NO885363D0 - Fremgangsmaate for fremstilling av en baaret metallocen-alumolsankatalysator for gassfasepolymerisasjon. - Google Patents

Fremgangsmaate for fremstilling av en baaret metallocen-alumolsankatalysator for gassfasepolymerisasjon.

Info

Publication number
NO885363D0
NO885363D0 NO885363A NO885363A NO885363D0 NO 885363 D0 NO885363 D0 NO 885363D0 NO 885363 A NO885363 A NO 885363A NO 885363 A NO885363 A NO 885363A NO 885363 D0 NO885363 D0 NO 885363D0
Authority
NO
Norway
Prior art keywords
gas phase
phase polymerization
silica gel
alumoxane
catalyst
Prior art date
Application number
NO885363A
Other languages
English (en)
Other versions
NO885363L (no
Inventor
Main Chang
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22463278&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NO885363(D0) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of NO885363D0 publication Critical patent/NO885363D0/no
Publication of NO885363L publication Critical patent/NO885363L/no

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/622Component covered by group C08F4/62 with an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
NO88885363A 1987-12-17 1988-12-01 Fremgangsmaate for fremstilling av en baaret metallocen-alumolsankatalysator for gassfasepolymerisasjon. NO885363L (no)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US13441387A 1987-12-17 1987-12-17

Publications (2)

Publication Number Publication Date
NO885363D0 true NO885363D0 (no) 1988-12-01
NO885363L NO885363L (no) 1989-06-19

Family

ID=22463278

Family Applications (1)

Application Number Title Priority Date Filing Date
NO88885363A NO885363L (no) 1987-12-17 1988-12-01 Fremgangsmaate for fremstilling av en baaret metallocen-alumolsankatalysator for gassfasepolymerisasjon.

Country Status (18)

Country Link
US (1) US4912075A (no)
EP (1) EP0323716B1 (no)
JP (1) JP2816469B2 (no)
KR (1) KR960005917B1 (no)
AT (1) ATE80167T1 (no)
AU (1) AU621320B2 (no)
BR (1) BR8806673A (no)
CA (1) CA1327347C (no)
DE (1) DE3874310T2 (no)
DK (1) DK677488A (no)
ES (1) ES2034269T3 (no)
FI (1) FI885570A (no)
HU (1) HUT48912A (no)
IL (1) IL88494A (no)
NO (1) NO885363L (no)
PL (1) PL276458A1 (no)
PT (1) PT89232B (no)
YU (1) YU228288A (no)

