SA515370156B1 - طريقة ونظام المحفز لتحضير بوليمر وبوليمرات مشتركة كتلية - Google Patents
طريقة ونظام المحفز لتحضير بوليمر وبوليمرات مشتركة كتلية Download PDFInfo
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- SA515370156B1 SA515370156B1 SA515370156A SA515370156A SA515370156B1 SA 515370156 B1 SA515370156 B1 SA 515370156B1 SA 515370156 A SA515370156 A SA 515370156A SA 515370156 A SA515370156 A SA 515370156A SA 515370156 B1 SA515370156 B1 SA 515370156B1
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- Saudi Arabia
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- monomer
- monomers
- aryl
- combination
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- 238000000034 method Methods 0.000 title claims abstract description 64
- 239000003054 catalyst Substances 0.000 title claims description 141
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- 239000000178 monomer Substances 0.000 claims abstract description 308
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- 125000001931 aliphatic group Chemical group 0.000 claims description 100
- 125000000623 heterocyclic group Chemical group 0.000 claims description 89
- 125000003118 aryl group Chemical group 0.000 claims description 74
- 150000001875 compounds Chemical class 0.000 claims description 73
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- 125000002877 alkyl aryl group Chemical group 0.000 claims description 51
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- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 19
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- 125000003342 alkenyl group Chemical group 0.000 claims description 15
- VWWMOACCGFHMEV-UHFFFAOYSA-N dicarbide(2-) Chemical compound [C-]#[C-] VWWMOACCGFHMEV-UHFFFAOYSA-N 0.000 claims description 15
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- 125000004446 heteroarylalkyl group Chemical group 0.000 claims description 5
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- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 claims description 4
- 239000002879 Lewis base Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
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- 150000007527 lewis bases Chemical class 0.000 claims description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
- XLSZMDLNRCVEIJ-UHFFFAOYSA-N methylimidazole Natural products CC1=CNC=N1 XLSZMDLNRCVEIJ-UHFFFAOYSA-N 0.000 claims description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-M octanoate Chemical compound CCCCCCCC([O-])=O WWZKQHOCKIZLMA-UHFFFAOYSA-M 0.000 claims description 4
- 108090000623 proteins and genes Proteins 0.000 claims description 4
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 4
- MLCHBQKMVKNBOV-UHFFFAOYSA-M dioxido(phenyl)phosphanium Chemical compound [O-]P(=O)C1=CC=CC=C1 MLCHBQKMVKNBOV-UHFFFAOYSA-M 0.000 claims description 3
- BEQVQKJCLJBTKZ-UHFFFAOYSA-M diphenylphosphinate Chemical compound C=1C=CC=CC=1P(=O)([O-])C1=CC=CC=C1 BEQVQKJCLJBTKZ-UHFFFAOYSA-M 0.000 claims description 3
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 claims description 3
- OEBXWWBYZJNKRK-UHFFFAOYSA-N 1-methyl-2,3,4,6,7,8-hexahydropyrimido[1,2-a]pyrimidine Chemical compound C1CCN=C2N(C)CCCN21 OEBXWWBYZJNKRK-UHFFFAOYSA-N 0.000 claims description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims 2
- 125000004474 heteroalkylene group Chemical group 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
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- YZERDTREOUSUHF-UHFFFAOYSA-N pentafluorobenzoic acid Chemical compound OC(=O)C1=C(F)C(F)=C(F)C(F)=C1F YZERDTREOUSUHF-UHFFFAOYSA-N 0.000 claims 2
- ZBNYCYQDFZWFFU-UHFFFAOYSA-N 1h-imidazole;1-methylimidazole Chemical compound C1=CNC=N1.CN1C=CN=C1 ZBNYCYQDFZWFFU-UHFFFAOYSA-N 0.000 claims 1
- 241000272522 Anas Species 0.000 claims 1
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- 235000010643 Leucaena leucocephala Nutrition 0.000 claims 1
- 229910015243 LiMg Inorganic materials 0.000 claims 1
- 241000321453 Paranthias colonus Species 0.000 claims 1
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- 102100036366 ProSAAS Human genes 0.000 claims 1
