LV10159B - Transparent emulsion with insecticide properties and process for preparation thereof - Google Patents
Transparent emulsion with insecticide properties and process for preparation thereof Download PDFInfo
- Publication number
- LV10159B LV10159B LVP-92-388A LV920388A LV10159B LV 10159 B LV10159 B LV 10159B LV 920388 A LV920388 A LV 920388A LV 10159 B LV10159 B LV 10159B
- Authority
- LV
- Latvia
- Prior art keywords
- methyl
- allyl
- oxocyclopent
- group
- cyano
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
LV 10159
MHCEKTMTOAfl ΠΡ03ΡΑΗΗΑΗ 3MyJILCM M CnOCOB EĒ nOJB^EHMH
OnHcaHHe
HacTOHUļee HSodpeTeHHe othochtch k ηηοθκτμφι,π,ηομ npo3panHott 3MyJIbCHM, ΠρΗΓΟΤΟΒΛβΉΗΟΜ ΠγΤΘΜ COJH06nJIH3aiļHM BOflOHepaCTBOpHMOrO nHpeTpOM,n,aJIbHOrO MHCeKTHIļH^HOrO KOMnOHeHTa B ΒΟ,Π,Θ C nOMOIIļbK) cne-iļHajībHoro CMemaHHoro ποβθρχηοοτηο aKTHBHoro Be^ecTBa, πρκ θτομ yKa3aHHan HHceKTMUM.n.HaH npo3patiHan 9MyjibCHH ηβληθτοη npo3panHOM Η Γ0Μ0Γ6ΗΗ0Μ, TaKHCe KaK Η ΠρβΒΟΟΧΟ,Π,Ηίςβίί B coctohhhh pacTBopa H b οτηοιιιθηηη CTa(5MJibH0CTH aKTHBHoro KOMnOHeHTa b mnpoKOM TeMnepa-TypHOM fluanasoHe. 2 nHpeTpOMflaJIbHbie HHCeKTMDļM,IļbI H3-3a HX ΗΗ3Κ0Η TOKCHīiHOCTH K MJieKOnHTaiOfflļMM niHpOKO HCrT0JIb30BaJIHCb B pacnbīJIHeMHX 0ΗΤΟΒΗΧ HH-ceKTHiļMflax.
Tan Kan nupeTpOīīflajībHbre μηοθκτμιι,κ,ιι,η HepacTBopuMH b βο,π,θ, ohm ο(5ηηηο pacTBOpHKTCH b opraHMnecKOM pacTBOpHTejie, TaKOM Kan KepocMH, mjim b apoMaTMqeeKHX pacTBopMTejrax, BHatiajie, κ (I) no-jiyqeHHb!H pacTBop ηθποορθ,π,οτβθηηο pa36pbf3rMBaeTCH c noMonļbio nyjib-BepH3aTopa, (2) noJiyqeHHbiM pacTBop npeo6pa3yeTCH b a3po30Jib h paenbīJineTCH pa30pH3rwBaioipM ra30M η τ.,π,., hjih (3) nojiyqeHHbiM pacTBop npeo<5pa3yiOT b 3MyjibCHio.. c nOMODļbio 3MyjibraTopa, pa3čaB-•JIHĪOT 30,110¾ M pa36pbI3rHBaiOT. B ηποηοκηχ naTeHTax B-58-2976I η B-60-54928 pacKpHTO ,π,ο-MaraHee πρμμθηθημθ, Kor^a cojiiodHJiH3HpoBaHHbīM Ha οοηοβθ βο,π,η hh-CeKTHEĶHfl pa3dpbI3rHBaeTCH flJIH yHHtiTO®eHHH HaceKOMbIX.
Korfla HHCeKTHDļHflbl pa36pH3rHBaDT BHyTpH ΠΟΜΘίςβΗΜΗ, OflHaKO, HHceKTHiļHflHbie npenapara, κοτορυβ co^epseaT 3HaqHTeJibHoe KOJnraecT-bo opraHMqecKMx pacTBopuTejieM h Mcnojib3yioT Kan b BbnneyKa3aHH0M nyHKTe (I), ΗΘ TOJIbKO ΗΘΠρΗίϊΤΘΗ flJIH ΤΘΧ, KTO paCnblJIHeT, HO TaK-ace h HeneJiaTejibHbi c to^kh 3peHHH 6e3onacHOCTH η γηγηθηη OKpyjKa-ιοω,θΐΐ cpeflH. Asposojin, KOTopbie co^epKaT Bocn.naMeHHiomHMcfl ra3 b flonojiHeHPie κ opraHimecKHM pacTBopHTejiHM η πρημθηηιοτοη Kan b nyHKTe (2) od-na^aiOT HeflocTaTKaMK, Tax Kan ohh BOCiuiaMeHMMbi b ΜΟΜΘΗΤ ΠρΗΜΘΗΘΗΗΗ Η HX TpyflHO pa3pemHTb nOCJIO ΠρΗΜΘΗΘΗΗΗ. ΚρΟΜΘ τογο, οροκ cjiy«(5bi 3MyjibCHH, KaK OHa πρημθηηθτοη no n.(3), nocjie pa36aBJieHHH βο,π,ομ cocTaBJiHST TOJIbKO HecKOJibKO nacoB caMoe 6ojib-mee, b pe3yjibTaTe qero 3MyjibCHH CTpa^aeT ot OTCTaHBaHHH cjioeB M ΟΤ,ΙΙ,ΘΠΘΗΗΗ MaCJlflHHCTOrO CJIOH Η ΗΘ MOJKeT COXpaHHTb reMOreHHOCTb b τθπθηηθ ^JiHTejibHoro nepno^a βρθμθηη. Πο θτοη πρηπηηθ 3MyjibCHH OČbflīHO ΠρΗΜΘΗΗΘΤΟΗ ΗΘΜΘ,Π,ΠΘΗΗΟ ΠΟΟΛΘ pa3(5aBJieHHH ΒΟ,Π,ΟΗ. ΚρΟΜΘ ΤΟ-ΓΟ, MoryT conpoBOJKflaTb HenpHHTHbie 3anaxM HenojiHpHbix pacTBopHTe-jien, TaKHX KaK apoMaTH^ecKue pacTBopHTejiH, KepocnHU η τ.,π;., κο-TOpbie ΠρΗΜΘΗΗΙΟΤΟΗ, ΒρθβΗΗΘ B03fleMCTBHH, KOTOpbīe 3TH paCTBOpHTeJIH OKa3biBaiOT . Ha pacnbuiHeMyio ποβθρχηοοτβ, η ηθμθηθηηη b 6emvi iļBeT noBepxHOCTH pacnbuieHHH H3-3a 3MyjibraTopa.
OtfbPiHO, Η3ΒΘ0ΤΗΗΘ ΗΗ0ΘΚΤΗΙ1Μ,Ι1Η, 0ΤΗ00ΗΪΙ1ΗΘ0Η k THny cojiio6hjih-3HpyeMbix Ha οοηοβθ βο^η, κοτορΗθ Hcnojib30BajiHCb b 6biT03bix ycjio-bhhx h b caflOBOflCTBe flJiH peryjiH'poBaHHH HaceKOMHX-BpeflHTeJieft, LV 10159 3 npHBO^HT K nOTepe CTadHJIbHOCTM paCTBOpa H3-3a Η3ΜΘΗΘΗΗΗ OKpy-TKarouieK TeMnepaTypH bo ΒρβΜΗ xpaHeHMH m C03p,am ocaflOK. TaKHM o<5pa30M, hx KatiecTBa nan HHceKTHiļMflOB HeHafleKHu, Kor,iļa OKpy-maromaa TeMnepaTypa pe3K0 noBBimaeTCH κ naflaeT. Ilo3TOMy ,π^ηηβιθ MHceKTMi^HflBi ΜΜθίοτ npodjieMy ,Β,ΟΛΓΟΒβηΗοοτη npn j^oeTaTO^HOM na-necTBe flJifl mx npaKTnnecKoro Hcnojib30BaHHH, h no3TOMy He Bcer-fla MOJKHO CKasaTb, ηΤΟ OHH yflOBJieTBOpHTeJIbHBl.·
CorJiacHO HacTOHmeMy MsodpeTetMio coa^aHa ηηοθκτμι1Ηιπ,η3.η npo3-panHan 3MyjibCHH, co^ep^amaa (A) no KpanHen Mepe ojpiH nHpeTpoHflajībHBin μηοθκτηινια, BbīdpaHHbin H3 rpynnH, COCTOHmeK H3 3-$eHOKcndeH3Hji-xpH3aHTeMaTa, 3-ajiJiHJi-2-MeTHJi-4-oKCOiJiHKJioneHT-2-eHHJi xpn3aHTeMaTa, 3-ajumji-2-MeTHji-4-OKCOLiHKJioneHT-2-eHHJi 2,2,3,3-TeTpaMemn-iļHKJionponaHKapdoKCHJiaTa, 2- MeTHJi-4-OKco-3-( 2-nponHHaji)iļiiKJīoneHT-2-eHHJi xpH3aHTeMaTa h <X-n;HaHO-3-$eHOKCH(5eH3HJi xpn3aHTeMaTa, hjih ομθοβ no KpaiiHen Mepe οαηογο nHpeTpoHflajībHoro HHceKTHiļHfla, BHdpanHoro H3 rpynrai, COCTOHHļeft H3 3- φβΗθκοκ6θΗ3Η;ι xpn3aHTeMaTa, 3-ajiJiHJi-2-MeTHJi-4-oKcou;KKJioneHT-2~eHHJi xpH3.aHTeMaTa, 3-ajiJīHJi-2-MeTHJi-4-OKCOiņiKJioneHT-2-eHHJi 2,2,3,3-TeTpaMeTMJi-rļMKJionponaHKapdoKCHJiaTa, 2- MeTHJi-4-OKCO-3- (2-nponnHHJi) ι1ηκλοπθητ-2θηηλ xpn3aHTeMaTa h <X-iļHaHO-3-$eHOKcndeK3HJi xpn3aHTeMaTa, h no KpanHefi Mepe oflHH nnpeTponflajībHHM HHceKTHijHfl, BudpaHHBm H3 rpynnbi, cocTOHiiļeft H3 (X-iļHaH0-3-$eH0KCHdeH3HJi 2,2,3,3-TeTpaMeTHJmnKJionponaH-KapdoKcmiaTa, . 3,4,5,6-TeTpartf£po$TajiHMHrn,MeTMJi xpH3aHTeMaTa, 3- $eH0KendeH3HJi-3- (2 ,· 2-,i!,hxjiopbkhhji) -2,2-flMMeTHJin;iiKJionponaH-KapdoKcnjiaTa, h I-3THHHJi-2-MeTHJi-2neHTeHHJi xpn3aHTeMaTa, b KanecTBe aKTHBHoro κομποηθητ3, (B) CMeniaHHoe ποΒβρχΗοοτπο aKTHBHoe Be^ecTBO c noJinpHBM pacT-BopnTeJieM, coflepstamee no Kpaftaeft Mepe ο,π,μη ajiKHJi(5eH3HJi-cyjib$o-HaT MeTanjia, no KpaftHeft Mepe ο,π,ηο HenoHHoe noBepxHOCTHo aKTHB-ηοθ BeiiļeCTBO, HMeioinee rMflpo$HJibHO-JiHno$HJibHHii čajiaHC ot 10 ,π,ο 18, n no KpanHen Mepe ο,π,κη nojiHpHBin pacTBopHTejib, n 4 (C) BO^y, πρπ 3tom coflepJKaHHe (B) b 3MyjibCHH paBHO hjih npeBBimaeT οο,η,θρ-jKaHue (A) h 6 Bec. % hjih ηη?κθ. B HaCTOHUieM Η30<5ρθΤΘΗΗΗ CMemaHHOe ΠΟΒθρΧΗΟΟΤΗΟ aKTHBHOe BemecTBO, co^epscatnee nojiHpHBiH pacTBopHTejib, othocmtch k TaKHM, κοτορΗβ coflepiaT no npanHen Mepe ο,ιι,ηη ajiKHJi6eH3HJtcyjib$OHaT Me-Tajuia, no KpaiiHen Mepe ο,π,ηο ηθηοηηοθ ποβθρχηοοτηο aKTHBHoe Be-iiiecTBO, mem\ee raflpo$HJibHo-Jinno$njibHun dajiaHC (TJIB) ot 10 18, h no KpaftHen Mepe ο,π,ηη nojinpHBiH pacTBopnTejib. Hhcjio aTOMOB yrJiepofla b ajiKHJībHOH rpynne He ηβληθτοη κρΗτκηεοκΗΜ, ho oho npe,n,nonTHTeJibHO ot 8 ,π,ο 13 h čojiee npeAnonTHTejibHO οτ 10 ,π,ο 13. Τηπ MeTajuia Η3 cojih MeTajuia ηθ HBJnreTCH κρητηπηβιμ, η οη bkjiio-yaeT β cedn, HanpnMep, HaTpnn h KajībiļHM.