Families Citing this family (159)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4937217A (en) * 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US4925821A (en) * 1987-12-17 1990-05-15 Exxon Chemical Patents Inc. Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst
US5008228A (en) * 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US5086025A (en) * 1988-03-29 1992-02-04 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US4935397A (en) * 1988-09-28 1990-06-19 Exxon Chemical Patents Inc. Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same
US5006500A (en) * 1988-10-27 1991-04-09 Exxon Chemical Patents Inc. Olefin polymerization catalyst from trialkylaluminum mixture, silica gel and a metallocene
US4914253A (en) * 1988-11-04 1990-04-03 Exxon Chemical Patents Inc. Method for preparing polyethylene wax by gas phase polymerization
FI85498C (fi) * 1988-11-08 1992-04-27 Neste Oy Foerfarande foer polymerisering och kopolymerisering av alfa-olefiner och ett i foerfarandet anvaent katalysatorsystem.
US4904631A (en) * 1988-11-08 1990-02-27 Exxon Chemical Patents, Inc. Supported vanadium catalyst for polymerization of olefins and a process of preparing and using the same
JP2607152B2 (ja) * 1989-08-15 1997-05-07 チッソ株式会社 オレフィン重合体の製造方法
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
DE4004477A1 (de) * 1990-02-14 1991-08-22 Schering Ag Verfahren zur herstellung von loesungen oligomerer methylaluminoxane
TW218884B (no) 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US6143854A (en) 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5393851A (en) * 1992-05-26 1995-02-28 Fina Technology, Inc. Process for using metallocene catalyst in a continuous reactor system
US5238892A (en) * 1992-06-15 1993-08-24 Exxon Chemical Patents Inc. Supported catalyst for 1-olefin(s) (co)polymerization
CA2141616A1 (en) * 1992-08-05 1994-02-17 Gregory G. Hlatky Gas phase polymerization of ethylene and c to c olefins
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5420220A (en) * 1993-03-25 1995-05-30 Mobil Oil Corporation LLDPE films
US5602067A (en) * 1992-12-28 1997-02-11 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
CA2152937A1 (en) 1992-12-28 1994-07-07 Subrahmanyam Cheruvu Linear low density polyethylene film
US5340840A (en) * 1993-03-18 1994-08-23 The Dow Chemical Company Foam structures of ethylenic polymer material having enhanced toughness and elasticity and process for making
WO1994025495A1 (en) 1993-05-20 1994-11-10 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
EP0739360B1 (en) 1993-09-17 2001-04-11 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5455741A (en) * 1993-10-26 1995-10-03 Pulse Engineering, Inc. Wire-lead through hole interconnect device
JPH09504825A (ja) * 1993-11-08 1997-05-13 モービル・オイル・コーポレーション オレフィン重合及び共重合用触媒
US5614456A (en) * 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
SG85578A1 (en) * 1993-11-18 2002-01-15 Mobil Oil Corp Process for the polymerization or copolymerization of ethylene
US6391817B1 (en) 1993-12-28 2002-05-21 Exxonmobil Chemical Patents Inc. Method for producing a prepolymerized catalyst
US5629253A (en) * 1994-04-26 1997-05-13 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
DE59503827D1 (de) * 1994-06-03 1998-11-12 Pcd Polymere Ag Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen
WO1996000243A1 (en) * 1994-06-24 1996-01-04 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
DE4431644A1 (de) * 1994-08-01 1996-03-07 Danubia Petrochem Deutschland Katalysatorsystem und Verfahren zur Polymerisation von Olefinen
US5972822A (en) * 1994-08-02 1999-10-26 The Dow Chemical Company Biscyclopentadienyldiene complex containing addition polymerization catalysts
TW454020B (en) * 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
TW369547B (en) * 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
US5525678A (en) * 1994-09-22 1996-06-11 Mobil Oil Corporation Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
US6043180A (en) * 1994-11-17 2000-03-28 The Dow Chemical Company Supported catalyst component, supported catalyst, their preparation, and addition polymerization process
DE69600892T2 (de) * 1995-02-21 1999-04-01 Mitsubishi Chem Corp Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren
US5882750A (en) * 1995-07-03 1999-03-16 Mobil Oil Corporation Single reactor bimodal HMW-HDPE film resin with improved bubble stability
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
ES2178712T3 (es) 1995-08-10 2003-01-01 Exxonmobil Chem Patents Inc Alumoxano estabilizado por metalocenos.
US6486089B1 (en) 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
US5854362A (en) * 1995-12-11 1998-12-29 The Dow Chemical Company Supported biscyclopentadienyl metal complexes
DE19606167A1 (de) 1996-02-20 1997-08-21 Basf Ag Geträgerte Katalysatorsysteme
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
ES2129323B1 (es) * 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
EP0912244A4 (en) * 1996-07-15 2001-09-12 Mobil Oil Corp BIMETALLIC CATALYST PRE-PROCESSED BY COMONOMER FOR BLOW MOLDING AND FOR FILM APPLICATIONS
US6759499B1 (en) 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
DE69726821T2 (de) * 1996-10-30 2004-10-21 Repsol Quimica Sa Katalysatorsysteme für die Polymerisation und die Copolymerisation von Alpha-Olefinen
US6635778B1 (en) 1996-10-30 2003-10-21 Repsol Quimica S.A. Catalysts systems for the polymerization and copolymerization of alpha-olefins