- 241000377350 Puan Species 0.000 claims 1
- 101100016889 Rattus norvegicus Hes2 gene Proteins 0.000 claims 1
- 102100028255 Renin Human genes 0.000 claims 1
- 108090000783 Renin Proteins 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 125000004948 alkyl aryl alkyl group Chemical group 0.000 claims 1
- 230000033228 biological regulation Effects 0.000 claims 1
- PKOMXLRKGNITKG-UHFFFAOYSA-L calcium;hydroxy(methyl)arsinate Chemical compound [Ca+2].C[As](O)([O-])=O.C[As](O)([O-])=O PKOMXLRKGNITKG-UHFFFAOYSA-L 0.000 claims 1
- DIBHLCJAJIKHGB-UHFFFAOYSA-N dec-5-ene Chemical compound [CH2]CCCC=CCCCC DIBHLCJAJIKHGB-UHFFFAOYSA-N 0.000 claims 1
- 238000002866 fluorescence resonance energy transfer Methods 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical group I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 1
- 230000005764 inhibitory process Effects 0.000 claims 1
- 125000005647 linker group Chemical group 0.000 claims 1
- DYMRYCZRMAHYKE-UHFFFAOYSA-N n-diazonitramide Chemical compound [O-][N+](=O)N=[N+]=[N-] DYMRYCZRMAHYKE-UHFFFAOYSA-N 0.000 claims 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims 1
- BXEMXLDMNMKWPV-UHFFFAOYSA-N pyridine Chemical compound C1=CC=NC=C1.C1=CC=NC=C1 BXEMXLDMNMKWPV-UHFFFAOYSA-N 0.000 claims 1
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- 238000007142 ring opening reaction Methods 0.000 abstract description 9
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
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- ZWAJLVLEBYIOTI-OLQVQODUSA-N (1s,6r)-7-oxabicyclo[4.1.0]heptane Chemical compound C1CCC[C@@H]2O[C@@H]21 ZWAJLVLEBYIOTI-OLQVQODUSA-N 0.000 description 11
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- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 7
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- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
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- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/18—Block or graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/40—Polyesters derived from ester-forming derivatives of polycarboxylic acids or of polyhydroxy compounds, other than from esters thereof
- C08G63/42—Cyclic ethers; Cyclic carbonates; Cyclic sulfites; Cyclic orthoesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
- C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
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| GBGB1308978.4A GB201308978D0 (en) | 2013-05-17 | 2013-05-17 | Method for producing polymers and block copolymers |
| PCT/GB2014/051511 WO2014184578A2 (en) | 2013-05-17 | 2014-05-16 | Method and catalyst system for preparing polymers and block copolymers |
Publications (1)
| Publication Number | Publication Date |
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| SA515370156B1 true SA515370156B1 (ar) | 2018-04-12 |
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Family Applications (1)
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| ES (1) | ES2702899T3 (enExample) |
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| SA (1) | SA515370156B1 (enExample) |
| SG (3) | SG11201509148RA (enExample) |
| WO (1) | WO2014184578A2 (enExample) |
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| GB0807607D0 (en) | 2008-04-25 | 2008-06-04 | Imp Innovations Ltd | Catalyst |
| GB201308978D0 (en) | 2013-05-17 | 2013-07-03 | Imp Innovations Ltd | Method for producing polymers and block copolymers |
| KR101767310B1 (ko) | 2015-07-10 | 2017-08-10 | 국민대학교산학협력단 | 전자끄는기를 포함하는 에폭사이드, 이산화탄소 및 전자끄는기를 포함하지 않는 에폭사이드의 삼원중합체 제조방법 |
| GB201514506D0 (en) * | 2015-08-14 | 2015-09-30 | Imp Innovations Ltd | Multi-block copolymers |
| GB201515350D0 (en) | 2015-08-28 | 2015-10-14 | Econic Technologies Ltd | Method for preparing polyols |
| ES2886653T3 (es) * | 2016-07-05 | 2021-12-20 | Nitto Kasei Co Ltd | Catalizador para la polimerización de poliéster y método para producir resina de poliéster |
| WO2018089566A1 (en) | 2016-11-11 | 2018-05-17 | Dow Global Technologies Llc | Polycarbonate Based Polyols |
| CN111051357B (zh) | 2017-09-04 | 2023-03-31 | 国立大学法人东京农工大学 | 新型高分子引发剂及其制造方法、以及嵌段共聚物的制造方法 |
