RU2415163C2 - Стабильные полиамиды для проведения одновременной твердофазной полимеризации сложных полиэфиров и полиамидов - Google Patents
Стабильные полиамиды для проведения одновременной твердофазной полимеризации сложных полиэфиров и полиамидов Download PDFInfo
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- RU2415163C2 RU2415163C2 RU2008120651/05A RU2008120651A RU2415163C2 RU 2415163 C2 RU2415163 C2 RU 2415163C2 RU 2008120651/05 A RU2008120651/05 A RU 2008120651/05A RU 2008120651 A RU2008120651 A RU 2008120651A RU 2415163 C2 RU2415163 C2 RU 2415163C2
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- Prior art keywords
- acid
- polyester
- polyamide
- granules
- crystallizable
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- 239000004952 Polyamide Substances 0.000 title claims abstract description 137
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 57
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- 239000002253 acid Substances 0.000 claims abstract description 39
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 28
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims abstract description 26
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- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 claims abstract description 11
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 claims abstract description 10
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- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 claims abstract description 7
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 7
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 claims abstract description 7
- OXIKYYJDTWKERT-UHFFFAOYSA-N [4-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCC(CN)CC1 OXIKYYJDTWKERT-UHFFFAOYSA-N 0.000 claims abstract description 6
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 claims abstract description 6
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- RGELPTBMYNRHGF-UHFFFAOYSA-N terephthalic acid;2,2,2-trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F.OC(=O)C1=CC=C(C(O)=O)C=C1 RGELPTBMYNRHGF-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
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- B29B9/12—Making granules characterised by structure or composition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/02—Conditioning or physical treatment of the material to be shaped by heating
- B29B13/021—Heat treatment of powders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J3/005—Processes for mixing polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Polyesters Or Polycarbonates (AREA)
- Wrappers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
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| US73019805P | 2005-10-25 | 2005-10-25 | |
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| US60/730,198 | 2005-10-25 |
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| RU2008120651/05A RU2415163C2 (ru) | 2005-10-25 | 2006-10-25 | Стабильные полиамиды для проведения одновременной твердофазной полимеризации сложных полиэфиров и полиамидов |
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| RU2008120650/05A RU2420543C2 (ru) | 2005-10-25 | 2006-10-25 | Улучшенные дисперсии полиамидов с высоким содержанием карбоксильных групп в сложных полиэфирах с использованием агента, снижающего межфазное натяжение |
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| JP2844151B2 (ja) | 1993-02-16 | 1999-01-06 | ワイケイケイ株式会社 | 押出形材の切断方法 |
| WO2005092963A1 (en) * | 2004-03-26 | 2005-10-06 | Do Gyun Kim | Recycled method for a wasted polymer which is mixed polyester polyamide and reclaimed materials thereof |
| US20070031546A1 (en) * | 2005-08-05 | 2007-02-08 | Curwood, Inc. | Polyester and polyamide blend containing article for packaging a CO2 respiring foodstuff |
