RU2007130730A - Полимочевинное соединение - Google Patents
Полимочевинное соединение Download PDFInfo
- Publication number
- RU2007130730A RU2007130730A RU2007130730/04A RU2007130730A RU2007130730A RU 2007130730 A RU2007130730 A RU 2007130730A RU 2007130730/04 A RU2007130730/04 A RU 2007130730/04A RU 2007130730 A RU2007130730 A RU 2007130730A RU 2007130730 A RU2007130730 A RU 2007130730A
- Authority
- RU
- Russia
- Prior art keywords
- polyurea
- chiral
- compound according
- monoamine
- polyurea compound
- Prior art date
Links
- 229920002396 Polyurea Polymers 0.000 title claims 47
- 150000001875 compounds Chemical class 0.000 title claims 46
- 239000000203 mixture Substances 0.000 claims 12
- 229920001228 polyisocyanate Polymers 0.000 claims 8
- 239000005056 polyisocyanate Substances 0.000 claims 8
- 239000003795 chemical substances by application Substances 0.000 claims 7
- RQEUFEKYXDPUSK-UHFFFAOYSA-N 1-phenylethylamine Chemical compound CC(N)C1=CC=CC=C1 RQEUFEKYXDPUSK-UHFFFAOYSA-N 0.000 claims 6
- 125000004429 atom Chemical group 0.000 claims 5
- 239000007795 chemical reaction product Substances 0.000 claims 5
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 claims 4
- 239000008199 coating composition Substances 0.000 claims 4
- 230000004941 influx Effects 0.000 claims 4
- 238000000034 method Methods 0.000 claims 4
- 238000001556 precipitation Methods 0.000 claims 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 125000003118 aryl group Chemical group 0.000 claims 3
- 239000011230 binding agent Substances 0.000 claims 3
- 239000004202 carbamide Substances 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 239000011248 coating agent Substances 0.000 claims 3
- 238000000576 coating method Methods 0.000 claims 3
- 230000001276 controlling effect Effects 0.000 claims 3
- 125000005842 heteroatom Chemical group 0.000 claims 3
- 239000007787 solid Substances 0.000 claims 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims 2
- 150000001412 amines Chemical class 0.000 claims 2
- 238000002844 melting Methods 0.000 claims 2
- 230000008018 melting Effects 0.000 claims 2
- 238000000518 rheometry Methods 0.000 claims 2
- 239000004594 Masterbatch (MB) Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000001413 amino acids Chemical class 0.000 claims 1
- 125000000732 arylene group Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000011111 cardboard Substances 0.000 claims 1
- 239000002537 cosmetic Substances 0.000 claims 1
- 125000004956 cyclohexylene group Chemical group 0.000 claims 1
- 239000003599 detergent Substances 0.000 claims 1
- 229920006351 engineering plastic Polymers 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 125000004404 heteroalkyl group Chemical group 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 239000000976 ink Substances 0.000 claims 1
- 239000013067 intermediate product Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 238000005065 mining Methods 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 239000000123 paper Substances 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 claims 1
