RU2135522C1 - Каталитическая композиция и способ полимеризации олефинов - Google Patents

Каталитическая композиция и способ полимеризации олефинов Download PDF

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Publication number
RU2135522C1
RU2135522C1 RU97108581A RU97108581A RU2135522C1 RU 2135522 C1 RU2135522 C1 RU 2135522C1 RU 97108581 A RU97108581 A RU 97108581A RU 97108581 A RU97108581 A RU 97108581A RU 2135522 C1 RU2135522 C1 RU 2135522C1
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group
groups
transition metal
olefin
catalytic composition
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RU97108581A
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English (en)
Russian (ru)
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RU97108581A (ru
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Антониус Мария Ван Бек Йоханнус
Хенрикус Йозефус Ван Доремале Герардус
Йоханнес Мария Грютер Герардус
Йоханнес Артс Хенрикус
Херманус Мария Рене Эггелс Гейллауме
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Дсм Н.В.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
RU97108581A 1994-10-31 1995-10-27 Каталитическая композиция и способ полимеризации олефинов RU2135522C1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
NL9401800 1994-10-31
NL9401800 1994-10-31
PCT/NL1995/000372 WO1996013529A1 (en) 1994-10-31 1995-10-27 Catalyst composition and process for the polymerization of an olefin

Publications (2)

Publication Number Publication Date
RU97108581A RU97108581A (ru) 1999-05-10
RU2135522C1 true RU2135522C1 (ru) 1999-08-27

Family

ID=19864842

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RU97108581A RU2135522C1 (ru) 1994-10-31 1995-10-27 Каталитическая композиция и способ полимеризации олефинов

Country Status (13)

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US (1) US5986029A (es)
EP (1) EP0789718B1 (es)
JP (1) JPH10508055A (es)
CN (1) CN1171794A (es)
AT (1) ATE164858T1 (es)
AU (1) AU3817595A (es)
BR (1) BR9509457A (es)
DE (1) DE69502028T2 (es)
ES (1) ES2116776T3 (es)
FI (1) FI119430B (es)
NO (1) NO971843L (es)
RU (1) RU2135522C1 (es)
WO (1) WO1996013529A1 (es)