| WO2007049233A1 (en) * | 2005-10-25 | 2007-05-03 | M & G Polimeri Italia S.P.A. | Stable polyamides for simultaneous solid phase polymerization of polyesters and polyamides |
| US9018293B2 (en) * | 2005-10-25 | 2015-04-28 | M&G Usa Corporation | Dispersions of high carboxyl polyamides into polyesters |
| EP2003169B1 (en) * | 2006-03-10 | 2014-10-15 | Mitsubishi Gas Chemical Company, Inc. | Polyester resin composition, method for producing same and molded body |
| US20090054567A1 (en) * | 2007-08-23 | 2009-02-26 | Heater Paul Lewis | Phosphite stabilizers for ionomeric polyester compounds |
| KR20120014889A (ko) | 2009-03-13 | 2012-02-20 | 바스프 에스이 | 폴리에스테르 및 폴리아미드의 안정화된 블렌드 |
| CN102348761A (zh) | 2009-03-13 | 2012-02-08 | 巴斯夫欧洲公司 | 聚酯和聚酰胺的稳定共混物 |
| JP5564851B2 (ja) * | 2009-08-11 | 2014-08-06 | 三菱瓦斯化学株式会社 | ポリエステル系容器 |
| JP5585024B2 (ja) * | 2009-08-11 | 2014-09-10 | 三菱瓦斯化学株式会社 | ポリエステル系容器 |
| JP5609039B2 (ja) * | 2009-08-11 | 2014-10-22 | 三菱瓦斯化学株式会社 | ポリエステル系容器 |
| MX2012002793A (es) * | 2009-09-11 | 2012-04-11 | Indorama Ventures Polymers Mexico S De R L De C V | Metodo para mezclas de resina de poliester mejoradas para eliminacion de oxigeno y productos de las mismas. |
| JP2011132394A (ja) * | 2009-12-25 | 2011-07-07 | Mitsubishi Gas Chemical Co Inc | 二軸延伸中空容器 |
| JP5673010B2 (ja) * | 2010-11-22 | 2015-02-18 | 三菱瓦斯化学株式会社 | 多層ボトル |
| JP5168432B2 (ja) * | 2011-06-10 | 2013-03-21 | 三菱瓦斯化学株式会社 | 反応性ポリアミド樹脂およびポリアミド樹脂組成物 |
| CN102329481A (zh) * | 2011-06-20 | 2012-01-25 | 江苏鹰翔化纤股份有限公司 | 1、2-丁二醇改性涤纶切片的制备方法 |
| WO2013028290A1 (en) | 2011-08-24 | 2013-02-28 | Amyris, Inc. | Oxygen scavengers |
| KR101596180B1 (ko) * | 2011-08-26 | 2016-02-19 | 로디아 오퍼레이션스 | 폴리아미드 수지 및 폴리에스테르 수지의 알로이를 포함한 난연성 조성물 |
| KR101570562B1 (ko) * | 2012-12-28 | 2015-11-19 | 제일모직주식회사 | 폴리아미드 수지, 이의 제조방법 및 이를 포함하는 성형품 |
| FR3008704B1 (fr) * | 2013-07-19 | 2015-08-21 | Rhodia Operations | Barriere a la vapeur adaptative |
| AU2016205389B2 (en) | 2015-01-06 | 2019-09-12 | Lawter, Inc. | Polyamide resins for coating of sand or ceramic proppants used in hydraulic fracturing |
| US10988572B2 (en) | 2017-11-20 | 2021-04-27 | Alliance For Sustainable Energy, Llc | Polymers and methods of making the same |
| US10800897B2 (en) | 2018-04-30 | 2020-10-13 | Skc Inc. | Heat shrinkable film and method for reproducing polyester container using same |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5340884A (en) * | 1992-04-02 | 1994-08-23 | Eastman Kodak Company | Polyamide concentrate useful for producing blends having improved flavor retaining property and clarity |
| US5747548A (en) * | 1995-03-20 | 1998-05-05 | Materials Research Innovations Corporation | Compartmented thermoplastic pellets |
| EP0964031A2 (en) * | 1998-06-11 | 1999-12-15 | SINCO RICERCHE S.p.A. | Polyester resin blends with high-level gas barrier properties |
| EP1063070A2 (en) * | 1999-06-25 | 2000-12-27 | Sumika Color Company Limited | Process for manufacturing multilayer pellets and use of the multilayer pellets |
| WO2001009245A1 (en) * | 1999-07-30 | 2001-02-08 | Eastman Chemical Company | Polyester-polyamide blends with reduced gas permeability and low haze |
| RU2006105756A (ru) * | 2003-08-26 | 2006-08-27 | Инвиста Технолоджис С.А.Р.Л. (Ch) | Способ изготовления однослойных пэт бутылок с высоким барьером и улучшенной прозрачностью |
Family Cites Families (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2997463A (en) * | 1957-03-18 | 1961-08-22 | California Research Corp | Process for the preparation of polymeric materials of the polymamide type |
| DE1694348C3 (de) * | 1967-11-21 | 1975-09-25 | Enka Glanzstoff Ag, 5600 Wuppertal | Verfahren zum kontinuierlichen Einmischen einer Pigmentdispersion in eine Polyamidschmelze |
| DE1769231A1 (de) | 1968-04-24 | 1972-03-02 | Hoechst Ag | Thermoplastische Formmassen aus Polyestern und Polyamiden |
| JPH0611797B2 (ja) | 1987-02-27 | 1994-02-16 | 東洋紡績株式会社 | ポリエステル中空成形体 |
