RU2011139168A - Способ концентрирования гомогенного катализатора из технологического потока - Google Patents
Способ концентрирования гомогенного катализатора из технологического потока Download PDFInfo
- Publication number
- RU2011139168A RU2011139168A RU2011139168/04A RU2011139168A RU2011139168A RU 2011139168 A RU2011139168 A RU 2011139168A RU 2011139168/04 A RU2011139168/04 A RU 2011139168/04A RU 2011139168 A RU2011139168 A RU 2011139168A RU 2011139168 A RU2011139168 A RU 2011139168A
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- Prior art keywords
- boiling components
- polymer
- carried out
- homogeneous
- separated
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract 46
- 229920000642 polymer Polymers 0.000 claims abstract 14
- 238000009835 boiling Methods 0.000 claims abstract 12
- 239000002815 homogeneous catalyst Substances 0.000 claims abstract 10
- 239000012528 membrane Substances 0.000 claims abstract 9
- 239000003054 catalyst Substances 0.000 claims abstract 6
- 229910052751 metal Inorganic materials 0.000 claims abstract 4
- 239000002184 metal Substances 0.000 claims abstract 4
- 239000012465 retentate Substances 0.000 claims abstract 4
- 238000000926 separation method Methods 0.000 claims abstract 4
- 239000012466 permeate Substances 0.000 claims abstract 3
- 238000006555 catalytic reaction Methods 0.000 claims abstract 2
- 150000002903 organophosphorus compounds Chemical class 0.000 claims 6
- 238000007037 hydroformylation reaction Methods 0.000 claims 4
- BGEHHAVMRVXCGR-UHFFFAOYSA-N tridecanal Chemical compound CCCCCCCCCCCCC=O BGEHHAVMRVXCGR-UHFFFAOYSA-N 0.000 claims 4
- 229910052703 rhodium Inorganic materials 0.000 claims 3
- 239000010948 rhodium Substances 0.000 claims 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 3
- 230000003197 catalytic effect Effects 0.000 claims 2
- 150000004696 coordination complex Chemical class 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000007983 Tris buffer Substances 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 239000013110 organic ligand Substances 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
- B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Catalysts (AREA)
- Polyethers (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009001225A DE102009001225A1 (de) | 2009-02-27 | 2009-02-27 | Verfahren zur Anreicherung eines Homogenkatalysators aus einem Prozessstrom |
| DE102009001225.7 | 2009-02-27 | ||
| PCT/EP2010/052242 WO2010097376A1 (de) | 2009-02-27 | 2010-02-23 | Verfahren zur anreicherung eines homogenkatalysators aus einem prozessstrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2011139168A true RU2011139168A (ru) | 2013-04-10 |
Family
ID=42144907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2011139168/04A RU2011139168A (ru) | 2009-02-27 | 2010-02-23 | Способ концентрирования гомогенного катализатора из технологического потока |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US8969628B2 (https=) |
| EP (1) | EP2401078B1 (https=) |
| JP (1) | JP5623435B2 (https=) |
| KR (1) | KR101593259B1 (https=) |
| CN (1) | CN102333593B (https=) |
| BR (1) | BRPI1009755B1 (https=) |
| DE (1) | DE102009001225A1 (https=) |
| ES (1) | ES2442769T3 (https=) |
| MX (1) | MX2011009008A (https=) |
| MY (1) | MY153102A (https=) |
| PL (1) | PL2401078T3 (https=) |
| RU (1) | RU2011139168A (https=) |
| SG (1) | SG174170A1 (https=) |
