RU2010150300A - Каталитическая система и способ гидропереработки тяжелых масел - Google Patents

Каталитическая система и способ гидропереработки тяжелых масел Download PDF

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RU2010150300A
RU2010150300A RU2010150300/04A RU2010150300A RU2010150300A RU 2010150300 A RU2010150300 A RU 2010150300A RU 2010150300/04 A RU2010150300/04 A RU 2010150300/04A RU 2010150300 A RU2010150300 A RU 2010150300A RU 2010150300 A RU2010150300 A RU 2010150300A
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catalytic system
catalyst
cocatalyst
sulfides
zeolites
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RU2010150300/04A
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RU2525470C2 (ru
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Джузеппе БЕЛЛУССИ (IT)
Джузеппе Беллусси
Джакомо РИСПОЛИ (IT)
Джакомо Рисполи
Анджела КАРАТИ (IT)
Анджела Карати
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Эни С.П.А. (It)
Эни С.П.А.
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Abstract

1. Каталитическая система, применяемая для гидропереработки тяжелых масел, отличающаяся тем, что она включает: ! а. катализатор, имеющий функцию катализатора гидрирования, содержащий МоS2 или WS2 или их смеси в форме пластинок, или их маслорастворимый предшественник; ! b. сокатализатор, включающий частицы наноразмеров или микронных размеров, выбранный из катализаторов крекинга и/или денитрификации. ! 2. Каталитическая система по п.1, в которой сокатализатор состоит из цеолитов, имеющих кристаллы небольших размеров и низкую степень агрегации первичных частиц, и/или оксидов или сульфидов, или предшественников сульфидов Ni, и/или Со, в смеси с Мо и/или W. !3. Каталитическая система по п.2, в которой цеолиты выбраны из группы, включающей цеолиты с промежуточными или крупными размерами пор. ! 4. Каталитическая система по п.3, в которой цеолиты с промежуточными или крупными размерами пор выбраны из бета-цеолита, цеолита Y и МСМ-22. ! 5. Каталитическая система по п.2, в которой сокатализатор, состоящий из оксидов или сульфидов, или предшественников сульфидов, нанесен на твердые частицы микронных или субмикронных размеров. ! 6. Каталитическая система по п.5, в которой твердые частицы, на которые нанесен сокатализатор, выбраны из оксида алюминия, диоксида кремния, алюмосиликатов, талька и слюды. ! 7. Каталитическая система по п.1, в которой катализатор также содержит сульфиды V, Ni и/или Fe. ! 8. Каталитическая система по п.1, в которой катализатор нанесен на оксид алюминия, диоксид кремния, алюмосиликат, тальк или слюду. ! 9. Каталитическая система по п.1, в которой катализатор состоит из МоS2, распределенного в углеродсодержащей матрице, включающе�

Claims (16)

