NZ240027A - Detergent containing enzymes and a performance-enhancing amount of a polyhydroxy fatty acid amide - Google Patents

Info

Publication number

NZ240027A

NZ240027A NZ240027A NZ24002791A NZ240027A NZ 240027 A NZ240027 A NZ 240027A NZ 240027 A NZ240027 A NZ 240027A NZ 24002791 A NZ24002791 A NZ 24002791A NZ 240027 A NZ240027 A NZ 240027A

Authority

NZ

New Zealand

Prior art keywords

fatty acid

composition according

alkyl

polyhydroxy fatty

acid amide

Prior art date

1990-09-28

Links

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• Global Dossier
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• 239000003599 detergent Substances 0.000 title claims abstract description 165
• 235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 137
• 239000000194 fatty acid Substances 0.000 title claims abstract description 137
• 229930195729 fatty acid Natural products 0.000 title claims abstract description 137
• 150000004665 fatty acids Chemical class 0.000 title claims abstract description 130
• 102000004190 Enzymes Human genes 0.000 title claims abstract description 98
• 108090000790 Enzymes Proteins 0.000 title claims abstract description 98
• 239000000203 mixture Substances 0.000 claims abstract description 319
• -1 2-hydroxy propyl Chemical group 0.000 claims abstract description 139
• 239000000463 material Substances 0.000 claims abstract description 73
• 239000003945 anionic surfactant Substances 0.000 claims abstract description 47
• 239000002736 nonionic surfactant Substances 0.000 claims abstract description 21
• 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 19
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 14
• 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims abstract description 7
• 230000006872 improvement Effects 0.000 claims abstract description 3
• 229940088598 enzyme Drugs 0.000 claims description 95
• 239000004094 surface-active agent Substances 0.000 claims description 92
• 125000000217 alkyl group Chemical group 0.000 claims description 85
• 239000003795 chemical substances by application Substances 0.000 claims description 85
• 238000000034 method Methods 0.000 claims description 49
• 239000007788 liquid Substances 0.000 claims description 45
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 44
• 102000004882 Lipase Human genes 0.000 claims description 38
• 108090001060 Lipase Proteins 0.000 claims description 38
• 239000004367 Lipase Substances 0.000 claims description 37
• KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 37
• 235000019421 lipase Nutrition 0.000 claims description 37
• 150000001875 compounds Chemical class 0.000 claims description 36
• 108091005804 Peptidases Proteins 0.000 claims description 32
• 239000004365 Protease Substances 0.000 claims description 25
• 229910052739 hydrogen Inorganic materials 0.000 claims description 25
• WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 24
• 239000008103 glucose Substances 0.000 claims description 23
• 239000001257 hydrogen Substances 0.000 claims description 23
• 235000000346 sugar Nutrition 0.000 claims description 23
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
• WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 22
• 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 21
• 229940040461 lipase Drugs 0.000 claims description 21
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 20
• 150000001768 cations Chemical group 0.000 claims description 18
• 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 18
• OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 16
• GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 16
• 150000008051 alkyl sulfates Chemical class 0.000 claims description 16
• 239000007859 condensation product Substances 0.000 claims description 16
• 108010084185 Cellulases Proteins 0.000 claims description 14
• 102000005575 Cellulases Human genes 0.000 claims description 14
• GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 14
• 108010065511 Amylases Proteins 0.000 claims description 12
• 102000013142 Amylases Human genes 0.000 claims description 12
• 150000001720 carbohydrates Chemical class 0.000 claims description 12
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
• 102000035195 Peptidases Human genes 0.000 claims description 11
• 108010059892 Cellulase Proteins 0.000 claims description 10
• 102000003992 Peroxidases Human genes 0.000 claims description 10
• 125000003342 alkenyl group Chemical group 0.000 claims description 10
• 235000019418 amylase Nutrition 0.000 claims description 10
• 230000015572 biosynthetic process Effects 0.000 claims description 10
• 239000002270 dispersing agent Substances 0.000 claims description 10
• 238000002360 preparation method Methods 0.000 claims description 9
• 229940025131 amylases Drugs 0.000 claims description 8
• 229940106157 cellulase Drugs 0.000 claims description 8
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
• 239000000126 substance Substances 0.000 claims description 8
• 150000002016 disaccharides Chemical class 0.000 claims description 7
• 230000002708 enhancing effect Effects 0.000 claims description 7
• CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 claims description 6