ES2154017T3 (es) 1996-10-31 2001-03-16 Repsol Quimica Sa Sistemas cataliticos para la polimerizacion y copolimerizacion de alfa-olefinas.
US6005463A (en) * 1997-01-30 1999-12-21 Pulse Engineering Through-hole interconnect device with isolated wire-leads and component barriers
EP0856524A1 (en) 1997-02-01 1998-08-05 Repsol Quimica S.A. Heterogeneous catalyst components for olefins polymerization, preparation process and use thereof
SK135199A3 (en) * 1997-04-04 2000-05-16 Dow Chemical Co Catalyst system for high yield synthesis of polyolefins
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
DE19732804A1 (de) 1997-07-30 1999-02-04 Bayer Ag Katalysatoren auf Basis von Fulven-Metallkomplexen
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US7232871B2 (en) * 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6635715B1 (en) 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US7026404B2 (en) * 1997-08-12 2006-04-11 Exxonmobil Chemical Patents Inc. Articles made from blends made from propylene ethylene polymers
DE69829423T2 (de) 1997-08-21 2006-04-13 Sumitomo Chemical Co., Ltd. Modifizierte Teilchen, daraus hergestellter Träger, daraus hergestellte Polymerisationskatalysatorkomponente sowie Polymerisationskatalysator und Verfahren zur Herstellung von Olefinpolymeren
US5990035A (en) * 1997-10-21 1999-11-23 Koeppl; Alexander Polymerization catalyst systems, their preparation, and use
WO1999024445A1 (de) 1997-11-07 1999-05-20 Bayer Aktiengesellschaft Verfahren zur herstellung von fulven-metallkomplexen
JP4440355B2 (ja) 1998-03-25 2010-03-24 住友化学株式会社 改質された粒子、それよりなる担体、それよりなるオレフィン重合用触媒成分、それを用いてなるオレフィン重合用触媒、およびオレフィン重合体の製造方法
US7148173B2 (en) 1998-04-27 2006-12-12 Repsol Quimica, S.A. Catalytic systems for the polymerization and copolymerization of alpha-olefins
DE19826743A1 (de) 1998-06-16 1999-12-23 Bayer Ag Verfahren zur Herstellung von geträgerten Polymerisationskatalysatorsystemen und Verwendung dieser zur Homo- und Copolymerisation ungesättigter Monomere
EP1098934A1 (en) * 1998-07-01 2001-05-16 Exxon Chemical Patents Inc. Elastic blends comprising crystalline polymer and crystallizable polymers of propylene
WO2000012565A1 (en) * 1998-08-26 2000-03-09 Exxon Chemical Patents Inc. Highly active supported catalyst compositions
KR100430438B1 (ko) 1998-10-22 2004-07-19 대림산업 주식회사 담지메탈로센촉매,그제조방법및이를이용한폴리올레핀의중합방법
EP1159351A1 (en) 1998-12-08 2001-12-05 The Dow Chemical Company Melt-bondable polypropylene/ethylene polymer fiber and composition for making the same
DE19857292A1 (de) 1998-12-11 2000-06-15 Targor Gmbh Talkumverstärkte Polypropylen-Formmasse mit hoher Schlagzähigkeit
DE19860174A1 (de) 1998-12-24 2000-06-29 Clariant Gmbh Polymeroxidate und ihre Verwendung
US6346586B1 (en) * 1999-10-22 2002-02-12 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US7220804B1 (en) 2000-10-13 2007-05-22 Univation Technologies, Llc Method for preparing a catalyst system and its use in a polymerization process
US6914027B2 (en) * 2000-12-01 2005-07-05 Univation Technologies, Llc Polymerization reactor operability using static charge modifier agents
JP5156167B2 (ja) 2001-04-12 2013-03-06 エクソンモービル・ケミカル・パテンツ・インク プロピレン−エチレンポリマー及び製造法
DE10151914A1 (de) * 2001-10-20 2003-04-30 Merck Patent Gmbh Chemische Modifizierung von Partikeloberflächen durch Vernetzung
WO2003048213A1 (en) * 2001-11-30 2003-06-12 Exxonmobil Chemical Patents, Inc. Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use
WO2004094487A1 (en) 2003-03-21 2004-11-04 Dow Global Technologies, Inc. Morphology controlled olefin polymerization process
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US8722787B2 (en) 2003-08-25 2014-05-13 Dow Global Technologies Llc Coating composition and articles made therefrom
US8357749B2 (en) * 2003-08-25 2013-01-22 Dow Global Technologies Llc Coating composition and articles made therefrom
US8349929B2 (en) * 2003-08-25 2013-01-08 Dow Global Technologies Llc Coating composition and articles made therefrom
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
US7803865B2 (en) 2003-08-25 2010-09-28 Dow Global Technologies Inc. Aqueous dispersion, its production method, and its use
US7763676B2 (en) 2003-08-25 2010-07-27 Dow Global Technologies Inc. Aqueous polymer dispersions and products from those dispersions
US8158711B2 (en) * 2003-08-25 2012-04-17 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US8779053B2 (en) 2003-08-25 2014-07-15 Dow Global Technologies Llc Coating compositions
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
WO2006044058A1 (en) * 2004-10-12 2006-04-27 Exxonmobil Chemical Patents Inc. Trialkylaluminum treated supports
US8093341B2 (en) * 2004-10-28 2012-01-10 Dow Global Technologies Llc Method of controlling a polymerization reactor
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
WO2007130305A2 (en) 2006-05-05 2007-11-15 Dow Global Technologies Inc. Hafnium complexes of carbazolyl substituted imidazole ligands
JP5695419B2 (ja) 2007-08-29 2015-04-08 アルベマール・コーポレーシヨン ジアルキルアルミニウム陽イオンの前駆剤から生じるアルミノキサン触媒活性剤、同物質の製造方法、ならびにオレフィンの触媒および重合におけるその用途
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
US7906588B2 (en) 2007-10-26 2011-03-15 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
KR101271055B1 (ko) * 2008-03-28 2013-06-04 에스케이종합화학 주식회사 메탈로센 담지촉매 조성물 및 이를 이용한 폴리올레핀의제조방법
EP2172490A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Controlled polymerisation process