Families Citing this family (120)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6440745B1 (en) 1994-10-18 2002-08-27 Symyx Technologies Combinatorial synthesis and screening of organometallic compounds and catalysts
US6030917A (en) * 1996-07-23 2000-02-29 Symyx Technologies, Inc. Combinatorial synthesis and analysis of organometallic compounds and catalysts
US6419881B1 (en) 1994-10-18 2002-07-16 Symyx Technologies, Inc. Combinatorial arrays of organometallic compounds and catalysts
DE59600760D1 (de) * 1995-06-12 1998-12-10 Targor Gmbh Übergangsmetallverbindung
US5962714A (en) * 1995-10-02 1999-10-05 Mccullough; Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
NL1003014C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met tertiaire groepen gesubstitueerde cyclopentadieenverbinding.
NL1003006C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met vertakte alkylgroepen gesubstitueerde cyclopentadieenverbinding.
NL1003008C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met een heteroatoom-bevattende groep gesubstitueerde cyclopentadieen- verbinding.
AU2653097A (en) * 1996-05-03 1997-11-26 Dsm N.V. Process for the production of functional polyolefins
NL1003004C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met onderling verschillende groepen gesubstitueerde cyclopentadieen- verbinding.
CA2253381A1 (en) * 1996-05-03 1997-11-13 Dsm N.V. Process for the co-polymerization of an olefin and a vinyl aromatic monomer
EP0896589A1 (en) * 1996-05-03 1999-02-17 Dsm N.V. Supported catalyst composition and process for the polymerization of olefin monomers
EA199800975A1 (ru) * 1996-05-03 1999-04-29 Дсм Н.В. СПОСОБ ПОЛУЧЕНИЯ ТЕРПОЛИМЕРА ЭТИЛЕНА, α-ОЛЕФИНА И ДИЕНА
JP2000509742A (ja) * 1996-05-03 2000-08-02 ディーエスエム エヌ．ブイ． α―オレフィンの重合法
TW370537B (en) * 1996-05-03 1999-09-21 Dsm Nv Process for the preparation of an ethylene/α-olefin copolymer
US6124488A (en) * 1996-05-03 2000-09-26 Dsm N.V. Cyclopentadiene compound substituted with branched alkyl groups
NL1003007C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met vertakte alkylgroepen gesubstitueerde cyclopentadieenverbinding.
AU2411797A (en) * 1996-05-03 1997-11-26 Dsm N.V. A process for making polyolefins having broad molecular weight distributions
AU2412597A (en) * 1996-05-03 1997-11-26 Dsm N.V. Inverted polyolefin copolymers
NL1003016C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Gesubstitueerde pentadieenverbinding.
AU2411697A (en) * 1996-05-03 1997-11-26 Dsm N.V. Process for the production of polymers containing cyclic olefins
US6117811A (en) * 1996-05-03 2000-09-12 Dsm N.V. Cyclopentadiene compound substituted with linear groups
WO1997043294A1 (en) * 1996-05-14 1997-11-20 The Dow Chemical Company Yttrium containing metal complexes and olefin polymerization process
WO1998004570A1 (de) * 1996-07-30 1998-02-05 Studiengesellschaft Kohle Mbh Organochrom-verbindungen enthaltende katalysatoren und ihre verwendung in der alkenpolymerisation
NZ333878A (en) 1996-08-08 2000-08-25 Dow Chemical Co 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
US6271322B1 (en) 1996-10-02 2001-08-07 Mccullough Laughlin Gerard Monocyclopentadienyl transition metal catalyst and olefin polymerization process
US6720186B1 (en) 1998-04-03 2004-04-13 Symyx Technologies, Inc. Method of research for creating and testing novel catalysts, reactions and polymers
EP0839833B1 (en) * 1996-10-30 2003-12-17 Repsol Quimica S.A. Catalyst systems for the polymerization and copolymerization of alpha-olefins
US6489261B1 (en) 1997-12-01 2002-12-03 Dsm N.V. Catalyst composition comprising a reduced transition metal complex and a cocatalyst
EP0919571A1 (en) * 1997-12-01 1999-06-02 Dsm N.V. Catalyst composition comprising a reduced transition metal complex and a cocatalyst
US6362294B1 (en) 1997-12-11 2002-03-26 Exxon Mobil Chemical Patents Inc. Reduced oxidation state transition metal compounds useful as olefin polymerization catalysts
DE19757524A1 (de) 1997-12-23 1999-06-24 Bayer Ag eta-Komplex-Verbindungen
DE19809159A1 (de) 1998-03-04 1999-09-09 Bayer Ag Metallorganische Verbindungen
DE19812881A1 (de) 1998-03-24 1999-10-07 Bayer Ag Neue dendrimere Verbindungen, ein Verfahren zu deren Herstellung sowie deren Verwendung als Katalysatoren
US6100414A (en) * 1998-04-02 2000-08-08 Eastman Chemical Company Cyclopentadienyl transition metal compounds useful as polymerization catalysts
JP2002513823A (ja) 1998-05-01 2002-05-14 エクソンモービル・ケミカル・パテンツ・インク オレフィン重合用の三座配位子含有金属触媒錯体