| CN109679077B (zh) * | 2018-12-09 | 2021-03-16 | 中山大学 | 一种用（硫）脲/有机碱催化环氧化物与环状酸酐开环共聚制备聚酯的方法 |
| WO2020159669A1 (en) | 2019-01-31 | 2020-08-06 | Dow Global Technologies Llc | Purification process for polyether-carbonate polyols |
| CN110511336B (zh) * | 2019-09-02 | 2020-07-10 | 华中科技大学 | 一种一氧化碳调控的脂肪族聚酯嵌段共聚物的合成方法 |
| CN111909366B (zh) * | 2020-08-13 | 2021-08-31 | 天津大学 | 一种由乙酸钾催化环酐/环氧化物开环交替共聚合制备聚酯的方法 |
| GB202017531D0 (en) | 2020-11-05 | 2020-12-23 | Econic Tech Limited | (poly)ol block copolymer |
| CN113072691B (zh) * | 2021-04-13 | 2023-08-01 | 上海华峰新材料研发科技有限公司 | 一种聚碳酸环己烯酯共聚物及其制备方法 |
| CN114377726B (zh) * | 2021-08-05 | 2023-03-24 | 清华大学 | 一种使用双核金属配合物催化剂进行的塑料水解方法 |
| CN114308120B (zh) * | 2021-12-30 | 2024-10-01 | 青岛科技大学 | 一种磷盐两亲性双功能化有机催化剂及其制备方法和应用 |
| CN114456366B (zh) * | 2022-01-27 | 2022-11-11 | 四川大学 | 低烟低热本征阻燃共聚碳酸酯及制备方法和应用 |
| CN114456363B (zh) * | 2022-02-25 | 2022-11-01 | 中国科学院长春应用化学研究所 | 一种催化体系和多嵌段共聚物的合成方法 |
| CN114891194B (zh) * | 2022-06-17 | 2023-08-29 | 中国科学院长春应用化学研究所 | 一种合成聚酯的双功能高分子催化剂及其应用 |
| CN115477744B (zh) * | 2022-10-18 | 2023-09-22 | 佛山科学技术学院 | 一种可降解聚酯双子表面活性剂及其制备方法 |
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| US4565845A (en) * | 1984-09-05 | 1986-01-21 | Hitachi Chemical Company, Ltd. | Process for producing polyester and block copolymer thereof |
| JPS6164724A (ja) * | 1984-09-05 | 1986-04-03 | Hitachi Chem Co Ltd | ブロツクコポリマ−の製造法 |
| JPS6164721A (ja) * | 1984-09-05 | 1986-04-03 | Hitachi Chem Co Ltd | ブロツクコポリマ−の製造方法 |
| US20060223973A1 (en) | 2005-03-29 | 2006-10-05 | Basf Corporation | Method of forming a polyethercarbonate polyol |
| CN100484983C (zh) * | 2007-02-12 | 2009-05-06 | 江苏中科金龙化工股份有限公司 | 一种聚酯多元醇的制备方法 |
| RU2355694C2 (ru) * | 2007-04-20 | 2009-05-20 | Игорь Леонидович Федюшкин | Катализатор получения полилактидов и способ его синтеза |
| CN101139436B (zh) * | 2007-10-18 | 2010-05-19 | 吉林大学 | 胺亚胺锌催化剂的用途 |
| GB0807607D0 (en) * | 2008-04-25 | 2008-06-04 | Imp Innovations Ltd | Catalyst |
| US20110087001A1 (en) | 2008-05-09 | 2011-04-14 | Cornell University | Polymers of ethylene oxide and carbon dioxide |
| CN103333330A (zh) | 2008-09-08 | 2013-10-02 | 诺沃梅尔公司 | 聚碳酸酯多元醇组合物和方法 |
| EP2196486A1 (en) * | 2008-12-12 | 2010-06-16 | Total Petrochemicals Research Feluy | Process to prepare di- and multiblock copolymers |
| WO2010110460A1 (ja) * | 2009-03-27 | 2010-09-30 | 国立大学法人名古屋大学 | ラクチド・ε－カプロラクトン共重合体の製造方法 |
| CA2794087A1 (en) | 2010-03-24 | 2011-09-29 | Christoph Guertler | Method for producing polyether carbonate polyols |
| US8859452B2 (en) * | 2010-08-13 | 2014-10-14 | Zhejiang University | Metal cyanide complex catalyst and its preparation and application |
| EP2616513B1 (en) | 2010-09-14 | 2019-11-06 | Saudi Aramco Technologies Company | Catalysts and methods for polymer synthesis |
| EP2640766B1 (en) * | 2010-11-18 | 2014-12-17 | Saudi Basic Industries Corporation | Process for preparing a polyester |
| KR101404702B1 (ko) | 2011-03-08 | 2014-06-17 | 에스케이이노베이션 주식회사 | 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법 |
| GB201115565D0 (en) * | 2011-09-08 | 2011-10-26 | Imp Innovations Ltd | Method of synthesising polycarbonates in the presence of a bimetallic catalyst and a chain transfer agent |
| CN102532494A (zh) * | 2012-01-06 | 2012-07-04 | 华东理工大学 | 丙交酯-ε-己内酯共聚催化剂及共聚方法 |
| MX372722B (es) | 2012-02-29 | 2020-06-19 | Chemocentryx Inc | Sulfonamidas de aza-aril 1h-pirazol-1-il benceno |
| KR101491119B1 (ko) | 2012-09-28 | 2015-02-10 | 부산대학교 산학협력단 | 폴리카보네이트의 제조방법 |
| CN103102480B (zh) * | 2013-01-24 | 2016-03-02 | 大连理工大学 | 用于合成立构规整性聚碳酸酯的双金属催化剂 |
| GB201308978D0 (en) | 2013-05-17 | 2013-07-03 | Imp Innovations Ltd | Method for producing polymers and block copolymers |
| GB201402109D0 (en) | 2014-02-07 | 2014-03-26 | Imp Innovations Ltd | Catalyst |
| CN106536048B (zh) | 2014-07-22 | 2020-05-05 | 埃科尼克科技有限公司 | 催化剂 |
| GB201514506D0 (en) | 2015-08-14 | 2015-09-30 | Imp Innovations Ltd | Multi-block copolymers |
| GB201515350D0 (en) | 2015-08-28 | 2015-10-14 | Econic Technologies Ltd | Method for preparing polyols |
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2015
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2018
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