| SE8702840D0 (sv) | 1987-07-10 | 1987-07-10 | Plm Ab | Barrierforsterkning |
| EP0301719A1 (en) | 1987-07-27 | 1989-02-01 | CarnaudMetalbox plc | Improvements in and relating to packaging |
| IN172789B (enExample) | 1988-07-01 | 1993-11-27 | Sir Padampat Research Centre | |
| JP2663578B2 (ja) | 1988-11-17 | 1997-10-15 | 東洋紡績株式会社 | ポリエステル中空成形体 |
| JP2864595B2 (ja) | 1989-12-22 | 1999-03-03 | 東洋紡績株式会社 | 色調の改善されたポリエステル中空成形体 |
| JPH03281246A (ja) | 1990-03-29 | 1991-12-11 | Kuraray Co Ltd | 多層構造体およびそれに用いる組成物 |
| US5300572A (en) * | 1991-06-14 | 1994-04-05 | Polyplastics Co., Ltd. | Moldable polyester resin compositions and molded articles formed of the same |
| JP2976078B2 (ja) † | 1991-07-17 | 1999-11-10 | 花王株式会社 | 静電荷像現像剤組成物 |
| EP0524840B1 (en) * | 1991-07-25 | 1997-06-18 | Toray Industries, Inc. | Polyester composition, process for preparing same and film formed using same |
| JP3235856B2 (ja) * | 1992-01-31 | 2001-12-04 | ポリプラスチックス株式会社 | 成形用樹脂組成物 |
| US5266413A (en) | 1992-05-18 | 1993-11-30 | Eastman Kodak Company | Copolyester/polyamide blend having improved flavor retaining property and clarity |
| CA2084866C (en) * | 1992-06-18 | 2000-02-08 | Matthew B. Hoyt | Reduced staining carpet yarns and carpet |
| DE4234602A1 (de) * | 1992-09-23 | 1994-03-24 | Basf Ag | Formmassen auf der Basis von Polyarylenethern und schlagzähmodifizierten teilaromatischen Copolyamiden |
| JP3458399B2 (ja) * | 1993-01-26 | 2003-10-20 | 三菱化学株式会社 | ポリアミド系組成物 |
| JPH08208950A (ja) | 1995-02-06 | 1996-08-13 | Unitika Ltd | 2軸配向ポリエステルフイルムおよびその製造方法 |
| JP3674650B2 (ja) * | 1996-06-25 | 2005-07-20 | 三菱瓦斯化学株式会社 | 樹脂組成物 |
| US5985389A (en) * | 1997-06-17 | 1999-11-16 | Eastman Chemical Company | Polyester and optical brightener blend having improved properties |
| JP4491848B2 (ja) * | 1998-04-03 | 2010-06-30 | 東レ株式会社 | ポリアミドの製造方法 |
| US6239233B1 (en) * | 1998-10-09 | 2001-05-29 | Eastman Chemical Company | Polyester/polyamide blends with improved color |
| WO2000058404A1 (fr) * | 1999-03-31 | 2000-10-05 | Toyo Boseki Kabusiki Kaisya | Materiau absorbant l'oxygene et objet moule a partir de ce materiau |
| JP2001009833A (ja) * | 1999-06-25 | 2001-01-16 | Sumika Color Kk | 乾燥促進性の良い熱可塑性ポリエステル樹脂とその乾燥方法および製造方法 |
| US6344539B1 (en) * | 2000-03-28 | 2002-02-05 | Walter M Palmer | Process for crystallization polyester granules |
| US6500895B1 (en) * | 2000-10-13 | 2002-12-31 | General Electric Company | Thermoplastic blend comprising poly(arylene ether) and polyamide |
| US6780941B2 (en) * | 2000-12-22 | 2004-08-24 | Prisma Fibers, Inc. | Process for preparing polymeric fibers based on blends of at least two polymers |
| JP4192541B2 (ja) * | 2001-09-20 | 2008-12-10 | 東洋紡績株式会社 | ポリアミドの製造方法およびポリアミド |
| JP4296476B2 (ja) * | 2002-03-19 | 2009-07-15 | 東洋紡績株式会社 | ポリエステル組成物及びそれからなる成形体 |
| WO2003080731A2 (en) * | 2002-03-21 | 2003-10-02 | Advanced Plastics Technologies, Ltd. | Compatibilized polyester/polyamide blends |
| KR100934555B1 (ko) * | 2002-06-03 | 2009-12-29 | 토요 보세키 가부시기가이샤 | 폴리에스테르 조성물 및 그것으로 되는 폴리에스테르포장재료 |
| JP2004210997A (ja) * | 2003-01-07 | 2004-07-29 | Toyobo Co Ltd | ポリエステル組成物およびその用途 |
| JP2004285333A (ja) * | 2003-02-28 | 2004-10-14 | Toyobo Co Ltd | ポリエステル樹脂組成物 |
| JP2005015791A (ja) * | 2003-06-05 | 2005-01-20 | Toyobo Co Ltd | ポリエステル組成物及びそれからなるポリエステル成形体 |
| JP3882802B2 (ja) * | 2003-10-16 | 2007-02-21 | 東洋製罐株式会社 | 包装体 |
| US7541091B2 (en) * | 2004-05-18 | 2009-06-02 | M & G Usa Corporation | Compartmentalized resin pellets for oxygen scavenging |
| CA2565922C (en) * | 2004-05-18 | 2013-02-19 | M & G Polimeri Italia S.P.A. | Compartmentalized resin pellets |
| US7375154B2 (en) | 2004-12-06 | 2008-05-20 | Eastman Chemical Company | Polyester/polyamide blend having improved flavor retaining property and clarity |
| WO2006079044A2 (en) * | 2005-01-24 | 2006-07-27 | Wellman, Inc. | Improved polyamide-polyester polymer blends and methods of making the same |