DE19837734C1 (de) 1998-08-20 1999-12-23 Bayer Ag Verfahren zur Herstellung von Katalysatoren auf Basis von Fulven-Metallkomplexen
DE19837739A1 (de) 1998-08-20 2000-02-24 Bayer Ag Katalysatorsystem auf Basis von Fulven-Cyclopentadienyl-Metallkomplexen
US6403773B1 (en) 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
US6465385B1 (en) 1999-02-12 2002-10-15 Sunoco, Inc. (R&M) Zwitterionic polymerization catalyst
JP2000283243A (ja) * 1999-03-29 2000-10-13 Bando Chem Ind Ltd 伝動ベルト
AU3902300A (en) 1999-04-29 2000-11-17 Dow Chemical Company, The Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof
WO2000069870A1 (en) 1999-05-13 2000-11-23 The Dow Chemical Company Metal complexes containing bridging heteroatom for olefin-polymerization-process
US6555634B1 (en) 1999-05-13 2003-04-29 The Dow Chemical Company Di- and tri-heteroatom substituted indenyl metal complexes
WO2000075146A1 (en) 1999-06-04 2000-12-14 The Dow Chemical Company Boron-substituted cyclopentadienes and metal complexes thereof
US6437161B1 (en) 1999-08-13 2002-08-20 Basf Aktiengesellschaft Monocyclopentadienyl complexes of chromium, molybdenum or tungsten
US6239062B1 (en) 1999-09-02 2001-05-29 Equistar Chemicals, L.P. Olefin polymerization catalysts containing indolyl-amido ligands
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
US6723675B1 (en) 2000-05-25 2004-04-20 Univation Technologies, Llc Catalyst for the production of olefin polymers
US7078164B1 (en) 2000-06-19 2006-07-18 Symyx Technologies, Inc. High throughput screen for identifying polymerization catalysts from potential catalysts
SG99905A1 (en) * 2000-06-21 2003-11-27 Sumitomo Chemical Co Transition metal compound, catalyst for addition polymerization, and process for producing addition polymer
GB0020613D0 (en) 2000-08-21 2000-10-11 Borealis Tech Oy Catalysts
KR20040010544A (ko) 2000-10-19 2004-01-31 엑손모빌 케미칼 패턴츠 인코포레이티드 양이온성 3족 촉매 시스템
ATE517115T1 (de) 2000-10-25 2011-08-15 Exxonmobil Chem Patents Inc Kationisches katalysatorsystem
DE10236112B4 (de) * 2001-08-13 2017-01-26 Bando Chemical Industries, Ltd. Kraftübertragungsriemen und Verfahren zu dessen Herstellung
US7196148B2 (en) 2001-10-25 2007-03-27 Exxon Mobil Chemical Patents Inc. Cationic catalyst system
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
ES2321806T3 (es) 2001-12-19 2009-06-12 Borealis Technology Oy Produccion de catalizadores soportados para la polimerizacion de olefinas.
US20060089253A1 (en) * 2002-08-13 2006-04-27 Shahram Mihan Monocyclopentadienyl complexes
US7202373B2 (en) 2002-08-22 2007-04-10 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
AU2003293769A1 (en) 2002-12-20 2004-07-14 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
EP1489110B1 (en) 2003-06-20 2012-01-18 Borealis Polymers Oy Method for preparing an olefin polymerisation catalyst composition
CN102153583A (zh) 2003-08-04 2011-08-17 帝斯曼知识产权资产管理有限公司 制备烃基化金属有机化合物的改进方法
CN1860142B (zh) * 2003-08-04 2010-12-01 帝斯曼知识产权资产管理有限公司 制备聚烯烃的方法
WO2005014674A2 (en) * 2003-08-04 2005-02-17 Dsm Ip Assets B.V. Process for the preparation of a polyolefin
EP1535936A1 (en) * 2003-11-25 2005-06-01 DSM IP Assets B.V. Improved method of preparing a hydrocarbylated metal-organic compound
JP2007513990A (ja) 2003-12-16 2007-05-31 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング モノシクロペンタジエニル錯体
EP1694719A2 (en) 2003-12-19 2006-08-30 Basell Polyolefine GmbH Monocyclopentadienyl complexes
GB0423555D0 (en) 2004-10-22 2004-11-24 Borealis Tech Oy Process
JO3088B1 (ar) * 2004-12-08 2017-03-15 Janssen Pharmaceutica Nv مشتقات كوينازولين كبيرة الحلقات و استعمالها بصفتها موانع كينيز متعددة الاهداف
NI200700147A (es) 2004-12-08 2019-05-10 Janssen Pharmaceutica Nv Derivados de quinazolina inhibidores de cinasas dirigidos a multip
CN102061024B (zh) 2004-12-28 2014-08-20 三井-杜邦聚合化学有限公司 太阳能电池密封材料
DE102005014395A1 (de) 2005-03-24 2006-09-28 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
CN1310970C (zh) * 2005-06-17 2007-04-18 中国科学院长春应用化学研究所 一类第四族烯烃聚合催化剂前体及制备方法
CN101305044B (zh) 2005-10-21 2011-12-21 保瑞利斯科技公司 组合物
EP1795542A1 (en) 2005-12-07 2007-06-13 Borealis Technology Oy Polymer
ES2588577T3 (es) 2005-12-30 2016-11-03 Borealis Technology Oy Partículas de catalizador
US20090326123A1 (en) 2006-12-26 2009-12-31 Sumitomo Chemical Company, Limited Polypropylene resin composition and molded article made thereof
KR100999592B1 (ko) 2007-02-15 2010-12-08 주식회사 엘지화학 새로운 시클로펜타디에닐 리간드를 갖는 4족 전이금속화합물, 이의 제조방법 및 이를 이용한 올레핀계 중합체의제조방법
US9102820B2 (en) 2007-04-03 2015-08-11 Sumitomo Chemical Company, Limited Polypropylene resin composition and molded article comprising the same
