RO121323B1 - Procedeu de obţinere a unui compus argilos anionic - Google Patents
Procedeu de obţinere a unui compus argilos anionic Download PDFInfo
- Publication number
- RO121323B1 RO121323B1 ROA200000426A RO200000426A RO121323B1 RO 121323 B1 RO121323 B1 RO 121323B1 RO A200000426 A ROA200000426 A RO A200000426A RO 200000426 A RO200000426 A RO 200000426A RO 121323 B1 RO121323 B1 RO 121323B1
- Authority
- RO
- Romania
- Prior art keywords
- compound
- hydrotalcite
- htl
- vanadium
- cerium
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 205
- 125000000129 anionic group Chemical group 0.000 title claims abstract description 86
- 239000004927 clay Substances 0.000 title claims abstract description 70
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 101
- 230000008569 process Effects 0.000 claims abstract description 70
- 229910052751 metal Inorganic materials 0.000 claims abstract description 30
- 239000002184 metal Substances 0.000 claims abstract description 30
- 239000011541 reaction mixture Substances 0.000 claims abstract description 28
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical class [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 255
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 168
- 229960001545 hydrotalcite Drugs 0.000 claims description 168
- 239000011777 magnesium Substances 0.000 claims description 91
- 238000010438 heat treatment Methods 0.000 claims description 64
- -1 hydrotalcite compound Chemical class 0.000 claims description 62
- 239000000203 mixture Substances 0.000 claims description 41
- 229910052749 magnesium Inorganic materials 0.000 claims description 36
- 229910052782 aluminium Inorganic materials 0.000 claims description 34
- 229910052720 vanadium Inorganic materials 0.000 claims description 30
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 30
- 229910052684 Cerium Inorganic materials 0.000 claims description 29
- 230000036571 hydration Effects 0.000 claims description 29
- 238000006703 hydration reaction Methods 0.000 claims description 29
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 28
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 27
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 24
- 239000007800 oxidant agent Substances 0.000 claims description 23
- 239000002250 absorbent Substances 0.000 claims description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- 230000002745 absorbent Effects 0.000 claims description 19
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
- 239000006096 absorbing agent Substances 0.000 claims description 15
- 238000002441 X-ray diffraction Methods 0.000 claims description 13
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
- 239000011651 chromium Substances 0.000 claims description 11
- 230000001590 oxidative effect Effects 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 239000004005 microsphere Substances 0.000 claims description 9
- 229910052697 platinum Inorganic materials 0.000 claims description 9
- 229910052804 chromium Inorganic materials 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 239000010937 tungsten Substances 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052770 Uranium Inorganic materials 0.000 claims description 6
- 229910052741 iridium Inorganic materials 0.000 claims description 6
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- 229910052703 rhodium Inorganic materials 0.000 claims description 6
- 239000010948 rhodium Substances 0.000 claims description 6
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 6
- 230000001131 transforming effect Effects 0.000 claims description 6
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052727 yttrium Inorganic materials 0.000 claims description 6
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 5
- 239000010941 cobalt Substances 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
- 150000002681 magnesium compounds Chemical class 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims 3
- 240000008042 Zea mays Species 0.000 claims 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims 1
- 235000005822 corn Nutrition 0.000 claims 1
