RU2005122823A - Гидрофилизированные блокированные полиизоцианаты - Google Patents
Гидрофилизированные блокированные полиизоцианаты Download PDFInfo
- Publication number
- RU2005122823A RU2005122823A RU2005122823/04A RU2005122823A RU2005122823A RU 2005122823 A RU2005122823 A RU 2005122823A RU 2005122823/04 A RU2005122823/04 A RU 2005122823/04A RU 2005122823 A RU2005122823 A RU 2005122823A RU 2005122823 A RU2005122823 A RU 2005122823A
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- RU
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- Prior art keywords
- necessary
- polyisocyanates
- ionic
- coatings
- electron
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8093—Compounds containing active methylene groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0828—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3821—Carboxylic acids; Esters thereof with monohydroxyl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3823—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
- C08G18/3831—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing urethane groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
Claims (8)
1. Полиизоцианаты, которые содержат
i) неионные гидрофилизирующие группы на основе простых полиалкиленоксид-полиэфиров, содержащих не менее 30 мас.% этиленоксидных звеньев,
и/или
ii) ионные или потенциально ионные гидрофилизирующие группы, которые при взаимодействии с водой образуют зависящее от величины рН равновесие диссоциации, и в зависимости от величины рН не имеющие заряда, заряженные положительно или отрицательно,
и
iii) по меньшей мере, одну структурную единицу формулы (1)
где Х - электронно-акцепторная группа,
R1, R2 - независимо друг от друга атом водорода, насыщенный или ненасыщенный алифатический или циклоалифатический, при необходимости замещенный ароматический или аралифатический остаток и каждый содержит до 12 атомов углерода и
n - целое число от 0 до 5.
2. Полиизоцианаты по п.1, отличающиеся тем, что электронно-акцепторная группа Х означает сложноэфирную, сульфоксидную, сульфоновую, нитро-, фосфонатную, нитрильную, изонитрильную или карбонильную группу.
3. Способ получения полиизоцианатов по п.1 или 2, при котором
А) один или несколько органических полиизоцианатов взаимодействуют с
Б) одним или несколькими, содержащими, по меньшей мере, одну реакционно-способную по отношению к изоцианатам группу, органическими соединениями, которые имеют
б1) неионные гидрофилизирующие группы на основе простых полиалкиленоксидполиэфиров, содержащих не менее 30 мас.% этиленоксидных звеньев,
и/или
б2) ионные или потенциально ионные гидрофилизирующие группы, образующие при взаимодействии с водой зависящее от величины рН равновесие диссоциации, и в зависимости от величины рН не имеющие заряда, заряженные положительно или отрицательно,
В) одним или несколькими блокирующими средствами, содержащими, по меньшей мере, один обладающий СН-кислотностью циклический кетон общей формулы (2),
где Х - электронно-акцепторная группа,
R1, R2 - независимо друг от друга атом водорода, насыщенный или ненасыщенный алифатический или циклоалифатический, при необходимости замещенный ароматический или аралифатический остаток и каждый содержит до 12 атомов углерода и
n - целое число от 0 до 5,
и
Г) при необходимости, с одним или несколькими (цикло)алифатическими моно- или полиаминами с количеством аминогрупп в молекуле от 1 до 4 и молекулярным весом до 400 и, при необходимости, одним или несколькими многоатомными спиртами с количеством гидроксильных групп в молекуле от 1 до 4 и молекулярным весом до 400, при необходимости, также с аминоспиртами в присутствии
Д) одного или нескольких катализаторов,
Е) при необходимости, вспомогательных веществ и добавок и
Ж) при необходимости, растворителей.
4. Применение полиизоцианатов по п.1 или 2 для изготовления лаков, покрытий, шлихты, клеящих средств и формованных изделий.
5. Водные растворы или дисперсии полиизоцианатов по п.1 или 2.