HenoHHBie ποβθρχηοοτηο βκτηβηβτθ Be^ecTBa, Hcnojib3yeMBie 3^ecb, HBJIHIOTCH TaKHMH, KOTOpbie COflepmaT OT 6 flO 40 M'OJieH 3TH-jieHOKCHfla, Kyn,a θτηλθηκομ,π, flodaBJinioT Tan, ητο6η θτο BenļecTBO MMejio TJIB οτ 10 ,π,ο 18. TJIB πρθ,π,ποητΗΤθΛΒΗο paBeH 12-16. CneiļH- φΗΗΗΒΙΜΗ npHMepaMH ΘΤΟΓΟ ΒΘΙΙ]|ΘΟΤΒΒ HBJIHKJTCH n0JIH0KCH3THJieHCTHp0JI-φθΗΟΙί, npOCTOH nOJIHOKCHOTHJieHaJIKH^eHHJIOBHH θφκρ, npOCTOM nOJIH-OKCH0THJieHaJIKHJIOBBIH θφηρ H T.fl. ΟπθφίφκηΗΒΪΜΜ npHMepaMH nOJTHpHO-ro pacTBopHTejiH hbjīhiotch nponnJieHrJīHKOJib, i5yTHJirjiHKOjib, 6yTHJi-flHrJIHKOJĪb , Η30Πρ0ΠΗΛ0ΒΒΐΜ οπκρτ, 3TaH0JI, MeTOKCHdyTaHOJī Η τ.,π,.
BecoBoe οοοτηοπιθηηθ β ομθοη Me?K,iiy ajiKHJi6eH3HJicyj^OHaTOM MeTaJIJia, ΗΘΚΟΗΗΒΙΜ ΠΟΒΘΡΧΗΟΟΤΗΟ aKTHBHBIM ΒΘ1Ι];Θ0ΤΒ0Μ H nOJIHpHBĪM pacTBOpnTejieM He ηβληθτοη κρμτηηηβιμ, h oho cocTaBJiHeT npe^non-THTejibHO 25-40 : 40-55 : 5-30, 6oJiee npe,n,nonTHTeJibHO 28-37 : 43-50 : 15-23. Βθοοβοθ οοοτηοπιθηηθ β ομθοη ajiKHJideH3HJicyjn4>o-HaTa MeTajuia κ HeMOHHOMy ποβθρχηοοτηο aKTHBHOMy BeiqecTBy npefl-nonTHTeJibHO cocTaBJiHeT 1:2 ,π,ο 1:1. MHceKTHiļH.n.HaH npo3panHan 3MyjibCHH no HacTOHiiļeMy Η3θ6ρθτθΗΗΚ> coflepjKHT BBimeyKa3aHHoe CMemaHHOe ποβθρχηοοτηο aKTHBHoe βθιιιθοτβο c nojiHpHbiM pacTBopHTejieM c βθοομ , paBHBiM hjih 6ojibūJHM Becy nnpe-TpOH^aJIbHOrO HHCeKTMUļHfla, KOTOpBlH HBJIHeTCH aKTHBHBIM ΚΟΜΠΟΗΘΗΤΟΜ, a Tarae β κοπηπθοτβθ 6 Bec. % hjih μθηβιπθ ot 0MyjibCHH. ΠρββποητΗ-TeJibHo 3MyjibCHH coflepjKHT CMemaHHOe ποβθρχηοοτηο aKTHBHoe βθ^θοτ-ΒΟ C nOJIHpHBĪM paCTBOpMTeJieM, C ΒΘΟΟΜ, COCTaBJIHIOmHM 3-6 ΒΘΟΟΒ ΠΗ-peTpoHflajībHoro pacTBopHTeJīH. LV 10159 5
CneiļH$M^ecKHe npHMepH nnpeTpoHflajībHoro pacTBopHTeJiH, hc-n0Jīb3yeM0r0 B HaCTOHIflļeM Η30(5ρθΤΘΗΗΗ, npHBOflHT 3-φθΗΟΚΟΗ(5θΗ3Μ xpM3aHTeMaT (φθΗΟτρηΗ), 3-ajiJi.HJī-2-MeTHJi-4-oKCHii;MKJioneHT-2-eHHJi xpH3aHT0MaT (ajiJieTpHH), 3-ajiJiMJi-2-MeTHJi-4-0KC0iļHK^oneHT-2-eHMJi 2,2,3,3-TeTpaMeTHJiiļHKJionponaHKapdoKCMJiaT (TepajiJieTpuH), 2-μθτηλ-4-oKco-3-(2-nponHHPiJi)iļHKJioneHT-2-eHHJi xpn3aHTeMaT (npajuieTpHH) iM-U[HaH0-3-$eH0KCH6eH3HJi xpw3aHTeMaT (ι1ηΦθηοτρηη) , <x-u;HaHo-3-φβΗ0Κ0Η6θΗ3ΗΛ 2,2,3,3-TeTpaMeTMJiij;nKJionponaHKapdoKCHJiaT (φθΗ-nponaTpHH), 3,4,5,6-τeτpaΓMr^poφτaJmMHrπ,Me'·ΓHJI xpn3aHTeMaT (TeTpa-ΜβτρΗΗ) , 3-φβΗΟΚΟΗ6θΗ3Ι«Ι 3-( 2,2-flMXJIOpBHHHJl) -2 ,2-flMMeTnJI-IļHKJIO-nponaHKap6oKCHJiaT (πβρΜθτρΗΗ), Ι-θτηηη·π-2-μθτμ.π-2-πθητθηη.π xpn-3aHT6MaT (3ΜΠΘΗΤρΜΗ) Μ ΗΧ Μ30ΜθρΗ, TaKne KaK ΓΘΟΜΘΤρΡΡΙβΟΚΗβ Η30-ΜβρΗ Η OnTiraeCKHe Η30ΜβρΗ. MHceKTKiiHflHaH npo3panHan 3MyjibCHH corJiacHO HacTOHiqeMy Η3θ6-ρθΤΘΗΗΚ) ΜΟΚβΤ CO^epiKaTb ΓφΗ ΗΘΟβχΟ,ϋ,ίΙΜΟΟΤΚ TaKOii CHHeprHCT KaK nHnepoHHJi6yTOKCHfl (flajiee o(5o3HanaeMHft ΠΒ0), προοτοη OKTaxjiop1ū,H-npOīIHJīOBblM 3φκρ H T.fl., ΠΟΟρβ,ηΟΤΒΟΜ ΧΙβΓΟ OJKHflaeTCH yCHJieHHe aK-THBHOCTH.
KpOMe ΤΟΓΟ, CTadMJIbHOCTb aKTHBHOrO KOMĪIOHeHTa ΜΟίΚΘΤ dHTb coxpaHeHa c πομοι^βιο flotfaBjreHHH no BH(5opy aHTHOKCHflaHTa (nanpH-Mep, 2,6-,iļn-TpeT6yTHJi-4-MeTH^eHOJi (ΒΗΤ), 2,2^μθτηλθη6ηο (4-MeTHJi-6-TpeT.6yTMJi$eHOji), H-OKTa,n,eiļMJi 3—(3’, 5’ -fln-TpeT(>ymn--4’-οκοκφθΗΗ;ι)-προπΗθΗ3τ), cojien (HanpuMep, <5eH3oaT HaTpun, 6eH3oaT aMMOHHH) h T.fl. KpOMe τογο, HHceKTHiiHflHaH npo3panHaH 3Myjibcna no HacTOHqeMy H30CfpeTeHHH) μοηθτ npeflynpeflHTi> bo3hhk-ΗΟΒΘΗΗΗ BOflHOft ΠΛΘΟΘΗΜ ΠΥΤΘΜ flOČaBJieHHH fl63Mi^HLl1HpyīOmerO Cpefl-CTBa, TaKoro KaK Ρ^οχθΙ w 6X1 (η3Γοτοβληθμογο φηρινιοΜ ICI Americans InC.). ΚρΟΜΘ ΤΟΓΟ, OHa TaKJKe ΜΟΚΘΤ <5bITb HCn0JIb30-BaHa flJiH ca,iļOBOflnecKHX iļeJieM βμθοτθ c Φ^γηι1η^μη . JļjIH np0H3B0flCTBa HHCeKTHIļHflHOft np03panH0ī5 3MyJIbCHM ΠΟ HaCTO— HiiļeMy H3o6peTeHHK caMHM o6idhm ηβληθτοη πρηγοτοβιιθηηθ KOHiļeHTpa— Ta πγτβΜ CMemHBaHHH impeTpoimajībHoro HHceKTHiņma, κοτορκη npe^,-CTaBJineT coOofi ,n,eii:cTByīoiiļHM κομποηθήτ, ομθιμηηογο ποβθρχηοοτηο aKTMBHoro BemecTBa c ποληρημμ pacTBopnTejieM n, npn HeodxoflKMoe-tm, MajTopacTBopHMbix flodaBOK (HanpuMep, ΒΗΤ), h pa36aBjieHHe noJiy-neHHoro KOHiļeHTpaTa bo^om (npoiļecc A). 6 B ajībTepHaTHBHOM npoiļecce (npoiļecc B) KOHiļeHTpaT γοτοβητ CMeuiHBaHHeM nupeTpoHflajībHoro MHceKTHiļHļļa b KaiiecTBe βκτμβηογο KOMnoHeHTa, CMemaHHoro noBepxHOCTHO aKTMBHoro BeiqecTBa c nojinp-ηβιμ pacTBopHTeJieM, MacjiopacTBopMMbrc flodaBOK (HanpMMep, BHT), ko-Topne jļodaBJiHKT πρη ηθο^χο^ημοοτη, m BemecTBa 1ļhh yBejiMneHMH βθ-ca KOHiļeHTpaTa, HanpMMep, nojinpHoro pacTBopHTejin, Bojļbi mjim CMecn o6omx, m 3aTeM πολυ^θηηηη KOHiļeHTpaT pa3daBJiHK)T BOļļott. IIpn npoiļecce A, KOHiļeHTpaT μμθθτ BbicoKyio βη3κοοτβ, m Kor,n,a ero B3BeiiiMBaiOT, pacneT πo,nJienamero B3BeniMBaHMio KOinmecTBa 3aT-pyjļHHTeJieH. CorjiacHo npoiļeccy B, HanpoTMB, onepaiļHH B3BeiiiMBa-hmh μοκθτ čbiTb yjiymneHa.
HanpMMep, KOrfla np0M3B0ļļMTCH MHCeKTMIļMfiHaH np03panHaH 9MyJIb-chh, coflepKaiiļaH 0,2¾ ajuieTpMHa m 0,2% (f)eHOTpnHa, KOHijeHTpaT BHa-najie nojiynaiOT CMeniMBaHHeM 5 BecoBbix nacTeft KaK ajuieTpMHa, TaK h $eHOTpMHa, 40 βθοοβηχ nacTen CMeinam-ioro ποβθρχηοοτηο Ακτμβηογο Be^ecTBa c nojinpHbiM pacTBopHTeJieM, I βθοοβομ nacTM BHT μ ηθκοτο-poro KOJinnecTBa nponMJieHrJiMKOJiH, CMecM nponHJieHrJiMKOJib/Bo.n.a (1:1 no Becy) b KOJinnecTBe, jļocTaTOUHOM jļjiH ,π,ΟΒβ,π,θΗΜΗ odmero Beca-,π,ο 100 nacTeM, h 3aTeM 4 βθοοβηχ nacTM KOHiļeHTpaTa cMenin-BaiOT c 96 Bec. nacTen βο,ιι,η ajih πρμγοτοβλθηηη jKejiaeMoM ηηοθκτμ-IļMflHOM np03panH0M 9MyJIbCHH.
