RU2012140024A - Синтез цинкового производного акрилатного сополимера - Google Patents
Синтез цинкового производного акрилатного сополимера Download PDFInfo
- Publication number
- RU2012140024A RU2012140024A RU2012140024/05A RU2012140024A RU2012140024A RU 2012140024 A RU2012140024 A RU 2012140024A RU 2012140024/05 A RU2012140024/05 A RU 2012140024/05A RU 2012140024 A RU2012140024 A RU 2012140024A RU 2012140024 A RU2012140024 A RU 2012140024A
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- Russia
- Prior art keywords
- copper
- acid
- composition
- combinations
- composition according
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract 3
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract 24
- 229920001002 functional polymer Polymers 0.000 claims abstract 11
- 229910052802 copper Inorganic materials 0.000 claims abstract 10
- 239000010949 copper Substances 0.000 claims abstract 10
- 150000002148 esters Chemical class 0.000 claims abstract 6
- 150000003751 zinc Chemical class 0.000 claims abstract 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000005749 Copper compound Substances 0.000 claims abstract 5
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 claims abstract 5
- 239000005750 Copper hydroxide Substances 0.000 claims abstract 5
- 150000001879 copper Chemical class 0.000 claims abstract 5
- -1 copper carboxylates Chemical class 0.000 claims abstract 5
- 150000001880 copper compounds Chemical class 0.000 claims abstract 5
- 229910001956 copper hydroxide Inorganic materials 0.000 claims abstract 5
- QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical compound [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000002245 particle Substances 0.000 claims abstract 5
- 150000007524 organic acids Chemical class 0.000 claims abstract 4
- 229940043810 zinc pyrithione Drugs 0.000 claims abstract 4
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims abstract 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract 2
- 229940116318 copper carbonate Drugs 0.000 claims abstract 2
- 229910000365 copper sulfate Inorganic materials 0.000 claims abstract 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims abstract 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims abstract 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract 2
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 claims abstract 2
- 239000000178 monomer Substances 0.000 claims abstract 2
- 229920000058 polyacrylate Polymers 0.000 claims abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 6
- 239000008199 coating composition Substances 0.000 claims 5
- 230000003373 anti-fouling effect Effects 0.000 claims 4
- 239000011347 resin Substances 0.000 claims 3
- 229920005989 resin Polymers 0.000 claims 3
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 claims 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 2
- YEOCHZFPBYUXMC-UHFFFAOYSA-L copper benzoate Chemical compound [Cu+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 YEOCHZFPBYUXMC-UHFFFAOYSA-L 0.000 claims 2
- 229940120693 copper naphthenate Drugs 0.000 claims 2
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 claims 2
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 claims 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 claims 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims 1
- PORQOHRXAJJKGK-UHFFFAOYSA-N 4,5-dichloro-2-n-octyl-3(2H)-isothiazolone Chemical compound CCCCCCCCN1SC(Cl)=C(Cl)C1=O PORQOHRXAJJKGK-UHFFFAOYSA-N 0.000 claims 1
- JXSRRBVHLUJJFC-UHFFFAOYSA-N 7-amino-2-methylsulfanyl-[1,2,4]triazolo[1,5-a]pyrimidine-6-carbonitrile Chemical compound N1=CC(C#N)=C(N)N2N=C(SC)N=C21 JXSRRBVHLUJJFC-UHFFFAOYSA-N 0.000 claims 1
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 claims 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims 1
- 239000005711 Benzoic acid Substances 0.000 claims 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 claims 1
- 229920001661 Chitosan Polymers 0.000 claims 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims 1
- 239000005751 Copper oxide Substances 0.000 claims 1
