NO315946B1 - Akrylkopolymersammensetning og fuktighetsherdbar tetningsmiddelformuleringinneholdende en slik sammensetning - Google Patents
Akrylkopolymersammensetning og fuktighetsherdbar tetningsmiddelformuleringinneholdende en slik sammensetning Download PDFInfo
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- NO315946B1 NO315946B1 NO19962639A NO962639A NO315946B1 NO 315946 B1 NO315946 B1 NO 315946B1 NO 19962639 A NO19962639 A NO 19962639A NO 962639 A NO962639 A NO 962639A NO 315946 B1 NO315946 B1 NO 315946B1
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- Norway
- Prior art keywords
- component
- acrylic copolymer
- copolymer composition
- sealant formulation
- molar parts
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 124
- 239000000565 sealant Substances 0.000 title claims abstract description 90
- 229920006243 acrylic copolymer Polymers 0.000 title claims abstract description 59
- 238000009472 formulation Methods 0.000 title claims description 75
- 239000000178 monomer Substances 0.000 claims abstract description 90
- 239000000758 substrate Substances 0.000 claims abstract description 14
- 239000011521 glass Substances 0.000 claims abstract description 12
- 239000003431 cross linking reagent Substances 0.000 claims description 29
- 229920001577 copolymer Polymers 0.000 claims description 24
- 238000007334 copolymerization reaction Methods 0.000 claims description 20
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 18
- 150000001282 organosilanes Chemical class 0.000 claims description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 17
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 17
- 229910000077 silane Inorganic materials 0.000 claims description 17
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 11
- 238000011084 recovery Methods 0.000 claims description 11
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical group S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 claims description 11
- 239000012986 chain transfer agent Substances 0.000 claims description 10
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- -1 methyl ethyl Chemical group 0.000 claims description 8
- 230000002028 premature Effects 0.000 claims description 8
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 238000012360 testing method Methods 0.000 claims description 7
- 125000002947 alkylene group Chemical group 0.000 claims description 6
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- 239000004570 mortar (masonry) Substances 0.000 claims description 5
- 239000011541 reaction mixture Substances 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 230000007062 hydrolysis Effects 0.000 claims description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 150000004756 silanes Chemical class 0.000 claims description 4
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 3
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims 1
- 125000005670 ethenylalkyl group Chemical group 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 abstract description 18
- 239000000463 material Substances 0.000 abstract description 9
- 238000003860 storage Methods 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 description 27
- 238000007792 addition Methods 0.000 description 26
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000003999 initiator Substances 0.000 description 15
- 229920000642 polymer Polymers 0.000 description 15
- 238000004132 cross linking Methods 0.000 description 12
- 150000003254 radicals Chemical class 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 239000008096 xylene Substances 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 8
- 229920002554 vinyl polymer Polymers 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000002318 adhesion promoter Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 238000007789 sealing Methods 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 5
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003974 emollient agent Substances 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 229920006158 high molecular weight polymer Polymers 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 150000002432 hydroperoxides Chemical class 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
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- 230000009257 reactivity Effects 0.000 description 2