| WO (1) | WO2010097376A1 (https=) |
| ZA (1) | ZA201105351B (https=) |
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| DE102008043422B3 (de) | 2008-11-03 | 2010-01-07 | Evonik Degussa Gmbh | Verfahren zur Aufreinigung niedermolekularer Hydridosilane |
| DE102009001230A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen |
| US20120123079A1 (en) | 2009-07-23 | 2012-05-17 | Evonik Fibres Gmbh | Polyimide membranes made of polymerization solutions |
| DE102009047351A1 (de) | 2009-12-01 | 2011-06-09 | Evonik Goldschmidt Gmbh | Komposit-Siliconmembranen mit hoher Trennwirkung |
| DE102011082441A1 (de) | 2011-09-09 | 2013-03-14 | Evonik Oxeno Gmbh | Strahlschlaufenreaktor mit Nanofiltration |
| GB201117950D0 (en) | 2011-10-18 | 2011-11-30 | Imp Innovations Ltd | Membranes for separation |
| DE102012202779A1 (de) | 2012-02-23 | 2013-08-29 | Evonik Oxeno Gmbh | Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches |
| EP2906573B1 (de) | 2012-10-12 | 2016-11-23 | Evonik Degussa GmbH | Gemisch von bisphosphiten und dessen verwendung als katalysatorgemisch in der hydroformylierung |
| DE102012223572A1 (de) | 2012-12-18 | 2014-06-18 | Evonik Industries Ag | Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren |
| DE102013203117A1 (de) | 2013-02-26 | 2014-08-28 | Evonik Industries Ag | Optimierte Trenntechnik zur Aufarbeitung von homogen katalysierten Hydroformylierungsmischungen |
| KR102126255B1 (ko) * | 2013-03-29 | 2020-06-24 | 제이에스알 가부시끼가이샤 | 조성물, 패턴이 형성된 기판의 제조 방법, 막 및 그의 형성 방법, 및 화합물 |
| DE102013215004A1 (de) * | 2013-07-31 | 2015-02-05 | Evonik Industries Ag | Membrankaskade mit sinkender Trenntemperatur |
| DE102014209421A1 (de) | 2014-05-19 | 2015-11-19 | Evonik Degussa Gmbh | Membrangestützte Katalysatorabtrennung bei der Epoxidierung von cyclischen, ungesättigten C12-Verbindungen zum Beispiel Cyclododecen (CDEN) |
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| US10239990B2 (en) | 2015-05-29 | 2019-03-26 | Dow Global Technologies Llc | Isatin copolymers having intrinsic microporosity |
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| DE112016005378T5 (de) | 2015-11-24 | 2018-09-13 | Dow Global Technologies Llc | Trögersche-base-polymere mit intrinsischer mikroporosität |
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| CN109689730A (zh) | 2016-09-12 | 2019-04-26 | 陶氏环球技术有限责任公司 | 包括troger碱和靛红部分并具有固有微孔性的聚合物 |
| US10472467B2 (en) | 2016-09-20 | 2019-11-12 | Dow Global Technologies Llc | Polymers having intrinsic microporosity including sub-units with troger's base and spirobisindane moieties |
| US10953369B2 (en) | 2018-03-08 | 2021-03-23 | Georgia Tech Research Corporation | Spirocentric compounds and polymers thereof |
| US20210013536A1 (en) * | 2018-06-29 | 2021-01-14 | Sepion Technologies, Inc. | Membranes for aqueous redox flow batteries |
| MX2021000733A (es) | 2018-07-27 | 2021-05-12 | Form Energy Inc | Electrodos negativos para celdas electroquimicas. |
| DE202019001414U1 (de) | 2019-02-01 | 2019-04-12 | Evonik Canada Inc. | Vorrichtung zum Trennen von Gaskomponenten aus einem Gasstrom mit veränderlicher Zusammensetzung oder Strömungsrate |
| US12281063B2 (en) | 2020-02-11 | 2025-04-22 | Basf Se | Low-pressure hydroformylation of diisobutene |
| WO2022014243A1 (ja) * | 2020-07-17 | 2022-01-20 | パナソニックＩｐマネジメント株式会社 | 水電解セルの電極触媒、水電解セル、及び水電解装置 |
| CN116157202B (zh) * | 2020-07-17 | 2026-04-03 | 松下知识产权经营株式会社 | 水电解单元的电极催化剂、水电解单元及水电解装置 |