6. Материалы для покрытий, содержащие
а) один или несколько полиизоцианатов по п.1 или 2,
б) один или несколько пленкообразующих смол,
в) при необходимости, катализаторы,
г) при необходимости, растворитель и
д) при необходимости, вспомогательные вещества и добавки.
7. Покрытия, получаемые из материалов для покрытий по п.6.
8. Субстраты с покрытиями по п.7.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10260298A DE10260298A1 (de) | 2002-12-20 | 2002-12-20 | Hydrophilierte blockierte Polysocyanate |
| DE10260298.0 | 2002-12-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2005122823A true RU2005122823A (ru) | 2006-01-20 |
| RU2345097C2 RU2345097C2 (ru) | 2009-01-27 |
Family
ID=32404131
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2005122823/04A RU2345097C2 (ru) | 2002-12-20 | 2003-12-06 | Гидрофилизированные блокированные полиизоцианаты |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US7220814B2 (ru) |
| EP (1) | EP1581576B1 (ru) |
| JP (1) | JP4538327B2 (ru) |
| KR (1) | KR101080442B1 (ru) |
| CN (1) | CN1326903C (ru) |
| AT (1) | ATE471347T1 (ru) |
| AU (1) | AU2003292202A1 (ru) |
| BR (1) | BR0317429A (ru) |
| CA (1) | CA2510554C (ru) |
| DE (2) | DE10260298A1 (ru) |
| ES (1) | ES2345883T3 (ru) |
| HK (1) | HK1088024A1 (ru) |
| MX (1) | MXPA05006531A (ru) |
| RU (1) | RU2345097C2 (ru) |
| WO (1) | WO2004058847A1 (ru) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10260269A1 (de) * | 2002-12-20 | 2004-07-01 | Bayer Ag | Neue Dual Cure-Systeme |
| DE102005048823A1 (de) * | 2005-10-10 | 2007-04-12 | Bayer Materialscience Ag | Reaktivsysteme, deren Herstellung und Verwendung |
| JP5399625B2 (ja) * | 2007-11-13 | 2014-01-29 | 日東電工株式会社 | 複合フィルム |
| ES2439011T3 (es) * | 2009-02-13 | 2014-01-21 | Bayer Materialscience Llc | Recubrimientos de poliuretano basados en agua limpiables |
| US8940853B2 (en) * | 2011-03-16 | 2015-01-27 | Asahi Kasei Chemicals Corporation | Cationic blocked polyisocyanate and aqueous composition comprising the same |
| EP2971416A2 (en) * | 2013-03-15 | 2016-01-20 | Spectrum Brands, Inc. | Wireless lockset with integrated antenna, touch activation, and light communication method |
| EP3284765B1 (en) | 2013-08-23 | 2020-07-08 | Mitsui Chemicals, Inc. | Blocked isocyanate, coating composition, adhesive composition, and article |
| CN104448232B (zh) * | 2013-09-13 | 2017-12-15 | 万华化学集团股份有限公司 | 一种氨基磺酸改性的多异氰酸酯及其制备方法和用途 |
| JP2015102636A (ja) * | 2013-11-22 | 2015-06-04 | 富士フイルム株式会社 | 偏光子保護フィルム、偏光板及び画像表示装置 |
| JP6226762B2 (ja) * | 2014-01-31 | 2017-11-08 | 富士フイルム株式会社 | 光学用ポリエステルフィルム、偏光板、画像表示装置、光学用ポリエステルフィルムの製造方法、および易接着層用組成物 |
| CN109476817B (zh) | 2016-06-03 | 2021-08-03 | 亨茨曼国际有限公司 | 封端异氰酸酯组合物 |
| CN108264622B (zh) * | 2016-12-30 | 2020-06-19 | 比亚迪股份有限公司 | 水性聚氨酯及其制备中间体和制备方法 |
| EP3507318B1 (en) | 2017-01-31 | 2022-11-09 | Hewlett-Packard Development Company, L.P. | Reactive polyurethane dispersions |