Kor^a HHceKTMiļHflHaH npo3panHaH 9MyjibCMH no HacTOHiiļeMy m30(5-ρβτβΗΗΚ), npMroTOBJieHHan TaKHM odpa30M, Hcnojib3yeTCH b ļi;0MamHHX ycJiOBMHx, n;ejiecoo6pa3Ho 3anoJiHMTb 9MyjibCHeft HedojibmoM pynH0M nyjibBepM3aTop μ ηθποορθ,ιι,οτβθηηο onpHCKMBaTb τθλο JieTynMX Hace-κομηχ (HanpMMep, TapanaHOB), hjim ace HaHecTH Ha ydeF.Hme noji3y-tihx HaceKOMbix. HHceKTMiļMļļKaH npo3panHan 9MyjibCMH corjiacHO Hac-TOHineMy M3odpeTeHMio Tanme nojie3Ha 1ļtih yHnnTOFeHHH ποοτθλβηβιχ KJIOnOB, (5JI0X, BmeM M T.ļļ.
KoraļeHTpaT μηοθκτμημ,π,κομ npo3panHOM 9MyjibCHM, noJiyneHHHii BbiraeyKa3aHHbiM npoiļeccoM B, μοκθτ 6htb Mcnojib30BaH de3 pa3<5aBJie-hmh BOļiOM npM pacnbuieHMM CBepxMajioro oCh>eMa. MHceKTMiļMļļHaH npo3panHaH 9MyjibCMH corjiacHO HacTOHmeMy M3o6-peTGHMio coflep.FMT nMpeTpoMļļajībHbie MHceKTHiļMļļbi, KaK aKTMBHbie kom-ποηθητη, b KOjmnecTBe npeļļnonTMTejibHO ot 0,02 ļļo 2 Bec. %, dojiee πρβ,ςποητΜτβΛΒΗΟ οτ 0,05 ļļo I Bec. %. LV 10159 7
HacTOHinee Μ3θόρθτβΗΗθ όγ,π,θτ npoHJLznocTpHpoBaHO čojiee nofl-PO(5ho co cchjikom Ha HHJKecJie,nyK)iE[He πρκΜθρκ, ho oho ηθ orpaHH-tieHO 3TMMM npHMepaMH.
ΠρΗΜθρ I MHCeKTMIļHflHHe np03paqHbie 3MyJIbCHH, ΗΜβΚ)ΙΙ}ΗΘ COCTaB, nOKa3aH- hhM b TadJiMiļe I, γοτοβμλη c Hcnojib30BaHM6M Hymal III9, II4Ī, 1156 HJIH 1159 (npOflyKT φκρΜΗ Matsumoto Yushi sciyaku Co, Ltd,), CMecb flo,n;eiļHJī6eH3MJicyjib$OHaTa KajībiļMH, ποληοκοηθτηλθη-CTi^poji$eHOJia, HMem^an TJIB ot 12 flo 16, h npomureHrjiHKOJiH) b ksl-qecTBe CMemaHHoro ποβθρχηοοτηο aKTHBHoro BemecTBa c πο,πηρηκμ pacTBopHTeJieM. 8
Tačjmpa I
CocTaB ΠΟΒθρΧΗΟΠΤΗΟ aKTHBHOe BetnecTBox; b CMecu, coflepjKauļee nojiHpHHg pacTBopMTejib (Bec.%) Akthbhhh kom- ΠΟΗΘΗΤ (Bec.%) .IļočaBKH (βθο, I 0,8 TeTpaMaTpuH 0.1 d —ΦθΗΟΤρΜΗ 0,1 2 0,8 d -AjuieTpHH 0,1 IlepMaTpHH 0,1 3 0,8 TepajijieTpHH 0,2 4 0,8 d-AjijieTpHH 0,1 d —ΦθΗΟΤρΗΗ 0,1 5 1,5 d-AjiJieTpHH 0,25 d-ΦθΗΟΤρΚΗ 0,25 6 2,0 d-AjiJieTpMH 0,25 d-ΦθΗΟΤρΜΗ 0,25 7 3,0 d-AjiJieTpHH 0,25 d -ΦθΗΟΤρΜΗ 0,25 8 3,0 d -AjiJieTpHH 0,5 d -ΦθΗΟΤρΗΗ 0,5 9 0,8 d -ΦθΗΟΤρΚΗ 0,2 BHT 0,01 10 0,8 d -TeTpaMeTpHH 0,1 d -ΦθΗΟΤρΗΗ 0,1 BHT 0,01 II 0,8 IlpajiJieTpMH 0,05 ΠΕ0 0,15 BHT 0,01 12 0,8 d-AjuieTpwH 0,1 ΦβΗπροΓ^τρΜΗ 0,1 BHT 0,01 13 0,8 d-AjuieTpHH 0,1 d-ΦΘΗΟΤρΜΗ 0,1 BHT ΠρΟΠΗ- JieHrJIH- KOJIb 0,01 0,01 14 0,8 d-AjDieTpHH 0,1 d—ΦβΗΟΤρΗΗ 0,1 H30np0- ΠΗϋΟΒΗΜ cnwpT 0,01 15 0,8 d-AjuieTpHH 0,2 AmmohmM- 6eH3oaT 0,7 16 0,8 d- AjineTpHH 0,1 d-IļM$eHOTpHH 0,1 Ammohhh- 6eH3oaT 0,7 9 LV 10159
TačjiHīļa I (npoflOJijKeHHe) 17 0,8 d-AjuieTpHH d-ΦθΗΟΤρΗΗ 0,1 BHT 0,1 IIponHJīeH- rJIHKOJIb ProxeI GXL 0,2 0,98 0,1 18 0,8 d —Ι1ΗφθΗΟΤρΗΗ 0,2 19 0,8 ά-ΙίΗφβΗΟ'τρΗΗ 0,2 BHT 0,02 20 0,35 IIpajiJieTpHH 0,05 21 0,70 IIpajiJieTpHH 0,1 22 0,70 IlpajīJīeTpHH 0,1 BHT 0,01 23 0,70 IlpajiJieTpKH 0,1 ProxeI GXL 0,2 24 0,70 IlpajīJīeTpHH 0,05 BHT ProxeI SXL 0,01 0,2 25 1,40 IIpajiJieTpMH 0,2 26 1,80 IlpajīJīeTpHH ΠΒ0 0,1 0,3 >lcnojib3yeMbiM noJinpHHM pacTBopHTeJib, coflepacaiiļHM cMemaHHoe noBepxHOCTHO aKTHBHoe BemecTBO, $ I—17 Hywal III9, # 18, 19 Eymal II4I, » 20-25 Hymal 1156, #'26 Hywal 1159. ΙΟ Β cocTaBax npMMepoB 1-8 BHanajie πηοτβι$ η ομθιμηηβιΜ aKTHBHBie κομποηθητη KajKflHM CMeuiHBajiH c Ejfnal III9 β οοοτηοπιθηηη, noKa3aH-hom b TaČJīMLļe I, npn narpeBe po npHMepHO 40°C c nepeMeniHBaHHeM. flocjie Toro KaK $a3a pacTBopa CTaHeT ο,π,Ηορο,π,ΗΟΗ, KOHiļeHTpaTH pa3- ČaBJIHJIH BOJļOM flO ΟΟΟΤΒβΤΟΤΒγβΙΙ^ΗΧ KOHIļeHTpaiļHM aKTHBHBDC ΚΟΜΠΟΗβΗ- tob, noKa3aHHBix b Ta6jiHi.i;e I, aji# πολώθηκα ο,ηΗορο,π,ΗΒΓχ: κ npo3pati-ΗΒΙΧ HHCeKTHIļHflHBK 3MyJIbCHH. B cocTaBe npuMepa 13 d -ajuieTpnH η .^-φθΗοτρΗΗ, κοτορΒίθ npefl-CTaBJifliOT cočofl aKTHBHBifi κομποηθητ, cMemuBajin Hy/n ai III9, BHT h npoiiHJiaHrJiHKOJib b cooTHomeHHH, noKa3aHHOM β TadJiHiļe I, npn Har-peBe npHMepHO po 40°C c nepeMeiHHBaHHeM. Ilocjie τογο, KaK $a3a pacTBopa CTaHeT ο,ηΗοροβΗοίί, KOHi^eHTpaT pa3(5aBJMJiH ΒΟ,ςοβ po koh-Li;eHTpau;nH aKTHBHoro KOMnoHeHTa, noKa3aHHOH b Tačjmiļe I, ajih ΠΟΛΏΘΗΚΑ OflHOpOflHOK Η ΠρΟθρθΠΗΟΗ ΗΗΟβΚΤΗΙ^Η,Π,ΗΟΗ np03paHH0ft 3MyJIbCHH. B cocTaBe npHMepa 14 paBHOMepHyio h np03panHyīo. HHceKTM^flHyio npo3paqHyio 3MyjībCKīo nojiyqajiK τθκημ me odpasoM, ητο m cocT-aB npH-Mepa 13, 3a HCKJHOHeHHeM τογο, πτο βμθοτο nponHJieHrjiHKOJiA Hcnojib-30Ba;iH M3onponHJiOBBiiļ οππρτ, η He ^očaBJiAjm BHT. B C0CTaBax npHMepoB 15 h 16 ηθομθιμηηβιη κομποηθητ h cuecb JļByX aKTHBHBDC ΚΟΜΠΟΗΘΗΤΟΒ CMeiIIHBaJIH, KajKflJblft, C Hy?7?al III9 B cooTHomeHHH, noKa3aHHOM b Tadjiniļe I, πρκ HarpeBe po πρκΜβρΗο 40°C c nepeMeuiHBaHHeM. TaKHM o<5pa30M, čbijih πολώθηβι KOHpeHTpaTH, hmeīoiiļrīe oflHopo,iļHyK} $a3y pacTBopa. 3th KOHiļeHTpaTBi 3aTeM pa3(5aB-JIAJIH 0,7%-HBIM BOJļHBIM paCTBOpOM aMM0HHft<5eH30aTa flO KOHIļeHTpaiļHH aKTHBHoro KOMnoHeHTa, noKa3aHHBix β Ta^JiHiļe I, ,i];jia πολώθηηα ofl-HOpOflHBDC H np03paHHBDC HHCeKTHIļHflHBDC np03paHHBDC 3MyJIbCMft. B cocTaBe npHMepa 17 CMecb d-ajuieTpHHa h d-$eHOTpHHa, ko-Topan hbjihstch aKTHBHBiM κομποηθητομ , Hymal II19, BHT η ΡγοχθΙ GXL CMeraHBajiH β οοοτηοπθηηη, ποκο3θηηom b Tačjiniļe I, πρκ HarpeBe flo npHMepHO 40°C c nepeMetiiMBaHHeM. nocjie τογο, KaK $a3a pacTBopa CTaHeT Ο^ΗΟρΟ^ΗΟΜ, KOHIļeHTpaT pa3daBJIHJIH BOJļOM flO KOHIļeH— TpaiļHH aKTHBHoro KOMnoHeHTa, noKa3aHHOH β TadjiHiļe I, ajia nojiy-ΗΘΗΗΗ OflHOpOflHOtt H np03paHH0H ΗΗΟΘΚΤΗΠ,Η,Π,ΗΟΑ np03paHH0M 3MyJIbCHH. B cocTaBax npHMepoB 18 h 19 HecMemaHH&ift εκτηβηβιΜ κομποηθητ d -ΙίπφθΗΟτρΗΗ, Hyfl?al II4I h BHT CMeniHBajiH β οοοτηοπιθηηη, noKa-3aHH0M b Ta6jiHE[e I, npn HarpeBe po npHMepHO 40°C npn nepeMemnBa- HHH. LV 10159
II