| ES2974422T3 (es) * | 2020-07-30 | 2024-06-27 | Evonik Oxeno Gmbh & Co Kg | Procedimiento para la preparación de aldehídos y separación del sistema catalítico mediante separación por membrana |
| ES2992645T3 (en) | 2021-11-19 | 2024-12-16 | Evonik Oxeno Gmbh & Co Kg | Process for producing aldehydes and cooling a mass flow |
| ES2992663T3 (en) | 2021-11-19 | 2024-12-16 | Evonik Oxeno Gmbh & Co Kg | Process for producing aldehydes and cooling a mass flow |
| EP4223737A1 (de) * | 2022-02-08 | 2023-08-09 | Evonik Operations GmbH | Optimierte thermische trennung durch vorherigen gasaustausch |
| CN119775550B (zh) * | 2024-11-01 | 2025-10-10 | 山东大学 | 一种可溶性单位点的钌基自具微孔聚合物催化剂及其制备方法和应用 |
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| DE102007005508A1 (de) | 2007-02-03 | 2008-08-07 | Evonik Goldschmidt Gmbh | Verfahren zur Reduktion des Trennwert-Anstiegs bei der Herstellung von No-Label-Look-Etiketten |
| DE102007041028A1 (de) | 2007-08-29 | 2009-03-05 | Evonik Goldschmidt Gmbh | Verwendung estermodifizierter Organopolysiloxane zur Herstellung kosmetischer oder pharmazeutischer Kompositionen |
| DE102007044148A1 (de) | 2007-09-15 | 2009-03-26 | Evonik Goldschmidt Gmbh | Neuartige siloxanhaltige Blockcopolymere, Verfahren zu deren Herstellung und deren Verwendung für Schmiermittel |
| DE102007054885A1 (de) | 2007-11-15 | 2009-05-20 | Evonik Degussa Gmbh | Verfahren zur Fraktionierung oxidischer Nanopartikel durch Querstrom-Membranfiltration |
| DE102008000243A1 (de) | 2008-02-06 | 2009-08-13 | Evonik Goldschmidt Gmbh | Neuartige Kompatibilisierungsmittel zur Verbesserung der Lagerstabilität von Polyolmischungen |
| DE102008000287A1 (de) | 2008-02-13 | 2009-08-20 | Evonik Goldschmidt Gmbh | Reaktives, flüssiges Keramikbindemittel |
| DE102008001788A1 (de) | 2008-05-15 | 2009-11-26 | Evonik Goldschmidt Gmbh | Verwendung organomodifizierter Siloxanblockcopolymere zur Herstellung kosmetischer oder pharmazeutischer Zusammensetzungen |
| DE102008001786A1 (de) | 2008-05-15 | 2009-11-26 | Evonik Goldschmidt Gmbh | Verwendung organomodifizierter Siloxanblockcopolymere als Pflegewirkstoff zur Pflege von menschlichen oder tierischen Körperteilen |
| DE102008040986A1 (de) | 2008-08-05 | 2010-02-11 | Evonik Goldschmidt Gmbh | Hydrophobierung von Bauelementen aus Mineralfasern |
| DE102008041601A1 (de) | 2008-08-27 | 2010-03-04 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung verzweigter SiH-funtioneller Polysiloxane und deren Verwendung zur Herstellung flüssiger, SiC- oder SiOC-verknüpfter, verzweigter organomodifizierter Polysiloxane |
| DE102008041652A1 (de) | 2008-08-28 | 2010-03-04 | Evonik Oxeno Gmbh | Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas |
| DE102008041870A1 (de) | 2008-09-08 | 2010-03-11 | Evonik Degussa Gmbh | Reaktor mit Titansilikat-Rezyklierung |
| DE102008042381A1 (de) | 2008-09-26 | 2010-04-01 | Evonik Goldschmidt Gmbh | Emulgator-Systeme für kosmetische und pharmazeutische Öl-in-Wasser-Emulsionen |
| BRPI0920125B1 (pt) | 2008-10-17 | 2017-03-28 | Evonik Degussa Gmbh | composição oleosa agroquímica compreendendo auxiliares de alquilpolissiloxano de silicone de alto caráter, e método para controle de ervas daninhas indesejadas ou tratamento de plantas contra pestes |
| DE102008043422B3 (de) | 2008-11-03 | 2010-01-07 | Evonik Degussa Gmbh | Verfahren zur Aufreinigung niedermolekularer Hydridosilane |