- 239000005642 Oleic acid Substances 0.000 claims 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims 1
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 claims 1
- 235000021314 Palmitic acid Nutrition 0.000 claims 1
- 235000021355 Stearic acid Nutrition 0.000 claims 1
- 229960000583 acetic acid Drugs 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 claims 1
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 claims 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims 1
- 229940106681 chloroacetic acid Drugs 0.000 claims 1
- DEETYPHYGZQVKD-UHFFFAOYSA-N copper ethyl hexanoate Chemical compound [Cu+2].CCCCCC(=O)OCC DEETYPHYGZQVKD-UHFFFAOYSA-N 0.000 claims 1
- 229910000431 copper oxide Inorganic materials 0.000 claims 1
- BQVVSSAWECGTRN-UHFFFAOYSA-L copper;dithiocyanate Chemical compound [Cu+2].[S-]C#N.[S-]C#N BQVVSSAWECGTRN-UHFFFAOYSA-L 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims 1
- YKSNLCVSTHTHJA-UHFFFAOYSA-L maneb Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S YKSNLCVSTHTHJA-UHFFFAOYSA-L 0.000 claims 1
- 229920000940 maneb Polymers 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 1
- 229960002446 octanoic acid Drugs 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
- 235000021313 oleic acid Nutrition 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 claims 1
- 229920001289 polyvinyl ether Polymers 0.000 claims 1
- 235000019260 propionic acid Nutrition 0.000 claims 1
- 229940095574 propionic acid Drugs 0.000 claims 1
- WJSXSXUHWBSPEP-UHFFFAOYSA-N pyridine;triphenylborane Chemical compound C1=CC=NC=C1.C1=CC=CC=C1B(C=1C=CC=CC=1)C1=CC=CC=C1 WJSXSXUHWBSPEP-UHFFFAOYSA-N 0.000 claims 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 239000008117 stearic acid Substances 0.000 claims 1
- XNFIRYXKTXAHAC-UHFFFAOYSA-N tralopyril Chemical compound BrC1=C(C(F)(F)F)NC(C=2C=CC(Cl)=CC=2)=C1C#N XNFIRYXKTXAHAC-UHFFFAOYSA-N 0.000 claims 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims 1
- 239000011787 zinc oxide Substances 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
- C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Nanotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
1. Композиция, содержащая цинковое производное сложноэфирного функционального полимера и частицы пиритиона меди, в которой указанные частицы, имеют среднее соотношение сторон в пределах диапазона от около 8 до около 15, предпочтительно, от около 9 до около 12.2. Композиция по п.1, в которой указанное цинковое производное сложноэфирного функционального полимера является цинковым производным акрилатного полимера.3. Композиция по п.1, в которой указанное цинковое производное сложноэфирного функционального полимера и указанный пиритион меди получают взаимодействием кислотно-функционального полимера с пиритионом цинка и соединением меди, выбранным из группы, состоящей из солей меди, карбоксилатов меди, гидроксида меди, элементарной меди и комбинаций вышеперечисленного.4. Композиция по п.3, в которой указанный кислотно-функциональный полимер является кислотно-функциональным акрилатным сополимером.5. Композиция по п.4, в которой кислотно-функциональный акрилатный сополимер имеет среднечисловую молекулярную массу меньше 10000, предпочтительно, между 2000 и 6000.6. Композиция по п.4, в которой кислотно-функциональный акрилатный сополимер получают из ненасыщенного органического кислотного мономера, выбранного из группы, состоящей из акриловой кислоты, метакриловой кислоты и комбинаций вышеперечисленного.7. Композиция по п.4, в которой указанную медную соль выбирают из группы, состоящей из карбоната меди, нитрата меди, сульфата меди, хлорида меди и комбинаций вышеперечисленного.8. Композиция по п.4, в которой указанным соединением меди является гидроксид меди.9. Композиция по п.7 или 8, дополнительно содержащая органическую ки�
Claims (18)
1. Композиция, содержащая цинковое производное сложноэфирного функционального полимера и частицы пиритиона меди, в которой указанные частицы, имеют среднее соотношение сторон в пределах диапазона от около 8 до около 15, предпочтительно, от около 9 до около 12.