Ilocjie τογο icaK $a3a pacTBOpa CTaHeT oļļHopoļļHOM, KOHiļeHTpaT pa3-daBJĪHJIM BOflOM ļļO KOHIļĢHTpaiļHH aKTMBHOrO KOMĪIOHeHTa, I10Ka3aHH0M b Tačjmiļe I, ļļJiH nojiy^eHHH OļļHopoļļHOM h npo3paHHoii HHceKTHiļHļļ-HOM np03patIH0M 9MyJIbCHH. B cocTaBax npHMepoB 20-25 HecMemaHHHf! aKTMBHHft κομποηθητ, ĪIpajuieTpHH, Hyr?al 1156, BHT h ProxeI 6XL CMenMBajm b cooTHome-hmm, n0Ka3aHH0M b Tačjmiļe I, npn HarpeBe ļļo npMMepHO 40°C c nepeMeniHBaHMeM. Ilocjie τογο Kaic $aea-pacTBOpa CTaHeT oflHopoflHoii, KOHiļeHTpaT pa3daBJifljm BOļļOft ļļo KOHiļeHTpaiļiiM εκτηβηογο κομποηθη-Ta, noKa3aHHOM b TaČJimļe I, ļļjin nojiyqeHHfi oļļHopoļļHOft h npo3paq-ΗΟίί . HHCeKTHIļMļļHOft np03paHH0M 3MyJIbCHH. B cocTaBe npHMepa 26 CMecb IIpajījieTpHHa η ΠΒ0, KOTopaa npeļļ-CTaBJineT co6oM εκτηβηβιμ κομποηθητ, k Hy/nal 1159 CMenmBajincb b cooTHoineHHH, noKa3aHHOM b Ta6nHiļe I, npn HarpeBe ,π,ο npHMepHO 40°G c nepeMeinHBaHHeM. Ilocjie τογο, KaK $a3a pacTBopa CTaHeT OflHOpOļļHOM, KOHiļeHTpaT pa3(5aBJIHJIM BOļļOM ļļO KOHIļeHTpatļHH aKTHB— ηογο KOMnoHeHTa, noKa3aHHOH b Ta6jiniļe I, ajih nojiyneHHH oļļHopoļļ-HOM M np03paHH0M HHCeKTHIļHflHOM np03patīH0ft 3MyJIbCHH. ilpHMepbl COCTaBOB, B KOTOpbDC HCnOJIb3yiOT nOBepXHOCTHO aKTHB-Hbie BemecTBa, He BKjnoneHHbie b ο6·βθμ HacToaiiļero Η3θόρβτβΗΗΗ, no-Ka3aHbi b TadjiMiļe 2 b KanecTBe epaBHHTejibHbrc npHMepoB. B npHMepax A-E co cpaBHMTejibHHMH cocTaBaMH HecMemaHHHe hjih CMemaHHbie aKTHBHHe κομποηθητη η noBepxHOCTHO aKTHBHbie BeiiļecTBa, He BKJnoneHHbie b ο(5ί>θμ HacTOHiiļero Η3θ6ρβτβΗΗΗ, CMeniHBajm b coot-ηοιπθηηηχ, nOKa3aHHbix b Ta^jiHiļe 2, πρκ HarpeBe ļļo πρπΜβρΗΟ 40°C c nepeMeniHBaHneM. noJiyneHHbie KOHiļeHTpaTH pa3(5aBJiHjm εο,π,οΜ ļļo KOHiļeHTpaiļMfi aKTMBHoro KOMnoHeHTa, noKa3aHHbix b Tačjiniļe 2, ļļjin nOJiyneHHH CpaBHHTeJIbHbK COCTaBOB. a d crd a s o 2 a φ od Μ O td > o o od O P 0 ra P a cd S P 0 Φ I 2 d a s 2 d a s x d d d 2 d d a s d p Ο s ο o o Φ o s o o o p o o o o o Ο a a a a a a a o a a a o a a a a Cd ί=ι S Φ o o s a o a s s s a s s a o Φ ο ο X o o o a o o o o o o o o o d X a a -3 K s a ►3 X X s X x a X ο ^ ω Φ o K Φ E O o o o O d(D a S S P p s O P s s s s s ap o ο dJ >-3 d Φ a 0 "-Ό o φ ω o trl0 o 0 O P 0 a d0 i-3 0 1-3 0 X» 0 S tj a 0 S a as S s s s a a U a o a —Ό Ka a a a a i-io o ω a φ da « φ ω φ ω φ coa ΐ <-->s a faS a a a a a - s P do CČO 1—1 <>0 CJIO X ,—s ,—> - "t; CJd ---- ^ X -—X x—a 0 (jJo rv> O - >o< H-f o l£· Ι-H o s ο - s o 1—IS cns O i-3 o o s ω ω C0G3 ^-d S 03 a 2 i—iv-3 S* - 0 2 d 2 s 3 o ο CCS o ois o o O o O S φ ί=ι - a a '-'a i-3 a a a a a ω αίφ φ ω Φ φ >& φ φ φ cd Sc ^a ' Sc a P Sc ω SC sc a φ d X—s a X—' J3 m o • a s • o • • a Φ χ o o o a o a X o o O ρ a o a o 0 P 0 a 0 ο s d s a S <^~X o s s ω 0 a cx a E d d •-3 d a o Ο d s d Sc o O o d d o i-3 o a W d a o s ο 1 P a o N0 o o a ω a s φ 1-3 « Φ s īd ο 1 1 a o a a d φ o >0 Φ Ο Φ • a o a a ω a a W ο o o o o o o 1—3 o os Φ V· s0 \0 *0 »0 N0 \0 >0 X* X» I o TV) TV) σi cn tv> CJi o i-a TV) t-3 10i h3 a» d Φ Φ Φ X Φ α >-3 a 0j i-3 0 Ch Qj CL. ^ 1 d o 1 d s 1 1 1 d e P 0 dP cd > > dP φ 2 d Φ 2 a a a Φ 2 a Φ s Ο Φ E i~9 a a Ο Φ o i-3 a 2 0 Sc P φ φ 2 0 i-3 d (Dd ov i-3 i-3 (Dd d S 0 S S a d d 0 S s a d a o s s s d a a s 2 ja a a s a a P a o a TV) φ a 0 ^-x Cd o o oo o o o oo Φ «« *0 N0 S0 V* <0 o TV) t-H 1—11—1 1—1 1—1 CO 1—11—1 4% LV 10159 13 ΠρΗΜθρ 2 ΜΗΟθκτΗΐ^Η,π,ΗΒΐβ npo3paxiHbie 3Myjibcnn κ cpaBHHTejibHbie 3MyjibCMH, npnr0T0BJI6HHH6 B ΠρΗΜβρθ I , XpaHHJIH B CJie,IiyK)mHX pa3JIHXIHbIX ycjio-ΒΗΗΧ H HadJIBflaJIHCb B ΟΤΗΟΠΙΘΗΜΜ COCTOHHHH paCTBOpa*. (I) IJļByxHe,n,e.nbHoe xpaHeHMo πρκ pa3JinnHbix TeMnepaTypax, I0°C, 25°C h 40°C b cocyfle mjih πομθιι1Θηηη c ποοτοηηηομ TeMnepaTypoft, h (2) flByxHeflejibHoe xpaHeHne npn TeMnepaType - 20°C n 3aTeM CTOflHHe b TeneHne 24 nacoB npn 25°C hjih BCTpHXKBaHHe nocJie bh-,ϋ,ΘρκκΗ. Jļajiee, noejie τογο, «aic ncnHTHBaeMbie 3MyjibCHM BbiflepmBa-jih b cypoBbix ycjiOBHHX πρκ 60°C x 2 He^ejm, προη,βΗΤΗ ocTaTonHoro aKTMBHOrO K0MĪI0H6HTa 3aMepHJIH ra30B0H XpOMaTOrpa$HeH CJieffinOIIļHM 00pa30M. Κ I r npo6bi flodaBJiHJin 10 mm.20 mji pacTBopa b aijeTOHe πρκ . 0,1% (sec/od-beM) BenjecTBa no BHyTpeHHHM CTaH,n;apTaM, κ CMecb KOHDļeHTpMpoBajiH πρκ ποηκικθηηομ flaBJieHHM. OcTaTOK 3aTeM pacTBopn-jīm b 2 mji aiļeTOHa. iIojiyneHHbin HcnbīTbiBaeMbiH pacTBop aHajin3 κρ o ba— jim b KOjmnecTBeHHOM οτηοπιθηηη c πομοιι^βιο ra30B0ft xpoMaTorpa$nn corjiacHo MeTOfly BHyTpeHHero cTaH,n,apTHoro BeņecTBa c nJiaMeHHbiM ΗOHH3aiļHOHHbIM βΘΤΘΚΤΟρΟΜ. yCJīOBMH Η3ΜβρθΗΗΗ ČbUIH CJieflyiOIHHMH. 14
KojiOHKa: 5% E-30 (100-200 Mem) ra3-H0CHTejib: A30T (cKopocTb npoTOKa 50 mji/mhh) AHaJIH3MpyeMbIM Κ0ΜΠ0Η6ΗΤ BHyTpeHHee CTaH-flapTHoe BemecTBO TeMnepaTvpa KOJTOHKH, 0 TeMnepaTypa Ka-Mepbi ra3Hq)HKa-IļHH UC TeTpaMeTpMH (HJIM d -ΤΘΤ-paMeTpMH) H d —φθΗΟΤρΗΗ Tpi^emuiMeTaH I80°C 230°C TepajuieTpHH TaKoe ste,xiTO Bbinie Tanan ®e, KaK Bbniie TaKan Hce, χϊτο Bbime d -AjIJīeTpHH H d-ΦθΗΟΤρΗΗ ΤρΜφθΗΗΙ[φθθφ3Τ 220°C 270°C d -AjiJieTpHH TaKoe ate,KaK Bbime TaKan we, KaK Bbime TaKan ace, KaK BHIIie d -AjIJieTpHH H d -ΙίΗφθΗΟΤρΗΗ TaKoe me,KaK Bbime TaKan ace, KaK Bbniie TaKan Hce, KaK Bbime d -ΙίπφθΗΟΤρΗΗ Tanoe ®e,KaK Bbiine TaKan ate, KaK Bbime TaKan me, KaK Bbmie IIpajiJieTpHH η ΠΒ0 ,IļH$eHHJī$TajiaT 200°C 250°C līpajuieTpHH d -AjIJieTpHH M ΠβρΜΘΤρΗΗ TaKoe «e,KaK βηιιιθ Tpw$eHMJī$oc$aTX ^ ,I]^eHM.flK|)TajiaTXX ^ TaKan ®e, KaK Bbime 200°Cx) 2I5°Cxx) TaKan ace, KaK Bbime 270°Cx) 270°Cxx) IlpMMe^aHHe: x) ΥCJIOBMH npH aHaJIM3e d -ajuieTpHHa. xx' ycjioBHH πρκ aHajiH3e nepMeTpHHa. ΠρΗΜβρΒΐ noKa3aHH b Tačjmiļe 3. Οοοτοηημθ pacTBopa noKa3aHO C CJīeflyīOipMH 0603HaneHHHMHΪ O : npo3patļHHH A : ΠοηγπροΗΗΐφβΜΒίίί x : Henpo3paxiHHM ( čejibift μυτηημ) hjih 0(5pa30BaHHe oca^KOB. LV 10159 £ ο ω ι=; Χίο ο t=C C ω— : 2¾¾. cd ο ^ t* £CV Ο Ο Ο Ο trD Ρ Ε-Ό Εη Ο O'vD £ £ >5 (D ffl Ε £ prsaft Ο Ε-ι C Ρν£ «3 t£ cd eh £ Ο Εη tu Eh O 2: E o £ ¢=5 .0 Ct ω X cmcd P O ffl E-t Ocd Pj ω s x tu o Eh o o o o « 1 PvCd o Eh ff) 0 to O £ £ CM O * X o 1 tu o O 0 o &H £ cO 13 X o 1 tu 1 o PvCd LO Eh CQ 0 CM O £ £ 5NĪ o o o CM I o o o I tu ο ω Eh s 13 x
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IlpMMep 3 JūļBaflņaTb B3pocjn>ix flOMaffiHnx Myx (M Usca domstica ) Ha rpynny (οοοτηοιπθηκθ nojioB 1:1) dbijm BbinynļeHbi b CTeKJiHHHoft ηοπη- Π
TaTejibHOH KaMepe ο^βομομ 0,34 μ , κ npefliiMcaHHoe κο-πμηθοτβο hh-CeKTHIļHJļHOH np03pa^H0M 3MyJIbCHH, ΠρΗΓΟΤΟΒ,ΠΘΗΗΟίί corjiacHo COCTa-By npHMepa, pacnbīJiHJin Ha B3pocJibix c noMOiiļbīo TpurrepHoro pacnbī-ΛΗΤβΛΗ (CanyoH CHS -3B; np0H3B0,n,CTB0 φκρΜΗ CanyoH Co., Ltd )· īloCJie pacnblJieHHH HMCJIO ΠΟΤβρΗΒΙΠΗΧ 003ΗΘΗΗΘ HaceKOMHX nOflCHMTbl-BaJIH C ΤΘΗΘΗΗΘΜ ΒρθΜΘΗΗ, H CnyCTH 20 MHHyT, Bce HaceKOMbie OnblTa co6xpajiMGb b HHCTyio namKy. Hocjie AOčaBJieHMH boah b πρημθηκη, naniKy nepeHOCHJin b KOMHaTy HatfjnofleHMH η noflcmiTHBajni cMepTHOCTb 24 naca cnycTiī. BpeMH rnčejm KT^q noflCHHTHBajiH corjiacHo MeTO#y HcrīHTaHHH no BjiHCcy. 3to HcnbīTanne noBTopHJin τρη pa3a ,ηο πητη pa3.