JP5462439B2 (ja) 2007-10-31 2014-04-02 住友化学株式会社 樹脂組成物、発泡成形体およびその製造方法
DE112008002889T5 (de) 2007-10-31 2010-09-23 Sumitomo Chemical Company, Ltd. Polypropylenharzzusammensetzung, Verfahren zu deren Herstellung und geschäumter Formgegenstand
US8501842B2 (en) 2007-12-21 2013-08-06 Sumitomo Chemical Company, Limited Polypropylene resin composition and molded article
KR20140060590A (ko) 2008-10-30 2014-05-20 듀폰-미츠이 폴리케미칼 가부시키가이샤 다층 시트, 태양 전지 소자용 밀봉재, 및 태양 전지 모듈
WO2010052264A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
EP2186831B1 (en) 2008-11-10 2013-01-02 Borealis AG Process for the preparation of an unsupported, solid olefin polymerisation catalyst and use in polymerisation of olefins
EP2186832B1 (en) 2008-11-10 2012-09-12 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
DE112010000780T5 (de) 2009-02-17 2012-07-26 Du Pont-Mitsui Polychemnicals Co., Ltd. Folie für ein Solarzellen-Verkapselungsmittel und Solarzellenmodul
WO2010131716A1 (ja) 2009-05-13 2010-11-18 三井・デュポンポリケミカル株式会社 太陽電池封止材用シート及び太陽電池モジュール
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
EP2338920A1 (en) 2009-12-22 2011-06-29 Borealis AG Preparation of single-site catalysts
CN102666603B (zh) 2009-12-22 2014-10-15 北欧化工公司 在单活性中心催化剂存在的情况下的聚丙烯制备
ES2535323T3 (es) 2009-12-22 2015-05-08 Borealis Ag Preparación de catalizadores de sitio único
EP2386581B1 (en) 2010-05-07 2014-03-26 Borealis AG Preparation of a solid catalyst system
EP2385073A1 (en) 2010-05-07 2011-11-09 Borealis AG Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins
EP2386582B1 (en) 2010-05-07 2016-02-17 Borealis AG Preparation of a solid catalyst system
EP2386583A1 (en) 2010-05-07 2011-11-16 Borealis AG Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins
WO2012055932A1 (en) 2010-10-28 2012-05-03 Borealis Ag Single site polymer
EP2554375B1 (en) 2011-08-03 2014-04-09 Borealis AG Film
WO2013076733A2 (en) 2011-10-10 2013-05-30 Reliance Industries Ltd. A process for synthesis of ethylene polymers
EP2606970A1 (en) 2011-12-19 2013-06-26 Basell Polyolefine GmbH Monocyclopentadienyl binuclear complexes, ligands used in their preparaion, catalyst systems comprising them and olefin polymerisation process
EP3034545B1 (en) 2014-12-17 2020-11-04 SABIC Global Technologies B.V. A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains and the products obtained therefrom
EP3034544B1 (en) 2014-12-17 2019-10-16 SABIC Global Technologies B.V. A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains
EP3034546B1 (en) 2014-12-17 2019-10-16 SABIC Global Technologies B.V. A process for the preparation of a block copolymer comprising a first polyolefin block and a second polymer block
EP3034547B1 (en) 2014-12-17 2019-10-09 SABIC Global Technologies B.V. A process for the preparation of a block copolymer comprising a first polyolefin block and a second polymer block
EP3037437A1 (en) 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Process for the preparation of a polyolefin having one or multiple end-functionalized branches.
EP3037438A1 (en) 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Process for the preparation of a branched polyolefin
EP3387046B1 (en) 2015-12-09 2019-12-25 SABIC Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first functionalized short chain branched polyolefin block and one or multiple polymer side chains
WO2017097568A1 (en) 2015-12-09 2017-06-15 Sabic Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains
GB201522437D0 (en) * 2015-12-18 2016-02-03 Univ Leeds Tethered ligands
EP3261093B1 (en) 2016-06-21 2023-08-02 Borealis AG Cable with advantageous electrical properties
EP3261095A1 (en) 2016-06-21 2017-12-27 Borealis AG Cable with improved electrical properties
CN109328211A (zh) 2016-06-21 2019-02-12 博里利斯股份公司 具有有利的热机械性能和电气特性的用于电线和电缆应用的聚合物组合物
EP3261096A1 (en) 2016-06-21 2017-12-27 Borealis AG Cable and composition
KR102631634B1 (ko) 2016-12-06 2024-01-31 사빅 글로벌 테크놀러지스 비.브이. 극성 기를 갖는 올레핀 공중합체의 제조 방법 및 그로부터 수득된 생성물
CN108191910B (zh) * 2016-12-08 2020-11-10 中国石油化工股份有限公司 单茂金属化合物及制备方法和烯烃聚合用催化剂组合物及应用和制备丙烯均聚物的方法
CN111511786A (zh) 2017-12-22 2020-08-07 Sabic环球技术有限责任公司 制备乙烯和丙烯离聚物的方法
WO2019122455A1 (en) 2017-12-22 2019-06-27 Sabic Global Technologies B.V. Process for preparation of amorphous functionalized olefin copolymer
CN116685638A (zh) 2021-01-08 2023-09-01 博里利斯股份公司 组合物
WO2024105089A1 (en) 2022-11-15 2024-05-23 Sabic Global Technologies B.V. Asphalt composition with an improved life span