- 230000000887 hydrating effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 67
- 239000003054 catalyst Substances 0.000 description 62
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 53
- 238000001994 activation Methods 0.000 description 37
- 239000000047 product Substances 0.000 description 37
- 230000015572 biosynthetic process Effects 0.000 description 33
- 239000002243 precursor Substances 0.000 description 31
- 239000011029 spinel Substances 0.000 description 31
- 229910052596 spinel Inorganic materials 0.000 description 31
- 229940091250 magnesium supplement Drugs 0.000 description 29
- 239000000395 magnesium oxide Substances 0.000 description 27
- 239000002594 sorbent Substances 0.000 description 27
- 239000010802 sludge Substances 0.000 description 25
- 239000011230 binding agent Substances 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 238000006243 chemical reaction Methods 0.000 description 22
- 230000003197 catalytic effect Effects 0.000 description 19
- 238000007254 oxidation reaction Methods 0.000 description 18
- 230000003647 oxidation Effects 0.000 description 17
- 230000004913 activation Effects 0.000 description 16
- 150000001450 anions Chemical class 0.000 description 14
- 229930195733 hydrocarbon Natural products 0.000 description 12
- 150000002430 hydrocarbons Chemical class 0.000 description 12
- 239000004615 ingredient Substances 0.000 description 12
- 239000010410 layer Substances 0.000 description 12
- 238000009740 moulding (composite fabrication) Methods 0.000 description 12
- 238000003786 synthesis reaction Methods 0.000 description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 239000011575 calcium Substances 0.000 description 9
- 238000005336 cracking Methods 0.000 description 9
- 229910000000 metal hydroxide Inorganic materials 0.000 description 9
- 150000004692 metal hydroxides Chemical class 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- 238000001354 calcination Methods 0.000 description 8
- 150000001768 cations Chemical class 0.000 description 8
- 150000002739 metals Chemical class 0.000 description 8
- 239000008188 pellet Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 7
- 239000000347 magnesium hydroxide Substances 0.000 description 7
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 7
- 229960000816 magnesium hydroxide Drugs 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 238000002411 thermogravimetry Methods 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 6
- 229910052791 calcium Inorganic materials 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000004902 Softening Agent Substances 0.000 description 5
- 239000012467 final product Substances 0.000 description 5
- 238000005342 ion exchange Methods 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 4
- 239000002734 clay mineral Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000005349 anion exchange Methods 0.000 description 3
- 239000000378 calcium silicate Substances 0.000 description 3
- 229910052918 calcium silicate Inorganic materials 0.000 description 3
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000014509 gene expression Effects 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 3
- 229960000869 magnesium oxide Drugs 0.000 description 3
- 239000000391 magnesium silicate Substances 0.000 description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 description 3
- 235000019792 magnesium silicate Nutrition 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- 238000007669 thermal treatment Methods 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229910020489 SiO3 Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000011149 active material Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- PPQREHKVAOVYBT-UHFFFAOYSA-H dialuminum;tricarbonate Chemical compound [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 description 2
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000008570 general process Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 2