| DE102009001230A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen |
| DE102009015211A1 (de) | 2009-03-31 | 2010-10-14 | Evonik Goldschmidt Gmbh | Selbstvernetzende Polysiloxane in Beschichtungen von Enzymimmobilisaten |
| DE102009002415A1 (de) | 2009-04-16 | 2010-10-21 | Evonik Goldschmidt Gmbh | Emulgator enthaltend glycerinmodifizierte Organopolysiloxane |
| DE102009003275A1 (de) | 2009-05-20 | 2010-11-25 | Evonik Goldschmidt Gmbh | Verzweigte Polydimethylsiloxan-Polyoxyalkylen Copolymere, ein Verfahren zu ihrer Herstellung und ihre Verwendung als Anti-Vernebelungsadditiv in UV-härtenden Silikonen |
| DE102009028636A1 (de) | 2009-08-19 | 2011-02-24 | Evonik Goldschmidt Gmbh | Neuartige Urethangruppen enthaltende silylierte Präpolymere und Verfahren zu deren Herstellung |
| DE102009028640A1 (de) | 2009-08-19 | 2011-02-24 | Evonik Goldschmidt Gmbh | Härtbare Masse enthaltend Urethangruppen aufweisende silylierte Polymere und deren Verwendung in Dicht- und Klebstoffen, Binde- und/oder Oberflächenmodifizierungsmitteln |
| DE102010002180A1 (de) | 2010-02-22 | 2011-08-25 | Evonik Goldschmidt GmbH, 45127 | Stickstoffhaltige silizium-organische Pfropfmischpolymere |
| DE102010002178A1 (de) | 2010-02-22 | 2011-08-25 | Evonik Goldschmidt GmbH, 45127 | Verfahren zur Herstellung von Amin-Amid-funktionellen Siloxanen |
| DE102010031087A1 (de) | 2010-07-08 | 2012-01-12 | Evonik Goldschmidt Gmbh | Neuartige polyestermodifizierte Organopolysiloxane |
-
2009
- 2009-02-27 DE DE102009001225A patent/DE102009001225A1/de not_active Withdrawn
-
2010
- 2010-02-23 WO PCT/EP2010/052242 patent/WO2010097376A1/de not_active Ceased
- 2010-02-23 EP EP10711629.5A patent/EP2401078B1/de not_active Not-in-force
- 2010-02-23 BR BRPI1009755-4A patent/BRPI1009755B1/pt not_active IP Right Cessation
- 2010-02-23 RU RU2011139168/04A patent/RU2011139168A/ru not_active Application Discontinuation
- 2010-02-23 MX MX2011009008A patent/MX2011009008A/es active IP Right Grant
- 2010-02-23 MY MYPI2011004020 patent/MY153102A/en unknown
- 2010-02-23 SG SG2011062072A patent/SG174170A1/en unknown
- 2010-02-23 CN CN201080009645.1A patent/CN102333593B/zh not_active Expired - Fee Related
- 2010-02-23 US US13/203,639 patent/US8969628B2/en not_active Expired - Fee Related
- 2010-02-23 ES ES10711629.5T patent/ES2442769T3/es active Active
- 2010-02-23 KR KR1020117019820A patent/KR101593259B1/ko not_active Expired - Fee Related
- 2010-02-23 PL PL10711629T patent/PL2401078T3/pl unknown
- 2010-02-23 JP JP2011551482A patent/JP5623435B2/ja not_active Expired - Fee Related
-
2011
- 2011-07-20 ZA ZA2011/05351A patent/ZA201105351B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN102333593A (zh) | 2012-01-25 |
| CN102333593B (zh) | 2014-08-27 |
| DE102009001225A1 (de) | 2010-09-02 |
| EP2401078B1 (de) | 2013-10-23 |
| WO2010097376A1 (de) | 2010-09-02 |
| JP2012519061A (ja) | 2012-08-23 |
| JP5623435B2 (ja) | 2014-11-12 |
| MX2011009008A (es) | 2011-11-29 |
| US20120046503A1 (en) | 2012-02-23 |
| MY153102A (en) | 2014-12-31 |
| BRPI1009755A2 (pt) | 2016-03-15 |
| PL2401078T3 (pl) | 2014-03-31 |
| ZA201105351B (en) | 2012-10-31 |
| BRPI1009755B1 (pt) | 2018-02-14 |
| US8969628B2 (en) | 2015-03-03 |
| EP2401078A1 (de) | 2012-01-04 |
| KR101593259B1 (ko) | 2016-02-12 |
| SG174170A1 (en) | 2011-10-28 |
| ES2442769T3 (es) | 2014-02-13 |
| KR20110124759A (ko) | 2011-11-17 |
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