2. Композиция по п.1, в которой указанное цинковое производное сложноэфирного функционального полимера является цинковым производным акрилатного полимера.
3. Композиция по п.1, в которой указанное цинковое производное сложноэфирного функционального полимера и указанный пиритион меди получают взаимодействием кислотно-функционального полимера с пиритионом цинка и соединением меди, выбранным из группы, состоящей из солей меди, карбоксилатов меди, гидроксида меди, элементарной меди и комбинаций вышеперечисленного.
4. Композиция по п.3, в которой указанный кислотно-функциональный полимер является кислотно-функциональным акрилатным сополимером.
5. Композиция по п.4, в которой кислотно-функциональный акрилатный сополимер имеет среднечисловую молекулярную массу меньше 10000, предпочтительно, между 2000 и 6000.
6. Композиция по п.4, в которой кислотно-функциональный акрилатный сополимер получают из ненасыщенного органического кислотного мономера, выбранного из группы, состоящей из акриловой кислоты, метакриловой кислоты и комбинаций вышеперечисленного.
7. Композиция по п.4, в которой указанную медную соль выбирают из группы, состоящей из карбоната меди, нитрата меди, сульфата меди, хлорида меди и комбинаций вышеперечисленного.
8. Композиция по п.4, в которой указанным соединением меди является гидроксид меди.
9. Композиция по п.7 или 8, дополнительно содержащая органическую кислоту, выбранную из группы, состоящей из уксусной кислоты, хлоруксусной кислоты, пропионовой кислоты, каприловой кислоты, кислоты «версатик», этилгексановой кислоты, бензойной кислоты, нафтеновой кислоты, пальмитиновой кислоты, стеариновой кислоты, олеиновой кислоты, жирных кислот, кислот канифоли и комбинаций вышеперечисленного.
10. Композиция по п.9, в которой указанная органическая кислота является уксусной кислотой или нафтеновой кислотой.
11. Композиция по п.3, в которой указанный карбоксилат меди, выбран из группы, состоящей из ацетата меди, нафтената меди, хинолинолата меди, стеарата меди, бензоата меди, этилгексаноата меди, розинатов меди и комбинаций вышеперечисленного.
12. Композиция по п.11, в которой указанный карбоксилат меди является ацетатом меди или нафтенатом меди.
13. Композиция по п.3, в которой указанные частицы пиритиона меди имеют D50 от около 3 до около 5 микрон.
14. Предохраняющая от обрастания композиция покрытия, содержащая композицию согласно пп.1-13.
15. Предохраняющая от обрастания композиция покрытия по п.14, дополнительно включающая растворимую в воде или немного растворимую в воде смолу, в которой указанная смола присутствует в количестве от около 4 до около 15%, считая на общую массу композиции покрытия.
16. Предохраняющая от обрастания композиция покрытия по п.15, в которой смола выбрана из группы, состоящей из канифоли, поливинилового эфира, хитозана и комбинаций вышеперечисленного.
17. Предохраняющая от обрастания композиция покрытия по п.14, дополнительно содержащая добавку, выбранную из группы, состоящей из металлов, содержащих медь, оксида меди, тиоцианата меди, оксида цинка, бората цинка, метабората бария, пиридин трифенилборона, трифенил(октидециламин)борона, тралопирила, хлорфенапира, толифлуанида, дихлофлуанида, пиритиона цинка, 4,5-дихлор-2-н-октил-4-изотиазолин-3-она, 2-метилтио-4-трет-бутиламино-6-циклопропиламино-симм-триазина, цинеба, зирама, поликарбамата, манеба, хлорталонила и комбинаций вышеперечисленного.