- 235000011285 magnesium acetate Nutrition 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 230000035800 maturation Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 239000011049 pearl Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- OZXIZRZFGJZWBF-UHFFFAOYSA-N 1,3,5-trimethyl-2-(2,4,6-trimethylphenoxy)benzene Chemical compound CC1=CC(C)=CC(C)=C1OC1=C(C)C=C(C)C=C1C OZXIZRZFGJZWBF-UHFFFAOYSA-N 0.000 description 1
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 1
- RRKXGHIWLJDUIU-UHFFFAOYSA-N 5-bromo-8-chloroisoquinoline Chemical compound C1=NC=C2C(Cl)=CC=C(Br)C2=C1 RRKXGHIWLJDUIU-UHFFFAOYSA-N 0.000 description 1
- 229910000505 Al2TiO5 Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- HDYRYUINDGQKMC-UHFFFAOYSA-M acetyloxyaluminum;dihydrate Chemical compound O.O.CC(=O)O[Al] HDYRYUINDGQKMC-UHFFFAOYSA-M 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000005882 aldol condensation reaction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- MJWPFSQVORELDX-UHFFFAOYSA-K aluminium formate Chemical compound [Al+3].[O-]C=O.[O-]C=O.[O-]C=O MJWPFSQVORELDX-UHFFFAOYSA-K 0.000 description 1
- 229940009827 aluminum acetate Drugs 0.000 description 1
- 229940118662 aluminum carbonate Drugs 0.000 description 1
- GSWGDDYIUCWADU-UHFFFAOYSA-N aluminum magnesium oxygen(2-) Chemical compound [O--].[Mg++].[Al+3] GSWGDDYIUCWADU-UHFFFAOYSA-N 0.000 description 1
- RJZNFXWQRHAVBP-UHFFFAOYSA-I aluminum;magnesium;pentahydroxide Chemical class [OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Al+3] RJZNFXWQRHAVBP-UHFFFAOYSA-I 0.000 description 1
- SMYKVLBUSSNXMV-UHFFFAOYSA-K aluminum;trihydroxide;hydrate Chemical class O.[OH-].[OH-].[OH-].[Al+3] SMYKVLBUSSNXMV-UHFFFAOYSA-K 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 229940069428 antacid Drugs 0.000 description 1
- 239000003159 antacid agent Substances 0.000 description 1
- 229940077744 antacid containing magnesium compound Drugs 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000027455 binding Effects 0.000 description 1
- 239000005385 borate glass Substances 0.000 description 1
- 229910052599 brucite Inorganic materials 0.000 description 1
- 235000001465 calcium Nutrition 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000002447 crystallographic data Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005906 dihydroxylation reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 235000021158 dinner Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- UYXQSEVJEOMGFV-UHFFFAOYSA-N ethaneperoxoic acid;magnesium Chemical compound [Mg].CC(=O)OO UYXQSEVJEOMGFV-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- GMDNUWQNDQDBNQ-UHFFFAOYSA-L magnesium;diformate Chemical compound [Mg+2].[O-]C=O.[O-]C=O GMDNUWQNDQDBNQ-UHFFFAOYSA-L 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000010198 maturation time Effects 0.000 description 1
- SHOJXDKTYKFBRD-UHFFFAOYSA-N mesityl oxide Natural products CC(C)=CC(C)=O SHOJXDKTYKFBRD-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/16—Clays or other mineral silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/007—Mixed salts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/14—Methods for preparing oxides or hydroxides in general
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/78—Compounds containing aluminium, with or without oxygen or hydrogen, and containing two or more other elements
- C01F7/784—Layered double hydroxide, e.g. comprising nitrate, sulfate or carbonate ions as intercalating anions
- C01F7/785—Hydrotalcite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/20—Two-dimensional structures
- C01P2002/22—Two-dimensional structures layered hydroxide-type, e.g. of the hydrotalcite-type
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/30—Three-dimensional structures
- C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/10—Solid density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/21—Attrition-index or crushing strength of granulates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Geology (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Catalysts (AREA)
- Glass Compositions (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Saccharide Compounds (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/955,017 US6028023A (en) | 1997-10-20 | 1997-10-20 | Process for making, and use of, anionic clay materials |