- 239000006254 rheological additive Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 239000013008 thixotropic agent Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical class CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 description 1
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 1
- XDQWJFXZTAWJST-UHFFFAOYSA-N 3-triethoxysilylpropyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C=C XDQWJFXZTAWJST-UHFFFAOYSA-N 0.000 description 1
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical group SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
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- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
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- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- VXQOFNJETKUWLT-UHFFFAOYSA-N [dimethoxy(methyl)silyl]methanethiol Chemical compound CO[Si](C)(CS)OC VXQOFNJETKUWLT-UHFFFAOYSA-N 0.000 description 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
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- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
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- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical class CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
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- NICWAKGKDIAMOD-UHFFFAOYSA-N ethyl 3,3-bis(2-methylbutan-2-ylperoxy)butanoate Chemical compound CCOC(=O)CC(C)(OOC(C)(C)CC)OOC(C)(C)CC NICWAKGKDIAMOD-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
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- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
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- XPDGHGYGTJOTBC-UHFFFAOYSA-N methoxy(methyl)silicon Chemical compound CO[Si]C XPDGHGYGTJOTBC-UHFFFAOYSA-N 0.000 description 1
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 1
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- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
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- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
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- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000004655 tetrazenes Chemical class 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- HLOLETUOZGAKMT-UHFFFAOYSA-N trimethoxysilyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)OC(=O)C(C)=C HLOLETUOZGAKMT-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Sealing Material Composition (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17194693A | 1993-12-22 | 1993-12-22 | |
| PCT/IB1995/000016 WO1995017443A1 (en) | 1993-12-22 | 1994-12-22 | Moisture-curable modified acrylic polymer sealant composition |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO962639D0 NO962639D0 (no) | 1996-06-20 |
| NO962639L NO962639L (no) | 1996-07-30 |
| NO315946B1 true NO315946B1 (no) | 2003-11-17 |
Family
ID=22625745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19962639A NO315946B1 (no) | 1993-12-22 | 1996-06-20 | Akrylkopolymersammensetning og fuktighetsherdbar tetningsmiddelformuleringinneholdende en slik sammensetning |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5705561A (de) |
| EP (1) | EP0736050B1 (de) |
| JP (1) | JP3335359B2 (de) |
| KR (1) | KR100336216B1 (de) |
| CN (1) | CN1150810A (de) |
| AT (1) | ATE171959T1 (de) |
| AU (1) | AU704705B2 (de) |
| BR (1) | BR9408477A (de) |
| CA (1) | CA2179637A1 (de) |
| DE (1) | DE69413849T2 (de) |
| DK (1) | DK0736050T3 (de) |
| ES (1) | ES2127507T3 (de) |
| FI (1) | FI113660B (de) |
| NO (1) | NO315946B1 (de) |
| NZ (1) | NZ277875A (de) |
| RU (1) | RU2144045C1 (de) |
| WO (1) | WO1995017443A1 (de) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998054255A1 (fr) * | 1997-05-30 | 1998-12-03 | Shiseido, Co., Ltd. | Copolymere contenant des groupes silyles reactifs, compositions contenant ce copolymere et methode de traitement afferente |
| IT1301974B1 (it) * | 1998-07-31 | 2000-07-20 | Atochem Elf Italia | Copolimeri acrilici idrosolubili |
| US6414077B1 (en) * | 1999-07-29 | 2002-07-02 | Schnee-Morehead, Inc. | Moisture curable acrylic sealants |
| EP1277766B1 (de) * | 2001-07-20 | 2009-06-24 | Rohm And Haas Company | Polymerverbindung enthaltend Siliciumestergruppen und diese enthaltende Zusammensetzungen |