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3836059A1 (de) * 1988-10-22 1990-05-03 Hoechst Ag Verfahren zur herstellung eines ethylen-propylen-copolymers
US5208357A (en) * 1990-12-31 1993-05-04 Exxon Chemical Patents, Inc. Chiral metallocene compounds and preparation thereof by attachment of chiral center
US5349100A (en) * 1991-01-02 1994-09-20 Exxon Chemical Patents Inc. Chiral metallocene compounds and preparation thereof by creation of a chiral center by enantioselective hydride transfer
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
GB9300934D0 (en) * 1993-01-19 1993-03-10 Bp Chem Int Ltd Metallocene complexes
WO1995010549A1 (en) * 1993-10-08 1995-04-20 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers using reduced metal catalyst
AU1049195A (en) * 1994-01-18 1995-08-01 Dow Chemical Company, The Process for preparation of reduced metal titanium complexes
US5512693A (en) * 1994-12-07 1996-04-30 The Dow Chemical Company Preparation of titanium (II) or zirconium (II) complexes
US5747406A (en) * 1997-01-10 1998-05-05 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the production of olefin polymers
US5780698A (en) * 1997-03-31 1998-07-14 Chevron Chemical Company Olefin oligomerization catalyst and process employing and preparing same

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ES2116776T3 (es) 1998-07-16
NO971843D0 (no) 1997-04-22
AU3817595A (en) 1996-05-23
EP0789718A1 (en) 1997-08-20
ATE164858T1 (de) 1998-04-15
FI971823A (fi) 1997-06-27
EP0789718B1 (en) 1998-04-08
FI119430B (fi) 2008-11-14
US5986029A (en) 1999-11-16
CN1171794A (zh) 1998-01-28
WO1996013529A1 (en) 1996-05-09
BR9509457A (pt) 1998-01-06
NO971843L (no) 1997-06-26
DE69502028D1 (de) 1998-05-14
DE69502028T2 (de) 1998-12-10
JPH10508055A (ja) 1998-08-04
FI971823A0 (fi) 1997-04-29
MX9703254A (es) 1997-10-31

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