| PCT/US1998/019081 WO1999020389A1 (en) | 1997-10-20 | 1998-09-15 | Process for making and use of anionic clay materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RO121323B1 true RO121323B1 (ro) | 2007-03-30 |
Family
ID=25496264
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ROA200000426A RO121323B1 (ro) | 1997-10-20 | 1998-09-15 | Procedeu de obţinere a unui compus argilos anionic |
Country Status (13)
| Country | Link |
|---|---|
| US (5) | US6028023A (enExample) |
| EP (1) | EP1027151B1 (enExample) |
| JP (1) | JP2001520162A (enExample) |
| KR (2) | KR100691048B1 (enExample) |
| AT (1) | ATE394165T1 (enExample) |
| AU (1) | AU760089B2 (enExample) |
| CA (1) | CA2308748C (enExample) |
| DE (1) | DE69839451D1 (enExample) |
| HU (1) | HUP0004045A3 (enExample) |
| ID (1) | ID24937A (enExample) |
| PL (1) | PL197739B1 (enExample) |
| RO (1) | RO121323B1 (enExample) |
| WO (1) | WO1999020389A1 (enExample) |
Families Citing this family (80)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9720061D0 (en) | 1997-09-19 | 1997-11-19 | Crosfield Joseph & Sons | Metal compounds as phosphate binders |
| US6028023A (en) * | 1997-10-20 | 2000-02-22 | Bulldog Technologies U.S.A., Inc. | Process for making, and use of, anionic clay materials |
| US6333290B1 (en) * | 1998-02-11 | 2001-12-25 | Akzo Nobel Nv | Process for producing anionic clays using magnesium acetate |
| US6440887B1 (en) * | 1998-02-11 | 2002-08-27 | Akzo Nobel Nv | Continuous process for producing anionic clay |
| US6376405B1 (en) * | 1998-02-11 | 2002-04-23 | Akzo Nobel N.V. | Process for producing anionic clay using two types of alumina compounds |
| US6541409B1 (en) * | 1999-01-29 | 2003-04-01 | Akzo Nobel N.V. | Process for producing anionic clay using non-peptized boemite and compositions produced therefrom |
| ATE381520T1 (de) * | 1999-08-11 | 2008-01-15 | Akzo Nobel Nv | Abriebfeste formkörper, die anionische, kristalline tonerden enthalten |
| US6716785B2 (en) * | 1999-08-11 | 2004-04-06 | Akzo Nobel Nv | Composite and process for the in-situ preparation of a composite comprising a cationic clay and binder/matrix material |
| DE10028432A1 (de) * | 2000-06-13 | 2001-12-20 | Basell Polyolefine Gmbh | Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation |
| US6662951B1 (en) * | 2000-09-27 | 2003-12-16 | Basic Resources, Inc. | Process for extracting and purifying naturally occurring zeolite |
| CN1491186A (zh) * | 2001-02-09 | 2004-04-21 | ŵ�����˹ɷ�����˾ | 制备含有阴离子粘土和勃姆石的组合物的方法 |
| CN1491188A (zh) * | 2001-02-09 | 2004-04-21 | ŵ�����˹ɷ�����˾ | 掺杂的阴离子粘土 |
| DK1358128T3 (da) * | 2001-02-09 | 2005-11-28 | Akzo Nobel Nv | Fremgangsmåde til fremstilling af anionisk ler |
| ES2186547B1 (es) * | 2001-06-15 | 2004-08-01 | Universidad Politecnica De Valencia | Un catalizador bimetalico para el tratamiento de aguas que contienen nitratos. |
| GB2385341B (en) * | 2002-02-15 | 2005-12-21 | Target Well Control Ltd | Casing reaming assembly |
| ATE370917T1 (de) | 2002-06-25 | 2007-09-15 | Albemarle Netherlands Bv | Verwendung von kationischen schichtmaterialien, zusammensetzungen dieser materialien und die herstellung von kationischen schichtmaterialien |
| KR100972705B1 (ko) * | 2002-06-28 | 2010-07-28 | 알베마를 네덜란드 비.브이. | 가솔린 및 디젤 중의 황 함량을 감소시키기 위한 ｆｃｃ촉매 |
| EP1539641A4 (en) * | 2002-08-13 | 2009-12-23 | Intercat Inc | FLUE GAS TREATMENTS TO REDUCE NOX AND CO EMISSIONS |
| DE10237518A1 (de) * | 2002-08-16 | 2004-02-26 | Süd-Chemie AG | Verwendung von Schichtdoppelhydroxiden zur An- bzw. Abreicherung von Biomolekülen aus flüssigen oder fluiden Medien |
| WO2005003034A1 (es) * | 2003-07-07 | 2005-01-13 | Instituto Mexicano Del Petróleo | Obtención de óxidos multimetálicos derivados de compuestos del tipo hidrotalcita. |
| US20050100494A1 (en) | 2003-11-06 | 2005-05-12 | George Yaluris | Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking |
| EP1702027A4 (en) * | 2003-12-05 | 2011-01-12 | Intercat Inc | REDUCTION OF SULFUR INTO PETROL USING HYDROTALCITE-ARTICLE COMPOUNDS |
| US7431825B2 (en) * | 2003-12-05 | 2008-10-07 | Intercat, Inc. | Gasoline sulfur reduction using hydrotalcite like compounds |
| MXPA06006133A (es) * | 2003-12-05 | 2007-01-26 | Intercat Inc | Materiales absorbentes de oxido de metales mixtos. |