| US10640599B2 (en) | 2017-01-31 | 2020-05-05 | Hewlett-Packard Development Company, L.P. | Reactive polyurethane dispersions |
| US10920074B2 (en) | 2017-01-31 | 2021-02-16 | Hewlett-Packard Development Company, L.P. | Reactive polyurethane dispersions |
| EP3507319A4 (en) | 2017-01-31 | 2019-10-09 | Hewlett-Packard Development Company, L.P. | REACTIVE POLYURETHANE ISOLATIONS |
| CN106565928A (zh) * | 2017-02-23 | 2017-04-19 | 北京理工大学 | 一种混合亲水聚异氰酸酯固化剂 |
| CN107236114B (zh) * | 2017-06-15 | 2021-01-29 | 盐城工学院 | 一种含纳米二氧化硅结构的水性封闭型聚异氰酸酯交联剂及其制备方法 |
| EP3560974A1 (de) | 2018-04-25 | 2019-10-30 | Covestro Deutschland AG | Ionisch hydrophilierte polyisocyanate, wassergehalt |
| ES2884214T3 (es) | 2018-04-25 | 2021-12-10 | Covestro Deutschland Ag | Poliisocianatos hidrofilizados iónicamente y secuestradores de radicales y/o descomponedores de peróxidos |
| EP3560975B2 (de) | 2018-04-25 | 2023-12-06 | Covestro Intellectual Property GmbH & Co. KG | Ionisch hydrophilierte polyisocyanate und antioxidantien |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4108814A (en) * | 1974-09-28 | 1978-08-22 | Bayer Aktiengesellschaft | Aqueous polyurethane dispersions from solvent-free prepolymers using sulfonate diols |
| DE2456469C2 (de) * | 1974-11-29 | 1983-01-13 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von in Wasser löslichen bzw. dispergierbaren blockierten Polyisocyanaten und ihre Verwendung als Beschichtungsmittel |
| DE2853937A1 (de) * | 1978-12-14 | 1980-07-03 | Bayer Ag | Verfahren zur herstellung von wasserdispergierbaren oder -loeslichen blockierten polyisocyanaten, die nach dem verfahren erhaeltlichen blockierten polyisocyanate, sowie diese blockierte polyisocyanate als isocyanatkomponente enthaltende lackbindemittel |
| DE4240480A1 (de) * | 1992-12-02 | 1994-08-25 | Bayer Ag | Organische Polyisocyanate mit zumindest teilweise blockierten Isocyanatgruppen |
| GB2290793B (en) * | 1994-06-20 | 1998-05-06 | Cray Valley Ltd | Powder coating compositions |
| JP3431285B2 (ja) * | 1994-07-13 | 2003-07-28 | 旭化成株式会社 | 水性ブロックポリイソシアナート組成物及びそれを含む水性塗料組成物 |
| US6025433A (en) * | 1995-12-20 | 2000-02-15 | Basf Coatings Ag | Thermosetting paint composition |
| JP3947260B2 (ja) * | 1997-02-19 | 2007-07-18 | 旭化成ケミカルズ株式会社 | 水性ブロックポリイソシアネート組成物 |
| DE19750186A1 (de) | 1997-11-13 | 1999-05-20 | Bayer Ag | Hydrophilierungsmittel, ein Verfahren zu dessen Herstellung sowie dessen Verwendung als Dispergator für wäßrige Polyurethan-Dispersionen |
| DE19813352A1 (de) * | 1998-03-26 | 1999-09-30 | Bayer Ag | Malonesterblockierte Polyisocyanate mit Formaldehyd gegen Thermovergilbung |
| DE10024624A1 (de) | 2000-05-18 | 2001-11-22 | Bayer Ag | Modifizierte Polyisocyanate |
| JP3884277B2 (ja) * | 2001-02-21 | 2007-02-21 | 関西ペイント株式会社 | ブロックイソシアネート基含有樹脂組成物及びこれを含む熱硬化性組成物 |
