RU2008152245A - Прослойки, включающие модифицированный пирогенный диоксид кремния - Google Patents

Прослойки, включающие модифицированный пирогенный диоксид кремния Download PDF

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RU2008152245A
RU2008152245A RU2008152245/05A RU2008152245A RU2008152245A RU 2008152245 A RU2008152245 A RU 2008152245A RU 2008152245/05 A RU2008152245/05 A RU 2008152245/05A RU 2008152245 A RU2008152245 A RU 2008152245A RU 2008152245 A RU2008152245 A RU 2008152245A
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specified
fumed silica
layer according
interlayer
polymer coating
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RU2008152245/05A
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Пин ЮАНЬ (US)
Пин ЮАНЬ
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Солютиа Инкорпорейтед (Us)
Солютиа Инкорпорейтед
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • C03C27/10Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10018Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10688Adjustment of the adherence to the glass layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/14Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28Compounds of silicon
    • C09C1/30Silicic acid
    • C09C1/3081Treatment with organo-silicon compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/32Thermal properties
    • C01P2006/33Phase transition temperatures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/80Compositional purity
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259Silicic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31598Next to silicon-containing [silicone, cement, etc.] layer
    • Y10T428/31601Quartz or glass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31616Next to polyester [e.g., alkyd]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31627Next to aldehyde or ketone condensation product
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31627Next to aldehyde or ketone condensation product
    • Y10T428/3163Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31645Next to addition polymer from unsaturated monomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31645Next to addition polymer from unsaturated monomers
    • Y10T428/31649Ester, halide or nitrile of addition polymer

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Silicon Compounds (AREA)

Abstract

1. Прослойка для применения в многослойном остеклении, включающая: ! термопластический полимер; и ! пирогенный диоксид кремния, где указанный пирогенный диоксид кремния алкилированный. ! 2. Прослойка по п.1, где указанный пирогенный диоксид кремния имеет содержание углерода, по меньшей мере, 0,5 процента по весу. ! 3. Прослойка за п.1, где указанный пирогенный диоксид кремния является метилированным. ! 4. Прослойка за п.1, где указанный пирогенный диоксид кремния имеет среднюю длину агрегата от 0,15 до 0,35 мкм. ! 5. Прослойка по п.1, где указанный пирогенный диоксид кремния имеет среднюю длину агрегата от 0,2 до 0,3 мкм. ! 6. Прослойка по п.1, где указанная прослойка состоит, главным образом, из одного полимерного покрытия. ! 7. Прослойка по п.1, где указанная прослойка включает более чем одно полимерное покрытие. ! 8. Прослойка по п.1, где указанная прослойка включает полимерное покрытие, имеющее от 10 до 70 частей на сто частей смолы указанного пластификатора и от 0,05 до 15 частей на сто частей смолы указанного пирогенного диоксида кремния. ! 9. Прослойка по п.1, где указанная прослойка включает полимерное покрытие, имеющее от 20 до 60 частей на сто частей смолы указанного пластификатора и от 0,1 до 10 частей на сто частей смолы указанного пирогенного диоксида кремния. !10. Прослойка по п.1, где указанный термопластический полимер включает полимер, выбранный из группы, состоящей из поли(винилбутираля), поли(винилхлорида), поли(этилен-со-винилацетата), поли(этилен-со-этилакрилата), иономеров частично нейтрализированного сополимера этилена и (мет)акриловой кислоты, полиэтилена, полиэтиленовых сополимеров, полиуретана и сополиэфира поли(циклогексан�

Claims (20)