18. Способ получения композиции по п.1, включающий стадию взаимодействия кислотно-функционального полимера с пиритионом цинка и соединением меди, выбранным из солей меди, карбоксилата меди, гидроксида меди, элементарной меди и комбинаций вышеперечисленного в растворителе.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/660,053 | 2010-02-19 | ||
| US12/660,053 US8541493B2 (en) | 2010-02-19 | 2010-02-19 | Synthesis of zinc acrylate copolymer from acid functional copolymer, zinc pyrithione, and copper compound |
| PCT/US2011/023865 WO2011102983A1 (en) | 2010-02-19 | 2011-02-07 | Synthesis of zinc acrylate copolymer |
Publications (2)
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| RU2012140024A true RU2012140024A (ru) | 2014-03-27 |
| RU2573466C2 RU2573466C2 (ru) | 2016-01-20 |
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| CN (1) | CN102869257B (ru) |
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| CL (1) | CL2012002277A1 (ru) |
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| WO (1) | WO2011102983A1 (ru) |
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2010
- 2010-02-19 US US12/660,053 patent/US8541493B2/en not_active Expired - Fee Related
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2011
- 2011-02-07 SG SG2012060661A patent/SG183339A1/en unknown
- 2011-02-07 RU RU2012140024/05A patent/RU2573466C2/ru not_active IP Right Cessation
- 2011-02-07 EP EP11745044.5A patent/EP2536281B1/en not_active Not-in-force
- 2011-02-07 DK DK11745044.5T patent/DK2536281T3/en active
- 2011-02-07 ES ES11745044.5T patent/ES2585877T3/es active Active
- 2011-02-07 AU AU2011218367A patent/AU2011218367B2/en not_active Ceased
- 2011-02-07 KR KR1020127023351A patent/KR20130054228A/ko active IP Right Grant
- 2011-02-07 MY MYPI2012003742A patent/MY156570A/en unknown
- 2011-02-07 JP JP2012553932A patent/JP5722919B2/ja not_active Expired - Fee Related
- 2011-02-07 WO PCT/US2011/023865 patent/WO2011102983A1/en active Application Filing
- 2011-02-07 PT PT117450445T patent/PT2536281T/pt unknown
- 2011-02-07 CN CN201180016521.0A patent/CN102869257B/zh not_active Expired - Fee Related
- 2011-02-07 PL PL11745044.5T patent/PL2536281T3/pl unknown
- 2011-02-07 BR BR112012020841-1A patent/BR112012020841A2/pt not_active Application Discontinuation
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2012
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Also Published As
| Publication number | Publication date |
|---|---|
| US20130183362A1 (en) | 2013-07-18 |
| SG183339A1 (en) | 2012-09-27 |
| CN102869257B (zh) | 2014-06-25 |
| ES2585877T3 (es) | 2016-10-10 |
| CN102869257A (zh) | 2013-01-09 |
| US20110206632A1 (en) | 2011-08-25 |
| US8541493B2 (en) | 2013-09-24 |
| RU2573466C2 (ru) | 2016-01-20 |
| PL2536281T3 (pl) | 2016-12-30 |
| US9156997B2 (en) | 2015-10-13 |
| HRP20161028T1 (hr) | 2016-11-04 |
| EP2536281A4 (en) | 2013-09-11 |
| WO2011102983A1 (en) | 2011-08-25 |
| JP5722919B2 (ja) | 2015-05-27 |
| MY156570A (en) | 2016-03-15 |
| CL2012002277A1 (es) | 2012-09-28 |
| EP2536281B1 (en) | 2016-05-18 |
| PT2536281T (pt) | 2016-08-19 |
| AU2011218367B2 (en) | 2014-03-20 |
| DK2536281T3 (en) | 2016-09-05 |
| AU2011218367A1 (en) | 2012-09-13 |
| JP2013520417A (ja) | 2013-06-06 |
| EP2536281A1 (en) | 2012-12-26 |
| KR20130054228A (ko) | 2013-05-24 |
| BR112012020841A2 (pt) | 2020-09-29 |
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