| FR2864062B1 (fr) * | 2003-12-22 | 2006-01-27 | Rhodia Chimie Sa | Hydrotalcite intercalee silice et utilisation comme charge dans des compositions de polymeres |
| US20050232839A1 (en) | 2004-04-15 | 2005-10-20 | George Yaluris | Compositions and processes for reducing NOx emissions during fluid catalytic cracking |
| US7304011B2 (en) | 2004-04-15 | 2007-12-04 | W.R. Grace & Co. -Conn. | Compositions and processes for reducing NOx emissions during fluid catalytic cracking |
| JP4843603B2 (ja) * | 2004-04-26 | 2011-12-21 | アルベマーレ ネザーランズ ビー．ブイ． | 添加物含有アニオン性粘土の調製方法 |
| CN1956781A (zh) * | 2004-04-26 | 2007-05-02 | 阿尔伯麦尔荷兰有限公司 | 含金属组合物的制备方法 |
| JP2007534594A (ja) * | 2004-04-26 | 2007-11-29 | アルベマーレ ネザーランズ ビー．ブイ． | 添加物含有アニオン性粘土の調製方法 |
| TWI342335B (en) * | 2004-06-02 | 2011-05-21 | Intercat Inc | Mixed metal oxide additives |
| US20060060504A1 (en) * | 2004-09-08 | 2006-03-23 | Vierheilig Albert A | Additives for metal contaminant removal |
| WO2006095001A1 (en) * | 2005-03-09 | 2006-09-14 | Albemarle Netherlands Bv | Fluid catalytic cracking additive |
| BRPI0607578A2 (pt) * | 2005-03-24 | 2009-09-15 | Grace W R & Co | método para o controle de emissões de nox nas fccu |
| CA2606249C (en) | 2005-04-27 | 2013-07-23 | W.R. Grace & Co.-Conn. | Compositions and processes for reducing nox emissions during fluid catalytic cracking |
| CA2610181A1 (en) * | 2005-06-06 | 2006-12-14 | Albemarle Netherlands Bv | Oxidic metal composition, its preparation and use as catalyst composition |
| EP1904607A1 (en) * | 2005-06-06 | 2008-04-02 | Albemarle Netherlands B.V. | Metal-doped mixed metal oxide, its preparation and use as catalyst composition |
| US7449425B2 (en) * | 2005-06-29 | 2008-11-11 | Exxonmobil Chemical Patents Inc. | Production of alcohols from synthesis gas |
| MY157620A (en) | 2006-01-31 | 2016-06-30 | Cytochroma Dev Inc | A granular material of a solid water-soluble mixed metal compound capable of binding phosphate |
| US7993623B2 (en) * | 2007-06-29 | 2011-08-09 | Albemarle Netherlands B.V. | Additives for removal of metals poisonous to catalysts during fluidized catalytic cracking of hydrocarbons |
| AR063736A1 (es) * | 2006-10-31 | 2009-02-18 | Intercat Inc | Aditivos removedores de oxido de azufre y metodos para condiciones de oxidacion parcial |
| US8137646B2 (en) * | 2007-03-27 | 2012-03-20 | The Shepherd Color Company | Non-chromate corrosion inhibitor formulas based on zirconium vanadium oxide compositions |
| GB0714670D0 (en) * | 2007-07-27 | 2007-09-05 | Ineos Healthcare Ltd | Use |
| WO2009039094A2 (en) * | 2007-09-18 | 2009-03-26 | Shepherd Color Company | Non-chromate corrosion inhibitor formulas based on permanganate sodalite compositions |
| AU2008302416B2 (en) * | 2007-09-20 | 2013-06-06 | Shepherd Color Company | Non-chromate corrosion inhibitor formulas based on highly crystalline hydrotalcite analogs |
| GB0720220D0 (en) * | 2007-10-16 | 2007-11-28 | Ineos Healthcare Ltd | Compound |
| EP2321381B1 (en) | 2008-07-17 | 2024-08-28 | Johnson Matthey Process Technologies, Inc. | Method of material delivery to a plurality of FCC units |
| EP2408717A4 (en) | 2009-03-20 | 2016-01-06 | Commw Scient Ind Res Org | PREPARATION OR RENOVATION OF RAW OR WASTE WATER |
| US20100327224A1 (en) * | 2009-06-26 | 2010-12-30 | Manuela Serban | Compounds for Desulfurization of Hot Fuel Gases |
| US20100135884A1 (en) * | 2009-06-26 | 2010-06-03 | Manuela Serban | Process for Desulfurization of Hot Fuel Gases |
| WO2010151461A2 (en) * | 2009-06-26 | 2010-12-29 | Uop Llc | Compounds and process for desulfurization of hot fuel gases |
| GB0913525D0 (en) | 2009-08-03 | 2009-09-16 | Ineos Healthcare Ltd | Method |
| KR101130282B1 (ko) * | 2009-10-26 | 2012-03-26 | 이화여자대학교 산학협력단 | 층상형 금속 이중층 수산화물 변이체 세피오사이트 화합물 및 그의 제조방법 |
| GB201001779D0 (en) | 2010-02-04 | 2010-03-24 | Ineos Healthcare Ltd | Composition |
| US8921628B2 (en) * | 2011-03-10 | 2014-12-30 | Kior, Inc. | Refractory mixed-metal oxides and spinel compositions for thermo-catalytic conversion of biomass |
| SG11201404945XA (en) | 2012-02-23 | 2014-09-26 | Johnson Matthey Process Technologies Inc | Process of removing nox from flue gas |
