos
KR101805648B1 (ko) 2010-09-14 2017-12-14 사우디 아람코 테크놀로지스 컴퍼니 중합체 합성용의 촉매 및 방법
KR20130118342A (ko) * 2010-11-18 2013-10-29 사우디 베이식 인더스트리즈 코포레이션 폴리에스테르의 제조 방법
KR101404702B1 (ko) 2011-03-08 2014-06-17 에스케이이노베이션 주식회사 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법
CN102532494A (zh) * 2012-01-06 2012-07-04 华东理工大学 丙交酯-ε-己内酯共聚催化剂及共聚方法
DK2820006T3 (da) 2012-02-29 2017-11-06 Chemocentryx Inc Pyrazol-1-yl benzen sulfonamider som ccr9 antagonister
KR101491119B1 (ko) 2012-09-28 2015-02-10 부산대학교 산학협력단 폴리카보네이트의 제조방법
CN103102480B (zh) * 2013-01-24 2016-03-02 大连理工大学 用于合成立构规整性聚碳酸酯的双金属催化剂
GB201308978D0 (en) 2013-05-17 2013-07-03 Imp Innovations Ltd Method for producing polymers and block copolymers
GB201402109D0 (en) 2014-02-07 2014-03-26 Imp Innovations Ltd Catalyst
TWI675700B (zh) 2014-07-22 2019-11-01 英商伊康尼克科技有限公司 催化劑
GB201514506D0 (en) 2015-08-14 2015-09-30 Imp Innovations Ltd Multi-block copolymers
GB201515350D0 (en) 2015-08-28 2015-10-14 Econic Technologies Ltd Method for preparing polyols

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4565845A (en) * 1984-09-05 1986-01-21 Hitachi Chemical Company, Ltd. Process for producing polyester and block copolymer thereof
US4665134A (en) * 1984-09-05 1987-05-12 Hitachi Chemical Company Ltd. Process for producing block copolymer
US20120172566A1 (en) * 2010-08-13 2012-07-05 Zhejiang University Metal cyanide complex catalyst and its preparation and application
WO2013034750A2 (en) * 2011-09-08 2013-03-14 Imperial Innovations Limited Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Darensbourg D. J. et. al. Kinetic studies of the alternating copolymerization of cyclic acid anhydrides and epoxides, and the terpolymerization of cyclic acid anhydrides, epoxides, and CO2 catalyzed by (salen)CrIIICl. Macromolecules, 2012, v. 45, p. 2242-2248. *

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ES2702899T3 (es) 2019-03-06
EP3461853A1 (en) 2019-04-03
CN105683241B (zh) 2017-10-20
HK1221727A1 (zh) 2017-06-09
JP6484608B2 (ja) 2019-03-13
WO2014184578A2 (en) 2014-11-20
SG10201801884VA (en) 2018-05-30
KR102036213B1 (ko) 2019-10-24
RU2015150307A (ru) 2017-06-22
US10030106B2 (en) 2018-07-24
PL2997071T3 (pl) 2019-05-31
US20160108181A1 (en) 2016-04-21
EP2997071A2 (en) 2016-03-23
MX2015015749A (es) 2016-07-06
KR20190120424A (ko) 2019-10-23
SG11201509148RA (en) 2015-12-30
SG10201811371YA (en) 2019-01-30
CN105683241A (zh) 2016-06-15
US10696797B2 (en) 2020-06-30
PT2997071T (pt) 2019-01-10
RU2018127212A (ru) 2019-03-14
KR20160013874A (ko) 2016-02-05
US20180305501A1 (en) 2018-10-25
WO2014184578A3 (en) 2015-03-19
AU2018200450A1 (en) 2018-02-08
MX376960B (es) 2025-03-07
AU2014267009B2 (en) 2017-12-21
EP2997071B1 (en) 2018-10-03
BR112015028582A2 (pt) 2017-07-25
AU2018200450B2 (en) 2019-10-31
CN107686552A (zh) 2018-02-13
SA515370156B1 (ar) 2018-04-12
GB201308978D0 (en) 2013-07-03
AU2014267009A1 (en) 2015-11-26
HK1245984A1 (zh) 2018-08-31
JP2016518502A (ja) 2016-06-23
JP2019048994A (ja) 2019-03-28

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