WO2010080871A1 (en) 2009-01-08 2010-07-15 Univation Technologies, Llc Additive for gas phase polymerization processes
BRPI1007430B1 (pt) 2009-01-08 2020-05-12 Univation Technologies, Llc Processo de polimerização de poliolefina
DE102009020090A1 (de) 2009-05-06 2010-11-11 Lanxess Deutschland Gmbh Reduktion des Einflusses der Wasseraufnahme auf die elektrische Leitfähigkeit von elektrisch leitfähigen Polyamid-Formmassen
US8309749B2 (en) 2009-06-11 2012-11-13 W R Grace & Co-Conn Process of making aluminoxane and catalysts containing thus prepared aluminoxane
RU2011152483A (ru) 2009-07-23 2013-06-27 Юнивейшн Текнолоджиз, Ллк Реакционная система для полимеризации
WO2011078923A1 (en) 2009-12-23 2011-06-30 Univation Technologies, Llc Methods for producing catalyst systems
EP2357035A1 (en) 2010-01-13 2011-08-17 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
EP2536767B1 (en) 2010-02-18 2015-05-06 Univation Technologies, LLC Methods for operating a polymerization reactor
ES2693720T3 (es) 2010-02-22 2018-12-13 Univation Technologies, Llc Sistemas catalíticos y métodos para usar los mismos para producir productos poliolefínicos
EP2558531B1 (en) 2010-04-13 2017-02-15 Univation Technologies, LLC Polymer blends and films made therefrom
EP2383298A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
EP2383301A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
US20130115708A1 (en) 2010-07-16 2013-05-09 Univation Technologies, Llc Systems and Methods for Measuring Particle Accumulation on Reactor Surfaces
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
CN103140506B (zh) * 2010-09-29 2015-06-10 Lg化学株式会社 制备负载型复合金属茂催化剂的方法
BR112013013384B1 (pt) 2010-11-29 2021-03-16 Ineos Sales (Uk) Limited processo de controle de polimerização
WO2012082674A1 (en) 2010-12-17 2012-06-21 Univation Technologies, Llc Systems and methods for recovering hydrocarbons from a polyolefin purge gas product
BR112013016116B1 (pt) 2010-12-22 2020-04-28 Univation Tech Llc processo de polimerização e sistema catalisador
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
WO2013028283A1 (en) 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
SG11201400866RA (en) 2011-10-17 2014-10-30 Ineos Europe Ag Polymer degassing process control
US9181371B2 (en) 2011-11-08 2015-11-10 Univation Technologies, Llc Methods for producing polyolefins with catalyst systems
CA2863694C (en) 2012-03-05 2020-11-03 Univation Technologies, Llc Methods for making catalyst compositions and polymer products produced therefrom
BR112015011215B1 (pt) 2012-11-26 2018-11-21 Braskem S.A. Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metalocenosuportado e polímero de etileno com distribuição de massa molar ampla ou bimodal
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
EP2922925B1 (en) 2012-12-28 2019-12-04 Dow Global Technologies LLC Coating compositions
ES2918582T3 (es) 2012-12-28 2022-07-19 Univation Tech Llc Catalizador soportado con fluidez mejorada
CN110551424B (zh) 2012-12-28 2022-07-29 陶氏环球技术有限责任公司 涂料组合物和由其制成的物品
WO2014123598A1 (en) 2013-02-07 2014-08-14 Univation Technologies, Llc Preparation of polyolefin
WO2014149361A1 (en) 2013-03-15 2014-09-25 Univation Technologies, Llc Ligands for catalysts
WO2014143421A1 (en) 2013-03-15 2014-09-18 Univation Technologies, Llc Tridentate nitrogen based ligands for olefin polymerisation catalysts
CN107266402A (zh) 2013-06-05 2017-10-20 尤尼威蒂恩技术有限责任公司 保护酚基
US10208139B2 (en) 2014-08-19 2019-02-19 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
US10233270B2 (en) 2014-08-19 2019-03-19 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
US10189917B2 (en) 2014-08-19 2019-01-29 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
CN107107433B (zh) 2015-01-21 2019-09-13 尤尼威蒂恩技术有限责任公司 用于聚烯烃中的凝胶减少的方法
WO2016118599A1 (en) 2015-01-21 2016-07-28 Univation Technologies, Llc Methods for controlling polymer chain scission
JP6621845B2 (ja) 2015-05-08 2019-12-18 エクソンモービル ケミカル パテンツ インコーポレイテッド 重合方法
JP7017413B2 (ja) 2015-05-29 2022-02-08 ダウ グローバル テクノロジーズ エルエルシー ポリオレフィンを生成するためのプロセス
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
CA3038149C (en) 2016-09-27 2023-08-22 Univation Technologies, Llc Method for long chain branching control in polyethylene production
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
CA3052770C (en) 2017-02-07 2021-09-07 Exxonmobil Chemical Patents Inc. Processes for reducing the loss of catalyst activity of a ziegler-natta catalyst
US11193008B2 (en) 2017-04-10 2021-12-07 Exxonmobil Chemical Patents Inc. Methods for making polyolefin polymer compositions
US10947329B2 (en) 2017-05-10 2021-03-16 Univation Technologies, Llc Catalyst systems and processes for using the same
WO2019118073A1 (en) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization process
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
CN112055720B (zh) 2018-05-02 2022-11-22 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
US11447587B2 (en) 2018-05-02 2022-09-20 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2022020025A1 (en) 2020-07-22 2022-01-27 Exxonmobil Chemical Patents Inc. Polyolefin compositions and articles thereof
CN116635431A (zh) * 2020-11-23 2023-08-22 埃克森美孚化学专利公司 Smao的无甲苯制备:在tma存在下加热以提高活性
EP4259669A1 (en) 2020-12-08 2023-10-18 ExxonMobil Chemical Patents Inc. High density polyethylene compositions with long-chain branching