| US8465818B2 (en) * | 2005-10-07 | 2013-06-18 | M & G Usa Corporation | Polyamides and polyesters blended with a lithium salt interfacial tension reducing agent |
| DE102005051400A1 (de) | 2005-10-25 | 2007-04-26 | Basf Ag | Polyamide aus meta-Xylylendiamin und Adipinsäure mit einem Aminoendgruppengehalt kleiner als 15 mmol/kg |
| WO2007049233A1 (en) | 2005-10-25 | 2007-05-03 | M & G Polimeri Italia S.P.A. | Stable polyamides for simultaneous solid phase polymerization of polyesters and polyamides |
-
2006
- 2006-10-25 WO PCT/IB2006/053924 patent/WO2007049233A1/en not_active Ceased
- 2006-10-25 BR BRPI0619344-7A patent/BRPI0619344A2/pt not_active Application Discontinuation
- 2006-10-25 RU RU2008120650/05A patent/RU2420543C2/ru active
- 2006-10-25 WO PCT/IB2006/053922 patent/WO2007049232A2/en not_active Ceased
- 2006-10-25 AR ARP060104648A patent/AR058495A1/es active IP Right Grant
- 2006-10-25 KR KR1020087012573A patent/KR101328135B1/ko not_active Expired - Fee Related
- 2006-10-25 US US11/552,612 patent/US20070093616A1/en not_active Abandoned
- 2006-10-25 JP JP2008537286A patent/JP5219821B2/ja not_active Expired - Fee Related
- 2006-10-25 TW TW095139324A patent/TWI402304B/zh not_active IP Right Cessation
- 2006-10-25 DK DK06831868.2T patent/DK1943310T3/en active
- 2006-10-25 AR ARP060104649A patent/AR058817A1/es active IP Right Grant
- 2006-10-25 AT AT06809699T patent/ATE437920T1/de not_active IP Right Cessation
- 2006-10-25 CA CA2626862A patent/CA2626862C/en not_active Expired - Fee Related
- 2006-10-25 DE DE602006008176T patent/DE602006008176D1/de active Active
- 2006-10-25 BR BRPI0619343-9A patent/BRPI0619343A2/pt active Search and Examination
- 2006-10-25 PL PL06831868.2T patent/PL1943310T5/pl unknown
- 2006-10-25 DK DK06809699T patent/DK1951810T3/da active
- 2006-10-25 US US11/552,591 patent/US8314174B2/en not_active Expired - Fee Related
- 2006-10-25 AU AU2006307492A patent/AU2006307492B2/en not_active Ceased
- 2006-10-25 RU RU2008120651/05A patent/RU2415163C2/ru active
- 2006-10-25 KR KR1020087012522A patent/KR101323835B1/ko not_active Expired - Fee Related
- 2006-10-25 ES ES06809699T patent/ES2330791T3/es active Active
- 2006-10-25 CA CA2626878A patent/CA2626878C/en not_active Expired - Fee Related
- 2006-10-25 LT LTEP06831868.2T patent/LT1943310T/lt unknown
- 2006-10-25 AU AU2006307493A patent/AU2006307493B2/en not_active Ceased
- 2006-10-25 TW TW095139319A patent/TWI432513B/zh not_active IP Right Cessation
- 2006-10-25 JP JP2008537287A patent/JP5219822B2/ja not_active Expired - Fee Related
- 2006-10-25 ES ES06831868T patent/ES2628316T5/es active Active
- 2006-10-25 PL PL06809699T patent/PL1951810T3/pl unknown
- 2006-10-25 EP EP06831868.2A patent/EP1943310B2/en active Active
- 2006-10-25 EP EP06809699A patent/EP1951810B1/en not_active Revoked
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5340884A (en) * | 1992-04-02 | 1994-08-23 | Eastman Kodak Company | Polyamide concentrate useful for producing blends having improved flavor retaining property and clarity |
| US5747548A (en) * | 1995-03-20 | 1998-05-05 | Materials Research Innovations Corporation | Compartmented thermoplastic pellets |
| EP0964031A2 (en) * | 1998-06-11 | 1999-12-15 | SINCO RICERCHE S.p.A. | Polyester resin blends with high-level gas barrier properties |
| EP1063070A2 (en) * | 1999-06-25 | 2000-12-27 | Sumika Color Company Limited | Process for manufacturing multilayer pellets and use of the multilayer pellets |
| WO2001009245A1 (en) * | 1999-07-30 | 2001-02-08 | Eastman Chemical Company | Polyester-polyamide blends with reduced gas permeability and low haze |
| RU2006105756A (ru) * | 2003-08-26 | 2006-08-27 | Инвиста Технолоджис С.А.Р.Л. (Ch) | Способ изготовления однослойных пэт бутылок с высоким барьером и улучшенной прозрачностью |
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