- 125000004076 pyridyl group Chemical group 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 claims 1
- 238000007665 sagging Methods 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000013049 sediment Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 239000004753 textile Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/285—Nitrogen containing compounds
- C08G18/2865—Compounds having only one primary or secondary amino group; Ammonia
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/04—Thixotropic paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/02—Polyureas
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05075061.1 | 2005-01-11 | ||
| EP05075061 | 2005-01-11 | ||
| US65445505P | 2005-02-22 | 2005-02-22 | |
| US60/654,455 | 2005-02-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU2007130730A true RU2007130730A (ru) | 2009-02-20 |
Family
ID=34937986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2007130730/04A RU2007130730A (ru) | 2005-01-11 | 2006-01-10 | Полимочевинное соединение |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8742052B2 (enExample) |
| EP (1) | EP1846469B1 (enExample) |
| JP (2) | JP2008527126A (enExample) |
| KR (1) | KR20070100947A (enExample) |
| CN (2) | CN101103061B (enExample) |
| BR (1) | BRPI0606710A2 (enExample) |
| RU (1) | RU2007130730A (enExample) |
| WO (1) | WO2006075000A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2618225C2 (ru) * | 2012-03-29 | 2017-05-03 | Хантсмэн Интернэшнл Ллс | Форполимер на основе изоцианата |
| RU2621733C2 (ru) * | 2012-03-29 | 2017-06-07 | Хантсмэн Интернэшнл Ллс | Преполимер на основе изоцианата |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1838747B1 (en) * | 2005-01-11 | 2018-04-18 | Allnex Netherlands B.V. | Comixtures for use in rheology modification |
| FR2907336A1 (fr) * | 2006-10-19 | 2008-04-25 | Oreal | Vernis a ongles contenant un agent gelifiant polyuree |
| GB2462105A (en) | 2008-07-24 | 2010-01-27 | Nuplex Resins Bv | Thixotropic aqueous coating composition |
| CN102834474A (zh) * | 2010-04-09 | 2012-12-19 | 拜尔材料科学有限公司 | 双组分聚天冬氨酸类涂料组合物 |
| CN102372655B (zh) * | 2010-08-26 | 2014-03-26 | 中国石油化工股份有限公司 | 一种碳酰四胺化合物及其制备方法 |
| EP2463340A1 (de) | 2010-12-09 | 2012-06-13 | Sika Technology AG | Thixotrope Polyharnstoffaddukte |
| CN105985724A (zh) | 2011-10-07 | 2016-10-05 | 树脂核动力工业有限公司 | 可交联组合物 |
| ES2669524T3 (es) | 2013-04-08 | 2018-05-28 | Allnex Netherlands B.V. | Composición reticulable por reacción de adición de Michael Real (RMA) |
| US20150175834A1 (en) * | 2013-12-19 | 2015-06-25 | Axalta Coating Systems Ip Co., Llc | Low bake temperature curable coating compositions and processes for producing coatings at low bake temperatures |
| US20150175836A1 (en) * | 2013-12-19 | 2015-06-25 | Axalta Coating Systems Ip Co., Llc | Low bake temperature curable coating compositions and processes for producing coatings at low bake temperatures |
| JP6295706B2 (ja) * | 2014-02-19 | 2018-03-20 | 東ソー株式会社 | ポリオール組成物 |
| US9856384B2 (en) * | 2014-07-21 | 2018-01-02 | Axalta Coatings Systems Ip Co., Llc | Sag control compositions, methods of forming the same, and methods of forming coating systems using the same |