• 108700020962 Peroxidase Proteins 0.000 claims description 5
• 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 5
• 150000004676 glycans Chemical class 0.000 claims description 5
• 150000002772 monosaccharides Chemical class 0.000 claims description 5
• 229920001282 polysaccharide Polymers 0.000 claims description 5
• 239000005017 polysaccharide Substances 0.000 claims description 5
• 239000012736 aqueous medium Substances 0.000 claims description 4
• 239000012530 fluid Substances 0.000 claims description 4
• 125000001424 substituent group Chemical group 0.000 claims description 4
• KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 4
• UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 claims description 3
• 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims description 3
• 241000223198 Humicola Species 0.000 claims description 2
• 108091005658 Basic proteases Proteins 0.000 claims 2
• GVGLGOZIDCSQPN-PVHGPHFFSA-N Heroin Chemical compound O([C@H]1[C@H](C=C[C@H]23)OC(C)=O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4OC(C)=O GVGLGOZIDCSQPN-PVHGPHFFSA-N 0.000 claims 1
• 229920000805 Polyaspartic acid Polymers 0.000 claims 1
• 108010020346 Polyglutamic Acid Proteins 0.000 claims 1
• 229960002069 diamorphine Drugs 0.000 claims 1
• 108010064470 polyaspartate Proteins 0.000 claims 1
• 229920002643 polyglutamic acid Polymers 0.000 claims 1
• HEVUDNOESBVZAL-UHFFFAOYSA-M sodium;2,3-dihydroxybutanedioic acid;4-hydroxy-4-oxobutanoate Chemical compound [Na+].OC(=O)CCC([O-])=O.OC(=O)C(O)C(O)C(O)=O HEVUDNOESBVZAL-UHFFFAOYSA-M 0.000 claims 1
• 239000002689 soil Substances 0.000 description 67
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 57
• 238000006243 chemical reaction Methods 0.000 description 45
• 150000003839 salts Chemical class 0.000 description 42
• 125000004432 carbon atom Chemical group C* 0.000 description 40
• 239000000047 product Substances 0.000 description 35
• 239000007844 bleaching agent Substances 0.000 description 32
• 239000000243 solution Substances 0.000 description 29
• HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 27
• RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 27
• 229920005646 polycarboxylate Polymers 0.000 description 27
• 239000011734 sodium Substances 0.000 description 27
• 239000002253 acid Substances 0.000 description 26
• 229910052708 sodium Inorganic materials 0.000 description 26
• CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 24
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 23
• 239000003054 catalyst Substances 0.000 description 22
• QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 21
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 21
• 238000009472 formulation Methods 0.000 description 21
• 235000001727 glucose Nutrition 0.000 description 21
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 21
• 235000020357 syrup Nutrition 0.000 description 21
• 239000006188 syrup Substances 0.000 description 21
• BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 20
• 150000001412 amines Chemical class 0.000 description 20
• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 19
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• 125000000129 anionic group Chemical group 0.000 description 19
• 238000004140 cleaning Methods 0.000 description 19
• 238000005406 washing Methods 0.000 description 19
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• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 18
• 240000008042 Zea mays Species 0.000 description 18
• 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 18
• 235000002017 Zea mays subsp mays Nutrition 0.000 description 18
• 235000005822 corn Nutrition 0.000 description 18
• 229910052700 potassium Inorganic materials 0.000 description 18
• 229920003171 Poly (ethylene oxide) Polymers 0.000 description 17
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• 239000004615 ingredient Substances 0.000 description 17
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• 230000002209 hydrophobic effect Effects 0.000 description 15
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• 230000008021 deposition Effects 0.000 description 12
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• 229910000029 sodium carbonate Inorganic materials 0.000 description 12
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• 239000002904 solvent Substances 0.000 description 12
• BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 11
• 125000002947 alkylene group Chemical group 0.000 description 11
• 229910000323 aluminium silicate Inorganic materials 0.000 description 11
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• 239000007864 aqueous solution Substances 0.000 description 11
• 239000004744 fabric Substances 0.000 description 11
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• 229910052698 phosphorus Inorganic materials 0.000 description 1
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• 229940070721 polyacrylate Drugs 0.000 description 1
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• 229940093430 polyethylene glycol 1500 Drugs 0.000 description 1
• 229920001522 polyglycol ester Polymers 0.000 description 1