Pe3yjibTaTH πρηβθ^θηη b Tatfjmije 4. HHGeKTHiļHflHaH npo3panHaH SMyjibcnH corjiacHo HacToameMy H3o6-ροτβΗΗΐο CTa(5MJibHa b coctohhhh-pacTBopa κ TeMnepaTypHOMy η3μθηθ-HHio, ητο ABJineTCH Ba?KHbiM icanecTBOM, B pe3yjibTaTe nero mojkho CKa-3aTb, ητο dbuia penreHa npodjieMa fljiHTejibHoro xpaHeHHH. co I—{ cd cr s 3 Ό cd E-i 1 3 cd 3 ϋ o O CO o 3 Λ O cd'-' o O LO a p.3 1—1 f—l o O G ^ 3 o o G-CVi o "g co lO P- o LO S #> #\ E- H 3 C\2 1—1 C\2 cv Γ- O CO P- Ο cb o CO cb 1—1 1—1 lo 00 n co Γ Cb Cb CO Cb 3 s G cd X co o ιο s 95 65 60 lO co co LO o CO co co a LO s Ρ,Χ LO co ω s cv co LO 3 3 CO a o P • lo o o o p- ω rv co LO co s X ω 3 (—1 cv LO C\2 io o 1—1 l—l c\2 CV2 c\2 X 3 O o P- p~ o r> 1—1 Cb O 1—1 · 1 X 1 s 3 3 ω 3 G G 3 3 1=5 o o 3 X CQ z> a P- a P 3 »· •s o ω O o l—l O h-i cd o Φ ū. X X O 1 · I (Π ΟΌ X 3 cd o o cd o p#— c ω o 0 3 3 3 ω χ ω 3 ω 3 Ο 3 ffl X <=5 C\2 cv cv cv O X Ο Ρ,Φ «* 1 1 ω G ο ω κ 3 O o o o ΕΪ CtiXOt5S Φ 3 χ X Ο py m φ sp,cū G ο S Φ s « cb Ο φ 3 Ο 3 o X 3 /-N ω X G 1 Λ cd s s Φ 3 m 3¾¾ P- Py 3" o 3 Ο · 3 G 3 G Φ P 3 ΚΌ Φ S Φ G Cū 3 3 o 3 ft 3 P G G 5g^ cd 3 cd 3 Φ o G O 3 Py O P O o X s hc—1 t-^1 X 3 3 G 3 G G'— P m χ Φ Φ Φ Φ 3 3 S φ E-h a Eh a 3 O Φ 3 G 1 1 1 1 O (Ū P « ο T3 Ό T3 T3 cd 3 s <aļ G S O P MacjiHHoe βθπ^θοτβο npe^CTaBJineT co6oh kohtpojibhhh o(5pa3eu; m 6hjio πρμγοτοβλθηο pacTBopeHHeM npHpoflHoro nupeTpHHa b pacTBopHTejie, coflepjscameM pacTBopHTejib ajib; pacnHJieHHH Nisseki (KepOCHH flJIH HHCeKTHIļHflOB; np0H3B0flHTCH φκρΜΟΗ Nippon Sekiyu Kagaku Co. Ltd ). b pe3yjibTaTe tiero co,n,epmaHHe rrapeTpMHa cocTaBJitfjio 0,1 Bec.%, Ha οοηοβθ τιηοτογο aKTHBHoro LV 10159 19
ΦΟΠΜΑ I430BPETEHMH
I. MHceKTHiļH.n.HaH npo3paxjHaa 3MyjiBCHH, o.TJiH^aDDļafl-C Η ΤΘΜ, HTO CO^epTKHT (A) no KpanHen Mepe ο,π,ηη niipeTpOHflajībHHfi HHceKTHiļHjļ, BbičpaHHbifi H3 rpynnbl, COCTOflllļeM H3 3-$eHOKCH(5eH3HJi xpn3aHTeMaTa, 3-ajuiHJi-2-MeTHJi-4-oKCOiļHKJioneHT-2-eHHJi xpn3aHTeMaTa, 3-ajuiHJi-2-MeTHJī-4-OKCOiņiKJioneHT-2-eHHJī 2,2,3,3-τβτρβΜβτιυι-DļHKJionponaHKapdoKCHJiaTa, 2- MeTMJi-4-OKCo-3-(2-nponHHMJi)iņiKJioneHT-2eHHJi xpn3aHTeMaīa h o( -iļHaHO-3-$eHOKCH(5eH3HJi xpH3aHT8MaTa, hjih ομθοβ no KpanHen Mepe ο,π,ηογο nnpeTpoHflajībHoro HHceKTHipifla, BbīČpaHHOrO H3 rpynnbī, COCTOHIIieM H3 3- $eH0KCHdeH3HJi xpn3aHTeMaTa, 3-ajiJīHJi-2-MeTXJī-4-OKCOiļHKJīoneHT-2-eHnji xpn3aHτeMaTa, 3-ajuTMJi-2-MeTHJi-4-OKCOij;HKJīoneHT-2-eHHJi 2,2,3,3-TeTpaMeTHJi-iļHKJionponaHKāp^oKCKJiaTa, 2- MeTHJī-4-OKCo-3-(2-nponHHHJi)n;nKJīoneHT-2-eHHJī xpn3aHTeMaTa η ,χ -iļHaHO-3-$eHOKCH6eH3HJi xpn3aHTeMaTa, ιλ no.KpaftHeft Mepe ο,π,ηογο roipeTpoK,n,ajibHoro HHoeKTHiļHfla, BbičpaH-ηογο H3 rpynmj, οοοτοΗίςβϊί H3 << -i4HaHO-3-$eHOKCM6eH3HJi 2,2,3,3-TeTpaMemnipiKJionpoiiaHKaptfoK- CHJiaTa, 3,4,5,6-TeTparHflpo$TajiHMHflMeTHJi xpH3aHTeMaTa, 3- $eHOKCH6eH3HJI 3- ( 2,2-flKXJIOpBHHHJI) -2,2-JļHMeTHJIITHKJ10np0naH-
KapČOKCHJiaTa h I-3THHHJi-2-MeTHJi-2-neHTeHHJi xpn3aHTeMaTa, b KanecTBe aKTHBHoro KOMnoHeHTa, 20 (B) cMemaHHoe ποΒβρχΗοοτΗΟ aKTHBHoe BemecTBo c nojmpHbiM pacTBo-pMTeJieM, coflepmaiiļee no KpanHen Mepe ο,π,ηη aJiKHJi6eH30Jicyjib$0HaT MeTajuia, no KpaftHeft Mepe ο,ηΗΟ HenoHHoe ποβθρχηοοτηο aKTHBHoe Beu^ecTBO, mem^ee TJIB (rH,ņpo$njībHO-JīHno$HJibHtrtt 6ajiakc) ot 10 flo 18, h no Kpatoen Mepe ο,π,ηη nojmpHbiM pacTBopHTejib, h (C) BOfly, npn 3tom co,iļep)KaHHe (B) b 3MyjibCHH paBHO hjih npeBbimaeT co,n,ep-jK.aHHe (A), ho coflepKaHHe (B) He npeBbimaeT 6% Bec. 2. MHceKTHLļHflHaH npo3patiHan 3MyjibCHH, ο τ o u a 10 nļ a h -c η TeM, ητο οο^βρΜτ (A) no KpaiiHen Mepe ο,π,ηη nHpeTpoHflajībHbiM HHceKTHipm, .BbīdpaHHbiM H3 rpynnH, COCTOHUjeH H3: 3-$eHOKcn(5eH3HJi xpH3aHTeMaTa, 3-ajuiHJi-2-MeTHJi-4-oKcoiļHKJioneHT-2-eHHJi xpH3aHTeMaTa h 3-ajumJi-2-MeTHJi-4-OKCoiļHKJioneHT-2-eHHJi 2,2,3,3-TeTpaMeTHJi-nļHKJionponaHKapdoKCHJiaTa, hjih CMecb no KpanHen Mepe OflHoro nnpeTpOHflajībHoro HHceKTHiļHfla, BblfipaHHOrO H3 ΓργΠΠΗ, ΟΟΟΤΟΗΠίβΜ H3 3-$eHOKCHMeTHJi xpH3aHTeMaTa, 3-ajumji-2-MeTHJi-4-OKCon;HKJioneHT-2-eHHJi xpn3aHTeMaTa, 3-ajuiHJi-2-MeTnJi-4-OKCOu;HKJioneHT-2-eHHJi 2,2,3,3-TeTpaMeTHJi-iļHKJionponaHKapdoKCHJiaTa h no KpanHen Mepe ο^ηογο nnpeTpoHjļajībHoro HHceKTHiļHfla, BbičpaH-ηογο M3 rpynnu, οοοτοπηθΗ H3 •X -u;HaHO-3-$eHOKCH6eH3HJi 2,2,3,3-TeTpaMeTHJin;HKJionponaHKap-'ioKcmiaTa, 3,4,5,6-TeTparHflpo$TajiHMHflMeTHJi xpH3aKTeMaTa, 3-$eHOKCH(5eH3nji 3- (2, 2-,imxjiopBHHHJi) -2,2-flHMeTHJiipīKJionponaH-
KapdoKcnjiaTa, LV 10159 21 1- 3THHH.n-2-MeTHJI~2-neHTeHHJĪ XpH3aHT8MaTa,
2- MeTMJi-4-oKCO-3-(2-nponHHHJi)qnKJioneHT-2-eHHJi xpn3aHTeMaTa H <X -u;MaHO-3-$eHOKCH6eH3HJi xpM3aHTeMaTa, b nanecTBe εκτμβηογο κομποηθητε, (B) CMemaHHoe ποβθρχηοοτηο aKTHBHoe ΒβηβοτΒο c nojinpHBiM pacr-BopHTejreM, coflepacamee no Kpateen Mepe οαηη a;iKHjideH30Jicyjib$0HaT MeTajiJia, no KpanHeM Mepe o#ho ηθηοηηοθ noBepxHOCTHO βκτηβηοθ BemecTBo, HMeroiiļee Γ1Β (ΓΗ,ΐ1ροφΗϋΒΗθ-;ΐΗΠθφΗΛ&ΗΒΐη dajiaHc) οτ 10 ρ,ο 18, η no KpanHeft Mepe ο,π,μη nojiHpHBifi pacTBopuTejib, h (C) BOfly, npn 9tom coflepacaHHe (B) b 3MyjibCHK pa3H0 hjih npeBBimaeT coflep-McaHne (A) n 6 Eec.% hjih μθηθθ. 3. MHceKTHUjHjiHaH npospanHan 3MyjibCHH non.I, OTJinnaio-m 'a h c η τθμ, ητο aKTHBHBiM κομποηθητ npe^CTaBJineT co(5oh no KpaKHeH Mepe o^hh nHpeTpoHflajībHBift ηηοθκτηφή, BBičpaHHBift H3 rpyn-ΠΒΙ, COCTOflllļeft H3 3-$eHoiccn(5eH3HJi xpH3aHTeMaTa, 3-ajiJiHJi-2-MeTHJi-4-OKCOiļHKJioneHT-2-eHHJi xpn3aHTeMaTa, 3-ajrjiHJi-2-MeTHJi-4-OKCOiļHKJioneHT-2-eHHJi 2,2,3,3-TeTpaMeTHJi-LļHKJionponaHKapdoKCHJiaTa, 2-Memn-4-0KC0-3-(2-nponHHHJi)iļHKJioneHT-2-eHHJi xpH3aHTeMaTa h ol -n,HaHO-3^eHOKCHdeH3HJi xpn3aHTeMaTa. MHceKTHiļHAHaH npo3panHan 3MyjibCHH non.I, OTJiHnaio-iiļ a η c η τθμ, ητο BecoBoe cooTHomeHHe Me«,n;y no KpafiHefi Mepe OflHHM ajiKHJi(5eH30Jicyjib$0HaT0M MeTajijia, no KpanHen Mepe ο,π,ηημ He-HOHHBIM ΠΟΒθρΧΗΟΟΤΗΟ aKTHBHBIM BeiI^eCTBOM, HMeiOIIļHM TJIB ( ΓΗ,ΙφΟφΗΛΒ- 22 HO-jiHno$HJibHBiH dajiaHc) οτ 10 pjo 18, h no Kpannetf Mepe ο,π,ηημ nojmpHLiM pacTBopHTeJieM cocTaBJineT 25-40 : 40-55 : 5-30. 