| CN107667146B (zh) | 2015-04-17 | 2021-01-01 | 欧尼克斯荷兰有限公司 | 制造可交联组合物的方法 |
| CN107660227B (zh) | 2015-04-17 | 2021-07-16 | 欧尼克斯荷兰有限公司 | 地板涂料组合物 |
| EP3283588B1 (en) | 2015-04-17 | 2025-06-18 | Allnex Netherlands B.V. | A method for curing a rma crosslinkable resin coating, rma crosslinkable compositions and resins for use therein |
| EP3283585B1 (en) | 2015-04-17 | 2023-11-15 | Allnex Netherlands B.V. | Adhesion promotor for real michael addition crosslinkable compositions |
| JP6580166B2 (ja) * | 2015-07-27 | 2019-09-25 | ビイク−ヒエミー ゲゼルシャフト ミツト ベシユレンクテル ハフツングＢＹＫ−Ｃｈｅｍｉｅ ＧｍｂＨ | レオロジーコントロールのためのウレアウレタン |
| KR101835720B1 (ko) * | 2015-11-30 | 2018-03-08 | 케이에스케미칼 주식회사 | 전단유동화 특성을 갖는 점탄성 조절제의 제조방법 |
| CA3030942C (en) * | 2016-07-15 | 2020-04-07 | Kansai Paint Co., Ltd. | Coating composition |
| JP7004537B2 (ja) * | 2016-09-30 | 2022-01-21 | ライオン株式会社 | 粒子分散洗浄剤組成物 |
| ES2935646T3 (es) * | 2016-11-07 | 2023-03-08 | Allnex Netherlands Bv | Un procedimiento para la preparación de una composición tixotrópica |
| US20210054228A1 (en) * | 2017-12-28 | 2021-02-25 | Kansai Paint Co., Ltd. | Coating composition |
| JPWO2019235256A1 (ja) * | 2018-06-05 | 2021-06-24 | 東京エレクトロン株式会社 | 半導体装置の製造方法、成膜用組成物および成膜装置 |
| EP3663326A1 (en) | 2018-12-04 | 2020-06-10 | Allnex Netherlands B.V. | Rma crosslinkable polymer |
| CN113454175A (zh) * | 2019-02-15 | 2021-09-28 | 关西涂料株式会社 | 流变控制剂和涂料组合物 |
| JP7408586B2 (ja) * | 2019-02-15 | 2024-01-05 | 関西ペイント株式会社 | 塗料組成物 |
| MX2021011707A (es) | 2019-03-26 | 2021-10-22 | Kansai Paint Co Ltd | Composicion de pintura. |
| US11760897B2 (en) | 2019-07-30 | 2023-09-19 | Axalta Coating Systems Ip Co., Llc | Coating compositions including a sag control agent and wax |
| CN113045972A (zh) * | 2019-12-27 | 2021-06-29 | 深圳市精彩科技有限公司 | 聚脲涂料 |
| CN111303378A (zh) * | 2020-03-06 | 2020-06-19 | 长春工业大学 | 一种基于tmxdi的聚氨酯类抗流挂树脂及其制备方法 |
| CN111349370A (zh) * | 2020-04-24 | 2020-06-30 | 湖南湘江关西涂料有限公司 | 高触变性树脂及其制备方法与应用、涂料 |
| CN113024163B (zh) * | 2021-04-22 | 2021-11-23 | 广东省水利水电第三工程局有限公司 | 一种触变泥浆及其减阻方法 |
| EP4330337A1 (en) * | 2021-04-28 | 2024-03-06 | Allnex Netherlands B.V. | Process for overspray-free application of a resin composition and resin compositions for use in the process |
| CN114369219B (zh) * | 2021-12-20 | 2023-11-10 | 上海金仕迈树脂有限公司 | 一种聚脲颗粒改性触变树脂及其制备方法 |
| CN115820071B (zh) * | 2022-08-08 | 2023-08-18 | 山东奔腾漆业股份有限公司 | 一种耐腐蚀涂料及其制备方法 |
| CN116875160B (zh) * | 2023-08-05 | 2024-07-09 | 中海油常州涂料化工研究院有限公司 | 一种航空器蒙皮用珠光漆及其制备方法 |
| DE202024101935U1 (de) | 2024-04-18 | 2024-05-27 | Nippon Paint Automotive Europe Gmbh | Glitzernde Klarlackzusammensetzung und mehrschichtige Kraftfahrzeugbeschichtung, die diese Zusammensetzung enthält |
| EP4636045A1 (en) | 2024-04-18 | 2025-10-22 | NIPPON PAINT AUTOMOTIVE EUROPE GmbH | Sparkling clear coat composition and multilayer automotive coating including the same |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3367920A (en) | 1964-11-24 | 1968-02-06 | Merck & Co Inc | Polyurea and method of preparing same |
| US3620695A (en) * | 1969-04-10 | 1971-11-16 | Texaco Inc | Thickened compositions and process of preparing them |