• 229920001444 polymaleic acid Polymers 0.000 description 1
• 239000003505 polymerization initiator Substances 0.000 description 1
• 230000000379 polymerizing effect Effects 0.000 description 1
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• AVTYONGGKAJVTE-OLXYHTOASA-L potassium L-tartrate Chemical compound [K+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O AVTYONGGKAJVTE-OLXYHTOASA-L 0.000 description 1
• 229910000027 potassium carbonate Inorganic materials 0.000 description 1
• 235000011181 potassium carbonates Nutrition 0.000 description 1
• 239000001508 potassium citrate Substances 0.000 description 1
• QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
• 159000000001 potassium salts Chemical class 0.000 description 1
• LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 description 1
• 239000001472 potassium tartrate Substances 0.000 description 1
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• 230000002265 prevention Effects 0.000 description 1
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
• 230000002035 prolonged effect Effects 0.000 description 1
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• 238000005086 pumping Methods 0.000 description 1
• 239000012264 purified product Substances 0.000 description 1
• DNXIASIHZYFFRO-UHFFFAOYSA-N pyrazoline Chemical compound C1CN=NC1 DNXIASIHZYFFRO-UHFFFAOYSA-N 0.000 description 1
• 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
• 150000004023 quaternary phosphonium compounds Chemical class 0.000 description 1
• 238000005514 radiochemical analysis Methods 0.000 description 1
• 239000012429 reaction media Substances 0.000 description 1
• 238000001953 recrystallisation Methods 0.000 description 1
• 230000000717 retained effect Effects 0.000 description 1
• 238000005070 sampling Methods 0.000 description 1
• 229940071207 sesquicarbonate Drugs 0.000 description 1
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• ODBPOHVSVJZQRX-UHFFFAOYSA-M sodium;[2-[2-[bis(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]methyl-hydroxyphosphinate Chemical compound [Na+].OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)([O-])=O ODBPOHVSVJZQRX-UHFFFAOYSA-M 0.000 description 1
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• 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
• 125000005480 straight-chain fatty acid group Chemical group 0.000 description 1
• 125000005504 styryl group Chemical group 0.000 description 1
• 125000000547 substituted alkyl group Chemical group 0.000 description 1
• 238000006467 substitution reaction Methods 0.000 description 1
• 239000001384 succinic acid Substances 0.000 description 1
• 238000000967 suction filtration Methods 0.000 description 1
• DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical compound OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
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• 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
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• 229940042055 systemic antimycotics triazole derivative Drugs 0.000 description 1
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• 230000002277 temperature effect Effects 0.000 description 1
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• 150000003512 tertiary amines Chemical class 0.000 description 1
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• MSLRPWGRFCKNIZ-UHFFFAOYSA-J tetrasodium;hydrogen peroxide;dicarbonate Chemical compound [Na+].[Na+].[Na+].[Na+].OO.OO.OO.[O-]C([O-])=O.[O-]C([O-])=O MSLRPWGRFCKNIZ-UHFFFAOYSA-J 0.000 description 1
• 239000002562 thickening agent Substances 0.000 description 1
• QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
• 125000004306 triazinyl group Chemical group 0.000 description 1
• 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
• 125000005457 triglyceride group Chemical group 0.000 description 1
• TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical compound [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 description 1
• JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
• UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
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• 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
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• HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
• 229940038773 trisodium citrate Drugs 0.000 description 1
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• RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
• 235000019801 trisodium phosphate Nutrition 0.000 description 1
• 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
• WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
• GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
• 238000001665 trituration Methods 0.000 description 1
• OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
• 125000001493 tyrosinyl group Chemical group [H]OC1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 description 1
• 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
• 238000005292 vacuum distillation Methods 0.000 description 1
• 238000001291 vacuum drying Methods 0.000 description 1
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