| JP5875899B2 (ja) * | 2012-03-08 | 2016-03-02 | 日本化学工業株式会社 | 亜硝酸型ハイドロカルマイト組成物の製造方法 |
| US20130287658A1 (en) | 2012-04-26 | 2013-10-31 | Johnson Matthey Public Limited Company | NOx TRAP COMPOSITION |
| CN103523860B (zh) * | 2012-07-04 | 2015-04-01 | 中国科学院过程工程研究所 | 一种采用Friedel盐或Kuzel盐除去水溶液中有害阴离子的方法 |
| US9518229B2 (en) | 2012-07-20 | 2016-12-13 | Inaeris Technologies, Llc | Catalysts for thermo-catalytic conversion of biomass, and methods of making and using |
| BR112015002752A2 (pt) * | 2012-08-08 | 2017-07-04 | Albemarle Europe Sprl | método de desoxigenação catalítica seletiva de biomassa, composição de catalisador para o mesmo, seu método de preparação e método para converter material de biomassa em estado sólido em um ou mais produtos de hidrocarboneto fluidos |
| US20140171693A1 (en) * | 2012-12-19 | 2014-06-19 | Celanese International Corporation | Coated Hydrotalcite Catalysts and Processes for Producing Butanol |
| RU2533720C2 (ru) * | 2013-02-01 | 2014-11-20 | Общество с ограниченной ответственностью научно-производственное предприятие "Металл-Композит" | Композиция из нерастворимого магнийсодержащего соединения и гидроксида алюминия |
| CA2901111C (en) | 2013-02-22 | 2021-05-18 | Johnson Matthey Process Technologies, Inc. | Process of removing hcn from flue gas |
| US9522392B2 (en) | 2013-03-15 | 2016-12-20 | Inaeris Technologies, Llc | Phosphorous promotion of zeolite-containing catalysts |
| JP5703420B2 (ja) | 2013-03-25 | 2015-04-22 | 日本碍子株式会社 | 層状複水酸化物緻密体及びその製造方法 |
| WO2015004663A1 (en) | 2013-07-08 | 2015-01-15 | Phinergy Ltd. | Electrolyte regeneration |
| US20150096922A1 (en) | 2013-10-04 | 2015-04-09 | Johnson Matthey Process Technologies, Inc. | Process for reactivating an iron-contaminated fcc catalyst |
| WO2015159288A1 (en) | 2014-04-13 | 2015-10-22 | Alcoa Inc. | Systems and methods for regeneration of aqueous alkaline solution |
| CN105524670B (zh) * | 2014-10-24 | 2018-07-17 | 中国石油化工股份有限公司 | 硫砷净化剂及其用途 |
| KR20170135959A (ko) * | 2015-04-15 | 2017-12-08 | 커먼웰쓰 사이언티픽 앤드 인더스트리얼 리서치 오가니제이션 | 물의 처리 및/또는 정화를 위한 방법 |
| JP2018517840A (ja) * | 2015-04-15 | 2018-07-05 | コモンウェルス サイエンティフィック アンド インダストリアル リサーチ オーガナイゼーション | 水性流れにおける対象とする元素またはコモディティの選択的分離 |
| EP3723900A1 (en) | 2017-12-11 | 2020-10-21 | BASF Corporation | Reactive silica-alumina matrix component compositions for bottoms cracking catalysts |
| WO2019158635A1 (en) | 2018-02-16 | 2019-08-22 | Haldor Topsøe A/S | Copper-containing sox and nox removal additives for use in the fcc process |
| WO2019204259A1 (en) * | 2018-04-16 | 2019-10-24 | Rescurve, Llc | Composition of catalysts for conversion of ethanol to n-butanol and higher alcohols |
| MY205392A (en) * | 2019-04-19 | 2024-10-19 | Kurita Water Ind Ltd | Acidic exhaust gas treatment agent, acidic exhaust gas treatment method, and acidic exhaust gas treatment equipment |
| JP6898625B2 (ja) * | 2019-04-19 | 2021-07-07 | 栗田工業株式会社 | 酸性排ガス処理剤、酸性排ガス処理方法、及び酸性排ガス処理設備 |
| WO2022051283A1 (en) | 2020-09-02 | 2022-03-10 | Johnson Matthey Process Technologies, Inc | Metal trapping additive |
| KR20240025011A (ko) | 2021-07-28 | 2024-02-26 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 촉매 조성물 및 이의 제조 및 사용 방법 |
| EP4444468A1 (en) | 2021-12-06 | 2024-10-16 | ExxonMobil Chemical Patents Inc. | Catalyst compositions and processes for making and using same |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4789559A (en) * | 1981-02-12 | 1988-12-06 | Kabushiki Kaisha Hayashibara Seibutsu Kagaku Kenkyujo | Anhydrous crystals of maltitol and the whole crystalline hydrogenated starch hydrolysate mixture solid containing the crystals, and process for the production and uses thereof |
| US4465779A (en) * | 1982-05-06 | 1984-08-14 | Gulf Research & Development Company | Modified cracking catalyst composition |
| US4458026A (en) * | 1982-06-02 | 1984-07-03 | Union Carbide Corporation | Catalysts for aldol condensations |
| CA1275532C (en) | 1985-11-26 | 1990-10-23 | Johannes A. M. Van Broekhoven | Removal of catalyst remnants from ethene/co copolymers |
| DE3601378A1 (de) * | 1986-01-18 | 1987-07-23 | Degussa | Verfahren zur reinigung von oxide des stickstoffs und schwefels enthaltenden abgasen aus verbrennungsanlagen |