5. MHceKTHiļM.īļHaH npo3panHan 3Myjibcnfl no n.I, OTonaio-iii a h c h t6m, ΐίτο yKa3aHHHM ajiKHJi6eH30Jicyjib$0HaT MeTajiJia npefl-CTaBJiiieT co6oPi KajibiļMeByio vum HaTpMeByio cojib ajiKHJi6eH30Jicyjib$o- HOBOH KHCJIOTH C Cg-Cjg. 6. MHceKTHiļHflHaH npo3panHan 0MyjibCHH no n.I, OTJinnaro-m a h c η τθμ, ητο yKa3aHHoe ηθηοηηοθ ποβθρχηοοτηο aKTMBHoe BeiiļecTBO npe^CTaBJmeT codoft no Kpateen Mepe ojļHH 0JieMeHT, bh(5-paHHbiM M3 rpynnbi, cocTOflmen H3 n0JiH0KCH3THJieHCTHp0Ji$eH0Jia, npoc-τογο noJiHOKCH9THJieHajiKHJi$eHHJiOBoro a$npa h npocToro nojmoKCH-3THJieHaJIKHJI3$Hpa. 7. MHceKTHiļH,iļHaH npo3patiHan 9MyjibCHfl no n.I, OTJiHnaio-m a h c η τθμ, ητο yKa3aHHbin nojiHpHbift pacTBopuTejib npe^CTaBJineT codoft no KpanHeM Mepe oflHH θλθμθητ, BHtfpaHHHft H3 rpynrna, coctoh-njeK K3 nponifJieHrjiHKOJiH, 6yTHJirjiMKOJiH, 6yTHJiji,nrjmK0JiH, H3onpona-HOJia, 3TaH0Jia κ MeTOKCHdyTaHOJia. 8. MHceKTHiļHflHaH npo3paxjHan 9MyjibcnH no n.I, OTonaio-iiļ a h c η τθμ, ητο ajiKHJi6eH30Jicyjib$0HaT MeTaouia npe^CTaBjmeT cod.oft rū,0fleij1MJi6eH30jicyjib$0HaT. 9. MHceKTKiTHflHaH npo3panHaH 9MyjibCHH no n.I, OTJIHna κ-ΐΰ a H C Η ΤΘΜ, ητο yKa3aHH0e ΗβΜΟΗΗΟβ ΠΟΒθρΧΗΟΟΤΗΟ aKTKBHOe BenļecTBO npe^CTaBJineT codoM ποΛΗοκοΗθτιυιβΗοτιιροΛφβΗΟΛ, HMeromHft FJ1B οτ 12 flo 16. 10. MHceKTHiļn.n.HaH npo3panHaH 9MyjibCHH no n.I, OTJinnaro-m a h c h TeM, ητο yKa3aHHtifi noJiflpHtift pacTBopnTejib npe^CTaB- JIHeT codon nponHJieHrJIMKOJIb. LV 10159 23 II. Cnocoč nojiyqeHHH ηηοθκτηι^η^ηοΚ npospaīrnoft 3MyjibCHH, coflepaamei! (A) no KpanHen Mepe oflHH nnpeTpoHAajībHHn ηηοθκτηινιλ, BHČpaHHHK H3 rpynnu, cocTOHiiļen H3 3-φβΗθκοηββΗ3Ηη xpH3aHTeMaTa, 3-ajījmjī-2-MeTMJi-4-OKCOD;HKJīoneHT-2-eHMJi 2,2,3,3-Te.TpaMeTHJi-LļnKJionponaHKap6oKCHJiaTa, 2- MeTHJi-4-oKCO-3"(2-nponHHHJi) iļHKJioneHT-2-eHHJi xpn3aHT0MaTa h oC -iļHaH0-3-$eH0KCMdeH3MJi xpn3aHT0MaTa, hjih CMecb no KpaftHeft Mepe ο^ηογο nupeTpOK.n.ajībHoro MHceKTHiņifla, bh(5-paHHoro M3 rpynnH, οοοτοπηβίι H3 3- $eHOKCH6eH3Hjr xpn3aHTeMaTa, 3-ajumJī-2-MeTHJī-4-OKCOti;HKJīoneHT-2-eHHJī xpn3aHT0MaTa, 3-ajijiHJi-2-MeTHJi-4-OKCOD;HKJioneHT“2-eHMJi 2,2,3,3-TeTpaMeTHJi- iļHKJionponaHKapdoKCHJiaTa, 2- MeTHJi-4-oKCO-3-(2-nponnHMJi) nļHKJioneHT-2-eHHJi xpn3aHT0MaTa n ο6-ι1Η3ηο-3-Φθηοκοη6θη3ηλ xpn3aHτeMaTa h no KpaftHeft Mepe ο,π,ηογο nnpeTpoKflajībHoro HHceKTniļHfla, BbīdpaH-Horo H3 rpynnu, cocTOHinen h3 o4“D;HaHO-3-$eHOKCH6eH3HJi 2,2,3,3-TeTpaMeTHJii4KKJionponaH-KapdoKCHJiaTa, 3,4,5,6-TeTparHflpo$TajinMHriiMeTHJī xpn3aHTeMaTa, 3- $eHOKCH6eH3HJi 3- (2,2-flHXJiopBHHMJi) -2,2-flnMeTHJiiļMK.nonponaH-
KapdoKCHJiaTa h I-3THHHJi-2-MeTHJī-2-neHTeHMJi xpn3aHTeMaTa, b nanecTBe βκτμβηογο KOMnoHeHTa, 24 (B) CMemaHHoe ποβθρχηοοτηο εκτηβηοθ BeiiļecTBO c nojiHpHHM pac'TBO-pMTeJieM, coffepjitamee no KpaifaeM Mepe ο,π,κη ajiKHJideH30Jicyjib(f)0HaT MeTajiJia, no Kpatoen Mepe ο,π,ηο ηθμόηηοθ ποβθρχηοοτηο aKTHBHoe Ben^ecTBo, HMeromļee PJ1E (rH,npo$MJibHo-JiMno$HJibHHft dajiaHc) ot 10 ΛΟ 18, h no KpattHeft Mepe ο,π,κη nojinpHbifi pacTBopHTeJib, h (C) BOfly, πρκ ΘΤΟΜ coflepmaHue (B) b 3MyjibCKH paBHO hjih npeBHinaeT coflepma-Hne (A), ho coftepftaHne (B) He npeBbnnaeT 6 % Bec., ο τ ji η n a io iq η tt c η . τθμ , ητο CMeiDHBaioT nnpeTpon^ajībHHM ηηοθκτηαη,ιι,,, koto-pwft npe^CTaBJineT codon aKTHBHHM κομποηθητ, CMemaHHoe ποβθρχηοοτηο aKTHBHoe ΒβιςβοτΒΟ c nojinpHHM pacTBopHTeJieM, η, πρκ Heodxorū,H-mocth, MacjiopacTBopHMbie flodaBKM, h pa3daBJiHiOT nojryneHHbiii KOHiļeH-TpaT βο,π,ομ, hjih CMemuBaiOT nnpeTpoH^ajībHHH κηοθκτηι1μ,π, b KanecTBe aKTMBHoro KOMnoHeHTa, CMemaHHoe ποΒβρχΗοοτΗΟ aKTHBHoe BemecTBo c nojinpHbiM pacTBopHTeJieM, MacjiopacTBopHMbie flodaBKH, κοτορπβ flo-daBjmioTCH no Mepe ηθο6χο,π,ημοοτη , m BemecTBO ajih yBejmneHHH Beca KOHiļeHTpaTa, HanpHMep, noJiHpHbift pacTBopHTeJib, BOfly hjih CMecb odonx, h pa3daBjwK)T noJiynaeMyio CMecb Bo;n,oft. LV 10159 25
AHHOTAIļMH
MHceKTHu;MflHyio npo3panHyio 3MyjibCHio corjiacHo HacTOHmeMy H3cdpeT6HHio nojiytiaiOT nyT0M CMeinuBaHHH (A) no KpanHen Mepe ο,π,ηογο nHpeTpoH,ii,ajibHoro HHceKTHiļH.n.a, bh(5-paHHOrO H3 rpynnbl, COCTOHIIļeM H3 3-$eHOKCndeH3HJi xpH3aHTeMaTa, 3-ajiJiHJi-2-MeTHJi-4-OKCOiļHKJioneHT-2-eHHJi xpH3aHTeMaTa, 3-ajīJiHJi-2-MeTHJi“4“OKCoiļHKJioneHT-2-eHHJi 2,2,3,3-TeTpaMeTHJi-LļHKJionponaHKapdoKcnJiaTa, 2- MeTnji-4-OKCO-3-(2-nponHHWJi)iiHKJioneHT-2-eHHJ! xpw3aHTeMaTa h jC -iļnaHO-3-$eHOKcn6eH3HJi xpn3aHTeMaTa, hjīh CMecb no KpanHeft Mepe ο^ηογο nHpeTpon,i];ajibHoro HHceKTMiļHfla, BHdpaHHoro H3 rpynnH, cocroflmeft H3 3- Φθηοκοη6θη3ηλ xpn3aHTeMaTa, 3-ajuiHJi-2-MeTHJi-4-OKCOiļHKJioneHT-2-eHHJi xpn3aHTeMaTa, 3-ajumj!-2-MeTHJi-4-oKcoīļHKJioneHT-2-eHHJi 2,2,3,3-TeTpaMeTHJi-LjMKJionponaHKapdoKCHJiaTa, 2- MeTHJi-4-oKCO-3-(2-nponHHHJi)iļHKJioneHT-2-eHHJi xpn3aHTeMaTa m oC -Ι1ΜβΗΟ-3-φβΗΟΚΟΗ6βΗ3ΜΛ xpH3aHTeMaTa, h no KpaiiHeft Mepe ο,ιι,ηογο nnpeTpOHflajībHoro MHceKTHiņifla, BbīdpaH-ΗΟΓΟ M3 rpynnH, ΟΟΟΤΟΗΠ1ΘΗ M3 -LiHaH0-3-$eH0KCHdeH3HJi 2,2,3,3-TeTpaMeTHJiiņīKJiDnponaHKap-doKCHJiaTa, 3,4,5,6-TeTparHflpo$TajiHMHflMeTHJi xpM3aHTeMaTa, 3- $eH0KCHdeH3HJi 3-(2,2-,ii,mxjiopbhhhji) -2,2-flHMeTHJiiļnKJionponaH-KapdoKCHJiaTa h I-3TnHn.n-2-MeTHJi-2-neHTeHHJ! xpn3aHTeMaTa, 26 β KatiecTBe aKTMBHoro KOMnopieHTa, (H) CMemaHHoro ποβθρχηοοτηο aKTMBHoro BemecTBa c nojmpHbiM pacT-BopHTejieM, co^epscamero no KpateM Mepe o^hh ajiKMJi0eH3MJicyJib(ļ)o-HaT MeTajiJia, no Kpatefi Mepe ο,π,ηογο ηθμοηηογο ποβθρχηοοτηο aKTMBHoro BemecTBa, MMeiomero ΓΙΙΒ (rM,ņpo$HJibHO-JiMno$MJibHHfi ČajiaHc) ot 10 ,ηο 18, m no KpaMHefi Mepe ο,αμη nojmpHHft pacTBopMTeJib, h (C) BOflbI,
Tan, HTotfbi ooflepKaHMe (B) b CMecH (5hjio paBHo mjim npeBbimajio co-^ep'/KaHMe (A), ηο coflepscaHMe (B) He npeBbimaeT 6% Bec. v 3aTeM pa3(5aBJieHHH nojīyneHHoft ομθοη. MHceKTHLiMflHaH npo3panHaH 3MyjibCMfl COrJiaCHO HaCTOHmeMy Μ3θ6ρβΤβΗΗΚ> ΜΜββΤ JļOCTOHHCTBO B TOM, tITO cocTOHHHe pacTBopa He μθηηθτοη ,n,a»e Kor^a OKpy>KaiomaH TeMnepaTy-pa pe3K0 μθηηθτοη. BBepx m bhh3.
