PT91363B - Processo para a preparacao de uma emulsao transparente insecticida - Google Patents
Processo para a preparacao de uma emulsao transparente insecticida Download PDFInfo
- Publication number
- PT91363B PT91363B PT91363A PT9136389A PT91363B PT 91363 B PT91363 B PT 91363B PT 91363 A PT91363 A PT 91363A PT 9136389 A PT9136389 A PT 9136389A PT 91363 B PT91363 B PT 91363B
- Authority
- PT
- Portugal
- Prior art keywords
- methyl
- enyl
- chrysanthemate
- polar solvent
- allyl
- Prior art date
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 45
- 239000002917 insecticide Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims description 16
- 238000002360 preparation method Methods 0.000 title claims description 5
- 239000004480 active ingredient Substances 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 28
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 239000002798 polar solvent Substances 0.000 claims abstract description 24
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 12
- -1 2-methyl-4-oxo-3- (2-propynyl) cyclopent-2-enyl Chemical group 0.000 claims description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 21
- 239000012141 concentrate Substances 0.000 claims description 20
- 239000002728 pyrethroid Substances 0.000 claims description 13
- 239000002736 nonionic surfactant Substances 0.000 claims description 10
- SFHVXKNMCGSLAR-UHFFFAOYSA-N 2,2,3,3-tetramethylcyclopropanecarboxylic acid Chemical compound CC1(C)C(C(O)=O)C1(C)C SFHVXKNMCGSLAR-UHFFFAOYSA-N 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- LLMLSUSAKZVFOA-UHFFFAOYSA-M 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)Cl)C1C([O-])=O LLMLSUSAKZVFOA-UHFFFAOYSA-M 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 150000005215 alkyl ethers Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- SBNFWQZLDJGRLK-UHFFFAOYSA-N phenothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-UHFFFAOYSA-N 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- VEQMUQZKBLIXLT-UHFFFAOYSA-N 2,3-dimethylcyclopropane-1-carboxylic acid Chemical compound CC1C(C)C1C(O)=O VEQMUQZKBLIXLT-UHFFFAOYSA-N 0.000 claims 1
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 claims 1
- 208000000474 Poliomyelitis Diseases 0.000 claims 1
- 229940092714 benzenesulfonic acid Drugs 0.000 claims 1
- YMGUBTXCNDTFJI-UHFFFAOYSA-M cyclopropanecarboxylate Chemical compound [O-]C(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-M 0.000 claims 1
- 159000000000 sodium salts Chemical class 0.000 claims 1
- 210000002268 wool Anatomy 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 17
- 238000009472 formulation Methods 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 9
- 241000238631 Hexapoda Species 0.000 description 8
- 238000003756 stirring Methods 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 238000013019 agitation Methods 0.000 description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 3
- 229960000490 permethrin Drugs 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 2
- KWIPUXXIFQQMKN-UHFFFAOYSA-N 2-azaniumyl-3-(4-cyanophenyl)propanoate Chemical compound OC(=O)C(N)CC1=CC=C(C#N)C=C1 KWIPUXXIFQQMKN-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000255925 Diptera Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 2
- 229940090948 ammonium benzoate Drugs 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 2
- 235000010290 biphenyl Nutrition 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 230000009193 crawling Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000003898 horticulture Methods 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 2
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- JSGVZVOGOQILFM-UHFFFAOYSA-N 3-methoxy-1-butanol Chemical compound COC(C)CCO JSGVZVOGOQILFM-UHFFFAOYSA-N 0.000 description 1
- 206010004194 Bed bug infestation Diseases 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 241001408630 Chloroclystis Species 0.000 description 1