| US4866019A (en) * | 1987-01-13 | 1989-09-12 | Akzo N.V. | Catalyst composition and absorbent which contain an anionic clay |
| DE3731919A1 (de) | 1987-09-23 | 1989-04-06 | Giulini Chemie | Neue aluminium-magnesium-hydroxi-verbindungen |
| US5536526A (en) * | 1988-01-11 | 1996-07-16 | Cultor Ltd. | Xylitol-based binding and diluting agent and a process for the production thereof |
| US5112691A (en) * | 1988-08-29 | 1992-05-12 | Illinois Tool Works, Inc. | Adhesive for low temperature applications |
| US4886019A (en) * | 1988-11-14 | 1989-12-12 | Arrow Specialty Company | Engine breather assembly with oil drain back |
| US4889615A (en) * | 1988-12-06 | 1989-12-26 | Mobil Oil Corporation | Additive for vanadium capture in catalytic cracking |
| US5202496A (en) | 1989-04-18 | 1993-04-13 | Aristech Chemical Corporation | Method of making isophorne |
| US4970191A (en) * | 1989-04-18 | 1990-11-13 | Aristech Chemical Corporation | Basic mixed oxide |
| US5055620A (en) * | 1989-04-18 | 1991-10-08 | Aristech Chemical Corporation | Process for aldol condensation |
| US5153156A (en) * | 1989-04-18 | 1992-10-06 | Aristech Chemical Corporation | Process for making efficient anionic clay catalyst, catalysts made thereby, and method of making isophorone |
| GB8922359D0 (en) * | 1989-10-04 | 1989-11-22 | British Petroleum Co Plc | Process for the preparation of catalysts |
| GB8927130D0 (en) * | 1989-11-30 | 1990-01-31 | Cerestar Holding Bv | Chewing gum composition |
| US5114898A (en) * | 1990-01-18 | 1992-05-19 | Board Of Trustees Operating Michigan State University | Layered double hydroxide sorbents for the removal of SOx from flue gas and other gas streams |
| US5114691A (en) * | 1990-01-18 | 1992-05-19 | Board Of Trustees Operating Michigan State University | Process using sorbents for the removal of SOx from flue gas |
| US5334564A (en) * | 1990-07-16 | 1994-08-02 | Board Of Trustees Operating Michigan State University | Method for the preparation of highly reactive clay composites for the removal of SOx from flue gas streams |
| US5108979A (en) | 1991-02-25 | 1992-04-28 | Intercat, Inc. | Synthetic spinels and processes for making them |
| EP0561585B1 (en) * | 1992-03-17 | 1997-05-28 | Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo | Method for manufacturing powdery crystalline maltitol |
| US5358701A (en) * | 1992-11-16 | 1994-10-25 | Board Of Trustees Operating Michigan State University | Process of using layered double hydroxides as low temperature recyclable sorbents for the removal of SOx from flue gas and other gas streams |
| US5340466A (en) * | 1993-04-19 | 1994-08-23 | Texaco Inc. | Hydrodesulfurization of cracked naphtha with hydrotalcite-containing catalyst |
| US5399329A (en) * | 1993-07-06 | 1995-03-21 | Aristech Chemical Corporation | Hydrotalcite-like materials having a sheet-like morphology and process for production thereof |
| US5518704A (en) | 1993-07-06 | 1996-05-21 | Aristech Chemical Corporation | Nickel and cobalt containing hydrotalcite-like materials having a sheet-like morphology and process for production thereof |
| US5507980A (en) | 1993-07-06 | 1996-04-16 | Aristech Chemical Corporation | Basic inorganic binders |
| US5426083A (en) * | 1994-06-01 | 1995-06-20 | Amoco Corporation | Absorbent and process for removing sulfur oxides from a gaseous mixture |
| US5645810A (en) * | 1995-06-07 | 1997-07-08 | Aluminum Company Of America | High surface area meixnerite from hydrotalcites |
| US6028023A (en) * | 1997-10-20 | 2000-02-22 | Bulldog Technologies U.S.A., Inc. | Process for making, and use of, anionic clay materials |
| US6333290B1 (en) | 1998-02-11 | 2001-12-25 | Akzo Nobel Nv | Process for producing anionic clays using magnesium acetate |
| US6171991B1 (en) | 1998-02-11 | 2001-01-09 | Akzo Nobel Nv | Process for producing an anionic clay-containing composition |
| CN100377994C (zh) | 1999-08-11 | 2008-04-02 | 阿克佐诺贝尔公司 | 制备含镁的非铝阴离子型粘土的方法 |
| BR0013124A (pt) | 1999-08-11 | 2002-04-23 | Akzo Nobel Nv | Argila aniÈnica, processo para a preparação da mesma, corpos moldados, composição de catalisador, composição aditiva de catalisador, suporte de catalisador, e, composição absorvente |