1. Прослойка для применения в многослойном остеклении, включающая:
термопластический полимер; и
пирогенный диоксид кремния, где указанный пирогенный диоксид кремния алкилированный.
2. Прослойка по п.1, где указанный пирогенный диоксид кремния имеет содержание углерода, по меньшей мере, 0,5 процента по весу.
3. Прослойка за п.1, где указанный пирогенный диоксид кремния является метилированным.
4. Прослойка за п.1, где указанный пирогенный диоксид кремния имеет среднюю длину агрегата от 0,15 до 0,35 мкм.
5. Прослойка по п.1, где указанный пирогенный диоксид кремния имеет среднюю длину агрегата от 0,2 до 0,3 мкм.
6. Прослойка по п.1, где указанная прослойка состоит, главным образом, из одного полимерного покрытия.
7. Прослойка по п.1, где указанная прослойка включает более чем одно полимерное покрытие.
8. Прослойка по п.1, где указанная прослойка включает полимерное покрытие, имеющее от 10 до 70 частей на сто частей смолы указанного пластификатора и от 0,05 до 15 частей на сто частей смолы указанного пирогенного диоксида кремния.
9. Прослойка по п.1, где указанная прослойка включает полимерное покрытие, имеющее от 20 до 60 частей на сто частей смолы указанного пластификатора и от 0,1 до 10 частей на сто частей смолы указанного пирогенного диоксида кремния.
10. Прослойка по п.1, где указанный термопластический полимер включает полимер, выбранный из группы, состоящей из поли(винилбутираля), поли(винилхлорида), поли(этилен-со-винилацетата), поли(этилен-со-этилакрилата), иономеров частично нейтрализированного сополимера этилена и (мет)акриловой кислоты, полиэтилена, полиэтиленовых сополимеров, полиуретана и сополиэфира поли(циклогександиметилентерефталат-со-этилентерефталата).
11. Прослойка для применения в многослойном остеклении, включающая:
полимерное покрытие, включающее: поли(винилбутираль); пластификатор; и,
пирогенный диоксид кремния, где указанный пирогенный диоксид кремния алкилирован и где указанная прослойка включает полимерное покрытие, имеющее температуру стеклования менее чем 40°С.
12. Прослойка по п.11, где указанный пирогенный диоксид кремния имеет содержание углерода по меньшей мере 0,5 процента по весу.
13. Прослойка по п.11, где указанный пирогенный диоксид кремния является метилированным.
14. Прослойка по п.11, где указанный пирогенный диоксид кремния имеет среднюю длину агрегата от 0,15 до 0,35 мкм.
15. Прослойка по п.11, где указанный пирогенный диоксид кремния имеет среднюю длину агрегата от 0,2 до 0,3 мкм.
16. Прослойка по п.11, где указанная прослойка состоит, главным образом, из одного полимерного покрытия.
17. Прослойка по п.11, где указанная прослойка включает более чем одно полимерное покрытие.
18. Прослойка по п.11, где указанная прослойка включает полимерное покрытие, имеющее от 10 до 70 частей на сто частей смолы указанного пластификатора и от 0,05 до 15 частей на сто частей смолы указанного пирогенного диоксида кремния.
19. Прослойка по п.11, где указанная прослойка включает полимерное покрытие, имеющее от 20 до 60 частей на сто частей смолы указанного пластификатора и от 0,1 до 10 частей на сто частей смолы указанного пирогенного диоксида кремния.
20. Многослойная стеклянная панель, включающая прослойку, где указанная прослойка включает:
термопластический полимер; и,
пирогенный диоксид кремния, где указанный пирогенный диоксид кремния алкилирован.
RU2008152245/05A 2006-06-10 2007-06-08 Прослойки, включающие модифицированный пирогенный диоксид кремния RU2008152245A (ru)

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US11/423,435 2006-06-10
US11/423,435 US7348062B2 (en) 2006-06-10 2006-06-10 Interlayers comprising modified fumed silica

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AU2007256598B2 (en) 2012-07-05
CN101460303A (zh) 2009-06-17
US7867618B2 (en) 2011-01-11
ES2436618T3 (es) 2014-01-03
KR20090016571A (ko) 2009-02-16
WO2007143746A2 (en) 2007-12-13
EP2040918B8 (en) 2013-10-02
CA2654247A1 (en) 2007-12-13
WO2007143746A3 (en) 2008-01-24
PT2040918E (pt) 2013-10-02
US20080124540A1 (en) 2008-05-29
PL2040918T3 (pl) 2014-01-31
US7348062B2 (en) 2008-03-25
BRPI0712391A2 (pt) 2012-10-16
CN101460303B (zh) 2013-01-23
AU2007256598A1 (en) 2007-12-13
MX2008015465A (es) 2009-01-07
CA2654247C (en) 2013-10-29
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JP2009540065A (ja) 2009-11-19
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