- 241001414835 Cimicidae Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000124008 Mammalia Species 0.000 description 1
- 241000257229 Musca <genus> Species 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19662288 | 1988-08-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PT91363A PT91363A (pt) | 1990-03-08 |
| PT91363B true PT91363B (pt) | 1996-06-28 |
Family
ID=16360819
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PT91363A PT91363B (pt) | 1988-08-05 | 1989-08-03 | Processo para a preparacao de uma emulsao transparente insecticida |
Country Status (27)
| Country | Link |
|---|---|
| US (1) | US5028623A (enExample) |
| JP (1) | JP2861076B2 (enExample) |
| KR (1) | KR0129761B1 (enExample) |
| CN (1) | CN1027028C (enExample) |
| AT (1) | AT399082B (enExample) |
| AU (1) | AU610009B2 (enExample) |
| BR (1) | BR8903911A (enExample) |
| CA (1) | CA1308348C (enExample) |
| CH (1) | CH678588A5 (enExample) |
| DE (1) | DE3925765A1 (enExample) |
| EG (1) | EG19230A (enExample) |
| ES (1) | ES2014848A6 (enExample) |
| FR (1) | FR2634974B1 (enExample) |
| GB (2) | GB8916120D0 (enExample) |
| GR (1) | GR1000372B (enExample) |
| HU (1) | HU204390B (enExample) |
| IT (1) | IT1232164B (enExample) |
| LT (1) | LT3660B (enExample) |
| LV (1) | LV10159B (enExample) |
| MX (1) | MX17080A (enExample) |
| MY (1) | MY105014A (enExample) |
| NL (1) | NL8901862A (enExample) |
| PL (1) | PL159501B1 (enExample) |
| PT (1) | PT91363B (enExample) |
| RU (1) | RU2035862C1 (enExample) |
| TR (1) | TR25773A (enExample) |
| YU (1) | YU47001B (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4009142A1 (de) * | 1989-03-22 | 1990-09-27 | Sumitomo Chemical Co | Insektizidzusammensetzungen |
| JP3052142B2 (ja) * | 1989-09-14 | 2000-06-12 | 住友化学工業株式会社 | 殺虫、殺ダニ組成物 |
| FR2673075B1 (fr) * | 1991-02-22 | 1998-12-31 | Rhone Poulenc Chimie | Microemulsions de pyrethrouides et leur utilisation. |
| DE4108090C2 (de) * | 1991-03-13 | 1996-11-28 | Ruetgers Ag | Imprägniermittel für Holz |
| US6527716B1 (en) | 1997-12-30 | 2003-03-04 | Altea Technologies, Inc. | Microporation of tissue for delivery of bioactive agents |
| US20030078499A1 (en) | 1999-08-12 | 2003-04-24 | Eppstein Jonathan A. | Microporation of tissue for delivery of bioactive agents |
| US7141034B2 (en) | 2000-06-08 | 2006-11-28 | Altea Therapeutics Corporation | Transdermal drug delivery device, method of making same and method of using same |
| US8116860B2 (en) | 2002-03-11 | 2012-02-14 | Altea Therapeutics Corporation | Transdermal porator and patch system and method for using same |
| US9918665B2 (en) | 2002-03-11 | 2018-03-20 | Nitto Denko Corporation | Transdermal porator and patch system and method for using same |
| US20040191290A1 (en) * | 2003-03-28 | 2004-09-30 | Redline, Inc. | Solid pest control system |
| US8016811B2 (en) | 2003-10-24 | 2011-09-13 | Altea Therapeutics Corporation | Method for transdermal delivery of permeant substances |
| BRPI0708928B1 (pt) * | 2006-03-29 | 2018-02-06 | Agro-Kanesho Co., Ltd. | Formulação de microemulsão aquosa pesticida, uso da formulação, e, métodos para combater pragas nocivas, e para proteger colheitas e sementes do ataque de ou da infestação por pragas nocivas |
| CN101455194A (zh) * | 2007-12-10 | 2009-06-17 | S.C.约翰逊父子公司 | 透明水性杀虫剂组合物 |
| JP5262352B2 (ja) * | 2008-06-30 | 2013-08-14 | 住友化学株式会社 | ピレスロイド化合物含有の水性製剤 |
| JP2011144141A (ja) * | 2010-01-15 | 2011-07-28 | Fumakilla Ltd | 殺虫剤及び噴霧殺虫器 |
| JP5641868B2 (ja) * | 2010-10-19 | 2014-12-17 | 大日本除蟲菊株式会社 | 水性殺虫液剤 |
| JP6777981B2 (ja) * | 2015-10-13 | 2020-10-28 | フマキラー株式会社 | セアカゴケグモ用駆除スプレー剤 |
| US20220386616A1 (en) * | 2019-11-13 | 2022-12-08 | Jesmond Holding Ag | Combination of Encapsulated Phenothrin and Emulsified Prallethrin |
| WO2024225003A1 (ja) * | 2023-04-26 | 2024-10-31 | 大日本除蟲菊株式会社 | 害虫防除用組成物及び害虫防除成分の光安定化方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT186289B (de) * | 1954-09-28 | 1956-07-25 | Friedmann Kg Alex | Kugelschieber für Dampfheizungsanlagen, insbesondere für Eisenbahnfahrzeuge |