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3300458A (en) * 1963-08-19 1967-01-24 Union Carbide Corp Continuous processes for the production of ethylene polymers and catalysts suitable therefor
DE3240382A1 (de) * 1982-11-02 1984-05-03 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von gefuellten polyolefinen
DE3240383A1 (de) * 1982-11-02 1984-05-03 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von oligomeren aluminoxanen
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4508843A (en) * 1983-08-08 1985-04-02 Exxon Research & Engineering Co. Supported polyolefin catalyst for the polymerization of ethylene under high temperatures
DE3424697C2 (de) * 1984-07-05 1999-07-08 Targor Gmbh Verfahren zur Polymerisation von Ethylen oder von Mischungen von Ethylen mit anderen 1-Olefinen
US4568658A (en) * 1984-09-05 1986-02-04 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefins at low reactants partial pressures
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4665208A (en) * 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
CA1304746C (en) * 1987-08-31 1992-07-07 The Dow Chemical Company Preparation of polyhydrocarbylaluminoxanes
EP0315234A1 (en) * 1987-10-26 1989-05-10 Texas Alkyls, Inc. Process for preparation of aluminoxanes
US4937301A (en) * 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US4937217A (en) * 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst

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KR890009985A (ko) 1989-08-05
EP0323716B1 (en) 1992-09-02
KR960005917B1 (ko) 1996-05-03
ES2034269T3 (es) 1993-04-01
IL88494A (en) 1992-06-21
AU2596188A (en) 1989-06-29
HUT48912A (en) 1989-07-28
DE3874310D1 (de) 1992-10-08
YU228288A (en) 1990-10-31
FI885570A0 (fi) 1988-11-30
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IL88494A0 (en) 1989-06-30
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AU621320B2 (en) 1992-03-12
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NO885363L (no) 1989-06-19
ATE80167T1 (de) 1992-09-15
US4912075A (en) 1990-03-27
PT89232A (pt) 1989-12-29
PL276458A1 (en) 1989-07-24
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