| DE10163518A1 (de) | 2001-12-21 | 2003-07-10 | Fraunhofer Ges Forschung | Protonenleitfähige Membranen/Schichten und Verfahren zu deren Herstellung |
| US6767642B2 (en) * | 2002-03-11 | 2004-07-27 | E. I. Du Pont Nemours And Company | Preparation and use of crosslinkable acrylosilane polymers containing vinyl silane monomers |
| DE10212523A1 (de) * | 2002-03-21 | 2003-10-02 | Degussa | Lufttrocknende, silanhaltige Beschichtungsmittel |
| US7074856B2 (en) * | 2002-12-20 | 2006-07-11 | The Sherwin-Williams Company | Moisture cure non-isocyanate acrylic coatings |
| US6777512B1 (en) * | 2003-02-28 | 2004-08-17 | Dow Global Technologies Inc. | Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components |
| RU2358992C2 (ru) * | 2003-06-09 | 2009-06-20 | Дау Глобал Текнолоджиз Инк. | Стабилизированные органоборановые инициаторы полимеризации и способные к полимеризации композиции |
| DE10352673A1 (de) * | 2003-11-11 | 2005-06-16 | Weiss Chemie + Technik Gmbh & Co. Kg | Einkomponentige Klebedichtmasse auf Basis einer wässrigen Polyacrylat-Dispersion sowie deren Verwendung |
| US8501886B2 (en) * | 2003-12-22 | 2013-08-06 | Dow Global Technologies Llc | Accelerated organoborane amine complex initiated polymerizable compositions |
| EP1699625B1 (de) * | 2003-12-22 | 2008-08-13 | Dow Global Technologies Inc. | Organoboran-amin-komplex initiierte, beschleunigte polymerisierbare zusammensetzungen |
| ATE367960T1 (de) * | 2004-11-16 | 2007-08-15 | Bostik Sa | Verfahren zur abdichtung von schiffsdecks |
| DE102004055450A1 (de) * | 2004-11-17 | 2006-05-18 | Degussa Ag | Feuchtigkeitshärtendes Bindemittel |
| CA2624322A1 (en) | 2005-10-07 | 2007-04-19 | Dow Global Technologies Inc. | Amido-organoborate initiator systems |
| US7524907B2 (en) * | 2006-10-12 | 2009-04-28 | Dow Global Technologies, Inc. | Accelerated organoborane initiated polymerizable compositions |
| US20080103274A1 (en) * | 2006-10-12 | 2008-05-01 | Jialanella Gary L | Accelerated organoborane initiated polymerizable compositions |
| US8207252B2 (en) * | 2007-03-07 | 2012-06-26 | Momentive Performance Materials Inc. | Moisture-curable silylated polymer resin composition |
| AU2008228842B2 (en) * | 2007-03-21 | 2014-01-16 | Avery Dennison Corporation | Pressure sensitive adhesives |
| GB0714257D0 (en) * | 2007-07-23 | 2007-08-29 | Dow Corning | Sealant for insulating glass unit |
| US8148487B2 (en) * | 2009-08-19 | 2012-04-03 | Ppg Industries Ohio, Inc. | Polysiloxane coating with hybrid copolymer |
| KR101549265B1 (ko) | 2009-08-21 | 2015-09-01 | 코오롱인더스트리 주식회사 | 봉지재용 조성물, 경화물 및 유기발광소자 |
| KR101553717B1 (ko) | 2009-08-21 | 2015-09-16 | 코오롱인더스트리 주식회사 | 봉지재용 조성물, 경화물 및 유기발광소자 |
| ES2512440T3 (es) * | 2010-05-19 | 2014-10-24 | Avery Dennison Corporation | Arquitecturas ordenadas en polímeros acrílicos |
| KR101859749B1 (ko) * | 2011-01-14 | 2018-05-21 | 애버리 데니슨 코포레이션 | 폴리머 미소구체를 함유하는 제거 가능한 조성물 |
| CA2859353A1 (en) | 2011-12-15 | 2013-06-20 | Sumi Dinkar | Moisture curable organopolysiloxane compositions |
| TWI502031B (zh) * | 2012-03-01 | 2015-10-01 | Eternal Materials Co Ltd | 抗蝕刻組成物及其應用 |
| KR101499248B1 (ko) * | 2013-01-04 | 2015-03-05 | 제일모직주식회사 | 봉지용 조성물, 이를 포함하는 장벽층 및 이를 포함하는 봉지화된 장치 |
| CN103131358B (zh) * | 2013-02-01 | 2015-09-30 | 泉州德立化工有限公司 | 一种应用于服装业代替线迹缝纫的反应型自催化粘合剂及其制备方法 |
| WO2015005220A1 (ja) * | 2013-07-11 | 2015-01-15 | セメダイン株式会社 | 導電性硬化物の製造方法及び導電性硬化物並びにパルス光硬化性組成物の硬化方法及びパルス光硬化性組成物 |
| CN104448520B (zh) * | 2014-11-17 | 2017-05-24 | 浙江万马高分子材料有限公司 | 一种聚烯烃绝缘料及其制备方法和用途 |
| WO2021126988A1 (en) * | 2019-12-19 | 2021-06-24 | Henkel IP & Holding GmbH | Moisture curable polyacrylate compositions and uses thereof |
| US11739172B2 (en) | 2020-12-17 | 2023-08-29 | 3M Innovative Properties Company | Composition including monomer with a carboxylic acid group, monomer with a hydroxyl group, and crosslinker and related articles and methods |
| EP4148073A1 (de) * | 2021-09-08 | 2023-03-15 | Hexion Inc. | Bei umgebungstemperatur vernetzbare einpack-copolymere von verzweigtem vinylester und vinylsilanherstellung und verwendung davon |
| WO2023036456A1 (en) * | 2021-09-08 | 2023-03-16 | Hexion Inc. | One pack ambient cure crosslinkable copolymers of vinyl branched ester and vinyl silane compositions and use thereof |
| CN115850607A (zh) * | 2022-10-28 | 2023-03-28 | 科顺防水科技股份有限公司 | 硅丙乳胶的制备方法和硅丙乳胶、用途 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2956044A (en) * | 1956-08-06 | 1960-10-11 | Dow Corning | Acryloxymethylsilicon polymers |