| ATE381520T1 (de) | 1999-08-11 | 2008-01-15 | Akzo Nobel Nv | Abriebfeste formkörper, die anionische, kristalline tonerden enthalten |
| EP1358148A1 (en) | 2001-02-09 | 2003-11-05 | Akzo Nobel N.V. | Quasi-crystalline hydrated magnesium-aluminium hydroxy carboxylates, their preparation and their use |
-
1997
- 1997-10-20 US US08/955,017 patent/US6028023A/en not_active Expired - Lifetime
-
1998
- 1998-09-15 CA CA002308748A patent/CA2308748C/en not_active Expired - Lifetime
- 1998-09-15 PL PL340073A patent/PL197739B1/pl not_active IP Right Cessation
- 1998-09-15 DE DE69839451T patent/DE69839451D1/de not_active Revoked
- 1998-09-15 KR KR1020057019576A patent/KR100691048B1/ko not_active Expired - Fee Related
- 1998-09-15 ID IDW20000727A patent/ID24937A/id unknown
- 1998-09-15 JP JP2000516772A patent/JP2001520162A/ja active Pending
- 1998-09-15 AU AU94813/98A patent/AU760089B2/en not_active Expired
- 1998-09-15 AT AT98948188T patent/ATE394165T1/de not_active IP Right Cessation
- 1998-09-15 RO ROA200000426A patent/RO121323B1/ro unknown
- 1998-09-15 EP EP98948188A patent/EP1027151B1/en not_active Revoked
- 1998-09-15 WO PCT/US1998/019081 patent/WO1999020389A1/en not_active Ceased
- 1998-09-15 HU HU0004045A patent/HUP0004045A3/hu unknown
- 1998-09-15 KR KR1020007004268A patent/KR100562781B1/ko not_active Expired - Fee Related
-
1999
- 1999-12-09 US US09/457,802 patent/US6479421B1/en not_active Expired - Lifetime
-
2002
- 2002-11-07 US US10/290,012 patent/US7112313B2/en not_active Expired - Fee Related
-
2003
- 2003-05-23 US US10/444,629 patent/US6929736B2/en not_active Expired - Lifetime
-
2006
- 2006-08-10 US US11/501,990 patent/US7417005B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2308748A1 (en) | 1999-04-29 |
| HUP0004045A2 (en) | 2001-03-28 |
| WO1999020389A1 (en) | 1999-04-29 |
| EP1027151A4 (en) | 2002-07-03 |
| US20030203806A1 (en) | 2003-10-30 |
| KR100562781B1 (ko) | 2006-03-21 |
| US6028023A (en) | 2000-02-22 |
| KR20050103983A (ko) | 2005-11-01 |
| ID24937A (id) | 2000-08-31 |
| US6479421B1 (en) | 2002-11-12 |
| AU760089B2 (en) | 2003-05-08 |
| JP2001520162A (ja) | 2001-10-30 |
| US20030096697A1 (en) | 2003-05-22 |
| ATE394165T1 (de) | 2008-05-15 |
| PL340073A1 (en) | 2001-01-15 |
| US7112313B2 (en) | 2006-09-26 |
| US7417005B2 (en) | 2008-08-26 |
| HUP0004045A3 (en) | 2001-06-28 |
| KR20010031281A (ko) | 2001-04-16 |
| KR100691048B1 (ko) | 2007-03-12 |
| CA2308748C (en) | 2008-09-09 |
| AU9481398A (en) | 1999-05-10 |
| PL197739B1 (pl) | 2008-04-30 |
| US6929736B2 (en) | 2005-08-16 |
| US20060276328A1 (en) | 2006-12-07 |
| EP1027151B1 (en) | 2008-05-07 |
| EP1027151A1 (en) | 2000-08-16 |
| DE69839451D1 (de) | 2008-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| RO121323B1 (ro) | Procedeu de obţinere a unui compus argilos anionic | |
| EP1204595B1 (en) | Polytype mg-ai hydrotalcite | |
| AU2010202087A1 (en) | Gasoline sulfur reduction using hydrotalcite like compounds | |
| WO2008129034A1 (en) | Hydrotalcite-like layered double hydroxide (ldh) composition and process of making same | |
| US7964175B2 (en) | Obtaining multimetallic oxides derived from hydrotalcite type compounds | |
| JP2000512895A (ja) | ハイドロタルサイト硫黄酸化物の収着 | |
| Malherbe et al. | Use of organic media to modify the surface and porosity properties of hydrotalcite-like compounds | |
| Rossi et al. | An evaluation of calcined hydrocalumite as carbon dioxide adsorbent using thermogravimetric analysis | |
| CA2596421C (en) | Process for making and use of anionic clay materials | |
| US5750453A (en) | High surface area meixnerite from hydrotalcites infiltrated with metal salts | |
| JP6010083B2 (ja) | ＦＣＣ再生器からのＳＯｘ排出を低減するための添加剤を含む陰イオン性粘土およびそれらの製造プロセス | |
| EP0710624A1 (en) | Sol-gel synthesis of manganese oxide material possessing octahedral structure | |
| MXPA00003903A (en) | Process for making and use of anionic clay materials | |
| Valente | III III 0 II0 II0 III 101 100 III DID III IDI II DI II | |
| MXPA99006321A (en) | Process for the production of hydrotalcites mg-ai type, as precursors of reducing oxides of sox emissions and resulting product |