| US4165329A (en) * | 1972-06-02 | 1979-08-21 | Chevron Research Company | Grease thickening agent |
| NL176864C (nl) | 1976-11-25 | 1985-06-17 | Akzo Nv | Werkwijze voor de bereiding van een thixotrope bekledingssamenstelling. |
| US4528319A (en) * | 1984-07-20 | 1985-07-09 | General Motors Corporation | Sag control of high solid polyurethane clearcoats by urea thixotrope/silica systems |
| JPH0637602B2 (ja) | 1986-09-25 | 1994-05-18 | 日本油脂株式会社 | 塗料用流動性制御剤 |
| US5176907A (en) * | 1991-08-13 | 1993-01-05 | The Johns Hopkins University School Of Medicine | Biocompatible and biodegradable poly (phosphoester-urethanes) |
| ZA981569B (en) * | 1997-04-08 | 1999-08-25 | Du Pont | An engineered seed protein having a higher percentage of essential amino acids. |
| US7196154B2 (en) * | 2000-12-11 | 2007-03-27 | Light Black Inc. | Method of producing polymer resins |
| EP1641747B1 (en) * | 2001-10-26 | 2010-08-04 | Nuplex Resins B.V. | Acicular crystals of hydrazine-based diurea derivatives and their use as rheology modifiers in coating and adhesive compositions |
| US20050119422A1 (en) * | 2002-04-24 | 2005-06-02 | Basf Corporation | Thermally curable, thixotropic mixtures containing carbamate and/or allophanate groups |
| AU2003258013A1 (en) * | 2002-08-01 | 2004-02-23 | California Institute Of Technology | Synthesis of macrocyclic polymers by ring insertion polymerization of cyclic olefin monomers |
| ES2383634T3 (es) | 2003-07-08 | 2012-06-22 | Nuplex Resins B.V. | Derivados de aminoácidos y su uso como agente de control del descolgamiento |
| CN101213230B (zh) * | 2005-06-28 | 2011-12-28 | 树脂核动力工业有限公司 | 作为触变流变改进剂的聚脲制品 |
-
2006
- 2006-01-10 RU RU2007130730/04A patent/RU2007130730A/ru not_active Application Discontinuation
- 2006-01-10 JP JP2007550741A patent/JP2008527126A/ja not_active Withdrawn
- 2006-01-10 WO PCT/EP2006/050134 patent/WO2006075000A1/en not_active Ceased
- 2006-01-10 JP JP2007550788A patent/JP2008526922A/ja not_active Withdrawn
- 2006-01-10 CN CN2006800020901A patent/CN101103061B/zh active Active
- 2006-01-10 EP EP06700743.5A patent/EP1846469B1/en active Active
- 2006-01-10 BR BRPI0606710A patent/BRPI0606710A2/pt not_active IP Right Cessation
- 2006-01-10 CN CNA2006800020865A patent/CN101103060A/zh active Pending
- 2006-01-10 US US11/795,095 patent/US8742052B2/en active Active
- 2006-01-10 KR KR1020077016675A patent/KR20070100947A/ko not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2618225C2 (ru) * | 2012-03-29 | 2017-05-03 | Хантсмэн Интернэшнл Ллс | Форполимер на основе изоцианата |
| RU2621733C2 (ru) * | 2012-03-29 | 2017-06-07 | Хантсмэн Интернэшнл Ллс | Преполимер на основе изоцианата |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101103061A (zh) | 2008-01-09 |
| JP2008527126A (ja) | 2008-07-24 |
| WO2006075000A1 (en) | 2006-07-20 |
| JP2008526922A (ja) | 2008-07-24 |
| US20080139755A1 (en) | 2008-06-12 |
| EP1846469A1 (en) | 2007-10-24 |
| EP1846469B1 (en) | 2014-04-30 |
| CN101103061B (zh) | 2011-03-02 |
| US8742052B2 (en) | 2014-06-03 |
| BRPI0606710A2 (pt) | 2017-07-11 |
| CN101103060A (zh) | 2008-01-09 |
| KR20070100947A (ko) | 2007-10-15 |
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