| US3203919A (en) * | 1962-09-19 | 1965-08-31 | Du Pont | Acrylic/siloxane copolymer, polysiloxane composition containing same, and article coated with the composition |
| US3453230A (en) * | 1964-12-17 | 1969-07-01 | Dow Corning | Room temperature curable acrylate rubbers |
| US3951893A (en) * | 1970-11-18 | 1976-04-20 | Johnson & Johnson | Film-forming silane crosslinked acrylate interpolymers having water-barrier properties |
| BE789223A (fr) * | 1971-09-28 | 1973-03-26 | Wacker Chemie Gmbh | Dispersions de polymeres vinyliques |
| DE2148457C3 (de) * | 1971-09-28 | 1981-12-10 | Wacker-Chemie GmbH, 8000 München | Verwendung von polymeren Bindemitteln in wäßriger Dispersion zur Herstellung von Bautenbeschichtungsmitteln |
| JPS6018707B2 (ja) * | 1974-10-09 | 1985-05-11 | 日本原子力研究所 | 防曇性被覆用硬化性樹脂組成物 |
| US4048207A (en) * | 1975-10-14 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Polymeric materials with silane end groups |
| DE2917754A1 (de) * | 1979-05-02 | 1980-11-13 | Wacker Chemie Gmbh | Hydrophile, vernetzte, modifizierte organopolysiloxane verfahren zu ihrer herstellung und ihre verwendung |
| JPS5736109A (ja) * | 1980-08-12 | 1982-02-26 | Kanegafuchi Chem Ind Co Ltd | Haisoritsudokootenguyojushi |
| JPS57179210A (en) * | 1981-04-28 | 1982-11-04 | Sunstar Giken Kk | Room temperature curing elastic composition |
| AT372101B (de) * | 1982-01-04 | 1983-09-12 | Henkel Kgaa | Fugendichtmasse |
| US4491650A (en) * | 1982-05-05 | 1985-01-01 | Essex Specialty Products, Inc. | Acrylic resin having pendant silane groups thereon, and methods of making and using the same |
| JPS5978220A (ja) * | 1982-10-26 | 1984-05-07 | Sunstar Giken Kk | 室温硬化性弾性組成物 |
| EP0169536B1 (de) * | 1984-07-26 | 1994-05-18 | Kanegafuchi Chemical Industry Co., Ltd. | Vernetzbare Polymerzusammensetzung |
| JPS61141761A (ja) * | 1984-12-12 | 1986-06-28 | Kanegafuchi Chem Ind Co Ltd | 硬化性組成物 |
| JPH01292018A (ja) * | 1988-05-19 | 1989-11-24 | Shin Etsu Chem Co Ltd | 室温硬化性樹脂組成物 |
| JPH03149277A (ja) * | 1989-11-06 | 1991-06-25 | Sekisui Chem Co Ltd | 湿気硬化型接着剤組成物 |
| JP2920302B2 (ja) * | 1990-01-31 | 1999-07-19 | ヘキスト合成株式会社 | 安定な常温架橋型エマルジョンおよびその製造方法 |
-
1994
- 1994-12-22 BR BR9408477A patent/BR9408477A/pt not_active Application Discontinuation
- 1994-12-22 CN CN94194880A patent/CN1150810A/zh active Pending
- 1994-12-22 WO PCT/IB1995/000016 patent/WO1995017443A1/en active IP Right Grant
- 1994-12-22 ES ES95904672T patent/ES2127507T3/es not_active Expired - Lifetime
- 1994-12-22 NZ NZ277875A patent/NZ277875A/en not_active IP Right Cessation
- 1994-12-22 EP EP95904672A patent/EP0736050B1/de not_active Expired - Lifetime
- 1994-12-22 RU RU96115283A patent/RU2144045C1/ru not_active IP Right Cessation
- 1994-12-22 AU AU13262/95A patent/AU704705B2/en not_active Ceased
- 1994-12-22 AT AT95904672T patent/ATE171959T1/de not_active IP Right Cessation
- 1994-12-22 KR KR1019960703406A patent/KR100336216B1/ko not_active IP Right Cessation
- 1994-12-22 DE DE69413849T patent/DE69413849T2/de not_active Expired - Fee Related
- 1994-12-22 DK DK95904672T patent/DK0736050T3/da active
- 1994-12-22 JP JP51730295A patent/JP3335359B2/ja not_active Expired - Fee Related
- 1994-12-22 CA CA002179637A patent/CA2179637A1/en not_active Abandoned
-
1996
- 1996-06-17 US US08/664,761 patent/US5705561A/en not_active Expired - Fee Related
- 1996-06-20 FI FI962600A patent/FI113660B/fi not_active IP Right Cessation
- 1996-06-20 NO NO19962639A patent/NO315946B1/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ATE171959T1 (de) | 1998-10-15 |
| CN1150810A (zh) | 1997-05-28 |
| BR9408477A (pt) | 1997-03-04 |
| FI113660B (fi) | 2004-05-31 |
| NO962639L (no) | 1996-07-30 |
| US5705561A (en) | 1998-01-06 |
| WO1995017443A1 (en) | 1995-06-29 |
| DE69413849D1 (de) | 1998-11-12 |
| FI962600A0 (fi) | 1996-06-20 |
| DK0736050T3 (da) | 1999-06-21 |
| JPH09511264A (ja) | 1997-11-11 |
| JP3335359B2 (ja) | 2002-10-15 |
| NZ277875A (en) | 1998-03-25 |
| FI962600A (fi) | 1996-08-20 |
| DE69413849T2 (de) | 1999-04-29 |
| AU1326295A (en) | 1995-07-10 |
| NO962639D0 (no) | 1996-06-20 |
| AU704705B2 (en) | 1999-04-29 |
| EP0736050B1 (de) | 1998-10-07 |
| EP0736050A1 (de) | 1996-10-09 |
| ES2127507T3 (es) | 1999-04-16 |
| RU2144045C1 (ru) | 2000-01-10 |
| KR100336216B1 (ko) | 2002-10-18 |
| CA2179637A1 (en) | 1995-06-29 |
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