Claims (11)
- LV 10159 IZGUDROJUMA FORMULA 1.Caurspīdīgo insekticīda emulsija, kas atšķiras ar to, ka tā satur: (λ) vismaz vienu piretroīdu insekticīdu, kurš izvēlēts no grupas, kas sastāv no: 3-fenoksibenzilkriznntemāta, 3-allil-2-roetil-4-oksociklopent-2-enilkrizantemāta, · 3-a11i1-2-me til-4-oksociklopent-2-enil 2,2,3,3-tetra~ metilciklopropānkarboksilēto, 2- motil-/l-oI<so-3-(2-propinil^ ciklopent-2-enilkrizan-temāta un oC-oīāno-3-fenoksibenzilkrizantemā ta, vai vismaz viena piretroīda insekticīds, kurš izvēlēts no grupas, kas sastāv no: 3- fenoksibenzilkrizantemāta, 3-allil-2-meti1-4-oksociklopent~2-enilkrizantēmāta, 3-allil-2-rnetil—4-oksociklopent-2-enil 2,2,3,3-tet-r a me t i 3. c i k 1 o pr o pā n k a r bok s i 1 ā t a 2- metil-4-okso-3~{2-propinilJ ciklopent-2-enilkrizantemata un &-ciāno-3-fenoksibenzilkriza.n temata maisījuma ar vismaz vienu piretroīdu insekticīdu,kurš izvelēts no grupas, kas sastāv no od-ciano-3-fenoksibenzil-2,2,3,3-tetrametilciklopropān-knrboksilāta, 3,4,5,6-tetrahidroftalimīdmetilkrizantcmāta, 3- fenoksibenzil-3-(2,2-dihlorvini3) -2,2-dimeticiklopro-pānkarboksilāta un -2- f l-etinil-2-metil-2-pentenilkrizantemā ta kā aktīvo vielu, (b) jauktu virsmas aktīvu vielu ar polāru šķīdinātāju ,kas. satur vismaz vienu metāla alkilbenzolsulfonātu,vismaz vienu nejonizētu virsmas aktīvu vielu, kam HLL ^hidrofīli-li-pofīleis līdzsvarsj ir no 10 līdz 18 un vismaz vienu polāru šķīdinātāju un (cj ūdeni, pie kam(B() saturs emulsijā ir vienāds vai pārsniedz (a),saturu, bet (B) saturs nepārsniedz 6 % svara.
- 2.Caurspīdīga insekticīda emulsija, kas atšķiras ar to,ka tā satur: (aJ vismaz vienu piretroīdu insekticīdu, kurš izvēlēts no grupas, kas sastāv no: 3-feroksit)enzilkrizantemāta, 3-allil-2-metil-4-oksociklo.pent-2-enilkrizantemāta, 3-allil-2-metil-4-oksociklopent-2-enil 2,2,3,3-tetra-metilciklopropānkarboksilāta, vai vismaz viena piretroīda insekticīda, kurš izvēlēts no grupas, kas sastāv no: 3-i'enoksimetilkrizantemāta, 3-allil-2-metil-4-oksociklopent-2-enilkrizantemāta, 3-allil-2-rnetil-4-oksociklopent-2-enil 2,2,3,3-tetra-metilciklopropānkarboksilā.ta maisījuma ar vismaz vienu piretroīdu insekticīdu, kurš izvēlēts no grupas, kas sastāv no: o£-ciano-3-fenoksibenzil-2,2,3, 3-tetrarnetilciklopro-pānkarboksilāta, 3,4,3,6-tetrahidroftaiimīdmetilkrizantēmāta, 3-fenoksibenzil-3-(2,2-dihlorvinil) -2,2-^dimetilciklo-propānkarboksilā ta, 1- etinil-2-metil-2-pentenilkrizantemāta, 2- metilA4-okso-3-(i2-propinil)ciklopent-2-enilkrizan-temāta un -3- LV 10159 oC-ciāno-3-fenoksibenzilkrizsntemata kā aktīvās vielas, (b) jauktu virsmas aktīvu vielu ar polāru šķīdinātāju, kas satur vismaz vienu metāla alkilbenzolsulfonātu, vismaz vienu nejonizētu virsmas aktīvu vielu, kam HLL (hid-rofīli-lipofīlais līdzsvars) ir no 10 līdz 18 un vismaz vienu polāru šķīdinātāju un (c) ūdeni, pie kam (b) saturs emulsijā ir vienāds vai pārsniedz (a) daudzumu par 6 % vai mazāk.
- 3. Caurspīdīga insekticīda emulsija, atbilstoši pa-tentformulas 1.punktam, kas atšķiras ar to, ka aktīvā viela ir vismaz viens piretroīds insekticīds,kurš izvēlēts no grupas, kas sastāv no: 3-fenoksibenzilkrizantemāta, 3-allil-2-metil-4-oksociklopent-2-enilkrizantēmēta, 3~allil-2-inetil-4-oksociklopent-2-enil 2,2,3,3-tet-rametilciklopropānkarboksilāta, 2-raet:l-4-okso-3-(j2-propinil) -ciklopent-2-enilkrizan-temāta un oc-ciano-3-fenoksiber;zilkrizantemā ta.
- 4. Caurspīdīgi insekticīda emulsija, atbilstoši pa-tentformulas 1.punktam, kas atšķiras ar to, ka svara attiecība starp vismaz vienu metāla alkilbenzolsulfonātu, vismaz vienu nejonizētu virsmas aktīvu vielu, kam HLL ļ?hidrofīli-lipofīlais līdzsvars) ir no 10 līdz 18, un vismaz vienu polāru šķīdinātāju ir 25-40 : 40-55 : 5-30.
- 5. Caurspīdīga insekticīda, emulsija, atbilstoši patent-formulas 1.punktam, kas atšķiras ar to, ka norādītais metāla alkilbenzolsulfonāts ir alkilbenzolsulfoskābes ar Cq - - 0^2 kalcija vai nātrija sāls.
- 6. Caurspīdīga insekticīda emulsija, atbilstoši pateni- -4 formulas 1.punktam, kas atšķiras ar to, ka norādītā nējoni-zētā virsmas aktīvā viela ir vismaz viens savienojums,kas izvēlēts no grupas, kas sastāv no polioksietilēstirolfeno-la, polioksietilēnalkilfenilētera.un polioksietilēnalkil-ētera..
- 7. Caurspīdīga insekticīda emulsija, atbilstoši patent-formulas 1.punktam, kas atšķiras ar to, ka norādītais polārais šķīdinātājs ir vismaz viens savienojums, kurš izvē- · lēts no grupas, kas sastāv no propilēnglikola, butilgli-kola, butildiglikola, izopropanola, etanola un metoksibuta-nola. .
- 8. Caurspīdīga insekticīda emulsija, atbilstoši patent-formulas 1.punktam, kas atšķiras ar to, k§ metāla alkil-benzolsulfonāts ir dodecilbenzolsulfonāts.
- 9. Caurspīdīga insekticīda emulsija, atbilstoši patent-formulas 1.punktam, kas atšķiras ar to, ka nejonizētā virsmas aktīvā viela ir polioksietilēnstipolfenols, kam HLL (hidrofīli-lipofīlais līdzsvarsj ir 12-16.