| US3492402A (en) * | 1967-02-01 | 1970-01-27 | Mclaughlin Gormley King Co | Pyrethroid insecticidal compositions containing an emulsifier and a bacterio-fungistat |
| US3683078A (en) * | 1969-10-13 | 1972-08-08 | Cpc International Inc | Transparent toxicant compositions |
| DE2328374A1 (de) * | 1972-06-06 | 1973-12-20 | Procter & Gamble | Insektizide mittel |
| GB1355750A (en) * | 1972-07-17 | 1974-06-05 | Cpc International Inc | Transparent toxicant compositions |
| US4299839A (en) * | 1978-07-11 | 1981-11-10 | Kuraray Co., Ltd. | Novel pesticides and pesticidal compositions cyclopropanecarboxylates and pesticidal method |
| JPS59110604A (ja) * | 1981-01-26 | 1984-06-26 | ザンドツ・アクチェンゲゼルシャフト | 新規な農薬組成物 |
| DE3111934A1 (de) * | 1981-03-26 | 1982-10-07 | Bayer Ag, 5090 Leverkusen | Oel-in-wasser-emulsionen, verfahren zu deren herstellung und deren verwendung |
| JPS57197203A (en) * | 1981-05-27 | 1982-12-03 | Nippon Kayaku Co Ltd | Insecticidal composition |
| AU8627182A (en) * | 1981-07-22 | 1983-01-27 | Syntex (U.S.A.) Inc. | Substituted pyrrolidines |
| JPS6054928A (ja) * | 1983-09-01 | 1985-03-29 | Seiko Epson Corp | 石英ガラスの製造方法 |
| DE3343092A1 (de) * | 1983-11-29 | 1985-06-05 | Bayer Ag, 5090 Leverkusen | Wasserloesliche pestizide formulierung |
| ATE86067T1 (de) * | 1984-04-09 | 1993-03-15 | American Cyanamid Co | Insektizide waessrige mikroemulsionen. |
| GB8515459D0 (en) * | 1985-06-19 | 1985-07-24 | Young Robert Co Ltd | Parasitical compositions |
| PH22025A (en) * | 1985-08-19 | 1988-05-13 | Johnson & Son Inc S C | Aqueous pyrethroid insecticidal formulations and method of increasing the stability thereof |
| DE3624910A1 (de) * | 1986-07-23 | 1988-01-28 | Hoechst Ag | Konzentrierte waessrige mikroemulsionen |
-
1989
- 1989-07-06 JP JP1176585A patent/JP2861076B2/ja not_active Expired - Lifetime
- 1989-07-17 MY MYPI89000966A patent/MY105014A/en unknown
- 1989-07-19 NL NL8901862A patent/NL8901862A/nl active Search and Examination
- 1989-07-19 GB GB898916120A patent/GB8916120D0/en active Pending
- 1989-07-24 US US07/384,143 patent/US5028623A/en not_active Expired - Lifetime
- 1989-07-25 FR FR8909981A patent/FR2634974B1/fr not_active Expired - Fee Related
- 1989-07-27 PL PL1989280785A patent/PL159501B1/pl unknown
- 1989-07-28 GB GB8917243A patent/GB2221393B/en not_active Expired - Lifetime
- 1989-07-30 EG EG36189A patent/EG19230A/xx active
- 1989-08-01 AT AT0186289A patent/AT399082B/de not_active IP Right Cessation
- 1989-08-01 KR KR1019890011004A patent/KR0129761B1/ko not_active Expired - Lifetime
- 1989-08-03 IT IT8948275A patent/IT1232164B/it active
- 1989-08-03 CH CH2894/89A patent/CH678588A5/de not_active IP Right Cessation
- 1989-08-03 BR BR898903911A patent/BR8903911A/pt not_active IP Right Cessation
- 1989-08-03 CA CA000607497A patent/CA1308348C/en not_active Expired - Lifetime
- 1989-08-03 AU AU39253/89A patent/AU610009B2/en not_active Expired
- 1989-08-03 PT PT91363A patent/PT91363B/pt not_active IP Right Cessation
- 1989-08-03 DE DE3925765A patent/DE3925765A1/de not_active Ceased
- 1989-08-03 GR GR890100492A patent/GR1000372B/el not_active IP Right Cessation
- 1989-08-03 CN CN89106175A patent/CN1027028C/zh not_active Expired - Fee Related
- 1989-08-04 TR TR89/0577A patent/TR25773A/xx unknown
- 1989-08-04 YU YU154889A patent/YU47001B/sh unknown
- 1989-08-04 RU SU894614774A patent/RU2035862C1/ru active
- 1989-08-04 MX MX1708089A patent/MX17080A/es unknown
- 1989-08-04 ES ES8902782A patent/ES2014848A6/es not_active Expired - Lifetime
- 1989-08-04 HU HU893970A patent/HU204390B/hu not_active IP Right Cessation
-
1992
- 1992-12-22 LV LVP-92-388A patent/LV10159B/lv unknown
-
1993
- 1993-08-27 LT LTIP899A patent/LT3660B/lt not_active IP Right Cessation
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG3A | Patent granted, date of granting |
Effective date: 19960319 |
|
| MM3A | Annulment or lapse |
Free format text: LAPSE DUE TO NON-PAYMENT OF FEES Effective date: 20010930 |