1. Каталитическая система, применяемая для гидропереработки тяжелых масел, отличающаяся тем, что она включает:
а. катализатор, имеющий функцию катализатора гидрирования, содержащий МоS2 или WS2 или их смеси в форме пластинок, или их маслорастворимый предшественник;
b. сокатализатор, включающий частицы наноразмеров или микронных размеров, выбранный из катализаторов крекинга и/или денитрификации.
2. Каталитическая система по п.1, в которой сокатализатор состоит из цеолитов, имеющих кристаллы небольших размеров и низкую степень агрегации первичных частиц, и/или оксидов или сульфидов, или предшественников сульфидов Ni, и/или Со, в смеси с Мо и/или W.
3. Каталитическая система по п.2, в которой цеолиты выбраны из группы, включающей цеолиты с промежуточными или крупными размерами пор.
4. Каталитическая система по п.3, в которой цеолиты с промежуточными или крупными размерами пор выбраны из бета-цеолита, цеолита Y и МСМ-22.
5. Каталитическая система по п.2, в которой сокатализатор, состоящий из оксидов или сульфидов, или предшественников сульфидов, нанесен на твердые частицы микронных или субмикронных размеров.
6. Каталитическая система по п.5, в которой твердые частицы, на которые нанесен сокатализатор, выбраны из оксида алюминия, диоксида кремния, алюмосиликатов, талька и слюды.
7. Каталитическая система по п.1, в которой катализатор также содержит сульфиды V, Ni и/или Fe.
8. Каталитическая система по п.1, в которой катализатор нанесен на оксид алюминия, диоксид кремния, алюмосиликат, тальк или слюду.
9. Каталитическая система по п.1, в которой катализатор состоит из МоS2, распределенного в углеродсодержащей матрице, включающей кристаллические домены сульфидов V, Ni и Fe.
10. Каталитическая система по п.1, в которой катализатор и сокатализатор находятся на одном и том же носителе.
11. Каталитическая система по п.1, в которой массовое отношение катализатора к сокатализатору составляет от 100:1 до 1:70.
12. Каталитическая система по п.11, отличающаяся тем, что массовое отношение катализатора к сокатализатору составляет от 75:1 до 1:50.
13. Способ гидропереработки тяжелых масел, выбираемых из сырой нефти, тяжелой нефти, битумов из битуминозных песков, остатков после перегонки, тяжелых фракций перегонки, деасфальтированных остатков после перегонки, растительных масел, масел из углистых и битуминозных сланцев, масел, полученных при термическом разложении отходов, полимеров, биомасс, дистиллятов, например, вакуумного газойля или тяжелого газойля, который включает подачу тяжелого масла на стадию гидрообработки в виде суспензии, отличающийся тем, что он включает применение каталитической системы по пп.1-12.
14. Способ по п.13, в котором после стадии гидрообработки выполняют разделение выходящего из указанной стадии потока, при котором более тяжелую отделяемую жидкую фракцию, содержащую дисперсный катализатор и сокатализатор, направляют рециклом на стадию гидрообработки.
15. Способ по п.13, в котором концентрация катализатора гидрирования, диспергированного в сырье, включающем рециркулируемый поток, направляемом на стадию гидрообработки, определяемая на основании концентрации находящегося в катализаторе металла или металлов, составляет от 100 до 30000 млн-1.
16. Способ по п.13, в котором гидрообработку выполняют при температуре от 350 до 480°С и давлении от 8 до 22 МПа (от 80 до 220 атм.).
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Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1402748B1 (it) * 2010-10-27 2013-09-18 Eni Spa Procedimento per la raffinazione del greggio
ITMI20111626A1 (it) * 2011-09-08 2013-03-09 Eni Spa Sistema catalitico e procedimento per l'idroconversione totale degli oli pesanti
ITMI20112409A1 (it) * 2011-12-28 2013-06-29 Eni Spa Sistema catalitico, procedimento per la preparazione di detto sistema e procedimento di idrotrattamento utilizzante detto sistema
CN103801333B (zh) * 2012-11-07 2016-04-27 中国石油化工股份有限公司 一种载硫型加氢催化剂的制备方法
US9321037B2 (en) * 2012-12-14 2016-04-26 Chevron U.S.A., Inc. Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units
US20160068760A1 (en) 2013-04-22 2016-03-10 Eni S.P.A. Process for treating a hydrocarbon-based heavy residue
ITMI20131137A1 (it) 2013-07-05 2015-01-06 Eni Spa Procedimento per la raffinazione del greggio
ITUB20152927A1 (it) 2015-08-06 2017-02-06 Luigi Patron Sistema e metodo di idroconversione di oli pesanti mediante reattori a catalizzatore disperso o a letto catalitico espanso con immissione di gas alla testa del reattore
FR3052368A1 (fr) 2016-06-09 2017-12-15 Rhodia Operations Procede de preparation d'un catalyseur a base de sulfure de molybdene
CN107638885B (zh) * 2016-07-22 2019-08-09 中国石油大学(北京) 一种超深度脱硫催化剂及其制备方法
IT201600122525A1 (it) 2016-12-02 2018-06-02 Eni Spa Procedimento per la produzione di lipidi e altri composti organici da biomassa
RU2659076C1 (ru) * 2017-12-08 2018-06-28 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) Катализатор процесса облагораживания углеводородного сырья и способ его приготовления
WO2019115919A1 (fr) 2017-12-13 2019-06-20 Rhodia Operations Composition à base de molybdène
RU2675249C1 (ru) * 2018-08-06 2018-12-18 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Способ получения суспензии молибденсодержащего композитного катализатора гидроконверсии тяжелого нефтяного сырья
CN111099949B (zh) 2018-10-26 2021-04-06 中国石油化工股份有限公司 一种催化裂解的方法
RU2699065C1 (ru) * 2019-05-16 2019-09-03 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН) Катализатор процесса облагораживания тяжелого нефтяного сырья и способ его приготовления (варианты)
CN113617369A (zh) * 2020-05-07 2021-11-09 中国石油天然气股份有限公司 劣质重油改质磁载催化剂及其制备方法与应用
CN115678683A (zh) * 2022-10-20 2023-02-03 中国科学院青岛生物能源与过程研究所 一种废弃油脂生产氢化油的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5171727A (en) 1991-08-26 1992-12-15 Uop Method of preparing a catalyst for the hydroconversion of asphaltene-containing hydrocarbonaceous charge stocks
AU658937B2 (en) * 1991-11-19 1995-05-04 Mobil Oil Corporation Hydrocarbon upgrading process
US5871635A (en) * 1995-05-09 1999-02-16 Exxon Research And Engineering Company Hydroprocessing of petroleum fractions with a dual catalyst system
RU2148611C1 (ru) * 1999-01-06 2000-05-10 Научно-инженерный центр "Цеосит" Объединенного института катализа СО РАН Способ гидропереработки нефтяных фракций
IT1311512B1 (it) 1999-03-12 2002-03-13 Agip Petroli Composizione catalitica per l'upgrading di miscele idrocarburiche.
US20020112987A1 (en) * 2000-12-15 2002-08-22 Zhiguo Hou Slurry hydroprocessing for heavy oil upgrading using supported slurry catalysts
EP1762606A1 (en) 2005-09-13 2007-03-14 Shell Internationale Researchmaatschappij B.V. A process for hydrodesulphurisation of a hydrocarbonaceous feedstock
ITMI20071044A1 (it) * 2007-05-23 2008-11-24 Eni Spa Sistema e procedimento per l'idroconversione di oli pesanti
ITMI20071198A1 (it) * 2007-06-14 2008-12-15 Eni Spa Procedimento migliorato per l'idroconversione di oli pesanti con sistemi a letto ebullato

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