- 10. Caurspīdīga insekticīda emulsija, atbilstoši patent-formulas 1. punktam, kas atšķiras ar to, ka norādītais polārais šķīdinātājs ir propilēnglikols,
- 11. Paņēmiens caurspīdīgas insekticīdas emulsijas iegūšanai, kura satur: (a) vismaz vienu piretroīdu insekticīdu, kurš izvēlēts no grupas, kas sastāv no: 3-fenoksibenzilkarboksilāta, . 3-allil-2-metil-4-oksociklopent-2-enilkrizantemāta, 3-allil-2-metil-4-oksociklopent-2-enil 2,2,3,3-tet-rame tilciklopropānkarboksilāta, 2-metil-4-okso-3-(2-propinilJ'Ciklopent-2-enilkrizan~ temāta un oOciano-3-fenoksibenzilkrizantemāta vai· -5- LV 10159 vismaz viena piretroīda insekticīda, kurš izvēlēts no grupas, kas sastāv no: 3-fenoksibenzilkrizantemāta, 3-allil-2-metil-4-oksociklopent-2-enilkrizantemata, 3-allil-2-metil-4-oksociklopent-2-enil 2,2,3,3-tetra-metilciklbpropānkarboksilata. 2- metil-4-okso-3- '2-propinil ’ciklopent-2-enilkrizan- c tēmēta un c<-ciano-3-fenoksibenzilkrizantemāta maisījuma ar vismaz vienu piretroīdu insekticīdu, kurš izvēlēts no grupas, kas sastāv no: 0£-ciano-3-fenoksibenzil-2,2,3» 3-tetrametilciklopro-pānkarboksilāta, 3,4,5,6-tetrahidroftalimīdmetilkrizantemāta, 3- i'enoksibenzil-3-(2,2-dihlorvinil) -2,2-dimetilciklo-propānkarboksilāta un l-etinil-2-metil-2-pentenilkrizantemāta maisījuma kā aktīvās vielas, (Bj jauktu virsmas aktīvu vielu ar polāru šķīdinātāju, kas satur vismaz vienu metāla alkilbenzolsulfonātu, vismaz vienu nejonizētu virsmas aktīvu vielu, kam HLL ( hidrofīli-lipofīlais līdzsvars)ir no 10 līdz 18, vismaz vienu polāru šķīdinātāju un (C) ūdeni, pie kam(e)saturs emulsijā ir vienāds vai pārsniedz(A)satu-ru, bet^B) saturs nepārsniedz 6 % svara, kas atšķiras arto, ka tiek sajaukts piretroīdais insekticīds, kas ir aktīvā viela, jaukta virsmas aktīva viela ar polāru šķīdinātāju un, vajadzības gadījumā, eļļā šķīstošas piedevas, un iegūtais koncentrāts tiek atšķaidīts ar ūdeni; vai sajauc piretroīdo insekticīdu kā aktīvo vielu,· LV 10159 -č- jauktu virsmas aktīvu vielu ar polāru šķīdinātāju, eļļā šķīstošas piedevas, ko pievieno pēc vajadzības,un vielu koncentrāta masas palielināšanai, piemēram, polāru šķīdinātāju, ūdeņi vai abu maisījumu un iegūto maisījumu atšķaida ar ūdeni. -7- LV 10159 Caurspīdīga insekticīda emulsija Kopsavilkums Caurspīdīgu insekticīdu emulsiju, atbilstoši šim izgudrojumam, iegūst, sajaucot: (A) vismaz vienu piretroīdu insekticīdu, kurš izvēlēts no grupas, kas sastāv no: 3-fenoksibenzilkrizantēmēta, 3-allil-2-metil-4-oksociklopent‘-2rienilkrizan temata, 3-allil-2-metil-4-oksociklopent-2~enil 2,2,3,3-tetra-me tilciklopropānkarboksilāta, 2- metil-4-okso-3~(2-propiniļJ ciklopent-2-enilkrizan-temāts un oč-ciāno-3-fenoksiberizilkrizantemāta vai vismaz viena piretroīda insekticīda, kurš izvēlēts no grupas, kas sastāv no 3- renoksibenzilkrizantemāta, 3-allil-2-metil-4-oksociklopent-2-enilkrizentēmēta, 3-allil~2-metil-4-oksociklopent-2-enil 2,2,3,3-tetra-metilciklopropānkarboksilāta, 2- metil-4-okso-3-('2-propinil) ciklopen.t-2-enilkrizan-temāta un ci-ciāno-3-fenoksibenzilkrizantemāta maisījuma ar vismaz vienu piretroīdu insekticīdu,kurš izvēlēts no grupas, kas sastāv no: o4-ciāno-3-fenoksibenzil-2,2,3,3-tetrametilciklopropān- · karboksilāta, 3, 4,5» 6-tetra.hidrof talimīdmetilkrizan tēmēta, 3- fenoksibenzil-3-(2,2-dihlorvinil)-2,2-dimetilciklo-propānkarboksilāta un l-etinil-2-metil-2-pentenilkrizantēmēta kā aktīvas vielas, 8- (b) jauktu virsmas aktīvu vielu ar polāru šķīdinātāju, kas··· satur vismaz vienu metāla alkilbenzolsulfonātu, vismaz vienu nejonizētu virsmas aktīvu vielu, kam HLL (hidrofīli-li-pofīlais līdzsvars)ir no 10 līdz 18 un vismaz vienu polāru šķīdinātāju un (C) ūdeni tā, lai(B)saturs maisījumā būtu vienāds vai pārsniegtu (A) saturu, bet(B)saturs nepārsniegtu 6 % svara un pēc tam iegūto maisījumu atšķaidot. Caurspīdīgai insekticīdai emulsijai, kas iegūta atbilstoši šim izgudrojumam, jr priekšrocība, jo emulsija ir stabila, pat apkārtējai temperatūrai strauji paaugstinoties vai pazeminoties.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19662288 | 1988-08-05 |
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| Publication Number | Publication Date |
|---|---|
| LV10159A LV10159A (lv) | 1994-10-20 |
| LV10159B true LV10159B (en) | 1995-06-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| LVP-92-388A LV10159B (en) | 1988-08-05 | 1992-12-22 | Transparent emulsion with insecticide properties and process for preparation thereof |
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|---|---|
| US (1) | US5028623A (lv) |
| JP (1) | JP2861076B2 (lv) |
| KR (1) | KR0129761B1 (lv) |
| CN (1) | CN1027028C (lv) |
| AT (1) | AT399082B (lv) |
| AU (1) | AU610009B2 (lv) |
| BR (1) | BR8903911A (lv) |
| CA (1) | CA1308348C (lv) |
| CH (1) | CH678588A5 (lv) |
| DE (1) | DE3925765A1 (lv) |
| EG (1) | EG19230A (lv) |
| ES (1) | ES2014848A6 (lv) |
| FR (1) | FR2634974B1 (lv) |
| GB (2) | GB8916120D0 (lv) |
| GR (1) | GR1000372B (lv) |
| HU (1) | HU204390B (lv) |
| IT (1) | IT1232164B (lv) |
| LT (1) | LT3660B (lv) |
| LV (1) | LV10159B (lv) |
| MX (1) | MX17080A (lv) |
| MY (1) | MY105014A (lv) |
| NL (1) | NL8901862A (lv) |
| PL (1) | PL159501B1 (lv) |
| PT (1) | PT91363B (lv) |
| RU (1) | RU2035862C1 (lv) |
| TR (1) | TR25773A (lv) |
| YU (1) | YU47001B (lv) |
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| DE4009142A1 (de) * | 1989-03-22 | 1990-09-27 | Sumitomo Chemical Co | Insektizidzusammensetzungen |
| JP3052142B2 (ja) * | 1989-09-14 | 2000-06-12 | 住友化学工業株式会社 | 殺虫、殺ダニ組成物 |
| FR2673075B1 (fr) * | 1991-02-22 | 1998-12-31 | Rhone Poulenc Chimie | Microemulsions de pyrethrouides et leur utilisation. |
| DE4108090C2 (de) * | 1991-03-13 | 1996-11-28 | Ruetgers Ag | Imprägniermittel für Holz |
| US6527716B1 (en) | 1997-12-30 | 2003-03-04 | Altea Technologies, Inc. | Microporation of tissue for delivery of bioactive agents |
| US20030078499A1 (en) | 1999-08-12 | 2003-04-24 | Eppstein Jonathan A. | Microporation of tissue for delivery of bioactive agents |
| US7141034B2 (en) | 2000-06-08 | 2006-11-28 | Altea Therapeutics Corporation | Transdermal drug delivery device, method of making same and method of using same |
| US9918665B2 (en) | 2002-03-11 | 2018-03-20 | Nitto Denko Corporation | Transdermal porator and patch system and method for using same |
| US8116860B2 (en) | 2002-03-11 | 2012-02-14 | Altea Therapeutics Corporation | Transdermal porator and patch system and method for using same |
| US20040191290A1 (en) * | 2003-03-28 | 2004-09-30 | Redline, Inc. | Solid pest control system |
| US8016811B2 (en) | 2003-10-24 | 2011-09-13 | Altea Therapeutics Corporation | Method for transdermal delivery of permeant substances |
| CA2643653A1 (en) * | 2006-03-29 | 2007-10-04 | Basf Se | Aqueous microemulsions containing pyrethroid compounds |
| CN101455194A (zh) * | 2007-12-10 | 2009-06-17 | S.C.约翰逊父子公司 | 透明水性杀虫剂组合物 |
| JP5262352B2 (ja) * | 2008-06-30 | 2013-08-14 | 住友化学株式会社 | ピレスロイド化合物含有の水性製剤 |
| JP2011144141A (ja) * | 2010-01-15 | 2011-07-28 | Fumakilla Ltd | 殺虫剤及び噴霧殺虫器 |
| JP5641868B2 (ja) * | 2010-10-19 | 2014-12-17 | 大日本除蟲菊株式会社 | 水性殺虫液剤 |
| JP6777981B2 (ja) * | 2015-10-13 | 2020-10-28 | フマキラー株式会社 | セアカゴケグモ用駆除スプレー剤 |
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| AT186289B (de) * | 1954-09-28 | 1956-07-25 | Friedmann Kg Alex | Kugelschieber für Dampfheizungsanlagen, insbesondere für Eisenbahnfahrzeuge |
| US3492402A (en) * | 1967-02-01 | 1970-01-27 | Mclaughlin Gormley King Co | Pyrethroid insecticidal compositions containing an emulsifier and a bacterio-fungistat |
| US3683078A (en) * | 1969-10-13 | 1972-08-08 | Cpc International Inc | Transparent toxicant compositions |
| IT1006584B (it) * | 1972-06-06 | 1976-10-20 | Procter & Gamble | Composizioni insetticide |
| GB1355750A (en) * | 1972-07-17 | 1974-06-05 | Cpc International Inc | Transparent toxicant compositions |
| US4299839A (en) * | 1978-07-11 | 1981-11-10 | Kuraray Co., Ltd. | Novel pesticides and pesticidal compositions cyclopropanecarboxylates and pesticidal method |
| JPS59110604A (ja) * | 1981-01-26 | 1984-06-26 | ザンドツ・アクチェンゲゼルシャフト | 新規な農薬組成物 |
| DE3111934A1 (de) * | 1981-03-26 | 1982-10-07 | Bayer Ag, 5090 Leverkusen | Oel-in-wasser-emulsionen, verfahren zu deren herstellung und deren verwendung |
| JPS57197203A (en) * | 1981-05-27 | 1982-12-03 | Nippon Kayaku Co Ltd | Insecticidal composition |
| ZA825227B (en) * | 1981-07-22 | 1984-03-28 | Syntex Inc | Substituted pyrrolidine cardiovascular system regulators antihypertensives |
| JPS6054928A (ja) * | 1983-09-01 | 1985-03-29 | Seiko Epson Corp | 石英ガラスの製造方法 |
| DE3343092A1 (de) * | 1983-11-29 | 1985-06-05 | Bayer Ag, 5090 Leverkusen | Wasserloesliche pestizide formulierung |
| ATE86067T1 (de) * | 1984-04-09 | 1993-03-15 | American Cyanamid Co | Insektizide waessrige mikroemulsionen. |
| GB8515459D0 (en) * | 1985-06-19 | 1985-07-24 | Young Robert Co Ltd | Parasitical compositions |
| PH22025A (en) * | 1985-08-19 | 1988-05-13 | Johnson & Son Inc S C | Aqueous pyrethroid insecticidal formulations and method of increasing the stability thereof |
| DE3624910A1 (de) * | 1986-07-23 | 1988-01-28 | Hoechst Ag | Konzentrierte waessrige mikroemulsionen |
-
1989
- 1989-07-06 JP JP1176585A patent/JP2861076B2/ja not_active Expired - Lifetime
- 1989-07-17 MY MYPI89000966A patent/MY105014A/en unknown
- 1989-07-19 NL NL8901862A patent/NL8901862A/nl active Search and Examination
- 1989-07-19 GB GB898916120A patent/GB8916120D0/en active Pending
- 1989-07-24 US US07/384,143 patent/US5028623A/en not_active Expired - Lifetime
- 1989-07-25 FR FR8909981A patent/FR2634974B1/fr not_active Expired - Fee Related
- 1989-07-27 PL PL1989280785A patent/PL159501B1/pl unknown
- 1989-07-28 GB GB8917243A patent/GB2221393B/en not_active Expired - Lifetime
- 1989-07-30 EG EG36189A patent/EG19230A/xx active
- 1989-08-01 KR KR1019890011004A patent/KR0129761B1/ko not_active IP Right Cessation
- 1989-08-01 AT AT0186289A patent/AT399082B/de not_active IP Right Cessation
- 1989-08-03 BR BR898903911A patent/BR8903911A/pt not_active IP Right Cessation
- 1989-08-03 AU AU39253/89A patent/AU610009B2/en not_active Expired
- 1989-08-03 CA CA000607497A patent/CA1308348C/en not_active Expired - Fee Related
- 1989-08-03 GR GR890100492A patent/GR1000372B/el not_active IP Right Cessation
- 1989-08-03 PT PT91363A patent/PT91363B/pt not_active IP Right Cessation
- 1989-08-03 CH CH2894/89A patent/CH678588A5/de not_active IP Right Cessation
- 1989-08-03 DE DE3925765A patent/DE3925765A1/de not_active Ceased
- 1989-08-03 CN CN89106175A patent/CN1027028C/zh not_active Expired - Fee Related
- 1989-08-03 IT IT8948275A patent/IT1232164B/it active
- 1989-08-04 RU SU894614774A patent/RU2035862C1/ru active
- 1989-08-04 YU YU154889A patent/YU47001B/sh unknown
- 1989-08-04 HU HU893970A patent/HU204390B/hu not_active IP Right Cessation
- 1989-08-04 TR TR89/0577A patent/TR25773A/xx unknown
- 1989-08-04 MX MX1708089A patent/MX17080A/es unknown
- 1989-08-04 ES ES8902782A patent/ES2014848A6/es not_active Expired - Fee Related
-
1992
- 1992-12-22 LV LVP-92-388A patent/LV10159B/lv unknown
-
1993
- 1993-08-27 LT LTIP899A patent/LT3660B/lt not_active IP Right Cessation
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