| DE10132016A1 (de) * | 2001-07-03 | 2003-01-16 | Bayer Ag | Cyclische Ketone als Blockierungsmittel |
| WO2003004545A1 (de) * | 2001-07-03 | 2003-01-16 | Bayer Aktiengesellschaft | Cyclische ketone als blockierungsmittel |
| DE10226926A1 (de) * | 2002-06-17 | 2004-02-05 | Bayer Ag | Blockierte Polyisocyanate |
| DE10260299A1 (de) * | 2002-12-20 | 2004-07-01 | Bayer Ag | Reaktivsysteme, deren Herstellung und deren Verwendung |
| DE10260270A1 (de) * | 2002-12-20 | 2004-07-01 | Bayer Ag | Hydrophile Polyurethan-Polyharnstoff-Dispersion |
-
2002
- 2002-12-20 DE DE10260298A patent/DE10260298A1/de not_active Withdrawn
-
2003
- 2003-12-06 EP EP03767760A patent/EP1581576B1/de not_active Expired - Lifetime
- 2003-12-06 JP JP2004562697A patent/JP4538327B2/ja not_active Expired - Fee Related
- 2003-12-06 MX MXPA05006531A patent/MXPA05006531A/es active IP Right Grant
- 2003-12-06 CA CA2510554A patent/CA2510554C/en not_active Expired - Fee Related
- 2003-12-06 WO PCT/EP2003/013820 patent/WO2004058847A1/de active Application Filing
- 2003-12-06 RU RU2005122823/04A patent/RU2345097C2/ru not_active IP Right Cessation
- 2003-12-06 ES ES03767760T patent/ES2345883T3/es not_active Expired - Lifetime
- 2003-12-06 BR BR0317429-8A patent/BR0317429A/pt not_active Application Discontinuation
- 2003-12-06 DE DE50312819T patent/DE50312819D1/de not_active Expired - Lifetime
- 2003-12-06 AU AU2003292202A patent/AU2003292202A1/en not_active Abandoned
- 2003-12-06 CN CNB2003801068073A patent/CN1326903C/zh not_active Expired - Fee Related
- 2003-12-06 AT AT03767760T patent/ATE471347T1/de active
- 2003-12-06 KR KR1020057011419A patent/KR101080442B1/ko not_active IP Right Cessation
- 2003-12-17 US US10/738,504 patent/US7220814B2/en not_active Expired - Fee Related
-
2006
- 2006-07-28 HK HK06108433A patent/HK1088024A1/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1729223A (zh) | 2006-02-01 |
| ATE471347T1 (de) | 2010-07-15 |
| BR0317429A (pt) | 2005-11-16 |
| US7220814B2 (en) | 2007-05-22 |
| HK1088024A1 (en) | 2006-10-27 |
| JP2006510784A (ja) | 2006-03-30 |
| EP1581576B1 (de) | 2010-06-16 |
| ES2345883T3 (es) | 2010-10-05 |
| EP1581576A1 (de) | 2005-10-05 |
| RU2345097C2 (ru) | 2009-01-27 |
| KR20050085792A (ko) | 2005-08-29 |
| DE50312819D1 (en) | 2010-07-29 |
| JP4538327B2 (ja) | 2010-09-08 |
| CA2510554C (en) | 2011-09-20 |
| KR101080442B1 (ko) | 2011-11-04 |
| US20040138403A1 (en) | 2004-07-15 |
| CA2510554A1 (en) | 2004-07-15 |
| AU2003292202A1 (en) | 2004-07-22 |
| MXPA05006531A (es) | 2005-08-26 |
| CN1326903C (zh) | 2007-07-18 |
| DE10260298A1 (de) | 2004-07-01 |
| WO2004058847A1 (de) | 2004-07-15 |
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| Date | Code | Title | Description |
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| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20131207 |